US3418322A - Quinacridone dyestuffs - Google Patents
Quinacridone dyestuffs Download PDFInfo
- Publication number
- US3418322A US3418322A US370751A US37075164A US3418322A US 3418322 A US3418322 A US 3418322A US 370751 A US370751 A US 370751A US 37075164 A US37075164 A US 37075164A US 3418322 A US3418322 A US 3418322A
- Authority
- US
- United States
- Prior art keywords
- solution
- photoconductor
- water
- mixture
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 title description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 62
- 239000000975 dye Substances 0.000 claims description 21
- 239000000243 solution Substances 0.000 description 59
- 239000000203 mixture Substances 0.000 description 35
- -1 nitrogen containing compound Chemical class 0.000 description 35
- 238000002360 preparation method Methods 0.000 description 31
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 21
- 238000000034 method Methods 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- 238000003756 stirring Methods 0.000 description 15
- 239000007787 solid Substances 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
- 239000002253 acid Substances 0.000 description 13
- 230000033458 reproduction Effects 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000011541 reaction mixture Substances 0.000 description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000002585 base Substances 0.000 description 9
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000001043 yellow dye Substances 0.000 description 7
- XBNVWXKPFORCRI-UHFFFAOYSA-N 2h-naphtho[2,3-f]quinolin-1-one Chemical compound C1=CC=CC2=CC3=C4C(=O)CC=NC4=CC=C3C=C21 XBNVWXKPFORCRI-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 238000000151 deposition Methods 0.000 description 6
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 5
- 239000000908 ammonium hydroxide Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Natural products NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 4
- 239000000543 intermediate Substances 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229960000583 acetic acid Drugs 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- SDIOBNKHLKIWOP-UHFFFAOYSA-N 2,2-diethylpropane-1,3-diamine Chemical compound CCC(CC)(CN)CN SDIOBNKHLKIWOP-UHFFFAOYSA-N 0.000 description 2
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000004300 dark adaptation Effects 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000012456 homogeneous solution Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- CRRLDLPBQWRVGN-UHFFFAOYSA-N n-[2-methyl-4-[3-methyl-4-(3-oxobutanoylamino)phenyl]phenyl]-3-oxobutanamide Chemical compound C1=C(C)C(NC(=O)CC(=O)C)=CC=C1C1=CC=C(NC(=O)CC(C)=O)C(C)=C1 CRRLDLPBQWRVGN-UHFFFAOYSA-N 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229940076133 sodium carbonate monohydrate Drugs 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- OGNVQLDIPUXYDH-ZPKKHLQPSA-N (2R,3R,4S)-3-(2-methylpropanoylamino)-4-(4-phenyltriazol-1-yl)-2-[(1R,2R)-1,2,3-trihydroxypropyl]-3,4-dihydro-2H-pyran-6-carboxylic acid Chemical compound CC(C)C(=O)N[C@H]1[C@H]([C@H](O)[C@H](O)CO)OC(C(O)=O)=C[C@@H]1N1N=NC(C=2C=CC=CC=2)=C1 OGNVQLDIPUXYDH-ZPKKHLQPSA-N 0.000 description 1
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- KHUFHLFHOQVFGB-UHFFFAOYSA-N 1-aminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2N KHUFHLFHOQVFGB-UHFFFAOYSA-N 0.000 description 1
- MYMSJFSOOQERIO-UHFFFAOYSA-N 1-bromodecane Chemical compound CCCCCCCCCCBr MYMSJFSOOQERIO-UHFFFAOYSA-N 0.000 description 1
- NAZDVUBIEPVUKE-UHFFFAOYSA-N 2,5-dimethoxyaniline Chemical compound COC1=CC=C(OC)C(N)=C1 NAZDVUBIEPVUKE-UHFFFAOYSA-N 0.000 description 1
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
- PMYDPQQPEAYXKD-UHFFFAOYSA-N 3-hydroxy-n-naphthalen-2-ylnaphthalene-2-carboxamide Chemical compound C1=CC=CC2=CC(NC(=O)C3=CC4=CC=CC=C4C=C3O)=CC=C21 PMYDPQQPEAYXKD-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- GRDXCFKBQWDAJH-UHFFFAOYSA-N 4-acetamidobenzenesulfonyl chloride Chemical compound CC(=O)NC1=CC=C(S(Cl)(=O)=O)C=C1 GRDXCFKBQWDAJH-UHFFFAOYSA-N 0.000 description 1
- RNTNZRPCYDDMIA-UHFFFAOYSA-M 4478-76-6 Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC=C2C3=C1C(=O)C1=CC=CC=C1C3=CC(=O)N2C RNTNZRPCYDDMIA-UHFFFAOYSA-M 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- GKKZMYDNDDMXSE-UHFFFAOYSA-N Ethyl 3-oxo-3-phenylpropanoate Chemical compound CCOC(=O)CC(=O)C1=CC=CC=C1 GKKZMYDNDDMXSE-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 229920013620 Pliolite Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- SKZKKFZAGNVIMN-UHFFFAOYSA-N Salicilamide Chemical class NC(=O)C1=CC=CC=C1O SKZKKFZAGNVIMN-UHFFFAOYSA-N 0.000 description 1
- MZVQCMJNVPIDEA-UHFFFAOYSA-N [CH2]CN(CC)CC Chemical group [CH2]CN(CC)CC MZVQCMJNVPIDEA-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 238000003811 acetone extraction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- KSCQDDRPFHTIRL-UHFFFAOYSA-N auramine O Chemical compound [H+].[Cl-].C1=CC(N(C)C)=CC=C1C(=N)C1=CC=C(N(C)C)C=C1 KSCQDDRPFHTIRL-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
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- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- KQSBZNJFKWOQQK-UHFFFAOYSA-N hystazarin Natural products O=C1C2=CC=CC=C2C(=O)C2=C1C=C(O)C(O)=C2 KQSBZNJFKWOQQK-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- QZUPTXGVPYNUIT-UHFFFAOYSA-N isophthalamide Chemical compound NC(=O)C1=CC=CC(C(N)=O)=C1 QZUPTXGVPYNUIT-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229960000448 lactic acid Drugs 0.000 description 1
- 229940040102 levulinic acid Drugs 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- 239000012280 lithium aluminium hydride Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- KYCGURZGBKFEQB-UHFFFAOYSA-N n',n'-dibutylpropane-1,3-diamine Chemical compound CCCCN(CCCC)CCCN KYCGURZGBKFEQB-UHFFFAOYSA-N 0.000 description 1
- FPPYFDBIUGVMNA-UHFFFAOYSA-N n,n-diethyl-3-phenylpropan-1-amine Chemical compound CCN(CC)CCCC1=CC=CC=C1 FPPYFDBIUGVMNA-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- GVKCHTBDSMQENH-UHFFFAOYSA-L phloxine B Chemical compound [Na+].[Na+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 GVKCHTBDSMQENH-UHFFFAOYSA-L 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229940001593 sodium carbonate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- VVLFAAMTGMGYBS-UHFFFAOYSA-M sodium;4-[[4-(ethylamino)-3-methylphenyl]-(4-ethylimino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]-3-sulfobenzenesulfonate Chemical compound [Na+].C1=C(C)C(NCC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S(O)(=O)=O)=C1C=C(C)C(=NCC)C=C1 VVLFAAMTGMGYBS-UHFFFAOYSA-M 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- 238000001665 trituration Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- GFFQNEGBFFGLQG-UHFFFAOYSA-N vat yellow 2 Chemical compound S1C2=C3C(=O)C4=CC=C5N=C(C=6C=CC=CC=6)SC5=C4C(=O)C3=CC=C2N=C1C1=CC=CC=C1 GFFQNEGBFFGLQG-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/36—Dyes with acylated amino groups
- C09B1/42—Dyes with acylated amino groups the acyl groups being residues of an aromatic carboxylic acid
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B11/00—Diaryl- or thriarylmethane dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B11/00—Diaryl- or thriarylmethane dyes
- C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/0003—Monoazo dyes prepared by diazotising and coupling from diazotized anilines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
- C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
- C09B29/3604—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom
- C09B29/3647—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a five-membered ring with two nitrogen atoms as heteroatoms
- C09B29/3652—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a five-membered ring with two nitrogen atoms as heteroatoms containing a 1,2-diazoles or hydrogenated 1,2-diazoles
- C09B29/366—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only a nitrogen as heteroatom containing a five-membered ring with two nitrogen atoms as heteroatoms containing a 1,2-diazoles or hydrogenated 1,2-diazoles containing hydroxy-1,2-diazoles, e.g. pyrazolone
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
- C09B47/12—Obtaining compounds having alkyl radicals, or alkyl radicals substituted by hetero atoms, bound to the phthalocyanine skeleton
- C09B47/16—Obtaining compounds having alkyl radicals, or alkyl radicals substituted by hetero atoms, bound to the phthalocyanine skeleton having alkyl radicals substituted by nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
- C09B47/24—Obtaining compounds having —COOH or —SO3H radicals, or derivatives thereof, directly bound to the phthalocyanine radical
- C09B47/26—Amide radicals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B48/00—Quinacridones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B5/00—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
- C09B5/02—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings the heterocyclic ring being only condensed in peri position
