US3279958A - Method of rinsing conversion coatings with chromium complex solutions from chromic acid - Google Patents

Method of rinsing conversion coatings with chromium complex solutions from chromic acid Download PDF

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Publication number
US3279958A
US3279958A US230729A US23072962A US3279958A US 3279958 A US3279958 A US 3279958A US 230729 A US230729 A US 230729A US 23072962 A US23072962 A US 23072962A US 3279958 A US3279958 A US 3279958A
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United States
Prior art keywords
solution
coatings
coating
rinse
chromic acid
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Expired - Lifetime
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US230729A
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English (en)
Inventor
James I Maurer
Richard E Palmer
Vinod D Shah
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Occidental Chemical Corp
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Hooker Chemical Corp
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Publication date
Priority to BE634984D priority Critical patent/BE634984A/xx
Application filed by Hooker Chemical Corp filed Critical Hooker Chemical Corp
Priority to US230729A priority patent/US3279958A/en
Priority to US230744A priority patent/US3222226A/en
Priority to FR939111A priority patent/FR1388662A/fr
Priority to ES290121A priority patent/ES290121A1/es
Priority to DEM58505A priority patent/DE1295961B/de
Priority to GB40452/63A priority patent/GB988985A/en
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Publication of US3279958A publication Critical patent/US3279958A/en
Assigned to HOOKER CHEMICALS & PLASTICS CORP. reassignment HOOKER CHEMICALS & PLASTICS CORP. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: OXY METAL INDUSTRIES CORPORATION
Assigned to OCCIDENTAL CHEMICAL CORPORATION reassignment OCCIDENTAL CHEMICAL CORPORATION CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). EFFECTIVE MARCH 30, 1982. Assignors: HOOKER CHEMICAS & PLASTICS CORP.
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Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82—After-treatment
    • C23C22/83—Chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
    • C23C2222/10—Use of solutions containing trivalent chromium but free of hexavalent chromium

