US2203063A - Method of treating and coiling wire - Google Patents
Method of treating and coiling wire Download PDFInfo
- Publication number
- US2203063A US2203063A US202715A US20271538A US2203063A US 2203063 A US2203063 A US 2203063A US 202715 A US202715 A US 202715A US 20271538 A US20271538 A US 20271538A US 2203063 A US2203063 A US 2203063A
- Authority
- US
- United States
- Prior art keywords
- wire
- sulling
- treating
- lime
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 12
- 238000004140 cleaning Methods 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 12
- 238000000576 coating method Methods 0.000 description 12
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 11
- 235000011941 Tilia x europaea Nutrition 0.000 description 11
- 239000004571 lime Substances 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 239000007788 liquid Substances 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 5
- 238000005554 pickling Methods 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000005491 wire drawing Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000011437 continuous method Methods 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
- C23C22/76—Applying the liquid by spraying
Definitions
- An object of this invention is to provide an improved method of cleaning or pickling iron or steel rods or wire for the removal of scale acquired during a hot rolling process, and for sulling and/or lime coating the same, and for coiling the rods or wire thus treated, all as a continuous process applied to a strand, or preferably many parallel strands, of the wire running continuously through the apparatus.
- the word "wire as used in the specification and claims is intended for convenience to include both rods and wire of all shapes and sizes which are subject to the processes disclosed therein.
- Another object is the provision of means for varying the amount of pickling, sulling, liming or the like, applied to each wire individually while it travels at a uniform speed through the baths and other treating apparatus. It will be understood that while only a single strand of wire isshown, this process adapts itself advantageously to the use of a number of parallel strands of wire, each being drawn independently of the others through the various baths, or other treating apparatus.
- Fig. 2 is a vertical section of a modified form of cleaning or pickling tank.
- Fig. 1 is shown one form of the apparatus in which a coil of rod III as received from a rod mill is placed on a reel II from which it is unreeled as a rod or wire W. It is then passed through a tank l2 containing a suitable cleaning liquid such as dilute sulphuric acid which removes the scale (iron oxide) acquired by the rod during the process of hot rolling in the rod mill. This acid while partly dissolving the scale removes it principally by the formation of hydrogen gas between the scale and the rod, thus If a sull coating is desired, the wire then passes to a sulling well it where a coat of "sull i. e. iron rust is applied to act as a lubricant for later wire drawing operations.
- a suitable cleaning liquid such as dilute sulphuric acid which removes the scale (iron oxide) acquired by the rod during the process of hot rolling in the rod mill.
- This acid while partly dissolving the scale removes it principally by the formation of hydrogen gas between the scale and the
- the thickness of this sull coat may vary from a slight green to a very 5 dark brown depending on the use to which the wire is to be put.
- the sulling well which is preferably relatively deep and narrow is provided with a sheave l5 located near the top over which the wire passes, thence down to pass under a 10 sheave l8 joumaled at the bottom of a frame I! and up over a sheave l8, thus completing a loop.
- the frame is suspended as by a rope l9 attached to a hoist or the like (not shown) by means of which the frame may be raised and 15 lowered in the well at will to increase or decrease the length of wire exposed to the sulling action.
- Nozzles 20 serve to spray water or steam on the wire, and the well may be heated by steam pipes 2
- the wire may pass into a lime bath 23 where the wire acquires a coating of lime which acts as a lubricant to improve the drawing qualities of the wire and thence passes through a baking oven 24 which 30 is highly heated by any well known means so as to bake the lime on the wire, preferably in a matter of seconds.
- Sal soda and other chemicals in solution may be substituted for the lime for certain purposes, and baking may sometimes be 35 dispensed with.
- the wire passes to one of the coiling machines 25v where it is again coiled for shipping or storage preliminary to drawing into wire of smaller gauges, the pull of the coiling 40 machines providing a power for drawing the wire through the apparatus.
- the wire in the form of coils, as received from the mill may undergo an initial cleaning in the usual manner, if desired, by sulling while 45 still in coils, the wire being then uncoiled for liming and baking treatment in strands preliminary to drawing operations.
- All the apparatus shown and described is intended primarily for use with a number of parallel strands of wire, each running continuously and independently through the apparatus.
- adjacent strands may be of different size or composition and may be running at very diflerent speeds.
- Fig. 2 is shown a modified formof cleaning tank which, like the sulling well, is relatively deep and narrow to permit the wire W to pass over a pulley 3
- An electric generator 34 or other source of direct current is connected on its positive pole to the sheaves 3
- the anode and cathode are located in a suitable electrolyte such as dilute sulphuric acid.
- lead or other suitable metal may be plated on the treated wire which then passes into a bath similar to that of Fig. 2' whre the process is reversed and the plating material removed, the scale being removed at the same time. All cleaningsteps using an electrolyte or pickling bath are preferably followed by washing with clean water preliminary to travel of the wire into the sulling chamber.