- C09B5/14—Benz-azabenzanthrones (anthrapyridones)
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B5/00—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
- C09B5/24—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings the heterocyclic rings being only condensed with an anthraquinone nucleus in 1-2 or 2-3 position
- C09B5/32—1.3 azoles of the anthracene series
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B7/00—Indigoid dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B7/00—Indigoid dyes
- C09B7/10—Bis-thionapthene indigos
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G13/00—Electrographic processes using a charge pattern
- G03G13/01—Electrographic processes using a charge pattern for multicoloured copies
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G17/00—Electrographic processes using patterns other than charge patterns, e.g. an electric conductivity pattern; Processes involving a migration, e.g. photoelectrophoresis, photoelectrosolography; Processes involving a selective transfer, e.g. electrophoto-adhesive processes; Apparatus essentially involving a single such process
- G03G17/02—Electrographic processes using patterns other than charge patterns, e.g. an electric conductivity pattern; Processes involving a migration, e.g. photoelectrophoresis, photoelectrosolography; Processes involving a selective transfer, e.g. electrophoto-adhesive processes; Apparatus essentially involving a single such process with electrolytic development
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/08—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being inorganic
- G03G5/087—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being inorganic and being incorporated in an organic bonding material
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/09—Sensitisors or activators, e.g. dyestuffs
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/12—Recording members for multicolour processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S534/00—Organic compounds -- part of the class 532-570 series
- Y10S534/02—Azo compounds containing chains of eight or more carbon atoms not provided for elsewhere in this class
Definitions
- This invention relates to new and useful permanent reproductions and their method of preparation by selectively depositing a basic nitrogen containing compound on the surface of a photoconductor.
- An object of this invention is to disclose a method of selectively depositing basic nitrogen containing organic compounds on the surface of a photoconductor thereby producing reproductions in a fast and eicient manner.
- Another object of this invention is to disclose a process for preparing colored reproductions by electrophotography.
- Full colored reproductions are prepared by successively applying subtractive primary colors to the surface of the dye-sensitized photoconductor.
- the method of making colored reproductions from subtractive primaries is described in I. S. Friedmans A History of Color Photography, American Photographic Publishing Company, Boston, Mass. (1944).
- the tem-n dye-sensitized indicates that the photoconductor has been treated with an organic dyestuff so that radiant energy is absorbed by the dye on the surface of the photoconductor and the energy is transferred to the photoconductor thereby making the photoconductor conductive.
- This process may be employed in various ways to prepare permanent photographic reproductions.
- the preferred method of course is to directly deposit a basic nitrogen containing organic dyestuff directly on the photoconductor. If the basic nitrogen containing organic compound is colorless it may then be dyed or colored in a 3,418,322 Patented Dec. 24, 1968 ice subsequent step to produce a negative image, or the deposited compound may serve as a protective coating on the surface of the photoconductor and the unprotected areas dyed or modified chemically in some manner, such as by etching away the photoconductor with an acid or sol-vent. Likewise the compound deposited on the surface of the photoconductor may sufficiently modify the wetting characteristics of the photoconductive sheet. In this manner the two areas will have a differential repellency or attraction to water or oil.
- the varying of the surface wetting characteristics of the photoconductive sheet is particularly suitable for the production of lithographie plates where the photoconductor is rendered hydrophobic by the deposited compound.
- the structural formula of the basic nitrogen containing organic compound to be deposited from an aqueous solution in accordance with the teachings of this invention corresponds to the formula.
- M is an organic radical
- R and R are hydrogen or an alkyl radical containing up to 18 carbon atoms
- m is an integer of less than 4
- p is an integer of less than 6
- n is an integer of less than 6.
- a preferred class of compounds are those that contain an alkyl radical of at least 6 carbon atoms (preferably 10)
- R is an alkyl radical of at least 6 carbon atoms (preferably l0)
- the R radicals are alkyl radicals containing less than 6 carbon atoms.
- the long chain alkyl radical may also be present in the radical M, as in the case of the amino-polyamides described but is preferably one or more of the R constituents.
- the preferred class of dyestuffs falling within the above general formula is where M is an organic radical containing a chromogenic nucleus. Illustrative chromogenic nuclei are represented by the following general classes of dyestuffs:
- colorless images may be prepared or the colorless basic nitrogen containing organic compound may be deposited in the presence of colloidal organic 'or inorganic pigments.
- a reaction product of dimerized linoleic acid and an excess of a polyethylenamine having an amine number of about is dissolved in ethanol and acetic lacid as a one percent solution.
- This solution may then be neutralized ⁇ at the photoconductor-cathode and thereby a colorless insoluble solid is deposited on the surface of the photoconductor.
- the solution is mixed with colloidal titanium dioxide, neutralization and deposition of this dispersion results in the production of white images.
- the photoconductor-cathode is some color other than white, the titanium dioxide may be deposited yas the white portions of an image. In this manner, a direct positive image is formed.
- ⁇ Carbon black images may be formed by mixing colloidal carbon in the solution. Using this type of dispersion black images are prepared which are completely resistant to the action of light and most atmospheric conditions. As such, they represent one of the most permanent photographic elements attainable.
- These basic nitrogen containing organic compounds are dissolved in water by the formation of a salt with an acid moiety.
- Suitable organic acids include formic acid, acetic acid, lactic acid, levulinic acid and the like.
- Suitable inorganic -acids include hydrochloric acid, nitric acid7 sulfurie acid and the like.
- the final pH of these solutions is in the range of pH 2 to 7 (preferably 4.5 to 7).
- These aqueous solutions which are substantially free 'of positive ions other than those containing the basic nitrogen-containing organic compound are employed at solution concentrations of 0.1 to by weight.
- FIGURE 1 is a perspective view of developing apparatus useful in the practice of this invention and FLIGURE 2 is a cross-sectional view of FIGURE 1 lalong section lines 2 2.
- Developer tray 10 is composed of a base plate 12, which also serves as an electrode, top clamping frame member 14, and an intermediate yopen frame member 16 ttorrning upstanding walls around the base plate periphery.
- Frame member 14 and base plate 12 have cooperating, releasable clamping means 18, which draw these members toward one another when engaged to render the tray 10 water tight.
- the open frame member 16 is composed of a nonconductor such as polyethylene, polytetrauoroethylene or polytrifluorochloroethylene and is provided with a ledge 20 for supporting electrode 22 such that an electrical current passing to electrode 22 from the base plate-electrode 12 passes through ya photoconductor sheet 24 which is interposed between the open frame member 16 and the base plate 12.
- This photoconductor sheet 24 is composed of an electrically conductive carrier 26 which is placed in intimate contact with the base plate 12 and photoconductor particles 28.
- a solution 32 is placed in the developer tray 10, electrode 22 is connected to the positive terminal of the direct current power source 34 and the base plate 12 is attached to the negative terminal of the power supply 34.
- the electrical current passes through solution 32 and the photoconductive areas of the photoconductive she-et 24 resulting in image deposits 30 on the cathode-photoconductor surface.
- FIGURE 2 In order to graphically show the photoconductor particles 28 and the image deposit 30, they have been represented in FIGURE 2 in exaggerated size.
