US3560140A - Method of treating textile materials with liquid ammonia - Google Patents
Method of treating textile materials with liquid ammonia Download PDFInfo
- Publication number
- US3560140A US3560140A US686729A US3560140DA US3560140A US 3560140 A US3560140 A US 3560140A US 686729 A US686729 A US 686729A US 3560140D A US3560140D A US 3560140DA US 3560140 A US3560140 A US 3560140A
- Authority
- US
- United States
- Prior art keywords
- ammonia
- liquid ammonia
- textile materials
- treatment
- treating textile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
- D06M11/61—Liquid ammonia
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B7/00—Mercerising, e.g. lustring by mercerising
- D06B7/08—Mercerising, e.g. lustring by mercerising of fabrics of indefinite length
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Definitions
- the subject of this invention is a method of treating textile materials of a cellulosic nature.
- One of the best known methods of treating textile materials of a cellulosic nature to increase the strength and improve the lustre is the method known as mercerizing.
- the textile materials are normally treated in solutions of certain caustic alkalies, sometimes with application of a slight degree of tension during the process.
- caustic alkalies There are several disadvantages associated with the performance on any process which uses caustic alkalies, for example, immediately after the treatment the fibre must be washed very thoroughly otherwise it becomes detrimentally affected.
- liquid ammonia to treat textile materials since liquid ammonia does increase the lustre Without detrimentally affecting the material and can be comparatively easily removed from the material.
- the previous proposal for using liquid ammonia required only that the textile material should be immersed in the liquid ammonia for a few minutes, after which it is taken out of the ammonia and the ammonia removed from it.
- the lustre of the material is enhanced by the treatment the strength of the material is little affected.
- a process of treating textile materials of cellulosic nature consists in first treating the material with liquid ammonia, then subjecting the material to an ammonia-removing treatment and at the same time subjecting the material to a stretching action causing an elongation in the material of between 10% and 30% as measured against the length of the material immediately following the ammonia treatment.
- the ammonia may be pure liquid ammonia.
- the ammonia-removing treatment may be a treatment with a hot fluid.
- the hot fluid may be an aqueous fluid such as water or steam.
- the ammoniaremoving treatment may consist in bringing the material into a hot zone, e.g. that provided by a heating device such as a hot plate or an oven.
- the material may be subjected to infra red radiation.
- the ammoniaremoving treatment may consist of generating heat within the material e.g. by the use of a dielectric heating device or an induction heating device operating at high or radio frequency.
- the process according to the invention produces an increase in the tensile strength of the textile material which in the case of sewing thread may be as much as 40% and in some cases considerably higher and also improves the lustre.
- the increase in tensile strength produced by the process according to the invention is far greater than that produced by any previously known process or treatment.
- the subjection of the material to the previously unknown large degree of stretch stated during the ammonia-removing treatment is an essential part of the process according to the invention and produces the quite unexpected result of the large increase in tensile strength. Extensibility of the material is also reduced and this is a desirable feature as it reduces the tendency to puckering in any fabrics sewn with thread treated by the process.
- the degree of extensibility and the percentage increase of strength can be adjusted by altering the stretch applied within the range stated.
- a process of treating cellulosic textile materials comprising contacting the material with liquid ammonia, then removing ammonia from the material and at the same time stretching the material causing an elongation in the material of between 10% and 30% as measured against the length of the material immediately following the ammonia treatment.
- ammonia-removing treatment is a treatment with a hot fluid.
- ammonia-removing treatment consists in bringing the material into a hot zone.
- ammonia-removing treatment consists in subjecting the material to infra red radiation.
- ammonia-removing treatment consists in generating heat within the material.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatment Of Fiber Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB53960/66A GB1136417A (en) | 1966-12-02 | 1966-12-02 | Method of treating cellulosic textile materials |
Publications (1)
Publication Number | Publication Date |
---|---|
US3560140A true US3560140A (en) | 1971-02-02 |
Family
ID=10469531
