US3382607A - Figure toy having fibers impregnated with indicator dye - Google Patents

Figure toy having fibers impregnated with indicator dye Download PDF

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Publication number
US3382607A
US3382607A US423382A US42338265A US3382607A US 3382607 A US3382607 A US 3382607A US 423382 A US423382 A US 423382A US 42338265 A US42338265 A US 42338265A US 3382607 A US3382607 A US 3382607A
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United States
Prior art keywords
hair
dye
color
fiber
toy
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US423382A
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English (en)
Inventor
John W Ryan
John F Jones
Pearlman Marshall
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Mattel Inc
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Mattel Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mattel Inc filed Critical Mattel Inc
Priority to US423382A priority Critical patent/US3382607A/en
Priority to ES0311859A priority patent/ES311859A1/es
Priority to NL6504989A priority patent/NL6504989A/xx
Priority to FR17559A priority patent/FR1441822A/fr
Priority to DK281965AA priority patent/DK113905B/da
Priority to GB24348/65A priority patent/GB1117141A/en
Priority to BE665235D priority patent/BE665235A/xx
Priority to CH835165A priority patent/CH450989A/fr
Priority to DE19651478608 priority patent/DE1478608A1/de
Priority to DEM53535U priority patent/DE1932544U/de
Application granted granted Critical
Publication of US3382607A publication Critical patent/US3382607A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
    • D06P1/92—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
    • D06P1/928—Solvents other than hydrocarbons
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
    • A63H3/00—Dolls
    • A63H3/36—Details; Accessories
    • A63H3/44—Dolls' hair or wigs; Eyelashes; Eyebrows
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/004—Dyeing with phototropic dyes; Obtaining camouflage effects
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/13—Fugitive dyeing or stripping dyes
    • D06P5/138—Fugitive dyeing or stripping dyes fugitive dyeing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/913—Material designed to be responsive to temperature, light, moisture