- a stepwise procedure for producing an image in accordance with the -teachings of this invention is as follows:
- the negative electrode from a direct current power supply 34 is attached to the metal base plate thereby making electrical conta-ct with the conductive backing of the photoconductor sheet 24.
- the photoconductor sheet 24 in the developing tray 10 is exposed to light in selected areas such as by focusing and projecting a photographic negative on the photoconductor sheet 24 through a light projector.
- the electrode 22 is placed on the ledge 20 and connected to the positive terminal ofthe direct current power supply 34.
- the solution 32 is added to the tray.
- the electrical current is turned on so as to elect the electrolytic development.
- the solution is poured off and the photoconductor sheet is thoroughly washed with water. Aditer suitable dark adaptation additional images may be put on the photoconductor sheet by repeating the above procedure.
- An especially useful method for dark adaptation of the photoconductor sheet is to place it in contact with water heated to at least 100 F. which may be accomplished simultaneously with the washing by employing the hot Water as the wash water.
- Full color reproductions may be obtained by carrying out the above procedure three times with monochromatic light.
- a color negative is placed in a projector equipped with a photoflood lamp and a red lter is interposed between the photoflood lamp and the photoconductor sheet, preferably between the color negative and the phototlood lamp, thereby exposing the photoconductor sheet selectively to red light.
- a cyan image is then developed on the photoconductor using a cyan dye.
- the photoconductive paper is then washed with warm water (heated to at least F.) and dried with a stream of air.
- the developing tray is then returned to the enlarger and a green lter is interposed between the light source and the photoconductor sheet.
- the light intensity of the projected image, time of exposure which may be from 0.1 second to sixty seconds, and period of electrolytic development which may be from 1 to 30 seconds at a voltage of from 5 to 150 volts are varied in accordance with quality of the image required or desired and the relative effectiveness of the photoconductor surface.
- this sheet When dry and fully dark adapted, this sheet is used to produce reproductions and had high response spectral bands at 460-465 mu, 560 mu and 660 mu.
- N-(2- cyanoethyl)-N-decylN,N'-diethyl 1,3 propanediamine 969 g., 3.00 moles
- the reaction mixture was stirred and refluxed for 5 hours after all the nitrile had been added and allowed to stand overnight under dry nitrogen.
- Excess hydride was decomposed by the addition of ethyl acetate (264 g., 3.00 moles) slowly so as to produce a gentle reiiux.
- the resulting solution was then diazotized by the rapid addition of 5 N sodium nitrite solution (40 ml.). Additional ice was added t0 keep the mixture cold and the solution treated rapidly while stirring with a solution consi-sting of 34 g. (0.09 mole) of Naphthol AS-G Supra, a product of General Aniline & Film Corp., dissolved in 750 ml. of dimethylformamide and ml. of pyridine. More ice and water were added to insure good cooling and stirring. After one-half hour the dye was completely precipitated by the addition of concentrated ammonium hydroxide (300 ml.) and the product collected by filtration. The resulting yellow dye was washed with water and ethanol and was then crystallized from ⁇ a mixture of dimethylformamide and ethanol.
- Alpha,alphabis[4(4 decyl 8 ethyl 4,8 diazadecyl)sulfamylphenylazo] 4,4' bi-o-acetoacetoluidide was prepared by reacting the diazo prepared from N(4 decyl 8 ethyl 4,8 diazadecyl)sulfanilamide with Naphthol AS-G in a manner similar to Preparation A above.
- the ycorresponding terephthalyl derivative was prepared in a similar manner.
- thioindigo-7,7dicarboxylic acid (l0 g., 0.026 mole). This was heated slowly to 90-95" C. on the steam bath with stirring, and maintained at that temperature for hours. The red solid obtained by filtering the reaction mixture was washed with benzene, filtered, washed with benzene, and washed with petroleum ether to produce thioindigo- 7,7dicarbonyl chloride (10 g.).
- 3hydroxythionaphthene-7-carboxylic -acid (0.3 mole) was dissolved in Water (l liter) containing sodium carbonate monohydrate (40 g., 0.32 mole). To this was added with stirring a solution of potassium ferricyanide (218 g., 0.66 mole) in water (700 ml.). An additional 0 amount of sodium carbonate monohydrate (40 g., 0.32 mole) was added to keep the mixture alkaline. The mixture was stirred about one and one-half hours and filtered. The filter cake was mixed with Water (700 mL), and
- the basic nitrogen containing compounds such as are illustrated by Preparations A to L above, are dissolved in water in the presence of an acid.
- the solution concentration and acid employed may vary.
- the compounds are dissolved as the acetate or hydrochloride salts in 0.5 to 2% aqueous solution.
- Illustrative solutions of the compounds shown in Preparations A to L which may be used to form colored deposits on a photoconductor sheet are as follows:
- magenta solution The magenta dye (4 g.) from Preparation J was mixed with ethanol (40 1111.), glacial acetic acid (0.58 ml.)
- a colorless solution suitable for 4use in the process of this invention was prepared as follows:
- Solutions especially useful for the deposition of dye images by electrophotography are obtained by mixing this colorless solution with a dye solution. For instance, 50 g. portions of this colorless solution in admixture with 100 g. portions of solutions (a), (b) and (c) were found to be especially useful for the production of colored images.
- This colorless stock solution can, of course, also be deposited by itself or in admixture with other pigments. For instance, white images are obtained by using the solution in admixture with dispersed titanium dioxide in the following developmental procedure. Black images are obtained using dispersed carbon particles in this solution.
- a preferred combination of solutions for preparing a true-to-life colored reproduction are solutions (a), (b), and (c) above whereby the yellow dye [solution (c)] is deposited tirst, the magenta dye [solution (b)] is deposited second, and the cyan dye [solution (a)] is deposited third.
- NICHOLAS S. RIZZO Primary Examiner.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Photoreceptors In Electrophotography (AREA)
- Indole Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Pyridine Compounds (AREA)
- Color Printing (AREA)
Description
Dec. 24, 1968 v TuLAGm ETAL 3,418,322
` QUINACRIDONE DYESTUFFS Original Filed April 18, 1965A INVENTORS vsevoLoo ruLAGm y ROBERT F. coLEs RlcHARo A. MILLER United States Patent O 3,418,322 QUINACRIDONE DYESTUFFS Vsevolod Tulagin, St. Paul, Robert F. Coles, North St. Paul, and Richard A. Miller, St. Paul, Minn., assignors to Minnesota Mining and Manufacturing Company, St. Paul, Minn., a corporation of Delaware Original application Apr. 18, 1960, Ser. No. 23,017, now Patent No. 3,172,827, dated Mar. 9, 1965. Divided and this application May 7, 1964, Ser. No. 370,751
2 Claims. (Cl. 260--279) This application is a division of U.S. patent application Ser. No. 23,017, filed on Apr. 18, 1960, now U.S. Patent No. 3,172,827.
This invention relates to new and useful permanent reproductions and their method of preparation by selectively depositing a basic nitrogen containing compound on the surface of a photoconductor.
A method for making visible reproductions electrolytically is described in the application of Johnson and Neher, Ser. No. 575,070, filed Mar. 30, 1956, now US. Patent 3,010,883. The Johnson and Neher application discloses the preparation of light sensitive sheet material from a conductive backing and a photoconductor which is also useful in the practice of this invention.
An object of this invention is to disclose a method of selectively depositing basic nitrogen containing organic compounds on the surface of a photoconductor thereby producing reproductions in a fast and eicient manner.
Another object of this invention is to disclose a process for preparing colored reproductions by electrophotography. Full colored reproductions are prepared by successively applying subtractive primary colors to the surface of the dye-sensitized photoconductor. The method of making colored reproductions from subtractive primaries is described in I. S. Friedmans A History of Color Photography, American Photographic Publishing Company, Boston, Mass. (1944).
