Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
  • D06P1/30—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using sulfur dyes
  • D06P1/305—SO3H-groups containing dyes
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
  • C09B69/00—Dyes not provided for by a single group of this subclass
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
  • D06P1/30—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using sulfur dyes
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
  • Y10S8/916—Natural fiber dyeing
  • Y10S8/918—Cellulose textile

Definitions

• the present invention relates to a method for coloring textile fibers.
• the method of the present invention is particularly characterized in being a method for coloring textile fibers comprising the steps of applying an aqueous composition comprising water and dye having per dye molecule at least one pendant thiosulfate group selected from the group consisting of SSO Na, -SSO K and SSO NH to textile fibers selected from the group consisting of cotton, regenerated cellulose, polyamide and potlyacrylie; applying to the fibers an aqueous solution cornpnising Na S and Washing the fibers with Water.
• the unfixed dye Will be on the fiber and in the thiosulfate form, e.g. each dye molecule will have at least one pendant SSO Na, SSO K or SSO NH group per molecule of dye.
• sodium sulfide or sodium cyanide may be used for fixing azo, anthraquinone, vat, dioxazine and metal phthalocyanine dyes having thiosulfuric acid groups onto cellulosic fibers.
• Sodium sulfide presents a number of problems when used according to the above prior art method. For example, it must be used in combination with heat to effect fixation; or, when used at room temperature it must either be used in high concentrations or remain in contact with the dye for 10-60 minutes to effect fixation.
• Sodium sulfide affects unfavorably the softness and feel (hand) of cellulosic fibers and especially that of regenerated cellulose, and particularly so when used in combination with heat, or in high concentration, or when permitted to remain in contact with the cellulosics over a relatively long period of time.
• sodium sulfide is strongly alkaline and precipitates insolubles from water, especially from hard water, and these insolubles interfere with dyeing procedures and require additional soap for their removal in washing processes.
• Some azo dyes are particularly sensitive to sodium sulfide, in that the color value of the azo groups is destroyed and color yield is correspondingly lowered when sodium sulfide is used, and particularly so when the sodium sulfide is at high concentration, or in the presence of heat, and the longer the azo dye remains in contact with sodium sulfide the more color value is lost.
• azo dyes having pendant thiosulfate groups i.e. (1) those in which the thiosulfate group is attached directly to an aryl nucleus of the dye molecule, and (2) those in which a bridge member, such as an aliphatic or hydrocarbon radical which may be substituted and interrupted by hetero groups, is interposed between the thiosulfate group and an aryl nucleus of the dye.
• a bridge member such as an aliphatic or hydrocarbon radical which may be substituted and interrupted by hetero groups
• Sodium sulfide presents additional and special problems when used as a fixing agent for those azo dyes having a pendant thiosulfate group attached directly to an aryl nucleus of the dye molecule.
• the primary problem vis color yield.
• Na S is much less hazardous and toxic than sodium cyanide.
• fixation of the dyestuff may he achieved at room temperature, and at very low Na S concentration, and Without having the dye and Na S in contact for more than 1-30 seconds.
• the process of the present invention is particularly valuable for use with rnodern high speed dyeing equipment, such as continuous padding ranges.
• the fixation is achieved at a lower degree of alkalinity than with sodium sulfide, which results in a softer and improved hand of cellulosic fibers, as well as less precipitation of insolubles from water.
• azo dyes having a pendant thiosulfate group attached directly to an aryl group of the dye molecule may be fixed with about two-thirds less weight of Na S than Na s.
• fixation may be achieved at room temperature without any necessity for high Na S concentration or prolonged contact between the polysulfide and azo dyes results in less loss of color value of the sensitive azo groups and improved color yield, and in some cases in improved brightness of shade, in comparison with sodium sulfide.
• color yield is particularly noticeable in the dyeing of azo dyes having at least one pendant thiosulfate group attached directly to an aryl group of the dye molecule. With many of these dyes, color yield is 20%100% higher when Na S is used than when the optimum sodium sulfide concentration is used.