- the wires may also receive an initial heat treatment in which case they can be handled as strands by being passed through a heat treating furnace or the like, then allowed to cool preliminary to annealing; or quenched, if the wires are to be heat treated for tempering or hardening; the process, as to its remaining steps prior to wire drawing, being thereafter continued, 1. 12.,
- the heat treating furnace may be of any conventional type, depending on whether the wire is processedwire, patented wire, spring wire or the like.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Cleaning By Liquid Or Steam (AREA)
Description
June 4, 1940. J HUELER 2,203,063
METHOD OF TREATING AND G OILING WIRE Filed April 18, 1938 0 OOOOOOOOOOOOOQOOOOOOOOOO O O SULLl/VG CLEAN/N6 Patented June 4, 1940 UNITED STATES PATENT OFFICE 2,203,063 METHOD or TREATING AND comma wmn Application April 18, 1938, Serial No. 202,715
3Claims.
An object of this invention is to provide an improved method of cleaning or pickling iron or steel rods or wire for the removal of scale acquired during a hot rolling process, and for sulling and/or lime coating the same, and for coiling the rods or wire thus treated, all as a continuous process applied to a strand, or preferably many parallel strands, of the wire running continuously through the apparatus. The word "wire as used in the specification and claims is intended for convenience to include both rods and wire of all shapes and sizes which are subject to the processes disclosed therein.
Another object is the provision of means for varying the amount of pickling, sulling, liming or the like, applied to each wire individually while it travels at a uniform speed through the baths and other treating apparatus. It will be understood that while only a single strand of wire isshown, this process adapts itself advantageously to the use of a number of parallel strands of wire, each being drawn independently of the others through the various baths, or other treating apparatus.
These objects, as well as others which will hereinafter appear, are accomplished by this invention which is fully described in the following specification and shown in the accompanying drawing, in which- Figure 1 is a diagrammatic view, partly in vertical section, showing my apparatus for cleaning, sulling, liming, baking and coiling rods or wires; and
Fig. 2 is a vertical section of a modified form of cleaning or pickling tank.
In Fig. 1 is shown one form of the apparatus in which a coil of rod III as received from a rod mill is placed on a reel II from which it is unreeled as a rod or wire W. It is then passed through a tank l2 containing a suitable cleaning liquid such as dilute sulphuric acid which removes the scale (iron oxide) acquired by the rod during the process of hot rolling in the rod mill. This acid while partly dissolving the scale removes it principally by the formation of hydrogen gas between the scale and the rod, thus If a sull coating is desired, the wire then passes to a sulling well it where a coat of "sull i. e. iron rust is applied to act as a lubricant for later wire drawing operations. The thickness of this sull coat may vary from a slight green to a very 5 dark brown depending on the use to which the wire is to be put. The sulling well which is preferably relatively deep and narrow is provided with a sheave l5 located near the top over which the wire passes, thence down to pass under a 10 sheave l8 joumaled at the bottom of a frame I! and up over a sheave l8, thus completing a loop. The frame is suspended as by a rope l9 attached to a hoist or the like (not shown) by means of which the frame may be raised and 15 lowered in the well at will to increase or decrease the length of wire exposed to the sulling action. Nozzles 20 serve to spray water or steam on the wire, and the well may be heated by steam pipes 2| thereby maintaining an atmosphere where 99 sulling takes place rapidly. Any water collecting in the well passes out through the drain 22. It will be understood that sulling may be omitted for certain forms of continuous wire drawing machines.
As the wire leaves the sulling well, it may pass into a lime bath 23 where the wire acquires a coating of lime which acts as a lubricant to improve the drawing qualities of the wire and thence passes through a baking oven 24 which 30 is highly heated by any well known means so as to bake the lime on the wire, preferably in a matter of seconds. Sal soda and other chemicals in solution may be substituted for the lime for certain purposes, and baking may sometimes be 35 dispensed with.
After coating, the wire passes to one of the coiling machines 25v where it is again coiled for shipping or storage preliminary to drawing into wire of smaller gauges, the pull of the coiling 40 machines providing a power for drawing the wire through the apparatus. As an alternative procedure, the wire in the form of coils, as received from the mill, may undergo an initial cleaning in the usual manner, if desired, by sulling while 45 still in coils, the wire being then uncoiled for liming and baking treatment in strands preliminary to drawing operations.
After one coil is unwound from the reel Ii, another coil is mounted thereon, and the for- 50 ward end of the new coil is attached to the rear end of the coil that is just unwound, preferably by welding, so that the process is continuous.
All the apparatus shown and described is intended primarily for use with a number of parallel strands of wire, each running continuously and independently through the apparatus. Thus adjacent strands may be of different size or composition and may be running at very diflerent speeds.