Definitions

  • This invention relates to improvements in metal coating and more particularly relates to solutions for and a method of improving chemically formed coatings on metal surfaces as a base for paint, laquer, varnish or other organic finishes.
  • the predominant processes apply the phosphate or other chemical coating from an aqueous bath and after water rinsing the formed chemical coating, it is subjected to an aqueous chromic acid rinse, either by In many of these processes, the chromic acid rinsed coating is thereafter water-rinsed to remove uneven concentrations of chromic acid on certain areas of the surface. It is Well known that the final water rinse dissolves a substantial portion of the applied chromic acid rinse and yet the final water rinse continues to be employed because non-uniform distribution of chromic acid on the surface causes more serious paint failure than ,results from the reduction in the chromic acid content in the final rinsing step. Moreover, the final water rinse has the advantage that it prepares the surface for use with all types of paints and painting systems, even including those which are susceptible to contamination by excess chromic acid in the coating, since the rinse eliminates any water soluble chromic acid.
  • This invention provides a process which includes the conventional steps which are predominantly employed in high speed production line operation, namely, conventional cleaning, phosphate or other conversion coating forming steps and thereafter rinses the phosphate or conversion coating with the modified aqueous rinse solution of this 3,279,958 Patented Oct. 18, 1966 invention, and finally employs the step of water rinsing the rinsed conversion coating to insure the absence of uneven concentrations of rinse material on the surface.
  • This invention is based on the discovery that certain chromium-containing solutions are capable of forming water-insoluble chromium-containing complexes with certain integral chemical coatings on a metal surface by a simple rinsing step in a short time, which complexes remain on and in the coating during a subsequent water rinsing step. It was also found that the application of such rinse solutions, under the herein below specified conditions, forms such water-insoluble chromium-containing complexes in unexpectedly large quantities as an integral part of the conversion coating.
  • the rinse solution should be a dilute aqueous solution containing chromium complexes which include an anion portion that is displaceable upon contact by an anion in the chemical coating.
  • the complex is modified to contain the anion of the surface coating, and the chromium complex thus becomes attached to and an integral part of the coating. It has been found that in order to form dilute aqueous solutions which contain such a chromium complex, it is necessary to provide a solution containing at least about 0.001% w./v.
  • concentrations are expressed as percent w./v. or percent weight per unit volume of the solution, and pH refers tot he numerical values obtained from solutions prepared with deionized water. The pH should be adjusted in the rinse solution prior to the application of the solution to the surface since the necessary chromium complex must be present in the rinse solution at the moment of contact of the chemical coating.
  • the chromium complex which becomes attached to the chemical coating is water insoluble and the entire complex remains in place through the subsequent water rinse step.
  • the rinse solution of this invention it has been found that there is a substantial increase in the chromium concentration in the coating after water rinsing relative to that which is present in the coating after the use of the heretofore known dilute chromic acid solutions. It has also been found that the improvement in corrosion and humidity resistance after painting which is obtained correlates with the increase in the integral water insoluble chromium complex which is found in that coating.
  • the pH of the rinse solution containing at least about 0.001% tri-valent chromium ion must be adjusted to within the range of about 3.8 to 6.0.
  • the pH of the rinse solution is below about 3.8, the tendency for the formation of the necessary complexes in the rinse solution is reduced and the 'use of such solutions produces no commercially signifimodified dilute chromic acid rinse solutions.
  • solubility of the complex varies not only with the numerical pH value but is also a function of the additional anions which are present in the solution, for example, oxalate or the like, and gelation or precipitation does not always occur precisely at a pH of 6.
  • the upper limit of pH referred to in the claims as about 6 means that value at which the chromium complex remains stable in the dilute aqueous solution.
  • the dilute aqueous rinse solutions of this invention should contain chromium complexes which include an anion that is'displaceable by the anion portion of the coating to be rinsed.
  • chromium complexes which include an anion that is'displaceable by the anion portion of the coating to be rinsed.
  • the coating may be of the phosphate-oxide type such as is obtained from the use of alkali metal dihydrogen phosphate solutions, e.g., sodiu-m or potassium or ammonium dihydrogen phosphate solutions, or may be a chromate coating, an oxalate coating, or an arsenate coating.
  • the method is adaptable for use in conjunction with such chemical coatings on the surfaces of any metal which is susceptible to corrosion in the atmosphere or under other corrosive conditions and particularly including iron, steel, zinc, aluminum, copper, brass, bronze, magnesium, titanium and the like. It has been found that the anion of phosphate coatings most effectively displaces from a chromium complex one or more of the anions nitrate, chloride or chromate. The P0, anion will displace other anions to a somewhat lesser degree, such as sulfate ion, the formate ion and the acetate ion.
  • the dilute rinse solution containing the chromium complex may satisfactorily be one which contains any one of the anions nitrate, chloride, sulfate, phosphate, formate, acetate or sulfite, and when the coating is chromate or arsenate, the preferred anions are nitrate and chloride or mixtures thereof.
  • the dilute chromium complex rinse solution may contain certain other anions as well as those above mentioned, such as the nitrite, phosphate, chromate, oxalate or chlorate anions, and it is to be understood that in any case the rinse solution may contain chromium complexes which are mixtures of complexes containing one or more of the above named anions.
  • Therinse solutions of this invention may contain trivalent chromium in concentrations within the range of about 0.001% w./v., up to the limit of solubility of the selected chromic salt.
  • a preferred operating concentration is within the range of 0.01% to 0.25% and for typical commercial phosphate coating rinse applications no advantage has been found from the use of trivalent chromium concentrations exceedingabout 0.1% w./v.
  • the rinse solutions of this invention are those which are prepared from aqueous chromic acid solutions by reducing the chromic acid with any of a large number of known materials which are capable of reducing the hexavalent chromium ion to the trivalent state. Materials which contain an active hydroxyl, aldehyde or carboxyl group are suitable for this purpose and the materials of this type which are capable of relatively fast reduction of the hexavalent chromium ion are preferred. Suitable rinse solutions are formed so long as the quantity of reduction is insufficient to form a gel.
  • Such materials include the mono hydroxy alcohols including methyl, ethyl, propyl, isopropyl and butyl alcohols, etc., the dihydroxy alcohols, such as glycol, polyethylene glycols, and the polyhydroxy alcohols such as glycerine, mannitol, sorbitol; the aldehydes including aliphatic and aromatic aldehydessuch as formaldehyde, acetaldehyde, be'nzaldehyde; phenol and carboxylic acids including citric acid, tartaric acid, etc.
  • the reducing agent is preferably one which is capable of causing reduction of the hexavalent chromium ion to the trivalent chromium ion in a relatively short time.