Definitions

  • ABSTRACT OF THE DISCLOSURE A toy, such as a doll, having a visible portion comprising fibers permanently impregnated with an indicator dye capable of repeated and reversible color change in response to contact with liquids of different pH concentrations.
  • the invention relates directly to a mode of dyeing fiber and has direct application in the toy field as related to chlidrens dolls. Specifically the disclosed invention relates to an article produced and a method of use which will enable a child at play to readily dye the dolls hair, thus enhancing the play value of the toy.
  • Coloring dyes per se have been classified or categorized in many ways.
  • the chemist from his vantage point, has often classified the myriad of available dyes from the standpoint of chemical or molecular similarity.
  • the artisan on the other hand, being concerned with the application of color to various prodrfcts, has tended to classify dyes with respect to the properties that determine their use. In this area, the classifications have included acid dyes, azoic compositions, basic dyes, dispersed dyes, fiber-reactive dyes, mordant dyes to name only a few of the general classifications which will be familiar to those skilled in this art.
  • the present invention specifically com-prehends the use of those products which historically have been classified as indicator dyes. More specifically, the present invention is concerned with specific indicator dyes that effectuate a color change in response to a variation in hydrogen-ion concentration which may be defined as pH variation or pH sensitivity. Secondarily, the present invention comprehends pH responsive indicator dyes which have the capacity to initially color or tinge a fiber, and thereafter, in response to pH change, induce a visible color variation of the fiber.
  • Another specific object of the invention is to provide an article of the type described that is relatively stable under all normal use conditions and which will provide the child with a desirable toy over an extended service life.
  • the invention comprehends a mode of fiber dyeing utilizing pH sensitive coloring material as applied to dolls hair, which com prehends a reversible color variation in the dolls hair fiber in response to pH variation thereof.
  • pH has been defined as the negative logarithm of the effective hydrogen-ion concentration or hydrogen-ion activity in gram equivalents per liter of fluid. It is characteristically used for expressing both acidity and alkalinity in a relative manner on an empirical scale of zero to 14, in which 7 represents neutrality: the pH value of pure water at 25 degrees centigrade. Values less than 7 represent increasing hydrogenion concentration and increasing acidity or the acid range. Values greater than 7 represent decreasing hydrogen-ion concentration and increasing alkalinity or the basic range.
  • the indicator dyes here under consideration all exhibit a definite characteristic relative to the pH scale, namely,
  • the scale range through which the color change takes place is usually referred to as the shift range or shift point.
  • the doll industry has characterically utilized as dolls hair certain specific materials including nylon, orlon, viscous rayons, and cellulose acetate products.
  • human or animal hair products have been used to provide dolls hair.
  • the most frequently utilized fibers are in the cellulose acetate group in that they offer many application advantages. For example, they are relatively strong and are capable of being produced in very fine diameters that may be easily Worked by the child from the standpoint of brushing and hair setting.
  • acetate fibers are economical. Their physical and molecular structure is such that they readily take commercially available dyes and, upon impregnation are found to be satisfactorily color fast.
  • the invention as disclosed may be applied to any type of fiber and particularly any fiber that may be appropriate for use as a doll hair material.
  • the single figure of the drawing is illustrative of a portion of a doll embodying the present invention.
  • EXAMPLE 1 In a first illustration of the invention, clear acetate fiber as produced in its natural state and without any dye impregnation is obtained. Quality production control suggests that the fiber be first subjected to a clear water rinse to make it as clean as possible. Thereafter the fiber is preferably bathed in an appropriate alkaline solution to remove any residual acetic acid which may adhere to the fiber as an incident to fiber manufacture. A second clear water rinse may be used to clean the fiber of alkaline solution.
  • a suggested alkali that may be employed is tetrasodium pyrophosphate.
  • a dye solution is then prepared.
  • methyl red sometimes known as Acid Red No. 2
  • an appropriate solute which may comprise methyl alcohol and water in a 50% to 50% ratio, respectively.
  • a satisfactory methyl red dye concentration may be obtained by using /2% by weight of methyl red based on weight of solute.
  • the fiber is then thoroughly soaked in the dye solution for a period in excess of fifteen minutes and at a bath temperature of approximately 125 degrees F.
  • acetate fibers it has been found that the fiber diameter swells considerably as a result of the solute used for the dye.