In Fig. 2 is shown a modified formof cleaning tank which, like the sulling well, is relatively deep and narrow to permit the wire W to pass over a pulley 3| and thence down and under a pulley 32 and up over a pulley 33 to complete a loop. An electric generator 34 or other source of direct current is connected on its positive pole to the sheaves 3|, 33, so as to make the loop of wire the anode of a cell while an electrode 35 of any suitable metal serves as a cathode and is connected to the negative pole of the generator 34. The anode and cathode are located in a suitable electrolyte such as dilute sulphuric acid. As current of low voltage and heavy amperage passes through the electrolyte, hydrogen is formed between the wire and its oxide scale which causes the latter to raise and drop 01?. By this use of electric current the scale is removed much more rapidly and efilciently than where the pickling is done without the use of current.
As a modification of this cleaning process, tin,
. lead or other suitable metal may be plated on the treated wire which then passes into a bath similar to that of Fig. 2' whre the process is reversed and the plating material removed, the scale being removed at the same time. All cleaningsteps using an electrolyte or pickling bath are preferably followed by washing with clean water preliminary to travel of the wire into the sulling chamber.
The wires may also receive an initial heat treatment in which case they can be handled as strands by being passed through a heat treating furnace or the like, then allowed to cool preliminary to annealing; or quenched, if the wires are to be heat treated for tempering or hardening; the process, as to its remaining steps prior to wire drawing, being thereafter continued, 1. 12.,
through the steps of cleaning, liming and baking, with, or without, sulling. The heat treating furnace may be of any conventional type, depending on whether the wire is processedwire, patented wire, spring wire or the like.
-I claim:
1. The continuous methed of successively treating portions of a strand of iron or steel wire comprising removing scale from the wire, causing a portion of said wire to travel in a loop while sulling the wire to produce a rust'coating thereon, coating the wire with lime, and baking the lime, the wire traveling continuously. I
2. The continuous method of successively treating portions of a plurality of strands of iron and steel wire comprising passing each strand through a tank containing a cleaning liquid to remove scale, washing the wire to remove the cleaning liquid, causing a portion of said wire strands to travel in elongated loops while sulling the wire to produce a rust coating thereon, varying the lengths of the wire strands traveling in loops to control the amount of rust coating thereon for drawing, coating the wire with lime, and
baking the lime, each strand traveling continuously and independently of the others.
3. The continuous method of successively treating portions of a plurality of strands of iron and'steel wire comprising passing each strand through a tank containing a cleaning liquid. passing an electric current through the wire as an anode in the cleaning liquid to remove scale, washing the wire to remove the cleaning liquid, causinga portion of each wire to travel in'an elongated loop while sulling the wire to produce a rust coating thereon, adjusting the length of wire in said loops to control the amount of sull coating thereon for drawing, coating the wire with lime, and baking the lime, each strand traveling continuously and independently of the others.
- JULIAN L. SCHUELER.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US202715A US2203063A (en) | 1938-04-18 | 1938-04-18 | Method of treating and coiling wire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US202715A US2203063A (en) | 1938-04-18 | 1938-04-18 | Method of treating and coiling wire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2203063A true US2203063A (en) | 1940-06-04 |
Family
ID=22750966
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US202715A Expired - Lifetime US2203063A (en) | 1938-04-18 | 1938-04-18 | Method of treating and coiling wire |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2203063A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2577887A (en) * | 1949-02-12 | 1951-12-11 | Parker Rust Proof Co | Activation of oxalate metal coating compositions |
| US2728696A (en) * | 1948-12-23 | 1955-12-27 | Singer Fritz | Production of oxide coatings on ferrous surfaces and mechanically working the same |
| US2845376A (en) * | 1953-06-09 | 1958-07-29 | Neilson Chemical Company | Method of coating metal surfaces with phosphate |
| US2906238A (en) * | 1955-03-25 | 1959-09-29 | Rome Cable Corp | Apparatus for coating conduit sections |
| US2975506A (en) * | 1954-06-08 | 1961-03-21 | Northwestern Steel & Wire Comp | Apparatus for coating metal articles |
| DE976070C (en) * | 1951-10-26 | 1963-02-07 | Metallgesellschaft Ag | Process for preparing metallic semi-finished products for non-cutting deformation, especially cold deformation |
-
1938
- 1938-04-18 US US202715A patent/US2203063A/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2728696A (en) * | 1948-12-23 | 1955-12-27 | Singer Fritz | Production of oxide coatings on ferrous surfaces and mechanically working the same |
| US2577887A (en) * | 1949-02-12 | 1951-12-11 | Parker Rust Proof Co | Activation of oxalate metal coating compositions |
| DE976070C (en) * | 1951-10-26 | 1963-02-07 | Metallgesellschaft Ag | Process for preparing metallic semi-finished products for non-cutting deformation, especially cold deformation |
| US2845376A (en) * | 1953-06-09 | 1958-07-29 | Neilson Chemical Company | Method of coating metal surfaces with phosphate |
| US2975506A (en) * | 1954-06-08 | 1961-03-21 | Northwestern Steel & Wire Comp | Apparatus for coating metal articles |
| US2906238A (en) * | 1955-03-25 | 1959-09-29 | Rome Cable Corp | Apparatus for coating conduit sections |
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