US3550556A - Development apparatus - Google Patents
Development apparatus Download PDFInfo
- Publication number
- US3550556A US3550556A US697083A US3550556DA US3550556A US 3550556 A US3550556 A US 3550556A US 697083 A US697083 A US 697083A US 3550556D A US3550556D A US 3550556DA US 3550556 A US3550556 A US 3550556A
- Authority
- US
- United States
- Prior art keywords
- developer
- drum
- development
- flow
- auger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/06—Apparatus for electrographic processes using a charge pattern for developing
- G03G15/08—Apparatus for electrographic processes using a charge pattern for developing using a solid developer, e.g. powder developer
- G03G15/082—Apparatus for electrographic processes using a charge pattern for developing using a solid developer, e.g. powder developer for immersion
Definitions
- a development area is defined by a horizontally disposed drum bearing an electrostatic latent image and rotating in close proximity to a plate element generally concentric therewith and located on the upwardly moving side thereof.
- Separate auger means located at the entrance and exit of said area comprise means to circulate developer material therethrough.
- the entrance is located at the bottomside of the upwardly directed development area.
- a plate comprising a conductive backing upon which is placed a photoconductive insulating material, is charged uniformly and the photoconductive surface then exposed to a light image of an original object to be reproduced.
- the photoconductive coating is caused to become conductive under the influence of the light image so as to selectively dissipate the electrostatic charge found thereon to produce what is known as a latent electrostatic image.
- the development of the latent image is generally effected by electrostatically attracting a pigmented resin to the image areas on the plate. The amount of charge found in the image areas determines the amount of resin material attracted thereto.
- the amount of charge can be said to be proportional to image density and therefor areas of small charge concentration become areas of low toner density while the areas of greater charge concentration become proportionally more dense.
- a permanent record of the original object is obtained by transferring the developed image to a final support material and fixing the developed image thereto.
- a wide variety of pigmented resins have been developed for the purpose of developing a latent electrostatic image, these resins being commonly referred to as"toners.”
- the toner material is generally transported to the image areas by means of a relatively coarser material known as carrier, the carrier being adapted to support a quantity of toner upon its surface.
- the two components that is, the toner and carrier, are selected so that the materials interact electrostatically when placed in close rubbing contact to cause a triboelectric attraction therebetween.
- This two-component material is known in the xerographic art as developer material and this term is used herein to denote a two-component developer comprising carrier and toner material.
- toner is dislodged from the carrier material and attracted to the image areas on the photoconductiveplate.
- the cascade system has proven to be space consuming, The need for bulky conveyors or the like add greatly to the size of the xerographic reproducing apparatus'Unwanted powder clouds also result due to the relatively violent cascade action which, in turn, deposits unwanted toner material in background areas. Furthermore, dropping or cascading the developer material on the plate surface causes plate abrasions resulting in a relatively high rate of plate failures. A high rate of developer material failure due to bead fracture is also noted in the cascade system.
- the basic flow-contact system disclosed by Gundlach overcomes some of the previously mentioned disadvantages found in the prior art, the flow-contact system also has certain inherent disadvantages.
- the flow-contact system is basically a slow system in that a relatively small volume of material is moved through the system during each developing cycle. This low volumetric flow rate, in turn, results in a slow rate of developer mixing and triboelectrification and, therefore, the basic system does not lend itself for use in high-speed automatic machines. Furthermore, a relatively long response time after startup is needed in order to bring the system up to optimum operating conditions.
- Carrier material sticking to the photoconductive plate surface is another problem associated with the basic flow-contact system.
- a triboelectric relationship much like that found between toner and carrier, exists between the photoconductive surface and the carrier material.
- the carrier material upon becoming toner starved exhibits a charge relationship with the plate of a polarity and magnitude such that the carrier material is electrostatically attracted to the plate surface in the nonimage areas.
- the bond created, although weak, is sufficient to cause the carrier material to be pulled out of the relatively gentle developer flow pattern by the moving plate surface.
- This carrier, sticking to the moving plate is capable of being transported to subsequent processing stations where it can cause damage.