  • Dye impregnation takes place during solution soaking and the fiber is thor ug y colored n impregnated.
  • the dye actually molecularly enters the fiber to assure a good color set thereon.
  • the fiber is then again rinsed in clear water to accomplish initial removal of loose dye material and any foreign matter that may be adhering to the fiber as a result of the prior process steps.
  • a subsequent rinse employing a conventional detergent and adding a 1% by weight acetic acid solution in water.
  • the loose methyl red dye material fragments are effectively removed from the fiber but the coloring of the fiber per se is not attacked.
  • a subsequent Wash in clear water is suggested until the rinse runs clear.
  • the dolls hair be of uniform color throughout. Accordingly, it is suggested that the fiber be bathed or soaked at room temperature in a mild acid solution. The effect is to set the pH sensitive dye at a concentration on the acid side of its shift range and uniformity of product color results. The fiber is then dried in any suitable manner and it is ready for subsequent processing and use as dolls hair.
  • the child at play merely need obtain an appropriate basic solution having a pH concentration on the basic side of the shift range of the particular dye applied to the doll hair.
  • the child prepares a mild solution thereof in Water.
  • the child rinses the dolls hair therein.
  • the pH sensitive methyl red dye is driven in a basic direction by the reaction. On its acid side the methyl red dye exhibits a bright red color at approximately pH 5 or lower.
  • the hydrogen-ion concentration within the dye is changed and brought to pH 6 or higher, namely, in the basic direction.
  • the hair changes dramatically to a golden yellow.
  • the golden yellow condition obtains regardless of any further change in hydrogen-ion concentration in the basic direction.
  • the reaction may be reversed when the childs play inclination dictates.
  • the pH level of the solution must be below the pH shift range of the methyl red.
  • the pH concentration of the dye is again changed and is driven in an acid direction. As the pH concentration reaches approximately pH 5, the dolls hair resumes its previous bright red coloring.
  • EXAMPLE 2 For this example, we will again assume a natural acetate fiber in a natural or undyed condition. A readily available hydrogen-ion sensitive dye known as alizarine or Mordant Red No. 11 has been found to produce excellent results. A dyeing solution of approximately /2% by weight in methanol is prepared and again a 50% to 50% methanolwater ratio is used. The sequential steps noted above in Example 1 are again followed except that the alizarine solution is substituted for the methyl red solution in the dyeing step of the process. Again, after complete dyeing, the dyed hair is preferably set in the acid range by soaking in a mild acid solution. Using the alizarine indicator dye, the hair fiber presents a uniformly bright yellow color on the acid side of its shift range.
  • alizarine or Mordant Red No. 11 A readily available hydrogen-ion sensitive dye known as alizarine or Mordant Red No. 11 has been found to produce excellent results. A dyeing solution of approximately /2% by weight in methanol is prepared and again a 50% to 50% m
  • the child again prepares a solution having a pH level on the basic side of the alizarine shift range and rinses.
  • the dolls hair dye is driven in a basic direction from its initial pH of approximately 5 or lower to approximately pH 8 or higher, whereat the color changes distinctively to an attractive purple.
  • the application of a mild acid rinse drives the dye in the acid direction and the bright yellow color is resumed as the pH concentration reaches approximatly pH 5.
  • EXAMPLE 3 Another feature of the disclosed invention introduces a desirable quality of flexibility in the production of a variety of doll hair color patterns even though one or a few pH sensitive dyes are used.
  • the acetate fiber is first fast dyed to a first color in any conventional manner with a dye that when set is not pH sensitive. Thereafter, the pH sensitive dye is super-imposed on or applied over the pre-colored fiber in the general manner as above described. This procedure multiplies the available hair color effects many times since combinations of fast dyes and indicator dyes are virtually limitless and the sequential application of an indicator dye of one color over a pre-colored hair fiber produces the visual appearance of a third color.
  • the alizarine dye is superimposed on the base dye of the fiber, and, in the acid condition of the pH sensitive alizarine dye the hair coloring produced is a light brown, rather than the yellow of the prior example.
  • Subsequent rinsing of the hair in a basic solution changes the hydrogen-ion concentration of the dye in the hair with a resulting color change to a startling black.
  • the black hair is subjected to an acid bath as noted above, the original brown color returns.
  • the multiplicity of hair color patterns that may be economically obtained by utilizing the fast dye precoloring procedure enhances the play value of the toy.
  • EXAMPLE 4 The disclosed invention may be subject to another variant as applied to dolls hair to easily produce even further hair color variations.
  • the alizarine dye and the methyl red dye noted above may be combined in an appropriate dyeing solution.