  • the procedure employed for producing the desirable reduction product includes the steps of slowly adding an aqueous methyl alcohol solution to an aqueous chromic acid solution, and after preliminarily mixing, the mixture is further reacted, with agitation, preferably at a temperature in the range of about F. to about F. for about 5-36 hours, depending upon the time required to complete the reduction for the quantity of methyl alcohol present. As the temperature is increased, the speed of reduction or rate of the reaction similarly increases.
  • the method of this invention simply comprises the application of the dilute rinse solution to the preliminarily formed chemical coating on the metal surface to be prepared to receive paint or other organic finish in a conventional manner such as by spraying, dipping, brushing or the like.
  • the rinse solution is permitted to drain from the treated chemically coated metal surface, the surface is subjected to a water rinse to insure the absence from uneven concentrations of primarily water-soluble chromium in land on the coating and after drying, the surface is ready to receive an organic finish coating.
  • the after rinse solution is preferably deionized water and excellent results are obtained when it is applied in accordance with the method disclosed in Richards United States Patent No. 3,304,933.
  • the benefits of the invention are obtained even though the final rinse is tap water or other water which is not contaminated with unusually high concentrations of undesirable anions such as chlorides, sulfates, etc.
  • the coating may be permitted to dry in air or, if desired, may be dried in an oven or with forced Where greater speed is necessary.
  • Example I An aqueous acidic zinc phosphate coating solution, modified for coating zinc, was prepared in a conventional manner and upon analysis found to contain 0.27% zinc, 0.23% nickel, 0.98% P 0.21% fluoride, added as silicofluoride, 0.2% N0 and having a total acid of 26 points.
  • a number of 4" x 12" continuous hot dipped galvanized panels were cleaned in a conventional titanated cleaner, and phosphate coated by spraying the above solutions, at 160 F on the surfaces for 1 minute and therafter cold water rinsing for 30 seconds.
  • a number of these phosphate coated panels were then rinsed in a dilute aqueous chromic acid solution containing 0.05% CrO having a pH of approximately 3.5 fior 30 seconds at 125 F., then rinsed in deionized water by spraying for 5 seconds at room temperature and dried.
  • a dilute trivalent chromium containing solution was prepared by slowly adding 2,010 ml. of 20%, by volume, aqueous methyl alcohol solution to 51 lbs. of 25.5% by weight CrO aqueous solution. The rate of alcohol addition was controlled to insure that the temperature in the reaction solution did not exceed 175 F. and thereafter the total volume was increased to gallons by adding additional water. The dilute material was then heated for 6 hours, with stirring, at 170 F.l75 F. and at the end of this reaction period water was added to form a total of 93 lbs. reduced chromic acid concentrate. A portion of this concentrate was tested and found to have a CrO content of 9.6% by weight.
  • a number of 4" x 12" 3003 type aluminum alloy panels were conventionally cleaned in a non-etching cleaner and ehromatecoated with the above described solution by spraying the solution on the panels for 15-20 seconds at F.
  • the coating produced was a mixed oxidechromate coating having an average weight of about 3040 rnillignams per square ft.
  • a portion of the coated panels were then rinsed in a dilute chromic acid rinse solution containing 0.09% CrO and aving a pH of approximately 3.5 by immersing the panels in the solution for 30 seconds at F., and thereafter the panels were rinsed in deionized water by flushing the surface and the panels were then dried in an oven at 200 F. for 2 minutes.
  • the panels were then painted with the two-coat enamel, Dulux 707-6741, and subjected to the scratch adhesion test.
  • the panels which were rinsed in the chromic acid rinse solution having a pH of 3.5 had an adhesion rating of 7-8, whereas the panels rinsed in the reduced chromic acid rinse solution having a pH of 4.6 had an adhesion rating of 8-9.
  • the adhesion test rates the adhesion of the paint to the surface, the test comprising an attempt to scrape the paint from the surface by a knife-blade applied thereto at constant angle and pressure.
  • the numeral 10 represents excellent adhesion, 8, good adhesion, 6, fair adhesion, etc.
  • Example III A dilute trivalent chromium containing solution was prepared by slowly adding 28 grams of a 25% aqueous solution of formaldehyde to 364.4 grams of a 25% CrO by weight aqueous deionized water solution. The highest temperature reached during mixing was 174 F. and after partial cooling the reaction was continued at F. for 2 /2 hours and a determination showed that the reaction had elfected a 27% reduction of the CrO to trivalent chromium. A portion of the reduced concentrate was diluted with ordinary tap water to produce a solution containing 0.0138% trivalent chromium and having a pH of 3.9.
  • a number of 4" x 12" cold rolled steel panels were coated with a zinc phosphate coating by using a solution containing 0.23% zinc, 0.45% P0 0.56% calcium, 2.48% nitrate, 0.17% ferrous iron, having a total acid of 15.1 and a free acid number of 1.0, by spraying for 60 seconds at 177 F. followed by a 30-second cold water rinse.
  • a series of such coated panels were then rinsed in a dilute aqueous chromic acid rinse solution containing 0.05% CrO and having a pH of approximately 3.5 by immersion at room temperature for 30 seconds. After withdrawal from the chromic acid rinse solution the panels were sprayed for 10 seconds with deionized water and dried for 3 minutes at 375 F.
  • Example IV A dilute trivalent chromium containing solution was prepared by slowly adding grams of benzaldehyde to 404.3 grams of a 25% by weight, CrO -deionized water solution. There was no discernible rise in temperature which resulted from the mixing. The admixture was then heated to 160 F.170 F. and maintained at that temperature for 18-20 hours. At the end of this time, analysis of the product revealed that approximately 3.5% of the CrO had been reduced to trivalent chromium. A portion of this reduced concentrate was diluted with ordinary tap water to form a solution containing 0.001236% trivalent chromium.
  • a number of 4" x 12" cold rolled steel panels were coated with a zinc phosphate coating by using the solution and procedures described above in detail in Example III.
  • a series of these coated panels were rinsed in a dilute chromium aqueous rinse solution containing 0.05% CrO and having a pH of approximately 3.5 by immersion at room temperature for 30 seconds, and thereafter deionized-water rinsing for seconds by spraying at room temperature and then drying the panels for 3 minutes at 375 F.
  • Another series of the same phosphate coated panels were rinsed in the trivalent chromium containing solution, at a pH of 5.0, by immersion at room temperature for 30 seconds, spray rinsed in a deionized water spray for 10 seconds at room temperature, and thereafter dried for 3 minutes in an open at 375 P.
  • a method of preparing integral chemical coatings selected from the group consisting of phosphate coatings, phosphate-oxide coatings, chromate coatings, oxalate coatings and arsenate coatings, on a metal surface to receive an organic finish which comprises the steps of applying to said chemical coating a dilute aqueous solution containing at least about 0.001% trivalent chromium in the form of a chromium chromate complex, said solution having a pH in the range of about 3.8 to about 6, and thereafter water rinsing said surface.
  • a method of preparing integral chemical coatings selected from the group consisting of phosphate coatings, phosphate-oxide coatings, chromate coatings, oxalate coatings and arsenate coatings, on a metal surface to receive an organic finish which comprises the steps of applying to said chemical coating a dilute aqueous solution containing at least about 0.01% to about 0.25% trivalent chromium in the form of a chromium chromate complex, said solution having a pH in the range of about 3.8 to about 6, and thereafter water rinsing said surface.