• the optimum concentration of Na S for fixing azo dyes having at least one pendant thiosulfate group attached directly to an aryl nucleus of the dyestufi and obtaining high color yield extends over a very much wider range than does sodium sulfide, and thus color yield is not adversely affected by slight variations in Na S concentration, as contrasted to sodium sulfide.
• standard fixing solutions of Na S may be utilized in textile finishing plants without the necessity for changing concentrations every time a difierent dye is utilized.
• better color yield can be obtained in dyeing mixtures of certain azo dyes with Na S than with Na s.
• the system is very economical as Na S costs less than Na s, and less Na S is required than Na S; and soap, time and heat are saved.
• the present process may be used in dyeing or printing textile fibers selected from the group consisting of cotton, regenerated cellulose, polyamide and polyacrylic.
• the textile fibers may be in any desired form, such as fabric, yarn, ball warps, non-woven fabric, raw stock, etc.
• dyes which may be fixed according to the method of the present invention include azo, sulfur, phthalocyanine, 'metal phthalocyanine, perylene, dioxazine, anthraquinone, vat and dibenzanthrone dyes, said dyes being further characterized in having at least one pendant thiosulfate group selected from the group consisting of SSO Na, SSO K and SSO NH per molecule of dye.
• the dye stuff may be applied to the fibers in any desired manner, such as by jig, pad, beck, printing roller, etc.
• the amount of dye employed will depend upon the depth of shade desired.
• the dye composition may optionally contain conventional additives, such as inorganic electrolytes to increase adsorption of the dye onto the fiber, leveling agents such as sodium alginate, penetrating assistants such as anionic and non-ionic surface active agents, alkalies, urea, thiourea, etc., and in the case of printing pastes conventional gums, thickeners, emulsifiers, etc.
• additives such as inorganic electrolytes to increase adsorption of the dye onto the fiber, leveling agents such as sodium alginate, penetrating assistants such as anionic and non-ionic surface active agents, alkalies, urea, thiourea, etc.
• the fibers may optionally be batched for a period of time at ambient temperature or in a closed chamber controlled for humidity and temperature, steamed or dried to facilitate penetration of the dyestuff into the fibers.
• the fibers may be taken directly from the dye application to the Na S solution.
• Na S refers to a sodium polysulfide or to mixtures of sodium polysulfides, e.g. to disodium disulfide, or disodium trisulfide, or disodium tetrasulfide, or to mixtures of any two or three of these polysulfides. In the case of mixtures, the 2-4 subscript of the S atom would not necessarily be a whole number.
• Sodium polysulfides are well known, and are prepared by adding flowers of sulfur to a hot aqueous solution of sodium sulfide.
• Sulfur is precipitated from highly concentratedstock solutions of sodium tetrasulfide on extended exposure to the air, and this may be prevented by adding 5% by weight of Carbitol t0 the concentrated stock solutions, which stock solutions may be used subsequently in preparing the fixing solutions.
• the fibers, having thereon the unfixed dyestulT in thiosulfate salt form, are then contacted with the aqueous Na S fixing solution, such as by immersing the fibers in the fixing solution.
• the fibers may be wet or dry at the time of contact with the fixing solution.
• the fixing solution comprises an aqueous solution of Na S
• the amount of Na S utilized is basedupon the amount of dye which is to be fixed; about 0.07-0.64 gm. Na S and preferably about 0.214 gm. Na S may be applied to the fibers for each gram of dye to be fixed.
• the fixing solution may also optionally comprise a simple water soluble inorganic electrolyte, such as NaCl, to deter those dyes which tend to bleed into the fixing solution from so doing. About 25-300 gm. NaCl per liter of fixing solution is suitable for this purpose.
• the Na S is applied as an aqueous solution to the fibers, and may be applied by the pad-nip method, spraying, immersing the fibers in the solution, or any other convenient method.
• a convenient and illustrative method is to pass the fibers having the unfixed dye thereon through a pad box containing about 1-10 gm. Na S per liter of fixing solution for each percent by weight of the dye upon the fibers, and squeezing the fibers between rubber coated pressure rollers to permit 60% Wet pick up of fixing solution based on fabric weight. Fixation of the dye is very rapid, and in many cases may be regarded as instantaneous. In most cases, fixation -will be complete when the dye and Na S have been in contact about 1-30 seconds.
• the fibers After contact with the Na S the fibers are washed with water, which may be at room temperature.
• the water serves to remove polysulfide salt residues and other water soluble residues from the fibers.
• the fibers may optionally be passed through air, steam or brine prior to washing.