  • a solution is prepared of equal parts of methanol and water, and /2 by weight each of methyl red and alizarine is added.
  • Neutral acetate fiber, without pre-coloring, is then processed and dyed as defined in Example 1. The fiber is then subsequently processed in the described manner and acid set until ready for use as dolls hair.
  • the doll hair thus produced is an attractive auburn color.
  • an appropriate basic rinse solution as above noted, a rather remarkable color change to a pleasing brown ensues.
  • the auburn color may again be obtained by an appropriate acid rinse.
  • indicator dyes utilized and the suggested mode of use. Many commercially available indicator dyes reasonably would fall within the application of the invention and may be employed on an empirical test basis to obtain hair coloring desired. Some other examples of indicator dyes that may be utilized are the following: methyl violet, crystal violet, ethyl violet,
  • malachite green oxalate methyl green, cresol red, quinaldine red, para methyl red, metanil yellow, thymol blue, meta cresol purple, eyrthrosin disodium salt, benzopurpurin 4B, dinitrophenol, congo red, methyl orange-xylene cyanole solution, methyl orange, ethyl orange, methoxybenzenesulfonic acid, bromocresol green, resazurin, ethyl red laomoid, alizarin red, methyl red, propyl red, bromocresol purple, chlorophenol red, nitrophenol, bromothymol blue, dinitrobenzoylene urea, brilliant yellow, phenol red, neutral red, nitrophenol, curcumin, meta cresol purple, thymol blue, cresolphthalein, naphtholbenzein, phenolphthalein, thymalphthalein, alizarin yellow R, to mention only illustrative examples.
  • the utilitarian play value of the toy requires that the child sequentially utilizes acid and basic solutions to achieve the desired color change.
  • the toy may be vended as a unit, that is, as a complete doll having pH sensitive dyed hair, or, a group of doll wigs dyed in a similar manner, together with acid and basic solutions that will satisfactorily coact with the particular dyed hair to achieve the desired color change.
  • Solution concentrations are such that will be non-toxic if accidentally swallowed. In short, the solution concentration would in fact be edible in nature.
  • the toy may be vended as dolls hair together with instructions that the child employ readily available household items in the preparation of the acid and basic solutions required to induce color change.
  • acid and basic solution have relative meaning only with respect to the pH shift range of the particular indicator dye employed. They are not of necessity within the acid scale range or basic scale range with respect to neutral point pH 7, though they very well may be and still achieve the desired result.
  • indicator dyes in the practice of the disclosed invention whose shift point or range falls relatively close to the neutral point 7, as for example within the range 3 to 11, it has been found that conventionally available household items such as citric juices, vinegar or the like function satisfactorily to set the dolls hair at the color level on the acid side of its shift range.
  • methyl red and alizarine dyes noted are illustrative examples.
  • readily available household items such as sodium carbonate, namely, common washing soda, or sodium bicarbonate, frequently used as an antacid for human consumption, are satisfactory to accomplish the pH shift required for color change in the basic direction.
  • the solutions necessary to achieve the desired result may be of relatively weak concentration within the range of one-half percent to 5% by weight.
  • a figure toy having a plurality of fibers defining a portion only of said figure toy, at least a part of said fibers defining a visible portion thereof arranged in predetermined physical configuration, the material of said fibers being permanently impregnated with a dye to a first color, by a pH sensitive indicator dye, whereby the color thereof may be selectively and repeatedly changed to and from said first color and a second color by contact with liquids of predetermined pH concentrations.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Toys (AREA)
  • Coloring (AREA)
  • Artificial Filaments (AREA)
  • Outer Garments And Coats (AREA)
US423382A 1965-01-04 1965-01-04 Figure toy having fibers impregnated with indicator dye Expired - Lifetime US3382607A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
US423382A US3382607A (en) 1965-01-04 1965-01-04 Figure toy having fibers impregnated with indicator dye
ES0311859A ES311859A1 (es) 1965-01-04 1965-04-14 Procedimiento para preparar y teñir fibras artificiales, especialmente de las utilizadas como cabello en las muñecas.
NL6504989A NL6504989A (pl) 1965-01-04 1965-04-20
FR17559A FR1441822A (fr) 1965-01-04 1965-05-19 Jouet comportant des fibres et procédé pour teindre celles-ci
DK281965AA DK113905B (da) 1965-01-04 1965-06-04 Dukkehår af fibermateriale.
GB24348/65A GB1117141A (en) 1965-01-04 1965-06-09 Method of dyeing fibres used in children's toys
BE665235D BE665235A (pl) 1965-01-04 1965-06-10
CH835165A CH450989A (fr) 1965-01-04 1965-06-10 Jouet comportant des fibres teintes à coloration modifiable
DE19651478608 DE1478608A1 (de) 1965-01-04 1965-12-13 Spielzeugperuecke
DEM53535U DE1932544U (de) 1965-01-04 1965-12-13 Spielzeugperuecke.