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
US230729A 1962-10-15 1962-10-15 Method of rinsing conversion coatings with chromium complex solutions from chromic acid Expired - Lifetime US3279958A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
BE634984D BE634984A (de) 1962-10-15
US230729A US3279958A (en) 1962-10-15 1962-10-15 Method of rinsing conversion coatings with chromium complex solutions from chromic acid
US230744A US3222226A (en) 1962-10-15 1962-10-15 Method of and solution for improving conversion coated metallic surfaces
FR939111A FR1388662A (fr) 1962-10-15 1963-06-24 Procédé et solution pour le traitement des surfaces métalliques pourvues d'un revêtement chimique
ES290121A ES290121A1 (es) 1962-10-15 1963-07-19 Procedimiento para el tratamiento de superficies metálicas con un revestimiento químico
DEM58505A DE1295961B (de) 1962-10-15 1963-10-12 Verfahren zur Behandlung von chemisch aufgebrachten UEberzuegen auf Metallen
GB40452/63A GB988985A (en) 1962-10-15 1963-10-14 Improvements relating to the treatment of conversion coatings on metal surfaces

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US230729A US3279958A (en) 1962-10-15 1962-10-15 Method of rinsing conversion coatings with chromium complex solutions from chromic acid
US230744A US3222226A (en) 1962-10-15 1962-10-15 Method of and solution for improving conversion coated metallic surfaces