It has now been discovered that permanent reproductions may be made on the surface of a dye-sensitized photoconductor uniformly bonded to an electrically conductive carrier by selectively depositing a basic nitrogen containing organic compound which is soluble in the presence of an acid and substantially insoluble in water at a pH above 7 by neutralizing the solution with the electrons which are released at the photoconductor-cathode when an electric current passes through the water solution of the basic nitrogen containing organic compound and the conducting areas of the photoconductorcathode. The photoconductor surface is first exposed to a light source in the selected areas to render the photoconductor conductive in the exposed areas. The photoconductor surface is then contacted with an acid-water solution of the basic nitrogen containing organic compound. An electrical current is then passed through the water solution and the conducting areas of the photoconductor cathode to neutralize the acid solution at the conducting areas with the electrons which are released at the photoconductor-cathode. In this manner the basic nitrogen containing compound is insolubilized and deposited on the photoconductor at the exposed areas.
The tem-n dye-sensitized indicates that the photoconductor has been treated with an organic dyestuff so that radiant energy is absorbed by the dye on the surface of the photoconductor and the energy is transferred to the photoconductor thereby making the photoconductor conductive.
This process may be employed in various ways to prepare permanent photographic reproductions. The preferred method of course is to directly deposit a basic nitrogen containing organic dyestuff directly on the photoconductor. If the basic nitrogen containing organic compound is colorless it may then be dyed or colored in a 3,418,322 Patented Dec. 24, 1968 ice subsequent step to produce a negative image, or the deposited compound may serve as a protective coating on the surface of the photoconductor and the unprotected areas dyed or modified chemically in some manner, such as by etching away the photoconductor with an acid or sol-vent. Likewise the compound deposited on the surface of the photoconductor may sufficiently modify the wetting characteristics of the photoconductive sheet. In this manner the two areas will have a differential repellency or attraction to water or oil. The varying of the surface wetting characteristics of the photoconductive sheet is particularly suitable for the production of lithographie plates where the photoconductor is rendered hydrophobic by the deposited compound.
Broadly speaking, the structural formula of the basic nitrogen containing organic compound to be deposited from an aqueous solution in accordance with the teachings of this invention corresponds to the formula.
where M is an organic radical, R and R are hydrogen or an alkyl radical containing up to 18 carbon atoms, m is an integer of less than 4, p is an integer of less than 6 and n is an integer of less than 6. A preferred class of compounds are those that contain an alkyl radical of at least 6 carbon atoms (preferably 10) Especially preferred because of their solubility characteristics are compounds where R is an alkyl radical of at least 6 carbon atoms (preferably l0) and the R radicals are alkyl radicals containing less than 6 carbon atoms. The long chain alkyl radical may also be present in the radical M, as in the case of the amino-polyamides described but is preferably one or more of the R constituents. The preferred class of dyestuffs falling within the above general formula is where M is an organic radical containing a chromogenic nucleus. Illustrative chromogenic nuclei are represented by the following general classes of dyestuffs:
Azo Quinacridone Anthraquinone Thioindigo Anthrapyridone Xanthene Phthalocyanine Nonchromogenic basic nitrogen-containing organic compounds corresponding to the above formula lare best illustrated by polyamides derived ffrom polybasic acids, particularly .polymeric fat acids, such as dimerized ylinoleic acid, and polyamines containing unreacted amine groupings as evidenced by their high amine members. These compounds may be employed in the production of pigmented images of nonbasic nitrogen containing organic compounds.
1In the utilization of nonchromogenic basic nitrogen containing organic compounds colorless images may be prepared or the colorless basic nitrogen containing organic compound may be deposited in the presence of colloidal organic 'or inorganic pigments. For instance, a reaction product of dimerized linoleic acid and an excess of a polyethylenamine having an amine number of about is dissolved in ethanol and acetic lacid as a one percent solution. This solution may then be neutralized `at the photoconductor-cathode and thereby a colorless insoluble solid is deposited on the surface of the photoconductor. If the solution is mixed with colloidal titanium dioxide, neutralization and deposition of this dispersion results in the production of white images. If the photoconductor-cathode is some color other than white, the titanium dioxide may be deposited yas the white portions of an image. In this manner, a direct positive image is formed.
`Carbon black images may be formed by mixing colloidal carbon in the solution. Using this type of dispersion black images are prepared which are completely resistant to the action of light and most atmospheric conditions. As such, they represent one of the most permanent photographic elements attainable.
These basic nitrogen containing organic compounds are dissolved in water by the formation of a salt with an acid moiety. Suitable organic acids include formic acid, acetic acid, lactic acid, levulinic acid and the like. Suitable inorganic -acids include hydrochloric acid, nitric acid7 sulfurie acid and the like. The final pH of these solutions is in the range of pH 2 to 7 (preferably 4.5 to 7). These aqueous solutions which are substantially free 'of positive ions other than those containing the basic nitrogen-containing organic compound are employed at solution concentrations of 0.1 to by weight.
In the drawings, FIGURE 1 is a perspective view of developing apparatus useful in the practice of this invention and FLIGURE 2 is a cross-sectional view of FIGURE 1 lalong section lines 2 2.
The open frame member 16 is composed of a nonconductor such as polyethylene, polytetrauoroethylene or polytrifluorochloroethylene and is provided with a ledge 20 for supporting electrode 22 such that an electrical current passing to electrode 22 from the base plate-electrode 12 passes through ya photoconductor sheet 24 which is interposed between the open frame member 16 and the base plate 12. This photoconductor sheet 24 is composed of an electrically conductive carrier 26 which is placed in intimate contact with the base plate 12 and photoconductor particles 28.
In order to selectively deposit images 30 on the photoconductor sheet 24, a solution 32 is placed in the developer tray 10, electrode 22 is connected to the positive terminal of the direct current power source 34 and the base plate 12 is attached to the negative terminal of the power supply 34. When arranged in this manner the electrical current passes through solution 32 and the photoconductive areas of the photoconductive she-et 24 resulting in image deposits 30 on the cathode-photoconductor surface. -In order to graphically show the photoconductor particles 28 and the image deposit 30, they have been represented in FIGURE 2 in exaggerated size.
A stepwise procedure for producing an image in accordance with the -teachings of this invention is as follows:
(1) The negative electrode from a direct current power supply 34 is attached to the metal base plate thereby making electrical conta-ct with the conductive backing of the photoconductor sheet 24. (2) The photoconductor sheet 24 in the developing tray 10 is exposed to light in selected areas such as by focusing and projecting a photographic negative on the photoconductor sheet 24 through a light projector. (3) The electrode 22 is placed on the ledge 20 and connected to the positive terminal ofthe direct current power supply 34. (4) The solution 32 is added to the tray. (5) The electrical current is turned on so as to elect the electrolytic development. (6) The solution is poured off and the photoconductor sheet is thoroughly washed with water. Aditer suitable dark adaptation additional images may be put on the photoconductor sheet by repeating the above procedure. An especially useful method for dark adaptation of the photoconductor sheet is to place it in contact with water heated to at least 100 F. which may be accomplished simultaneously with the washing by employing the hot Water as the wash water.
Full color reproductions may be obtained by carrying out the above procedure three times with monochromatic light. For example, a color negative is placed in a projector equipped with a photoflood lamp and a red lter is interposed between the photoflood lamp and the photoconductor sheet, preferably between the color negative and the phototlood lamp, thereby exposing the photoconductor sheet selectively to red light. A cyan image is then developed on the photoconductor using a cyan dye. The photoconductive paper is then washed with warm water (heated to at least F.) and dried with a stream of air. The developing tray is then returned to the enlarger and a green lter is interposed between the light source and the photoconductor sheet. After the photoconductor has been exposed selectively to the green light, the above process is repeated using a magenta dye. This procedure is repeated again to produce a yellow image on those areas selectively exposed through a blue filter. In this manner a full true-to-life color picture is obtained by electrophotography.
Generally speaking, the light intensity of the projected image, time of exposure which may be from 0.1 second to sixty seconds, and period of electrolytic development which may be from 1 to 30 seconds at a voltage of from 5 to 150 volts are varied in accordance with quality of the image required or desired and the relative effectiveness of the photoconductor surface.
PREPARATION OF PHOTOCONDUCTOR SHEET (A) A Waring Blendor mixer is employed to thoroughly blend the following ingredients over a period of l5 methanol solutions in order to dye-sensitize the photoconductor sheet as follows:
Acid Blue 1 NaO Acid Red 92 IWCHJ):
I N (CH3) z 5 Basic Yellow 2* `-'C0lor Index 2d ed., Chorle Pickers ill Ltd. L d (s). y g ce s After being blended for an additional iive minutes and ltered through a coarse sintered glass iilter, the blend is coated with a doctor blade coater onto an aluminum sheet` (3 mils) to a wet thickness of .006 inch.