Applications Claiming Priority (1)

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US423382A US3382607A (en) 1965-01-04 1965-01-04 Figure toy having fibers impregnated with indicator dye

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US3382607A true US3382607A (en) 1968-05-14

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US423382A Expired - Lifetime US3382607A (en) 1965-01-04 1965-01-04 Figure toy having fibers impregnated with indicator dye

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US (1) US3382607A (pl)
BE (1) BE665235A (pl)
CH (1) CH450989A (pl)
DE (2) DE1932544U (pl)
DK (1) DK113905B (pl)
ES (1) ES311859A1 (pl)
FR (1) FR1441822A (pl)
GB (1) GB1117141A (pl)
NL (1) NL6504989A (pl)

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4023925A (en) * 1973-08-16 1977-05-17 Hoechst Aktiengesellschaft Process for obtaining multicolor effects
FR2447735A1 (fr) * 1979-01-30 1980-08-29 Cpg Prod Corp Figurine, notamment poupee
US4781647A (en) * 1987-05-04 1988-11-01 Hasbro, Inc. Toy doll construction with phosphorescent hair fibers
US4917643A (en) * 1987-06-26 1990-04-17 Mattel, Inc. Toy vehicle with thermochromic material
US5277644A (en) * 1993-02-05 1994-01-11 Mattel, Inc. Doll having illuminated color change fiber optic feature
US5346422A (en) * 1992-12-08 1994-09-13 Eastman Chemical Company Toy articles of manufacture comprising spontaneously wettable fibers
US5503583A (en) * 1987-06-26 1996-04-02 Mattel, Inc. Toy with thermochromic material
US5842905A (en) * 1992-02-26 1998-12-01 C.J. Associates, Ltd. Process for making a temporary color change on a plastic material
US6585555B2 (en) 2001-10-18 2003-07-01 Prime Time Toys, Ltd. Temperature sensitive color changing water toy
US6736692B1 (en) 2003-05-30 2004-05-18 Mattel, Inc. Hair styling doll head having color change hair crimper
EP1535599A1 (en) 2003-11-28 2005-06-01 Kao Corporation Method effecting a reversible colour change of dyed hair
US20060004110A1 (en) * 2004-06-17 2006-01-05 Sabnis Ram W Composition and method for producing colored bubbles
US20060222675A1 (en) * 2005-03-29 2006-10-05 Sabnis Ram W Personal care compositions with color changing indicator
US20060222601A1 (en) * 2005-03-29 2006-10-05 Sabnis Ram W Oral care compositions with color changing indicator
US20060236470A1 (en) * 2005-03-29 2006-10-26 Sabnis Ram W Novelty compositions with color changing indicator
US20070010400A1 (en) * 2005-07-06 2007-01-11 Sabnis Ram W Use of color changing indicators in consumer products
US20110079235A1 (en) * 2009-08-26 2011-04-07 Reed Gladys B System, apparatus, and method for hair weaving thread
US8590543B2 (en) 2010-11-17 2013-11-26 Mattel, Inc. Hair extension kit
US20150007847A1 (en) * 2013-07-05 2015-01-08 Vered Nissim Removal system for sewn-in hair extensions, hair weaves, hair augmentation, and wigs
US9364765B2 (en) 2010-08-18 2016-06-14 Mattel, Inc. Toy assembly with blower and color changing features
US11026874B2 (en) 2019-07-31 2021-06-08 L'oreal Systems and methods for changing the color of hair
CN114672996A (zh) * 2022-01-14 2022-06-28 中原工学院 一种二甲酚橙功能化聚乙烯醇纤维的制备方法和应用

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2486533A1 (fr) * 1980-07-08 1982-01-15 Mizoule Henri Composition pour teinture de cheveux artificiels de poupees changeant de couleur en fonction du ph
GB8823976D0 (en) * 1988-10-13 1988-11-23 B T Toy Marketing Artificial hair dyeing
CA2074776C (en) * 1991-09-27 2001-08-14 Minoru Abe Dye composition, dyeing method, and dyed protein fiber
GB0303303D0 (en) * 2003-02-13 2003-03-19 Nita Beverley Mannequin
DE102011003517A1 (de) 2011-02-02 2012-08-02 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Kleidungsstück
CN103590263A (zh) * 2013-11-15 2014-02-19 东华大学 一种pH值变色织物的制备方法
FR3075613B1 (fr) 2017-12-21 2022-06-10 Oreal Procede de traitement des fibres keratiniques mettant en œuvre un colorant direct triarylmethane halochrome, un revelateur alcalin puis un effaceur acide
FR3075616B1 (fr) * 2017-12-21 2022-06-10 Oreal Procede de traitement des fibres keratiniques mettant en œuvre un colorant direct oxazone ou phenazine halochrome, un revelateur puis un effaceur
CN109763355B (zh) * 2019-02-13 2021-09-03 江苏称意智能科技有限公司 一种智能汗液酸碱变色衣物

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US1442248A (en) * 1921-05-03 1923-01-16 Katharine S Brydone-Jack Doll
US1730177A (en) * 1927-08-02 1929-10-01 Lora C Van Cleave Doll for instruction in color
US1814344A (en) * 1930-04-11 1931-07-14 Walter O Snelling Reduction of yellowing of materials with age
US2073723A (en) * 1936-05-06 1937-03-16 Albert E Woolnough Stuffed animal toy
US2108838A (en) * 1935-04-03 1938-02-22 Celanese Corp Artificial material having modified characteristics and method of making same
US2185467A (en) * 1938-10-03 1940-01-02 Rit Products Corp Hair dyeing composition and method
US2464155A (en) * 1945-02-09 1949-03-08 Eastman Kodak Co Stop bath acidity indicator
US2656647A (en) * 1951-02-14 1953-10-27 Daniel G Kennedy Doll or the like
US2695259A (en) * 1949-01-03 1954-11-23 Union Francaise Commerciale Et Industrielle Sa Dermatologically harmless hair dyeing creams
US2953421A (en) * 1954-08-04 1960-09-20 Gen Aniline & Film Corp Anthraquinone dyestuffs
US2960443A (en) * 1956-10-11 1960-11-15 John H Breck Inc Temporary hair coloring composition