• the fibers may be scoured and dried in conventional manner.
• Example 1 Onto mercerized cotton 'fabric weighing 112 gms. per square yard is padded a dye composition consisting of per liter of water at F.; the fabric is squeezed to ing of 6.05 gm. Na S and 200 gm. NaCl per liter at room temperature; the fabric is squeezed to permit 60% wet pick up based on fabric weight (whereby the fabric has thereon 0.214 gm. Na S for each gm. of dye.
• the fabric is pre-dried in open width with infra-red units to about moisture content and then dried to substantial dryness in open width on a housed tenter frame heated fabric is Washed with water at room temperature and 5 to 350 F.; the fabric is steamed for 2 minutes at 230 dried. F. in an air-free steamer; padded through a solution A bright yellow dyeing with excellent wash fastness consisting of 4.537 gm. of the polysulfide shown in colresults. umn 3 and 200 gm.
• the NH; or K salt of the above dye may be temperature; squeezed so as to have picked up the numsubstituted for the dye used in this example. 10 her of gm. shown in the fourth column of the polysulfide The color yield in the above dyeing is at least twice shown in the third column (calculated as dry solids) for as great as obtainable by using Na s as the fixing agent.
• each gm. of dye on the fibers passed through pad boxes E 2 6 equipped with exit nip rollers and containing water at Xamples room temperature for seconds, and then soaped, rinsed
• Example 47 Onto cotton fabric is printed a paste consisting of, by weight, 2.5%
• Example 4-8 Onto cotton fabric weighing 112 gm./sq. yd. is padded a dye composition consisting of 12.5 gm.
• the fabric is squeezed to 60% wet pick up so as to retain 0.0075 gm. dye, calculated as solids, per gm. of fabric.
• the fabric is immersed for 30 seconds in a solution consisting of 0.375 gm. Nags4 per liter of Water at a liquor to goods ratio of 10:1, rinsed with water at room temperature for 5 minutes, soaped, rinsed with Water and dried, resulting in a bright orange dyeing.
• Example 49 N-Q-SSOaNa is padded onto cotton fabric and squeezed so as to deposit 1.5 gm. dye/ 100 gm. cotton.
• the fabric is dried and padded through a solution consisting of 7.86 gm. Na s, and 200 gm. NaCl per liter of water at room temperature, squeezed to permit 60% wet pick up, rinsed with water, scoured and dried. A bright orange dyeing results.
• Example 50 Onto cotton corduroy fabric is padded a dye composition consisting of 10 gm. of the sodium salt of the dye resulting from condensing a mole of FESO2C1 L a 10.7 and 2.3 moles sodium S-4-aminophenylthiosulfate, 7 gm. of the sodium salt of Cl. Solubilized Sulphur Green 2 (C. I. No. 53572), and 15 gm.
• Example 51 An aqueous composition containing 25 gm.
• Example 52 This example is the same as Example 51 above, except that the amount of the Na S per liter is increased from 1.9 to 10 gm., and except that the amount of Na S picked up per gm. of dye is increased from 0.07 to 0.64 gm.
• a method for coloring textile fibers consisting essentially of the steps of applying an aqueous composition comprising Water and dye having per dye molecule at least one pendant thiosulfate group selected from the group consisting of SSO Na, SSO K and SSO NH to textile fibers selected from the group consisting of cotton and regenerated cellulose; applying to the fibers an aqueous solution comprising Na S so that about 0.07- 0.64 gm. Na S are applied to the fibers for each gram of dye on the fibers; and washing the fibers with water.
• a method for coloring textile fibers consisting essentially of the steps of applying to textile fibers selected from the group consisting of cotton and regenerated cellulose, an aqueous composition comprising water and dye, said dye being selected from the group consisting of azo, sulfur, phthalocyanine, metal phthalocyanine, perylene, dioxazine, anthraquinone, vat and dibenzanthrone dyes having per dye molecule at least one pendant thiosulfate group selected from the group consisting of SSO Na, SSO K and SSO NH applying to the fibers an aqueous solution comprising Na S so that about 0.07-0.64 grn. Na S are applied to the fibers for each gram of dye on the fibers; and washing the fibers with water.

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• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Coloring (AREA)
• Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Priority Applications (6)

Applications Claiming Priority (1)

Publications (1)

Family

ID=23826745

Family Applications (1)

Country Status (5)

Citations (3)

• 1965
  • 1965-05-28 US US459933A patent/US3419343A/en not_active Expired - Lifetime
• 1966
  • 1966-05-24 BE BE681524D patent/BE681524A/xx unknown
  • 1966-05-27 GB GB23969/66A patent/GB1146002A/en not_active Expired
  • 1966-05-27 ES ES0327227A patent/ES327227A1/es not_active Expired
  • 1966-05-28 DE DE19661619604 patent/DE1619604A1/de active Pending

Patent Citations (3)

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