US3412044A - Diamine soap as dispersant in magnetic tape formulations - Google Patents

Diamine soap as dispersant in magnetic tape formulations Download PDF

Info

Publication number
US3412044A
US3412044A US461170A US46117065A US3412044A US 3412044 A US3412044 A US 3412044A US 461170 A US461170 A US 461170A US 46117065 A US46117065 A US 46117065A US 3412044 A US3412044 A US 3412044A
Authority
US
United States
Prior art keywords
soap
diamine
dispersant
magnetic tape
magnetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US461170A
Other languages
English (en)
Inventor
Graubart Lawrence
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ampex Corp
Original Assignee
Ampex Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ampex Corp filed Critical Ampex Corp
Priority to US461170A priority Critical patent/US3412044A/en
Priority to DEA52561A priority patent/DE1285004B/de
Priority to GB24004/66A priority patent/GB1079609A/en
Priority to BE681701D priority patent/BE681701A/xx
Priority to FR63665A priority patent/FR1481679A/fr
Priority to NL6607670A priority patent/NL6607670A/xx
Application granted granted Critical
Publication of US3412044A publication Critical patent/US3412044A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/62Record carriers characterised by the selection of the material
    • G11B5/68Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent
    • G11B5/70Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer
    • G11B5/7013Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer characterised by the dispersing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • C08L75/06Polyurethanes from polyesters
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/62Record carriers characterised by the selection of the material

Definitions

  • This invention relates to magnetic recording tapes and, more particularly, relates to magnetic recording tapes wherein a novel fatty acid soap of a long chain diamine is used as a dispersing agent informing a dispersion of the magnetic iron oxide utilized in making the recording tape.
  • the dispersant mixture contains at least 50% of the diamine soap in order to secure effective results.
  • the novel dispersant was employed in conjunction with a polyurethane resin system.
  • the particular polyurethane employed is sold under the trade name of Estane 5701 by B. F. Goodrich.
  • This particular polyurethane was made by reacting p-p'- diphenylmethane diisocyanate, adipic acid and butanediol- 1,4 in such proportions that all of the isocyanate groups have reacted to give a substantially unreactive polymer having the following characteristics:
  • This polyurethane resin can be used either alone or in combination with other resins such as a vinyl chloridevinyl acetate copolymer.
  • the particular copolymer selected is one sold under the trade name VAGH by Union Carbide and Chemical Corporation.
  • This particular vinyl chloride-vinyl acetate copolymer contains approximately: 91% vinyl chloride; 3% vinyl acetate; 6% vinyl alcohol.
  • This copolymer has an intrinsic viscosity in cyclohexanone at 20 C. of 0.57 c.p.s. and a specific gravity of 1.39.
  • a novel fatty acid soap of a long chain diamine is employed to replace all or part of the licithin which is normally used in pre paring dispersions of magnetic iron oxides.
  • One particularly suitable fatty acid soap is sold under the trade name Troykyd 98C, and this is a soap made by reacting stoichiometric amounts of a saturated fatty acid having from 12 to 18 carbon atoms and a diamine having from 12 to 18 carbon atoms in each chain.
  • Troykyd 98C has a molecular weight of about 490. As the following examples show, this can be effectively combined with lecithin for use as a dispersant or it can be used along as a dispersant.
  • Components 1 to 5 are dispersed in a pebble-mill using appropriate amounts of methylethyl ketone, methylisobutyl ketone and toluol for 48 hours. At the end of this grinding period a solution of the binder in similar solvents is added and grinding is continued for 24 hours. This mixture is then coated on a plastic base and dried.
  • Example 3 The dispersion and coating of this example is the same as Example 1.
  • the improvement consisting essentially of employing as a dispersing agent a diamine soap having a molecular weight of about 490; said soap being made from a fatty acid having 12 to 18 carbon atoms and a diamine having from 12. to 18 carbon atoms in each chain.
  • the dispersant comprises a mixture of the long chain fatty acid-diamine soap and lecithin, wherein the amine soap constitutes at least one half of the dispersant.
US461170A 1965-06-03 1965-06-03 Diamine soap as dispersant in magnetic tape formulations Expired - Lifetime US3412044A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US461170A US3412044A (en) 1965-06-03 1965-06-03 Diamine soap as dispersant in magnetic tape formulations
DEA52561A DE1285004B (de) 1965-06-03 1966-05-18 Verfahren zur Herstellung eines magnetisierbaren Aufzeichnungstraegers
GB24004/66A GB1079609A (en) 1965-06-03 1966-05-27 Improvements in or relating to magnetic iron oxide dispersions suitable for magnetic recording media
BE681701D BE681701A (xx) 1965-06-03 1966-05-27
FR63665A FR1481679A (fr) 1965-06-03 1966-06-01 Agent dispersant perfectionné pour la préparation d'une dispersion d'un oxyde de fer magnétique dans un solvant organique
NL6607670A NL6607670A (xx) 1965-06-03 1966-06-02

