US3391450A - Process for treating wire - Google Patents

Process for treating wire Download PDF

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US3391450A
US3391450A US437075A US43707565A US3391450A US 3391450 A US3391450 A US 3391450A US 437075 A US437075 A US 437075A US 43707565 A US43707565 A US 43707565A US 3391450 A US3391450 A US 3391450A
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wire
tin
bath
capstan
annealing
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US437075A
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Gordon L Bauer
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Advanced Wyrepak Co Inc
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Advanced Wyrepak Co Inc
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Assigned to KOVALESKI, MILDRED, KOVALESKI, JOSEPH J. reassignment KOVALESKI, MILDRED SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: WYREPAK INDUSTRIES, INC.
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/08Tin or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/08Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/38Wires; Tubes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4998Combined manufacture including applying or shaping of fluent material
    • Y10T29/49982Coating
    • Y10T29/49986Subsequent to metal working

Definitions

  • ABSTRACT OF THE DISCLOSURE A method of continuously processing wire containing a high percentage of copper, which involves pulling the wire through a reducing die and around a powered capstan to reduce its diameter and raise its temperature. The wire is then immediately, without cooling or bending or otherwise physically altering it, pulled through a molten tin bath to coat and simultaneously anneal the wire. Added heat may be imparted to the wire without contamination by means of an electric current passed through the wire via the pulling capstans as the wire passes through the tin bath.
  • This invention relates to wire treatment, and more particularly to wire drawing, coating and annealing.
  • An object of the invention is to provide a novel and improved method of and apparatus for continuously drawing, coating and annealing wire of the type containing a high percentage of copper, such as copper wire and brass wire, by which increased production is obtained with lower costs.
  • Another object of the invention is to provide an improved method and apparatus as above set forth, which produces a high quality in the finished product.
  • a further object of the invention is to provide an improved method and apparatus as characterized, which are especially simple, eliminating steps and equipment heretofore necessary in performing the operations of drawing, tinning and annealing.
  • the single figure of the drawing is a diagrammaticschematic representation of the improved and simplified wire treatment apparatus as provided by the invention, and which utilizes the improved method or process.
  • the broken-outline box 10 indicates a conventional wire drawing machine having a pay-off means 12 from which there is brought a wire strand 14.
  • the wire 14 is of copper, or has a high copper content, such as brass wire or other similar alloys.
  • the wire 14 is brought around a capstan 16 and then through a reducing die 18, by which the diameter is made smaller.
  • the wire 14 is then brought around a payout capstan 20, from which latter it is pulled in leaving the machine.
  • the wire 14 is not at this point stored or cleaned or provided with flux, or subjected to any similar operations. Instead, from the capstan 20 the wire 14 is brought directly and while in motion into a tin pot 22, being led into the molten tin from side areas thereof, as through inlet and exit dies 24, 26 respectively having their openings located below the level or top surface of the tin during the operation of the equipment.
  • the dies 24, 2-6 have bores which are only slightly larger than the wire 14 in diameter, whereby no reduction in the size of the wire is effected but instead an entry and exit is provided which does not permit leakage of the molten tin at these points.
  • the heat imparted to the wire 14 during working in the die 18 is not largely lost by passing the wire over the pulling capstan 20, for the reason that the capstan temperature increases above the ambient, and for the further reason that heat transmission from the wire to the capstan is low due to the small areas of contact between these elements.
  • the wire 14 in leaving the capstan 20 has an appreciably raised temperature, which in conjunction with the high temperature of the tin bath, results in a satisfactory coating of tin on the wire as well as an annealing of the wire.
  • the wire 14 After leaving the tin bath 22, the wire 14 passes into a water cooling tank or bath 30 and thereafter passes out of the water cooling bath through an airwiper 32 which removes the moisture and effects a drying of the wire. The wire 14 then passes around another pulling or powered capstan 34, which is the means by which the wire is pulled through the dies 24, 26, the tin bath 22, the water cooling bath 30 and the airwiper 32, and pulled around and from the capstan 20. From the capstan 34 the wire 14 which is now coated with tin and annealed, passes to a spooling machine 36 where it is placed on spools for shipment and use.
  • a spooling machine 36 From the capstan 34 the wire 14 which is now coated with tin and annealed, passes to a spooling machine 36 where it is placed on spools for shipment and use.
  • an electric heating current is provided.
  • Such current may come from a transformer secondary 38 having leads 40, 42 connected by means of suitable brushes 44, 46 to the capstans 20, 34.
  • the voltage and current may be regulated as required, depending on the size of the wire, the resistance of the contacts established between the wire and the capstans 20, 34 and other conditions involved with the coating and annealing.
  • the side entry of the wire into the bath 22 is also considered to contribute to the success of my simplified drawing, coating and annealing process, as at present understood.
  • essentially the improved process comprises pulling the wire through a die to reduce its diameter and raise its temperature, and immediately thereafter and at a closely adjacent point pulling the wire through a molten tin bath to coat the wire with tin and simultaneously to anneal the wire.
  • Such process eliminates intermediate steps and equipment, and enables treatment in the manner explained at a very high rate of speed whereby increased productivity is obtained with the use of fewer pieces of equipment.
  • the process is such that the wire in being brought directly into the tin bath is also perfectly clean and free of surface oxide and surface dirt, not only because of the high speed but also since it does not pass through the top surface of the tin bath.
  • the equipment is seen to eliminate bending of the wire during the tinning, annealing and water cooling. This reduces the likelihood of the wire breaking while being bent or flexed at higher annealing temperatures, where tensile strengths are considerably reduced. It also enables higher tinning and annealing speeds to be had. With the present process there is not required the cleaning of wire with acid or other means, which normally is practiced if the wire in leaving the drawing machine is stored on spools and coated at a later time.