- a space charge build up on the carrier material has also been found to occur in the basic flow-contact developing system. It is found that a preponderence of the individual carrier beads are electrostatically isolated from the neutralizing effect of the grounded housing simply by other carrier beads which surround it. Although electrically-isolated, in a sense, the carrier material nevertheless continues to electrostatically build up an excessive charge about its surface which is confined to an infinitely small area or space around the bead. This space charge in effect monopolizes the region around the individual carrier beads and has a deleterious effect upon the triboelectric balance of the system.
- Another object of this invention is to improve flow-contact development apparatus.
- a further object of this invention is to eliminate space charge buildups in a flow-contact development system.
- Yet another object of this invention is to increase developer availability in a flow-contact development apparatus.
- Still another object of this invention is to improve developer distribution and mixing throughout a flow-contact development apparatus.
- Another object of this invention is to reduce carrier bead stickage in a xerographic development apparatus and, in particular, in a flow-contact type development apparatus.
- Yet another object of this invention is to provide aflowcontact development apparatus adapted to continually produce a uniform quality of development adaptable for use in an automatic xerographic machine.
- a further object of this invention is to eliminate plate abrasion and carrier bead failure in a xerographic development apparatus.
- a developer apparatus having a housing with an opening provided therein through which a xerographic plate can be moved therethrough, said housing being adapted to hold a quantity of developer material therein such that a plate moving through said housing is brought into contact with the developer and causes the developer to flow in contact with the plate in an uphill direction through a development zone, a delivery auger positioned at the start of the development zone, a return auger positioned at the end of the development zone, and means by which the delivery and return augers communicate to supply a continuous flow of developer through the development apparatus.
- FIG. 1 is an isometric view of a developer housing and a xerographic drum embodying the present invention which is suitable for use in an automatic xerographic machine and having portions broken away to show the internal construction of the apparatus;
- FIG. 2 illustrates schematically a preferred embodiment of the development apparatus of the instant invention shown adapted for continuous use in an automatic xerographic machine
- FIG. 3 is a sectional view of the development apparatus taken along lines 33 of FIG. 2 with the xerographic drum shown invisible;
- FIG. 4 is an illustration of the basic flow-contact development system as disclosed in the prior art
- a drum I is rotatably mounted so as to move in the direction indicated through a clamshell-shaped housing 13.
- the housing contains sufficient developer material so that the drum surface eontinually moves in contact with the developer material as it moves through the housing.
- the frictional forces established between the moving drum surface and the developer material cause a thin layer of developer material adjacent to the drum surface to move in an uphill direction at approximately drum speed.
- the upward movement of developer material creates a void at the bottom of the housing which is filled as the entire back layer of developer moving down more or less as a unit. A flow of developer material is thus established within the housing.
- the path followed by the uphill flow of developer material as it moves in contact with the drum surface describes the active development zone.
- Theoretically, properly charged and toned developer material is delivered to the start of the active development zone from the supply of developer material found on the backside of the system.
- the developer material develops a latent image on the drum as it flows along in contact with the drum through this active development zone.
- toner is electrostatically attracted from the carrier material to the more highly charged image areas. Because of the relatively gentle action of the flow established within the housing, little or no toner is mechanically dislodged from the carrier material.
- the developer material continues to move along in contact with the moving drum surface until the frictional forces holding it to the drum are overcome, as for example by the drum moving out of contact with the developer material.
- the relatively deplete developer material returns to the backside of the system where it is replenished as it moves down to fill the void left by the continuous flow of upwardly moving material.
- the flow rate in the basic flow-contact development apparatus is not limited by the drum-developer zone but rather by the time required to return developer material to the active development zone through the backside of the system. Because this is a closed system, the volume rate of flow through the active development zone must be equal to the volume rate of flow found on the backside ofthe system. Tests have shown that a flow rate 8l0 times greater than that found in the basic system, (shown in FIG. 4) can be supported by the forces acting at the drum-developer interface. From this discussion, it should be clear that the flow rate in the basic flow-contact system is limited by the backside flow rate and the backside flow rate is, in turn, restricted by the return geometry. Ideally, the backside of the developer system should have the steepest possible return geometry in order to provide the most rapid flow rate possible.
- the angle of repose of the developer material acts to limit the return geometry of the system.