When dry and fully dark adapted, this sheet is used to produce reproductions and had high response spectral bands at 460-465 mu, 560 mu and 660 mu.
(B) Zinc oxide, USP 12 (34.4 parts lby weight); a binder (29.6 parts by weight), Pliolite S-7, a product of the Goodyear Tire and Rubber Company, Akron, Ohio; and acetone (11.8 parts by weight) were mixed in a ball mill for 8 hours until a smooth dispersion was obtained. This dispersion, diluted with ethyl acetate (23 parts by weight), was mixed with 0.5% methanol dye-sensitizer solutions of Phosphine R (2 parts), a product of the General Dyestut Corporation, and Xylene Cyanol FF (0.6 part), a product of British Drug Houses Ltd. The resulting mixture was filtered through a 325 mesh screen and coated at a wet thickness of .007 on a 3 mil aluminum backing. After being dried in a stream of warm u DYESTUFF PREPARATION Dyes employed in preparing the colored reproductions in accordance with the teachings of this invention are new and useful compositions of matter. Illustrative preparations of preferred dyes and their intermediates are as follows:
Intermediate preparations I. PREPARATION OF N-DECYIrN',N-DIETHYL In a five-liter, three-necked flask equipped with a mechanical stirrer, thermometer, reiiux condenser and dropping funnel was placed N,Ndiethyl1,3-propanediamine (1950 g., moles). The amine Was heated to 125 C. and 1-bromodecane (1106 g., 5 moles) was added with stirring at a rate sufficient to maintain the exothermic reaction at about 130-l40 C. The reaction mixture Was stirred for an additional hour at a temperature of 12S- 135 C., then cooled to room temperature. Sodium methoxide (250 g., 5 moles) was added to neutralize the hydrobromic acid formed. Upon cooling to room temperature a solid separated which was removed by iiltration and washed with petroleum ether. Unreacted amine and solvent were removed by distillation.
N-decyl-N,N'diethyl 1,3 propanediamine (1080 g.) having a boiling point of 130 C. at 1 mm. pressure was then collected by vacuum distillation.
II. PREPARATION OF N-(2-CYANOETHYL)NDECYL N ,N -DIETHYL-l,S-PROPANEDIAMINE In a two-liter, one-necked ask with thermometer well were placed acrylonitrile (250 g. 4.70 moles) and N- decylN,N-diethyl 1,3 propanediamine (1013 g. 3.76 moles). The flask was fitted with a reflux condenser and heated on a mantle to gentle reflux. The mixture was heated three days at a temperature not exceeding 110 C.
Unreacted acrylonitrile was removed at reduced pressure and 1206 grams of unpuriiied N-(2-cyanoethyl)-N decyl-N',N'diethyl1,3-propanediamine were recovered.
6 III. PREPARATION OF N-(3-AMINoPROPYm-N-DECYI, N',N'-DIETHYIA,a-PROPANEDIAMINE In a three-liter, three-necked iiask equipped with stirrer, reiiux condenser and dropping funnel were placed lithium aluminum hydride (114 g., 3.00 moles) and diethyl ether (750 ml.) in an atmosphere of dry nitrogen. After a 15 minute period of reiiuxing and stirring, N-(2- cyanoethyl)-N-decylN,N'-diethyl 1,3 propanediamine (969 g., 3.00 moles) was added slowly so as to produce only moderate reliux. The reaction mixture was stirred and refluxed for 5 hours after all the nitrile had been added and allowed to stand overnight under dry nitrogen. Excess hydride was decomposed by the addition of ethyl acetate (264 g., 3.00 moles) slowly so as to produce a gentle reiiux. The resulting mixture was hydrolyzed by the cautious addition of water (270 g., 15.0 moles) accompanied by external cooling and the addition of ether to facilitate stirring. The solution was filtered to remove insoluble inorganic salts, distilled through a 15-inch Vigreux column, and redistilled to produce N-(3- vaminopropyD-N-decyl N,N' diethyl 1,3 propancdiamine (499 g.) having a boiling range of 160 C./ 1.2 In'm. Hg to 170 C./0.9 mm. Hg.
IV. PREPARATION OF N(3-DIETYLAMINOPROPYL)- Nf-DECYLSULFANILAMIDE' A solution of N-decyl-N',Ndiethyl 1,3 propanediamine (135 g., 0.5 mole) in 100 ml. of benzene Was treated with p-acetylaminobenzenesulfonyl chloride (120 g., 0.5 mole). The resulting homogeneous solution was stirred for 1 hour. After removing the solvent, the residue was treated with 200 ml. of water and 100 ml. of -concentrated hydrochloric acid. This mixture was heated on a steam bath for six hours. N'(3diethylaminopropyl) N'decylsulfanilamide which separated as an oil was precipitated by the addition of an excess of alkali.
YELLOW DYE PREPARATIONS A. Preparation of alpha,alpha bis [4-(N-(3-diethy1- aminopropyl) N decyl)sulfamylphenylazo]-4,4'bio-acetoacetotoluidide N(3 diethylaminopropyl) N' decylsulfanilamide g., 0.2 mole) was dissolved in 75 ml. of glacial acetic acid, and diluted with m1. of water. This solution was poured into a mixture of ice (500 g.) and concentrated hydrochloric acid (75 ml.). The resulting solution was then diazotized by the rapid addition of 5 N sodium nitrite solution (40 ml.). Additional ice was added t0 keep the mixture cold and the solution treated rapidly while stirring with a solution consi-sting of 34 g. (0.09 mole) of Naphthol AS-G Supra, a product of General Aniline & Film Corp., dissolved in 750 ml. of dimethylformamide and ml. of pyridine. More ice and water were added to insure good cooling and stirring. After one-half hour the dye was completely precipitated by the addition of concentrated ammonium hydroxide (300 ml.) and the product collected by filtration. The resulting yellow dye was washed with water and ethanol and was then crystallized from `a mixture of dimethylformamide and ethanol.
(The diazo from N-(3-diethylaminopropyl)-Ndecyl- Isulfanilamide was also reacted with the coupler N-(2- naphthyl)-3-hydroxy-2-naphthamide to produce a reddish dye and with various salicylamides to produce yellow dyes.) i
Alpha,alphabis[4(4 decyl 8 ethyl 4,8 diazadecyl)sulfamylphenylazo] 4,4' bi-o-acetoacetotoluidide was prepared by reacting the diazo prepared from N(4 decyl 8 ethyl 4,8 diazadecyl)sulfanilamide with Naphthol AS-G in a manner similar to Preparation A above.
7 8 C. Preparation of alpha-[4 (2 diethylaminoethyl) toluene. After being heated on a steam bath for one hour, sulfamylphenylazo]-2,5'-dimethoxybenzoylacetanilide the reaction product was percipitated with 300 ml. of ligroin, collected and dried. The crude product was then O O ,)CH dissolved in hof ethancn and filtered. Upon dilution with il H ll N 5 water, a yellow dye precipitated from the ltrate which Q-C C N@ was collected and dried.
The ycorresponding terephthalyl derivative was prepared in a similar manner.
F. Preparation of 2,8 bis[4(3 diethylaminopropyl) N=N NHen.N ernm 10 sulfmylphenylydithiazo[5A-a] [5.4-h] enz-anthraquinone This yellow dye was prepared in the same manner as Algol Yellow GC, a product of General Aniline & Preparation A above using N-(2 diethylaminoethyl) Film Corp., was purified by water and acetone extraction. sulfanilamide and a coupler prepared by an ester-amide 5 -Ten grams of the dried material were added to chlorosulinterchange reaction between ethyl benzoylacetate and onic acid (50 mL). The mixture was then heated and 2,5-dimethoxyaniline as the intermediates. stirred at 13S-140 C. for 2 hours. The reaction mixture was then cooled and poured onto ice. A yellow green D. Preparation of 4 [4-(N-(3-d1ethylam1nopropyl)N solid was collected by filtration and washed with water decyl)sulfamylphenylazo]-3-methyl l phenyl-S-py- 30 and dried.
razolone Two grams of the yellow green solid were dissolved in N,Ndiethyl1,3-propanediamine (10 g.). This solution o 019ml was diluted with water and a large excess of ammonium CH C qq ISLN/ hydroxide added. The precipitated product was collected, 3- H 35 washed with water and then extracted with methanol.