Description

July 9, 1968 5 BAQER} v I 3,391,450
PROCESS FOR TREATING WIRE Filed March 4, 1965 INVENTOR.
Gowlon L. Bauer United States Patent ice 3,391,450 PROCESS FOR TREATING WIRE Gordon L. Bauer, Shelton, Conn, assignor to Advanced Wyrepak Company, Inc, Bridgeport, Conn., a corporation of Connecticut Filed Mar. 4, 1965, Ser. No. 437,075 7 Claims. (Cl. 29-528) ABSTRACT OF THE DISCLOSURE A method of continuously processing wire containing a high percentage of copper, which involves pulling the wire through a reducing die and around a powered capstan to reduce its diameter and raise its temperature. The wire is then immediately, without cooling or bending or otherwise physically altering it, pulled through a molten tin bath to coat and simultaneously anneal the wire. Added heat may be imparted to the wire without contamination by means of an electric current passed through the wire via the pulling capstans as the wire passes through the tin bath.
This invention relates to wire treatment, and more particularly to wire drawing, coating and annealing.
An object of the invention is to provide a novel and improved method of and apparatus for continuously drawing, coating and annealing wire of the type containing a high percentage of copper, such as copper wire and brass wire, by which increased production is obtained with lower costs.
Another object of the invention is to provide an improved method and apparatus as above set forth, which produces a high quality in the finished product.
A further object of the invention is to provide an improved method and apparatus as characterized, which are especially simple, eliminating steps and equipment heretofore necessary in performing the operations of drawing, tinning and annealing.
Features of the invention reside in the provision of an apparatus as above outlined, which is efiicient and etfective, easily used and put into practice, and which requires a minimum of upkeep and maintenance.
Other features and advantages will hereinafter appear.
The single figure of the drawing is a diagrammaticschematic representation of the improved and simplified wire treatment apparatus as provided by the invention, and which utilizes the improved method or process.
As shown, the broken-outline box 10 indicates a conventional wire drawing machine having a pay-off means 12 from which there is brought a wire strand 14. The wire 14 is of copper, or has a high copper content, such as brass wire or other similar alloys. The wire 14 is brought around a capstan 16 and then through a reducing die 18, by which the diameter is made smaller. The wire 14 is then brought around a payout capstan 20, from which latter it is pulled in leaving the machine.
In accordance with the present invention, the wire 14 is not at this point stored or cleaned or provided with flux, or subjected to any similar operations. Instead, from the capstan 20 the wire 14 is brought directly and while in motion into a tin pot 22, being led into the molten tin from side areas thereof, as through inlet and exit dies 24, 26 respectively having their openings located below the level or top surface of the tin during the operation of the equipment. The dies 24, 2-6 have bores which are only slightly larger than the wire 14 in diameter, whereby no reduction in the size of the wire is effected but instead an entry and exit is provided which does not permit leakage of the molten tin at these points.
I have found that it is possible to successfully coat a copper or copper containing wire with tin or tin alloys 3,391,45fl Patented July 9, 1968 without precleaning the wire 14 or fiuxing it, by means of the above procedure and process, and also that a satisfactory annealing of the wire may be accomplished by virtue of the heat to which it is subjected in the tin bath or pot 22. In part I attribute the success of this process to the heating effect of the drawing die 18, which reduces the wire diameter. Such working of the wire causes heat in the wire, presumably due to molecular friction as well as the friction between the die surfaces and the exterior or peripheral surfaces of the wire. The heat imparted to the wire 14 during working in the die 18 is not largely lost by passing the wire over the pulling capstan 20, for the reason that the capstan temperature increases above the ambient, and for the further reason that heat transmission from the wire to the capstan is low due to the small areas of contact between these elements. Thus, the wire 14 in leaving the capstan 20 has an appreciably raised temperature, which in conjunction with the high temperature of the tin bath, results in a satisfactory coating of tin on the wire as well as an annealing of the wire.
After leaving the tin bath 22, the wire 14 passes into a water cooling tank or bath 30 and thereafter passes out of the water cooling bath through an airwiper 32 which removes the moisture and effects a drying of the wire. The wire 14 then passes around another pulling or powered capstan 34, which is the means by which the wire is pulled through the dies 24, 26, the tin bath 22, the water cooling bath 30 and the airwiper 32, and pulled around and from the capstan 20. From the capstan 34 the wire 14 which is now coated with tin and annealed, passes to a spooling machine 36 where it is placed on spools for shipment and use.
To supply additional heat to the travelling wire 14 as it passes through the tin bath 22 an electric heating current is provided. Such current may come from a transformer secondary 38 having leads 40, 42 connected by means of suitable brushes 44, 46 to the capstans 20, 34. The voltage and current may be regulated as required, depending on the size of the wire, the resistance of the contacts established between the wire and the capstans 20, 34 and other conditions involved with the coating and annealing.