- the angle of repose is the maximum angle with the horizontal at which a quantity of loose particulate material, such as developer material, will retain its natural position before sliding.
- the angle of repose of the developer in the clamshell-shaped housing 12 precludes the developer from contacting the drum surface for a considerable distance as the drum rotates through the housing.
- drum contact cannot be made with the developer material before the drum has rotated through about 45of are from the vertical.
- the angle of repose of the material severely restricts the return geometry of the system and thus limits the rate of flow that can be maintained in a basic flow-contact apparatus.
- FIGS. 1, 2 and 3 The apparatus of the present invention is shown in FIGS. 1, 2 and 3. Although the instant invention is well adapted for use in any automatic xerographic reproduction apparatus, it is shown, for illustrative purposes, herein embodied in a drumtype xerographic apparatus. As shown in FIG. 2, a drum I0 is mounted on shaft 11 and the shaft adapted to be supported in the side frames of an automatic xerographic machine (not shown). The major xerographic processing components are mounted around the drum periphery so that they are able to act thereon as the drum continually rotates through the various stations.
- a charging station A at which a uniform electrostatic charge is deposited on the photoconductive drum surface
- a development station C at which a xerographic developing material, including toner particles having an electrostatic charge opposite to that of the electrostatic image, are placed in contact with the moving drum surface whereby the toner particles are caused to adhere to the electrostatic latent image found thereon;
- a transfer station D where the developed electrostatic image is transferred from the plate surface to a final support material
- a drum' cleaning and discharge station E. at which the plate surface is brushed to remove residual toner particles remaining thereon after image transfer and at which time the plate surface is exposed to a relatively intense light source to effect substantially complete discharge of any residual electrostatic charge remaining thereon.
- the apparatus of the present invention comprises a housing having an opening in the upper portion to receive, in moving relation therein, a rotatable xerographic drum 10.
- a section of the lower portion of the housing is formed into an arcuate-shaped shell or plate, generally designated 21, which is arranged to be positioned adjacent to, and running transverse along, the length of the drum surface.
- an opening, or gap, 22 is formed when the arcuate shell or plate and the drum surface are positioned in operative relation.
- opening 21 is the zone of active development, the operation of which will be explained in further detail below.
- the remaining section of the lower housing is shaped to form two elongated troughs or-sumps which extend longitudinally along the length of the drum surface.
- 'A supply trough 23 is located at the start of the active development zone, that is, at the upstream entrance to the active zone in regard to the direction of drum travel and a return trough 24 similarly positioned at the opposite end or downstream exit of the active development zone. It should be noted that both sump areas are arranged to communicate with the active development zone along the length of the drum surface through means of openings 29 and 30 which are provided.
- end plates 31 and 32 are closed at both ends by means of end plates 31 and 32, respectively.
- the end plates are provided with end seals 47 to prevent developer material from escaping from the developer housing as well as effectively preventing extraneous matter, such as dirt or grim which could mar the drum surface, from entering the system.
- end seals are utilized in this embodiment, it should be clear that any type of seal, as for example radial seals, could be employed to effectively isolate the developing zone.
- the housing is extended to form an inclined return chute 40.
- the return chute is closed at the extended or extreme end by means of plate 42.
- the other end of the inclinedreturn chute is closed by means of housing end plate 31 so as to form a reservoirlike area being capable of holding a quantity of developer material.
- End plate 31 has two circular apertures 43 and 44 therein by which supply trough 23 and return trough 24, respectively, communicate with the inclined return chute 40.
- the bearing blocks are, in turn, mounted in plates 32 and 42.
- the delivery auger is arranged so that when it is rotated in the direction indicated developer material is transported from the lower end of the inclined chute through aperture 43 into the supply trough.
- the shaft portion of auger 25 extends beyond main housing 20 and has securely affixed thereto drive sprocket 48 and the drive sprocket, in turn, is driven by any suitable drive means, as for example motor means 50 (FIG. 2).
- the delivery auger is tapered in relation to the preselected rotational speed at which it is driven so that in operation developer material delivered from inclined chute 40 is evenly distributed along the length of the supply sump.