N C=O O C H N C H5 N/ 3 s h MAGENTA DYEs G. Preparation of 1-methyl4(3-dibutylarninopropylamino anthrapyridone (H) A solution of the diazo (0.05 mole) prepared as shown C /N-CH3 in Preparation A above was added rapidly with stirring to a solution of 3 methyl-l-phenyl-S-pyrazolone (9 g., 0.05 mole) in a mixture of 100 ml. dimethylforrnamide and 100 ml. pyridine. Ice was added and after one-half I I hour the yellow dye was precipitated with ammonium N hydroxide and then washed with water, liltered and dried. o H CZHNmHm l'-methyl-4-bromoanthrapyridone (10 g.) and N,N dibutyl-1,3-propanediamine (20 ml.) were heated at 160-180 C. to yield a deep magenta colored solution. The reaction mixture was diluted with toluene, cooled E. Preparation of N-(4-decyl-8-ethyl-4,8diazadecyl)-N- l-anthraquinonyl)isophthalamide H and a solid product collected, which was transformed to 0 N G@ a gum by tritur'ating with ammonium hydroxide. After l H /CruHn mixing the gum with concentrated hydrochloric acid and C 'N CJH5N diluting the mixture with acetone, 1methyl4(3di O \C3HGN(CZH )l butylaminopropylamino)anthrapyridone Iwas obtained as a crystalline solid. Y H. Preparation of l'methyl4[3(4decyl8ethyl-4,8 0 diazadecylsulfamyl)-4-toluidino]anthrapyridone A solution of 45 g. (0.22 moie) of is0phrha1y1 chloil ride in 500 ml. of xylene was heated to near reux and C 1-aminoanthraquinone (23 g., 0.1 mole) was added slowly while stirring. The mixture was heated at reliux until HC /N CH3 the evolution of hydrogen chloride ceased. The hot mixture was then treated with decolorizing ycarbon and ltered. After the filtrate was cooled in ice, a solid was i l collected, Washed with xylene and recrystallized from fresh xylene. Il The recrystallized product was added slowly to a solu- O 1,3-propanediamine (22 g., 0.067 mole) in 50 ml. of
S OzNECaHaN(CioH21) C3HoN(C2H5)2 -CHa Alizarine Rubinol R-Cl:` (200 g), a product of the General Dyestuff Company, was mixed with water (2 liters) and heated on a steam bath. The mixture was made strongly acidic with concentrated hydrochloric acid and stirred and heated until the solid turned dark red. The mixture Was filtered and the solid was washed with water. After dispersing the solid in a dilute sodium chloride solution (1 liter) the mixture was made basic with sodium carbonate, heated on a steam bath, and filtered. The purified product was dried at reduced pressure at 100 C. for 24 hours.
Phosphorus oxychloride (250 ml.) was added with cooling to the nely powdered purified Alizarine Rubinol R-CF (46.8 g., 0.1 mole). To this mixture was added with cooling phosphorus pentachloride (46 g., 0.22 mole). 15
halides. This mixture was filtered and the solid was .2O
washed with cold water. The damp cake was stirred into hot nitrobenzene (500 ml.) and dry magnesium sulfate was added to help remove Water. After removal of the water, the mixture was ltered through a sintered glass funnel. Upon standing overnight at room temperature 25 crystals of 1-methyl4(3-chlorosulfonyl 4 toludino) anthrapyridone Were formed and removed from the filtrate by filtration, washed with heptane and twice with petroleum ether.
centr-ated hydrochloric acid and filtered. The solid collected was washed with dilute hydrochloric acid, and acctone, and dried under vacuum at 75 C. to produce thioindigo-7,7dicarboxylic acid (38 g.).
To a mixture of phosphorus pentachloride (12 g., 0.057 mole) and phosphorus oxychloride (70 =ml.) was added thioindigo-7,7dicarboxylic acid (l0 g., 0.026 mole). This was heated slowly to 90-95" C. on the steam bath with stirring, and maintained at that temperature for hours. The red solid obtained by filtering the reaction mixture was washed with benzene, filtered, washed with benzene, and washed with petroleum ether to produce thioindigo- 7,7dicarbonyl chloride (10 g.).
To a mixture of N-decyl-N,Ndiethyl1,3-propanediamine (2.9 g., 0.011 mole) and benzene (80 ml.) was added thioindigo7,7dicarbonylchloride (2.1 g., 0.005 mole). The mixture was stirred and reuxed about 5 hours. The solvent was removed at reduced pressure, The residue was dissolved in water (400 ml.) with vigorous agitation, and this solution was made alkaline with ammonium hydroxide solution. A small amount of saturated sodium chloride solution was added to agglomerate the dye, and the mixture was filtered. The solid N,N'bis(3diethyl aminopropyl) N,N didecylthioindigo 7,7' dicarboxamide was washed twice with water in which it became increasingly soluble and dried to produce an ultimate yield of 4 grams.
To a mixture of N-(3-aminopropyl)-N-decyl-N,N- diethyl-1,3-propanediamine g., 0.0306 mole) and pyridine (50 ml.) was added 1methyl4(3-chlorosul- 40 onyl-4-toluidino)anthrapyridone (7.0` g., 0.0151 mole). The reaction mixture was stirred and heated on the steam cone for one hour and allowed to stand at rooim temperature for 16 hours. The reaction mixture was then mixed with Water (500 m1,), made basic with concentrated ammonium hydroxide, and filtered. The collected D 3-hydroxythionaphthene-7-carboxylic acid was prepared from phenyl-l-thioglycollic-Z-carboxylic acid by the method described in British Patent 360,349. 6
3hydroxythionaphthene-7-carboxylic -acid (0.3 mole) was dissolved in Water (l liter) containing sodium carbonate monohydrate (40 g., 0.32 mole). To this was added with stirring a solution of potassium ferricyanide (218 g., 0.66 mole) in water (700 ml.). An additional 0 amount of sodium carbonate monohydrate (40 g., 0.32 mole) was added to keep the mixture alkaline. The mixture was stirred about one and one-half hours and filtered. The filter cake Was mixed with Water (700 mL), and
In a 2-liter, 3-necked ask equipped with stirrer, thermometer, and gas outlet tube connected to a calcium chloride-tilled drying tube and cooled in an ice bath was placed chlorosulfonic acid (1.00 liter, 15.2 moles). Quinacridone (100 g., 0.32 mole), which had been dried in a vacuum oven at C. was added so that the temperature of the reaction mixture did not exceed 20 C. The mixture was stirred at room temperature for 4 days at which time the reaction mixture was divided into 2 portions. Each portion Iwas added slowly with stirring to acetone (2.5 liters) which was cooled in an ice bath so that the temperature did not exceed 25 C. The resulting mixture was filtered. The solid was washed with acetone and petroleum ether and dried to yield 136 grams of quinacridone-X,X'- disulfonyl chloride.
In a one-liter, three-necked flask with stirrer and con- 5 denser was placed N-(3-aminopropyl)-N-decyl-N,N
diethyl-1,3-propanediamine g., 0.306 mole) and pyridine (650 ml.). To this was added with stirring quinacridone-X,X'-disulfonyl chloride (77 g., 0.152 mole) This mixture was stirred and heated on the steam bath for 24 hours. The reaction mixture was poured with stirring into water (1 liter), .and concentrated ammonium hydroxide (100 ml., 1.5 moles) was added. The resulting mixture was stirred and digested, then filtered. The filler cake was washed with water, digested and filtered. The solid product was Washed with acetone, digested and the resulting mixture 'was made strongly acid with con- 75 flltered. The resulting filler cake was washed twice with acetone and dried at reduced pressure to produce .a yield of 110 grams of the magenta dye, X,Xbis(4 decyl- 8- ethyl-4,8diazadecylsulfamyl)quinacridone, whose color purity was improved by trituration with warm N,N-dimethylformamide.