It will now be understood from the foregoing that I have provided a novel and improved, greatly simplified method and apparatus for continuously drawing, coating and annealing copper wire and wire containing a high percentage of copper. Between the wire drawing machine 10 and the tin bath 22 no intermediate steps nor equipment are required, such as cleaning baths, storage facilities if the wire is to be first spooled, fluxing baths and the like. Instead, the wire in leaving the wire drawing machine 10 passes into the tinning bath 22 from a side thereof whereby it is not contaminated by dirt, sludge, oxides and the like normally existing at the top surface of the bath.
The side entry of the wire into the bath 22 is also considered to contribute to the success of my simplified drawing, coating and annealing process, as at present understood. However, essentially the improved process comprises pulling the wire through a die to reduce its diameter and raise its temperature, and immediately thereafter and at a closely adjacent point pulling the wire through a molten tin bath to coat the wire with tin and simultaneously to anneal the wire. Such process eliminates intermediate steps and equipment, and enables treatment in the manner explained at a very high rate of speed whereby increased productivity is obtained with the use of fewer pieces of equipment.
The process is such that the wire in being brought directly into the tin bath is also perfectly clean and free of surface oxide and surface dirt, not only because of the high speed but also since it does not pass through the top surface of the tin bath. The equipment is seen to eliminate bending of the wire during the tinning, annealing and water cooling. This reduces the likelihood of the wire breaking while being bent or flexed at higher annealing temperatures, where tensile strengths are considerably reduced. It also enables higher tinning and annealing speeds to be had. With the present process there is not required the cleaning of wire with acid or other means, which normally is practiced if the wire in leaving the drawing machine is stored on spools and coated at a later time.
Variations and modifications may be made within the scope of the claims, and portions of the improvement may be used without others.
I claim:
1. The process of continuously treating wire containing a high percentage of copper, which includes the steps of pulling the wire through a die and around a powered capstan to reduce its diameter and raise its temperature, and immediately thereafter without bending it or reducing its temperature or physically changing the wire and at a closely adjacent point pulling the Wire through a molten tin bath to coat the wire with tin and simultaneously to anneal the wire.
2. The process of claim 1, wherein the wire is pulled into the tin bath through a side thereof.
3. The process of claim 2, wherein the wire is pulled out of the tin bath through a side thereof.
4. The process of claim 3, and including the further steps of pulling the wire leaving the tin bath immediately through a water cooling bath and thereafter spooling the wire.
5. The process of claim 4, and including the further step of passing a heating electric current through that portion of the wire which is travelling through the tin bath and water cooling bath.
6. The process of claim 1, and including the further step of adding heat to the wire without adding contaminants thereto prior to entry of the wire into the tin bath.
7. The process of claim 6, wherein the adding of heat to the wire and the pulling of the wire around the powered capstan are done simultaneously and at the same point.
References Cited UNITED STATES PATENTS 2,047,814 7/1936 Aken 1l751 2,304,069 12/ 1942 Beckwith 11751 2,382,868 8/1945 Fink. 2,511,274 6/1950 Kramer 1l7128 X 2,656,283 10/1953 Fink et al l17128 X JOHN F. CAMPBELL, Primary Examiner. J. L. CLINE, Assistant Examiner.
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3642523A (en) * 1967-04-26 1972-02-15 Siemens Ag Method and device for producing tin layers of {22 3{82 {0 on copper and copper alloy wire by hot tin plating
US3650017A (en) * 1969-10-02 1972-03-21 Licencia Method and apparatus for coating a workpiece with solder
US3779055A (en) * 1967-12-28 1973-12-18 Manuf De Fils Isoles Taurus Apparatus and method for manufacturing insulated conductive wires
FR2565255A1 (en) * 1984-06-01 1985-12-06 Edelhoff Adolf Feindrahtwerk PROCESS FOR PRODUCING ETAMES YARNS
AT388123B (en) * 1986-05-23 1989-05-10 Evg Entwicklung Verwert Ges Installation for drawing, annealing and zinc-plating iron or steel wire at high working speed
US5015496A (en) * 1989-01-03 1991-05-14 Vining Industries, Inc. Process for applying a protective coating to handles
WO1994026435A1 (en) * 1993-05-08 1994-11-24 United Wire Limited Wire plating
FR2749324A1 (en) * 1996-06-04 1997-12-05 Thermocompact Sa METHOD AND DEVICE FOR ZINC PLATING AN ELECTROEROSION WIRE, AND WIRE THUS OBTAINED
US20090139543A1 (en) * 2007-11-30 2009-06-04 Frank Feustel Reducing copper defects during a wet chemical cleaning of exposed copper surfaces in a metallization layer of a semiconductor device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2047814A (en) * 1930-06-18 1936-07-14 Gen Cable Corp Method for treating metals
US2304069A (en) * 1938-12-14 1942-12-08 American Steel & Wire Co Metal coating process
US2382868A (en) * 1941-12-16 1945-08-14 Metal Alloys Inc Art of metal-coating metals
US2511274A (en) * 1946-04-11 1950-06-13 American Steel & Wire Co Method of straightening and coating wire
US2656283A (en) * 1949-08-31 1953-10-20 Ohio Commw Eng Co Method of plating wire