- a kicker flight 37 (FIG. 3), mounted on the far end of the supply sump area, is employed to prevent developer material from building up against end plate 32.
- return auger 26 is rotatably mounted in bearing blocks 33 positioned in plates 32 and 42. Again, the shaft portion of return auger 26 extends beyond the main developer housing and has affixed thereto a drive sprocket 49.
- the drive sprocket is driven by any suitable drive means, as
- motor means 51 for example motor means 51, (FIG. 2) so as to rotate the return auger in the direction indicated in FIG. 2 to empty developer material in the return trough into the return chute.
- the apparatus of the present invention is first charged with sufficient developer material to sustain continu' ous operation and then the drum and the supply and return augers brought to operating speeds.
- the tapered delivery auger is caused to rotate in the direction indicated so that the helical feed threads thereon deliver a continuous supply of developer mixture to the supply trough 23.
- developer material is circulated evenly throughout the supply trough due to the mixing action of the tapered helical feed threads.
- Sidewall 46 (FIG. 2) of trough 23, that is. the sidewall opposite to the entrance to the active development zone, is extended in a vertical direction enabling the trough to support developer at a height whereby the granular developer material will slide into opening 29 when the angle of repose of the material is exceeded.
- the sliding action of the developer material at the entranceto the active development zone exerts a horizontal pressure at this point. This force insures that a rapid, continuous, trouble-free, flow of material moves from the trough 23 into the entrance of the active development zone.
- the developer material so delivered into the active development zone fills the entrance area 29 allowing the rotating drum 10 to contact and carry along the developer material.
- the developer material flows through the active development zone under the action of the rotating drum surface and then passes through opening 30 into return trough 24.
- Return auger 26, rotating in the direction indicated moves the mass or body of developer mixture laterally in the trough through aperture 44 in end plate 31 into inclined chute 40.
- the developer material falls to the bottom of the chute area where it once again can be acted upon by tapered supply auger 25.
- Additional developer material canbe, from time to time, added to the system through the open top of the inclined chute to replenish the developer material deposited on the photoconductive insulating material passing through the developing apparatus.
- any of a number of known devices for automatically feeding developer material which are known in the art may be provided.
- the apparatus of the present invention provides a closed flow system or loop utilizing the highly efficient flow-contact mechanism and in which the flow found in the backside or return portion of the system is controllable. That is, the flow of material through the system is not restricted by the system's return geometry. In fact, the flow through the system can be maintained at any desired rate by controlling the amount of material delivered by the delivery auger.
- the delivery auger and the return auger are preselected such that both are capable of moving approximately the same amount of material in a linear direction per revolution.
- the return auger is adapted to rotate at a slightly high speed in the delivery auger The system therefore does not have to be compensated for slight changes in the flow rate through the active development zone. Slight changes in the flow rate through the active development zone occur with changes in humidity or when developer of different materials are employed.
- the delivery auger is insensitive to these changes and therefore continues to deliver the same quantity of material to the start of the active development zone. By rotating the return auger at a higher rate than the delivery auger, increases in the flow rate will not materially effect the systems performance. In practice, it has been found that a 1.4 to 1 ratio between delivery and return auger speeds is satisfactory to attain the desired results.
- the apparatus of the present invention is not severely restricted onthe positioning of the augers and associated supply and return troughs.
- the return trough must be at a higher elevation than the supply trough.
- a wide latitude as to the length and positioning of the active development zone is afforded by the present apparatus so that it is readily adaptable for use in a wide variety of machine environments.
- the active development zone can be lengthened or shortened so as to optimize development in machines operating at varying speeds or having different size drums.
- the dual auger arrangement of the present invention is not restricted to use in conjunction with a cylindrical drum but can be readily adapted to be used with a wide variety of endless belt photoconductor configurations as well as with moving flat plate photoconductors.
- the dual auger arrangement isolates the active development zone from the backside or return portion of the system thus giving the apparatus greater flexibility than afforded by the basic flow-contact system.
- the arcuate plate 21 which forms the bottom wall of the active development zone is positioned in close proximity to the moving photoconductive surface and is capable of acting much in the same manner as a biased electrode in conventional development systems when a DC potential is applied thereto. As shown in FIG. 2, the arcuate plate is electrically isolated from housing and is biased with a sufficient DC potential to suppress background development and also to further enhance the solid area coverage capability of the development apparatus.