CYAN DYES K. Preparation of copper phthalocyanine C1uH2i H I CHz-N-CsHeN-CaHGN(C2Hs)2] l" H CnHzi -CHr-N-CaHeN-CsHaN (C zHa) 2 was collected by filtration, washed with acetone and dried.
L. Preparation of copper phthalocyanine H CwHzi -SO2N`CaHeN-C3H6N(C2Hs)2 Copper phthalocyanine (50 g.) was chlorosulfonated by the procedure described in British Patent 515,637. The damp cake of the tetrasulfonyl chloride was stirred vigorously with a mixture of ice and N(3aminopropyl)-N decy1-N',N diethyl-1,3-propanediamine (130 g., 0.4 mole). After one hour the reaction mixture was poured with stirring into 500 ml. of water containing 200 ml. of concentrated hydrochloric acid. The precipitated hydrochloride of copper phthalocyanine H CioHn -S OzN-CsHaN-CaHsN (C2H5)2 was collected, washed with cold water and dried.
SOLUTION PREPARATIONS The basic nitrogen containing compounds, such as are illustrated by Preparations A to L above, are dissolved in water in the presence of an acid. The solution concentration and acid employed may vary. Preferably, the compounds are dissolved as the acetate or hydrochloride salts in 0.5 to 2% aqueous solution. Illustrative solutions of the compounds shown in Preparations A to L which may be used to form colored deposits on a photoconductor sheet are as follows:
(a) Cyan solution The cyan dye (40 g.) from Preparation L was triturated with 200 ml. of hot absolute ethanol and gradually diluted with 150 ml. of water. The resulting homogeneous solution was poured rapidly with vigorous stirring into 1500 ml. of water. The solution was filtered and made up to 2 liters with water.
(b) Magenta solution The magenta dye (4 g.) from Preparation J was mixed with ethanol (40 1111.), glacial acetic acid (0.58 ml.)
12 and Water (360 ml.) with constant heating and stirring until the mixture was homogeneous.
(c) Yellow solution The yellow dye (16 g.) in the form of the terephthalyl derivative from Preparation E was dissolved in absolute ethanol ml.) and concentrated hydrochloric acid (2.8 ml.) and was diluted to 800 ml. with water.
A colorless solution suitable for 4use in the process of this invention was prepared as follows:
The polyamide reaction product of polymeric fat acids and a polyamine having unreacted amine groups, Versamid 100, a product of General Mills, Inc. (27.5 g.), was boiled gently with ml. of absolute ethanol until dissolved. A solution of 1.8 ml. of concentrated hydrochloric acid in 100 ml. of Water was added and the solution diluted to 1350 ml. with water.
Solutions especially useful for the deposition of dye images by electrophotography are obtained by mixing this colorless solution with a dye solution. For instance, 50 g. portions of this colorless solution in admixture with 100 g. portions of solutions (a), (b) and (c) were found to be especially useful for the production of colored images. This colorless stock solution can, of course, also be deposited by itself or in admixture with other pigments. For instance, white images are obtained by using the solution in admixture with dispersed titanium dioxide in the following developmental procedure. Black images are obtained using dispersed carbon particles in this solution.
The procedure employed to prepare reproductions by the deposition of the basic nitrogen-containing organic compounds, including the various dyestuifs shown in Preparations A to L and the colorless amine-containing polyamides, on the surface of a zinc oxide photoconductor sheet prepared as described was as follows:
(1) The negative electrode from a direct current power supply was attached to the metal base of a developer tray as illustrated in FIGURES 1 and 2 of the drawings thereby making electrical contact with the aluminum backing of the photoconductor sheet.
(2) The photoconductor sheet retained in the developer tray was exposed to a light source in the selected areas by projecting an image on the photoconductor sheet with the projector having a low F stop projection range and a 500 watt tungsten projection lamp as the light source, thereby rendering select areas conductive. Relative humidity of the atmosphere in the work area should be less than 40 percent.
(3) An electrode attached to the positive terminal was' placed in the developer tray and the various solutions were added to the tray.
(4) After a total lapse of time of about 20 seconds after exposure, a 30 volt electrical current was then passed through the photoconductor at the conductive areas for a period of 10 seconds.
(5) The solution was removed from the developer tray and the photoconductor sheet was thoroughly washed with water.
(6) If the photoconductor sheet was to be re-exposed, it was placed in contact with water heated to F. for a period of at least 20 seconds to restore it to a dark adapted state and the sheet was then dried by placing it under a stream of air.
By this procedure colored images were selectively deposited on the exposed interface of the photoconductor sheet using solutions of the dyestuts shown in Preparations A to L. A preferred combination of solutions for preparing a true-to-life colored reproduction are solutions (a), (b), and (c) above whereby the yellow dye [solution (c)] is deposited tirst, the magenta dye [solution (b)] is deposited second, and the cyan dye [solution (a)] is deposited third.
13 We claim: 1. A dyestut insoluble in water at a pH above 7 and soluble in water at a pH below 7 of the general structural formula Wherein M is a chromophore having a quinacridone nucleus unsubstituted in the central benzene ring, R is an alkyl group having from 6 to 18 carbon atoms, R is an alkyl group having less than 6 carbon atoms, m is either 2 or 3, p is an integer less than 6, and n is an integer less than 6.
2. X,X' bis(4 decyl 8-ethyl-4,8-diazadecylsulfamyl) quinacridone. References Cited UNITED STATES PATENTS 2,151,518 3/1939 Krizikalla et al. 260-163 l0 pages 1-18.
Dickey et al. 260-205 Kruckenberg et al. 260-176 X Kruckenberg et al. 260-163 X Elslager et al. 260-152 X Schulemann et al. 260--279 Elslager 260-278 OTHER REFERENCES Labana et al.: Chem. Reviews, vol. 67, February 1967,
NICHOLAS S. RIZZO, Primary Examiner.
D. G. DAUS, Assistant Examiner.
U.S. C1. X.R.
UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3,418,322 December 24, 19
Vsevolod Tulagin et al.
It is certified that error appears in the above identified patent and that said Letters Patent are hereby corrected as shown below:
Column 4, about line 4l, "Co." should read cc. 7, lines 32 to 42, the upper right-hand portion of the formul reading I C H should read C H 19 2l l0 2l Columns 7 and 8, lines l2 to 22 the portion of the formula reading s-c- C should read Column ll, lines 26 to 29, the portion of the formula reading (II-.19H21 Should read (IlOHZl Signed and sealed this 17th day of March 1970.