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US461170A US3412044A (en) 1965-06-03 1965-06-03 Diamine soap as dispersant in magnetic tape formulations

Publications (1)

Publication Number Publication Date
US3412044A true US3412044A (en) 1968-11-19

Family

ID=23831478

Family Applications (1)

Application Number Title Priority Date Filing Date
US461170A Expired - Lifetime US3412044A (en) 1965-06-03 1965-06-03 Diamine soap as dispersant in magnetic tape formulations

Country Status (5)

Country Link
US (1) US3412044A (xx)
BE (1) BE681701A (xx)
DE (1) DE1285004B (xx)
GB (1) GB1079609A (xx)
NL (1) NL6607670A (xx)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1431854A (en) * 1972-04-07 1976-04-14 Sony Corp Magnetic recording media and methods of making them
DE3128013C1 (de) * 1981-07-15 1982-11-11 Siemens Ag Ansteuerschaltung fuer wenigstens eine lichtemittierende Diode

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3149996A (en) * 1960-11-16 1964-09-22 Basf Ag Magnetic record member
US3262812A (en) * 1964-03-26 1966-07-26 Gen Electric Magnetic recording tape with magnetic layer of oxide coated iron-cobalt alloy particles in a binder

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3149996A (en) * 1960-11-16 1964-09-22 Basf Ag Magnetic record member
US3262812A (en) * 1964-03-26 1966-07-26 Gen Electric Magnetic recording tape with magnetic layer of oxide coated iron-cobalt alloy particles in a binder

Also Published As

Publication number Publication date
GB1079609A (en) 1967-08-16
NL6607670A (xx) 1966-12-05
BE681701A (xx) 1966-10-31
DE1285004B (de) 1968-12-12

Similar Documents

Publication Publication Date Title
US3247017A (en) Magnetic recording tape for sound, image and pulse recording
US3320090A (en) Phenoxy-polyurethane magnetic tape binder
US3149995A (en) Magnetic recording element and method of preparation thereof
DE3152313T1 (xx)
US4544601A (en) Magnetic recording medium
US4115290A (en) Magnetic recording medium
US4234438A (en) Magnetic recording medium
US3647539A (en) Magnetic recording tape and method for preparing the same
DE3023799A1 (de) Magnetisches aufzeichnungsmedium
US3412044A (en) Diamine soap as dispersant in magnetic tape formulations
US3558353A (en) Magnetic recording medium
US4671995A (en) Magnetic recording medium comprising an undercoating made of a mixture of thermosetting polyurethane and polyester resins
US4579778A (en) Magnetic recording medium
US3681137A (en) Magnetic recording media
DE3414926C2 (de) Magnetisches Aufzeichnungsmedium
EP0150005B1 (de) Magnetisches Speichermedium
US4414288A (en) Magnetic recording medium
JPH0263251B2 (xx)
US4404260A (en) Magnetic recording medium and method of manufacture
US4370383A (en) Magnetic recording medium
DE3151590A1 (de) Verfahren zur herstellung magnetischer aufzeichnungstraeger
JPS5857815B2 (ja) ジキキロクタイ
DE3423014C2 (xx)
DE3438431A1 (de) Magnetaufzeichnungsmedien mit einem gehalt an feinen teilchen von organokieselgel in der magnetischen aufzeichnungsschicht
EP0238116A1 (en) Magnetic recording element