- the present system is capable of delivering properly mixed and charged developer material to the entrance of the active development zone regardless of the flow rate being maintained in the system.
- the system is not dependent on the drum-developer interface flow for developer mixing but rather upon the agitation produced by the continuously rotating augers.
- Delivery auger 25 which contacts an extremely high percentage of particulate developer material prior to the materials delivery to the active development zone, is placed at a ground potential to bleed off any space charge build up which might occur about the carrier material.
- the return auger is used to suppress bead stickage.
- This auger is electrically isolated from the developer housing and a DC bias placed thereon. The auger is positioned in close proximity to the drum surface and biased with a charge having a polarity and magnitude sufficient to attract carrier beads triboelectrically adhering to the drum surface.
- Apparatus for developing an electrostatic latent image including:
- a photoconductive surface being adapted to support an electrostatic latent image thereon:
- a plate positioned adjacent to the upwardly moving portion of said photoconductive surface and extending transverse to the direction of surface movement to form an opening therebetween. the opening being at least equal to the image area on said surface;
- a delivery auger positioned transverse to the direction of surface travel at the lower entrance to the opening and being arranged to deliver a continuous supply of particulate developer material to said opening;
- a return auger positioned transverse to the direction of surface travel at the uphill exit to said opening and being arranged to continuously remove the developer material flowing from the exit of the opening;
- the apparatus of claim 1 having further means to replenish developer material as the developer material returns to the entrance of the opening.
- Apparatus to develop an electrostatic latent image on a photoconductive surface including:
- a xerographic drum adapted to support a latent electrostatic image thereon
- a housing having an opening to receive a portion of said rotating drum therein;
- said housing being adapted to hold a quantity of developer material in contact with the surface of said drum along a zone of active development so that a flow of developer moves in contact with the drum surface as the drum rotates through said housing;
- auger means positioned at the entrance of the active development zone adjacent to the drum surface and arranged to convey a continuous supply of developer material transverse to the direction of rotation of said drum;
- second auger means positioned at the exit of the active development zone adjacent to said drum surface and arranged to convey a continuous supply of developer material transverse to the drum surface;
- the apparatus of claim 9 having further means to replenish developer material used to develop an electrostatic latent image.
- the apparatus of claim 11 having a biasing electrode positioned in close proximity to the rotating drum surface in the zone of active development.
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Dry Development In Electrophotography (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US69708368A | 1968-01-11 | 1968-01-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3550556A true US3550556A (en) | 1970-12-29 |
Family
ID=24799714
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US697083A Expired - Lifetime US3550556A (en) | 1968-01-11 | 1968-01-11 | Development apparatus |
Country Status (9)
Country | Link |
---|---|
US (1) | US3550556A (xx) |
JP (1) | JPS4835011B1 (xx) |
BE (1) | BE726571A (xx) |
CH (1) | CH498431A (xx) |
DE (1) | DE1900803A1 (xx) |
FR (1) | FR1604314A (xx) |
GB (1) | GB1252494A (xx) |
NL (1) | NL6900329A (xx) |
SE (1) | SE351059B (xx) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3739749A (en) * | 1969-10-20 | 1973-06-19 | Minnesota Mining & Mfg | Magnetic powder applicator |