(SEAL) Attest:
EDWARD M.FLETCHER,JR. WILLIAM E. SCHUYLER, JF Attesting Officer Commissioner of Patents
Claims (1)
1. A DYESTUFF INSOLUBLE IN WATER AT A PH ABOVE 7 AND SOLUBLE IN WATER AT A PH BELOW 7 OF THE GENERAL STRUCTURAL FORMULA
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3172827D US3172827A (en) | 1960-04-18 | Permanent reproductions | |
NL263729D NL263729A (en) | 1960-04-18 | ||
DEM48723A DE1177005B (en) | 1960-04-18 | 1961-04-17 | Process for the production of single or multi-colored reproductions with the aid of electrolytic image development |
CH452161A CH455522A (en) | 1960-04-18 | 1961-04-17 | Process for making reproductions |
GB14061/61A GB990972A (en) | 1960-04-18 | 1961-04-18 | Photoconductive copy sheets |
GB44060/63A GB990973A (en) | 1960-04-18 | 1961-04-18 | Dyestuffs containing polyalkyleneamine groups |
FR859407A FR1290454A (en) | 1960-04-18 | 1961-04-18 | Manufacturing process for permanent photographic images |
NO149036A NO122384B (en) | 1960-04-18 | 1963-06-14 | |
US370751A US3418322A (en) | 1960-04-18 | 1964-05-07 | Quinacridone dyestuffs |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2301760A | 1960-04-18 | 1960-04-18 | |
US370751A US3418322A (en) | 1960-04-18 | 1964-05-07 | Quinacridone dyestuffs |
Publications (1)
Publication Number | Publication Date |
---|---|
US3418322A true US3418322A (en) | 1968-12-24 |
Family
ID=26696628
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US3172827D Expired - Lifetime US3172827A (en) | 1960-04-18 | Permanent reproductions | |
US370751A Expired - Lifetime US3418322A (en) | 1960-04-18 | 1964-05-07 | Quinacridone dyestuffs |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US3172827D Expired - Lifetime US3172827A (en) | 1960-04-18 | Permanent reproductions |
Country Status (7)
Country | Link |
---|---|
US (2) | US3418322A (en) |
CH (1) | CH455522A (en) |
DE (1) | DE1177005B (en) |
FR (1) | FR1290454A (en) |
GB (2) | GB990972A (en) |
NL (1) | NL263729A (en) |
NO (1) | NO122384B (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3753708A (en) * | 1971-03-29 | 1973-08-21 | Xerox Corp | Photoelectrophoretic imaging process employing quinacridone pigments |
US4310359A (en) * | 1980-02-25 | 1982-01-12 | Toyo Ink Manufacturing Co., Ltd. | Pigment compositions |
US4317682A (en) * | 1979-08-27 | 1982-03-02 | Toyo Ink Manufacturing Co. Ltd. | Pigment compositions and use thereof |
US5698024A (en) * | 1996-12-31 | 1997-12-16 | Bayer Corporation | Organic pigment compositions |
US5711800A (en) * | 1996-12-31 | 1998-01-27 | Bayer Corporation | Organic pigment compositions |
US5879444A (en) * | 1997-09-02 | 1999-03-09 | Bayer Corporation | Organic pigment compositions |
US5900213A (en) * | 1993-04-28 | 1999-05-04 | Alcon Laboratories, Inc. | Use of diamines to disinfect and clean contact lenses and preserve ophthalmic compositions |
US6066203A (en) * | 1998-05-01 | 2000-05-23 | Bayer Corporation | Pigment derivatives for waterborne coatings |
WO2013139006A1 (en) * | 2012-03-21 | 2013-09-26 | 大连理工大学 | Anthrapyridone fluorescent dye n-substituted in position 4, preparation method and use thereof |
CN107446374A (en) * | 2017-08-01 | 2017-12-08 | 南京工业大学 | Quinacridone polyquaternary ammonium salt derivatives and preparation method thereof |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1219328B (en) * | 1961-04-19 | 1966-06-16 | Agfa Ag | Process for developing charge images |
US3384565A (en) * | 1964-07-23 | 1968-05-21 | Xerox Corp | Process of photoelectrophoretic color imaging |
US3436321A (en) * | 1966-09-13 | 1969-04-01 | Minnesota Mining & Mfg | Developer compositions and their use in electrolytic electrophotography |
ZA6555105B (en) * | 1967-08-25 | |||
US4271088A (en) | 1978-06-16 | 1981-06-02 | Suntech, Inc. | High selectivity cyanoalkylation process |
GB8400984D0 (en) * | 1984-01-14 | 1984-02-15 | Hepburn C | Polychloroprene rubber |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1766403A (en) * | 1930-06-24 | Weener schtjlemann | ||
US2151518A (en) * | 1935-03-07 | 1939-03-21 | Gen Aniline Works Inc | Azo dyestuff |
US2238485A (en) * | 1939-11-04 | 1941-04-15 | Eastman Kodak Co | Azo compound and material colored therewith |
US2756234A (en) * | 1956-07-24 | Anthrapyridones | ||
US2945849A (en) * | 1957-03-04 | 1960-07-19 | Bayer Ag | Disazo compounds containing a quaternary ammonium group |
US2972508A (en) * | 1955-12-29 | 1961-02-21 | Bayer Ag | Dyeing of polymers of acrylonitrile |
US3139421A (en) * | 1960-03-14 | 1964-06-30 | Parke Davis & Co | Azo compounds and methods for producing same |
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US2297691A (en) * | 1939-04-04 | 1942-10-06 | Chester F Carlson | Electrophotography |
US2713576A (en) * | 1949-07-22 | 1955-07-19 | Rohm & Haas | Preparation of azo compounds |
US2677651A (en) * | 1950-10-09 | 1954-05-04 | State College Of Washington | Sheet for electrical inscription |
US2874101A (en) * | 1952-09-17 | 1959-02-17 | Farnsworth Res Corp | Method of making double-sided mosaic |
US2862816A (en) * | 1954-03-26 | 1958-12-02 | Rca Corp | Method of and means for reducing triboelectric forces in electrophotography |
US2824096A (en) * | 1954-07-13 | 1958-02-18 | Du Pont | Tricyanovinylaryleneazoarylene compounds |
US2857271A (en) * | 1954-09-28 | 1958-10-21 | Rca Corp | Electrostatic printing process for producing photographic transparencies |
US2854386A (en) * | 1955-02-07 | 1958-09-30 | Aladdin Ind Inc | Method of photographically printing conductive metallic patterns |
BE561403A (en) * | 1956-03-30 |
-
0
- NL NL263729D patent/NL263729A/xx unknown
- US US3172827D patent/US3172827A/en not_active Expired - Lifetime
-
1961
- 1961-04-17 DE DEM48723A patent/DE1177005B/en active Pending
- 1961-04-17 CH CH452161A patent/CH455522A/en unknown
- 1961-04-18 GB GB14061/61A patent/GB990972A/en not_active Expired
- 1961-04-18 GB GB44060/63A patent/GB990973A/en not_active Expired
- 1961-04-18 FR FR859407A patent/FR1290454A/en not_active Expired
-
1963
- 1963-06-14 NO NO149036A patent/NO122384B/no unknown
-
1964
- 1964-05-07 US US370751A patent/US3418322A/en not_active Expired - Lifetime
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1766403A (en) * | 1930-06-24 | Weener schtjlemann | ||
US2756234A (en) * | 1956-07-24 | Anthrapyridones | ||
US2151518A (en) * | 1935-03-07 | 1939-03-21 | Gen Aniline Works Inc | Azo dyestuff |
US2238485A (en) * | 1939-11-04 | 1941-04-15 | Eastman Kodak Co | Azo compound and material colored therewith |
US2972508A (en) * | 1955-12-29 | 1961-02-21 | Bayer Ag | Dyeing of polymers of acrylonitrile |
US2945849A (en) * | 1957-03-04 | 1960-07-19 | Bayer Ag | Disazo compounds containing a quaternary ammonium group |
US3139421A (en) * | 1960-03-14 | 1964-06-30 | Parke Davis & Co | Azo compounds and methods for producing same |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3753708A (en) * | 1971-03-29 | 1973-08-21 | Xerox Corp | Photoelectrophoretic imaging process employing quinacridone pigments |
US4317682A (en) * | 1979-08-27 | 1982-03-02 | Toyo Ink Manufacturing Co. Ltd. | Pigment compositions and use thereof |
US4310359A (en) * | 1980-02-25 | 1982-01-12 | Toyo Ink Manufacturing Co., Ltd. | Pigment compositions |
US5900213A (en) * | 1993-04-28 | 1999-05-04 | Alcon Laboratories, Inc. | Use of diamines to disinfect and clean contact lenses and preserve ophthalmic compositions |
US5698024A (en) * | 1996-12-31 | 1997-12-16 | Bayer Corporation | Organic pigment compositions |
US5711800A (en) * | 1996-12-31 | 1998-01-27 | Bayer Corporation | Organic pigment compositions |
US5879444A (en) * | 1997-09-02 | 1999-03-09 | Bayer Corporation | Organic pigment compositions |
US6066203A (en) * | 1998-05-01 | 2000-05-23 | Bayer Corporation | Pigment derivatives for waterborne coatings |
WO2013139006A1 (en) * | 2012-03-21 | 2013-09-26 | 大连理工大学 | Anthrapyridone fluorescent dye n-substituted in position 4, preparation method and use thereof |
CN107446374A (en) * | 2017-08-01 | 2017-12-08 | 南京工业大学 | Quinacridone polyquaternary ammonium salt derivatives and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
US3172827A (en) | 1965-03-09 |
NL263729A (en) | |
GB990973A (en) | 1965-05-05 |
NO122384B (en) | 1971-06-21 |
GB990972A (en) | 1965-05-05 |
CH455522A (en) | 1968-07-15 |
DE1177005B (en) | 1964-08-27 |
FR1290454A (en) | 1962-04-13 |
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