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1442248A (en) * 1921-05-03 1923-01-16 Katharine S Brydone-Jack Doll
US1730177A (en) * 1927-08-02 1929-10-01 Lora C Van Cleave Doll for instruction in color
US1814344A (en) * 1930-04-11 1931-07-14 Walter O Snelling Reduction of yellowing of materials with age
US2108838A (en) * 1935-04-03 1938-02-22 Celanese Corp Artificial material having modified characteristics and method of making same
US2073723A (en) * 1936-05-06 1937-03-16 Albert E Woolnough Stuffed animal toy
US2185467A (en) * 1938-10-03 1940-01-02 Rit Products Corp Hair dyeing composition and method
US2464155A (en) * 1945-02-09 1949-03-08 Eastman Kodak Co Stop bath acidity indicator
US2695259A (en) * 1949-01-03 1954-11-23 Union Francaise Commerciale Et Industrielle Sa Dermatologically harmless hair dyeing creams
US2656647A (en) * 1951-02-14 1953-10-27 Daniel G Kennedy Doll or the like
US2953421A (en) * 1954-08-04 1960-09-20 Gen Aniline & Film Corp Anthraquinone dyestuffs
US2960443A (en) * 1956-10-11 1960-11-15 John H Breck Inc Temporary hair coloring composition

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4023925A (en) * 1973-08-16 1977-05-17 Hoechst Aktiengesellschaft Process for obtaining multicolor effects
FR2447735A1 (fr) * 1979-01-30 1980-08-29 Cpg Prod Corp Figurine, notamment poupee
US4257188A (en) * 1979-01-30 1981-03-24 Cpg Products Corp. Toy dolls and figurines having surface portions of reversibly changeable color
US4781647A (en) * 1987-05-04 1988-11-01 Hasbro, Inc. Toy doll construction with phosphorescent hair fibers
US4917643A (en) * 1987-06-26 1990-04-17 Mattel, Inc. Toy vehicle with thermochromic material
US5503583A (en) * 1987-06-26 1996-04-02 Mattel, Inc. Toy with thermochromic material
US5842905A (en) * 1992-02-26 1998-12-01 C.J. Associates, Ltd. Process for making a temporary color change on a plastic material
US5346422A (en) * 1992-12-08 1994-09-13 Eastman Chemical Company Toy articles of manufacture comprising spontaneously wettable fibers
US5277644A (en) * 1993-02-05 1994-01-11 Mattel, Inc. Doll having illuminated color change fiber optic feature
US6585555B2 (en) 2001-10-18 2003-07-01 Prime Time Toys, Ltd. Temperature sensitive color changing water toy
US6736692B1 (en) 2003-05-30 2004-05-18 Mattel, Inc. Hair styling doll head having color change hair crimper
EP1535599A1 (en) 2003-11-28 2005-06-01 Kao Corporation Method effecting a reversible colour change of dyed hair
US20060004110A1 (en) * 2004-06-17 2006-01-05 Sabnis Ram W Composition and method for producing colored bubbles
US7910531B2 (en) 2004-06-17 2011-03-22 C2C Technologies Llc Composition and method for producing colored bubbles
US20060222675A1 (en) * 2005-03-29 2006-10-05 Sabnis Ram W Personal care compositions with color changing indicator
US20060222601A1 (en) * 2005-03-29 2006-10-05 Sabnis Ram W Oral care compositions with color changing indicator
US20060236470A1 (en) * 2005-03-29 2006-10-26 Sabnis Ram W Novelty compositions with color changing indicator
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CN114672996A (zh) * 2022-01-14 2022-06-28 中原工学院 一种二甲酚橙功能化聚乙烯醇纤维的制备方法和应用
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ES311859A1 (es) 1965-07-01
DE1932544U (de) 1966-02-10
BE665235A (pl) 1965-10-01
NL6504989A (pl) 1966-07-05
CH450989A (fr) 1968-05-15
GB1117141A (en) 1968-06-19
DE1478608A1 (de) 1969-02-20
FR1441822A (fr) 1966-06-10
DK113905B (da) 1969-05-05

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