US3865080A (en) * | 1973-01-17 | 1975-02-11 | Xerox Corp | Toner pickoff apparatus |
US3950092A (en) * | 1974-09-20 | 1976-04-13 | Xerox Corporation | Impeller member for use in transporting particulate material in a reproducing machine |
US4082061A (en) * | 1977-03-14 | 1978-04-04 | Xerox Corporation | Multi-color development system |
DE19546248A1 (de) * | 1995-12-12 | 1997-06-19 | Heidelberger Druckmasch Ag | Verfahren und Vorrichtung zum Entwickeln eines elektrostatischen latenten Bildes |
US5832826A (en) * | 1995-12-20 | 1998-11-10 | Heidelberger Druckmaschinen Ag | Device and method for acting upon sheets in a sheet delivery system |
US6510305B1 (en) * | 2000-11-28 | 2003-01-21 | Xerox Corporation | Toner transport apparatus using flexible augers |
US20070098452A1 (en) * | 2005-11-02 | 2007-05-03 | Eastman Kodak Company | Electrographic distributed replenishment apparatus and method |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50155707U (xx) * | 1974-06-10 | 1975-12-24 | ||
JPS52103121A (en) * | 1976-02-24 | 1977-08-30 | Senkoo Kk | Freight truck |
US5457517A (en) * | 1993-12-02 | 1995-10-10 | Matsushita Electric Industrial Co., Ltd. | Image forming apparatus having a plurality of support surfaces |
EP0656571A1 (en) * | 1993-12-02 | 1995-06-07 | Matsushita Electric Industrial Co., Ltd. | A developing device and an image forming apparatus using the same |
US5526099A (en) * | 1993-12-02 | 1996-06-11 | Matsushita Electric Industrial Co., Ltd. | Developing device and an image forming apparatus using the same |
-
1968
- 1968-01-11 US US697083A patent/US3550556A/en not_active Expired - Lifetime
- 1968-12-30 FR FR1604314D patent/FR1604314A/fr not_active Expired
-
1969
- 1969-01-06 CH CH8169A patent/CH498431A/de not_active IP Right Cessation
- 1969-01-07 SE SE00119/69A patent/SE351059B/xx unknown
- 1969-01-07 BE BE726571D patent/BE726571A/xx unknown
- 1969-01-08 JP JP44001327A patent/JPS4835011B1/ja active Pending
- 1969-01-08 DE DE19691900803 patent/DE1900803A1/de active Pending
- 1969-01-09 GB GB1252494D patent/GB1252494A/en not_active Expired
- 1969-01-09 NL NL6900329A patent/NL6900329A/xx unknown
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3739749A (en) * | 1969-10-20 | 1973-06-19 | Minnesota Mining & Mfg | Magnetic powder applicator |
US3865080A (en) * | 1973-01-17 | 1975-02-11 | Xerox Corp | Toner pickoff apparatus |
US3950092A (en) * | 1974-09-20 | 1976-04-13 | Xerox Corporation | Impeller member for use in transporting particulate material in a reproducing machine |
US4082061A (en) * | 1977-03-14 | 1978-04-04 | Xerox Corporation | Multi-color development system |
DE19546248A1 (de) * | 1995-12-12 | 1997-06-19 | Heidelberger Druckmasch Ag | Verfahren und Vorrichtung zum Entwickeln eines elektrostatischen latenten Bildes |
US5832826A (en) * | 1995-12-20 | 1998-11-10 | Heidelberger Druckmaschinen Ag | Device and method for acting upon sheets in a sheet delivery system |
US6510305B1 (en) * | 2000-11-28 | 2003-01-21 | Xerox Corporation | Toner transport apparatus using flexible augers |
US20070098452A1 (en) * | 2005-11-02 | 2007-05-03 | Eastman Kodak Company | Electrographic distributed replenishment apparatus and method |
WO2007053763A1 (en) | 2005-11-02 | 2007-05-10 | Eastman Kodak Company | Developer conveying device and method |
US7561833B2 (en) | 2005-11-02 | 2009-07-14 | Eastman Kodak Company | Electrographic distributed replenishment apparatus and method |
US20090190961A1 (en) * | 2005-11-02 | 2009-07-30 | Stelter Eric C | Electrographic distributed replenishment apparatus and method |
US7672623B2 (en) | 2005-11-02 | 2010-03-02 | Eastman Kodak Company | Electrographic distributed replenishment apparatus and method |
Also Published As
Publication number | Publication date |
---|---|
FR1604314A (xx) | 1971-10-11 |
GB1252494A (xx) | 1971-11-03 |
BE726571A (xx) | 1969-07-07 |
SE351059B (xx) | 1972-11-13 |
CH498431A (de) | 1970-10-31 |
NL6900329A (xx) | 1969-07-15 |
DE1900803A1 (de) | 1969-08-07 |
JPS4835011B1 (xx) | 1973-10-25 |
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