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US686729A Expired - Lifetime US3560140A (en) | 1966-12-02 | 1967-11-29 | Method of treating textile materials with liquid ammonia |
Country Status (12)
Country | Link |
---|---|
US (1) | US3560140A (de) |
AT (1) | AT288311B (de) |
BE (1) | BE707390A (de) |
CH (2) | CH498235A (de) |
DE (1) | DE1610928A1 (de) |
DK (1) | DK121363B (de) |
ES (1) | ES347862A1 (de) |
FR (1) | FR1546099A (de) |
GB (1) | GB1136417A (de) |
NL (2) | NL6716398A (de) |
NO (1) | NO127357B (de) |
SE (1) | SE358912B (de) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3767359A (en) * | 1971-05-07 | 1973-10-23 | Us Agriculture | Process for the liquid ammonia treatment of yarns |
US3849067A (en) * | 1971-05-07 | 1974-11-19 | Us Agriculture | Process for the mercerization of cotton fabrics with liquid ammonia and ammonia/amine solutions |
DE2523433A1 (de) * | 1974-05-28 | 1975-12-11 | Opi Cryochimie | Verfahren zur behandlung von ganz oder teilweise aus cellulosefasern bestehenden materialien mit fluessigem ammoniak |
US4199319A (en) * | 1978-05-24 | 1980-04-22 | Ivanovsky Nauchno-Issledovatelsky Institut Khlopchatobumazhnoi Promvshlennosti | Method for treatment of cotton yarn |
US4295847A (en) * | 1980-01-25 | 1981-10-20 | Basf Aktiengesellschaft | Finishing process for textiles |
US4475917A (en) * | 1981-09-24 | 1984-10-09 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for modifying regenerated cellulose fiber |
EP1057919A2 (de) * | 1999-05-31 | 2000-12-06 | Nisshinbo Industries Inc. | Vorrichtung und Verfahren zur Nassbehandlung mit Ammoniak von Garnsträhnen |
CN116924472A (zh) * | 2023-09-14 | 2023-10-24 | 崇义章源钨业股份有限公司 | 一种含钨磷酸铵镁渣综合利用的方法 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4189847A (en) * | 1977-12-15 | 1980-02-26 | Cluett, Peabody & Co., Inc. | Process and apparatus for removal of ammonia in a liquid ammonia fabric treating system |
US4871370A (en) * | 1987-06-18 | 1989-10-03 | The United States Of America As Represented By The Secretary Of The Agriculture | Stable crystalline cellulose III polymorphs |
DE4312219C2 (de) * | 1993-04-14 | 2002-05-08 | Thueringisches Inst Textil | Verfahren zur Reduzierung der Fibrillierbarkeit von lösungsgesponnenen Cellulosefasern |
-
0
- NL NL136750D patent/NL136750C/xx active
-
1966
- 1966-12-02 GB GB53960/66A patent/GB1136417A/en not_active Expired
-
1967
- 1967-11-29 US US686729A patent/US3560140A/en not_active Expired - Lifetime
- 1967-11-29 FR FR130149A patent/FR1546099A/fr not_active Expired
- 1967-12-01 NL NL6716398A patent/NL6716398A/xx unknown
- 1967-12-01 CH CH1693767A patent/CH498235A/fr not_active IP Right Cessation
- 1967-12-01 BE BE707390D patent/BE707390A/xx not_active IP Right Cessation
- 1967-12-01 SE SE16566/67A patent/SE358912B/xx unknown
- 1967-12-01 DE DE19671610928 patent/DE1610928A1/de active Granted
- 1967-12-01 DK DK605167AA patent/DK121363B/da unknown
- 1967-12-01 CH CH1693767D patent/CH1693767A4/xx unknown
- 1967-12-01 NO NO00170784A patent/NO127357B/no unknown
- 1967-12-01 ES ES347862A patent/ES347862A1/es not_active Expired
- 1967-12-01 AT AT1090167A patent/AT288311B/de not_active IP Right Cessation
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3767359A (en) * | 1971-05-07 | 1973-10-23 | Us Agriculture | Process for the liquid ammonia treatment of yarns |
US3849067A (en) * | 1971-05-07 | 1974-11-19 | Us Agriculture | Process for the mercerization of cotton fabrics with liquid ammonia and ammonia/amine solutions |
DE2523433A1 (de) * | 1974-05-28 | 1975-12-11 | Opi Cryochimie | Verfahren zur behandlung von ganz oder teilweise aus cellulosefasern bestehenden materialien mit fluessigem ammoniak |
US4213761A (en) * | 1974-05-28 | 1980-07-22 | Dalle Jean Paul | Process for treating cellulosic materials with liquid ammonia |
US4199319A (en) * | 1978-05-24 | 1980-04-22 | Ivanovsky Nauchno-Issledovatelsky Institut Khlopchatobumazhnoi Promvshlennosti | Method for treatment of cotton yarn |
US4295847A (en) * | 1980-01-25 | 1981-10-20 | Basf Aktiengesellschaft | Finishing process for textiles |
US4475917A (en) * | 1981-09-24 | 1984-10-09 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for modifying regenerated cellulose fiber |
EP1057919A2 (de) * | 1999-05-31 | 2000-12-06 | Nisshinbo Industries Inc. | Vorrichtung und Verfahren zur Nassbehandlung mit Ammoniak von Garnsträhnen |
EP1057919A3 (de) * | 1999-05-31 | 2001-10-10 | Nisshinbo Industries Inc. | Vorrichtung und Verfahren zur Nassbehandlung mit Ammoniak von Garnsträhnen |
CN116924472A (zh) * | 2023-09-14 | 2023-10-24 | 崇义章源钨业股份有限公司 | 一种含钨磷酸铵镁渣综合利用的方法 |
Also Published As
Publication number | Publication date |
---|---|
CH498235A (fr) | 1970-05-29 |
GB1136417A (en) | 1968-12-11 |
NO127357B (de) | 1973-06-12 |
BE707390A (de) | 1968-04-16 |
DK121363B (da) | 1971-10-11 |
CH1693767A4 (de) | 1970-05-29 |
NL136750C (de) | |
ES347862A1 (es) | 1969-02-16 |
SE358912B (de) | 1973-08-13 |
FR1546099A (fr) | 1968-11-15 |
AT288311B (de) | 1971-02-25 |
NL6716398A (de) | 1968-06-04 |
DE1610928A1 (de) | 1970-07-16 |
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