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2047814A (en) * 1930-06-18 1936-07-14 Gen Cable Corp Method for treating metals
US2304069A (en) * 1938-12-14 1942-12-08 American Steel & Wire Co Metal coating process
US2382868A (en) * 1941-12-16 1945-08-14 Metal Alloys Inc Art of metal-coating metals
US2511274A (en) * 1946-04-11 1950-06-13 American Steel & Wire Co Method of straightening and coating wire
US2656283A (en) * 1949-08-31 1953-10-20 Ohio Commw Eng Co Method of plating wire

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3642523A (en) * 1967-04-26 1972-02-15 Siemens Ag Method and device for producing tin layers of {22 3{82 {0 on copper and copper alloy wire by hot tin plating
US3779055A (en) * 1967-12-28 1973-12-18 Manuf De Fils Isoles Taurus Apparatus and method for manufacturing insulated conductive wires
US3650017A (en) * 1969-10-02 1972-03-21 Licencia Method and apparatus for coating a workpiece with solder
FR2565255A1 (en) * 1984-06-01 1985-12-06 Edelhoff Adolf Feindrahtwerk PROCESS FOR PRODUCING ETAMES YARNS
AT388123B (en) * 1986-05-23 1989-05-10 Evg Entwicklung Verwert Ges Installation for drawing, annealing and zinc-plating iron or steel wire at high working speed
US5015496A (en) * 1989-01-03 1991-05-14 Vining Industries, Inc. Process for applying a protective coating to handles
WO1994026435A1 (en) * 1993-05-08 1994-11-24 United Wire Limited Wire plating
FR2749324A1 (en) * 1996-06-04 1997-12-05 Thermocompact Sa METHOD AND DEVICE FOR ZINC PLATING AN ELECTROEROSION WIRE, AND WIRE THUS OBTAINED
EP0811701A1 (en) * 1996-06-04 1997-12-10 Thermocompact Method of hot-dip-zinc-plating an electroerosion wire and wire obtained
US5966975A (en) * 1996-06-04 1999-10-19 Thermocompact Societe Anonyme Method and device for zinc plating a spark erosion wire, and wire obtained in this way
US20090139543A1 (en) * 2007-11-30 2009-06-04 Frank Feustel Reducing copper defects during a wet chemical cleaning of exposed copper surfaces in a metallization layer of a semiconductor device
US8673087B2 (en) * 2007-11-30 2014-03-18 Advanced Micro Devices, Inc. Reducing copper defects during a wet chemical cleaning of exposed copper surfaces in a metallization layer of a semiconductor device

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Owner name: KOVALESKI, JOSEPH J.

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