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US230729A Expired - Lifetime US3279958A (en) 1962-10-15 1962-10-15 Method of rinsing conversion coatings with chromium complex solutions from chromic acid

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BE (1) BE634984A (de)
DE (1) DE1295961B (de)
ES (1) ES290121A1 (de)
GB (1) GB988985A (de)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3501352A (en) * 1965-08-02 1970-03-17 Hooker Chemical Corp Composition and method for treating zinc surfaces
US4161409A (en) * 1978-03-06 1979-07-17 Louis Schiffman Corrosion inhibitive pigment
US4230770A (en) * 1978-10-06 1980-10-28 The Goodyear Tire & Rubber Company Metal photopolymer substrates
US4539051A (en) * 1983-03-02 1985-09-03 Parker Chemical Company Process for producing phosphate coatings
US5368655A (en) * 1992-10-23 1994-11-29 Alchem Corp. Process for chromating surfaces of zinc, cadmium and alloys thereof
US5433773A (en) * 1994-06-02 1995-07-18 Fremont Industries, Inc. Method and composition for treatment of phosphate coated metal surfaces
US6537678B1 (en) 2000-09-20 2003-03-25 United Technologies Corporation Non-carcinogenic corrosion inhibiting additive
EP1493846A1 (de) 2003-06-30 2005-01-05 United Technologies Corporation Korrosionsinhibirendes Additiv und Korrosionsinhibirender Überzug
US20070228332A1 (en) * 2006-04-04 2007-10-04 United Technologies Corporation Chromate free waterborne corrosion resistant primer with non-carcinogenic corrosion inhibiting additive
US20090004486A1 (en) * 2007-06-27 2009-01-01 Sarah Arsenault Corrosion inhibiting additive
US20130078382A1 (en) * 2010-05-26 2013-03-28 Atotech Deutschland Gmbh Process for forming corrosion protection layers on metal surfaces

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3404046A (en) * 1964-09-25 1968-10-01 Hooker Chemical Corp Chromating of zinc and aluminum and composition therefor
US3932198A (en) * 1974-05-24 1976-01-13 Amchem Products, Inc. Coating solution having trivalent chromium and manganese for coating metal surfaces
CA1062560A (en) * 1974-09-25 1979-09-18 Hidejiro Asano Method for the manufacture of a steel sheet adapted for use in ironing processing having good lubrication property
JPH0633465B2 (ja) * 1986-04-26 1994-05-02 日本パ−カライジング株式会社 りん酸塩処理した自動車車体の後処理方法
TW538138B (en) * 2000-04-27 2003-06-21 Otsuka Kagaku Kk Process for treating and producing the parts made of magnesium and/or magnesium alloy
CN100393910C (zh) * 2006-05-23 2008-06-11 河海大学常州校区 镁合金表面柠檬酸盐化学转化膜处理溶液

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US900597A (en) * 1908-01-16 1908-10-06 Franz Salzer Process for producing an electrolytic deposit of metallic chromium.
US1922853A (en) * 1927-12-01 1933-08-15 United Chromium Inc Process for the electrolytic deposition of chromium
US2768104A (en) * 1952-03-25 1956-10-23 Heintz Mfg Co Method for coating iron
US2846342A (en) * 1955-09-30 1958-08-05 Leo P Curtin Bonding coats for metal
US2882189A (en) * 1954-10-20 1959-04-14 Parker Rust Proof Co Alkali metal phosphate coating method for metals and article produced thereby
US2911332A (en) * 1956-05-25 1959-11-03 Kelsey Hayes Co Process of coating metal and resulting articles
US3063877A (en) * 1960-10-10 1962-11-13 Amchem Prod Method and solutions for treating metal surfaces
US3094441A (en) * 1958-09-03 1963-06-18 Curtin Leo Vincent Chromic phosphate bonding coats for metal

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US2313925A (en) * 1937-04-16 1943-03-16 Parker Rust Proof Co Coating metals by the aid of acid sulphites
US2377229A (en) * 1937-07-03 1945-05-29 Little Inc A Electrolytic deposition of chromium
DE825041C (de) * 1948-10-01 1952-01-31 Metallgesellschaft Ag Passivierungsmittel
DE1093167B (de) * 1957-01-19 1960-11-17 Metallgesellschaft Ag Verfahren zur Ausbildung von duennen Phosphatueberzuegen auf Eisen und Stahl

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US900597A (en) * 1908-01-16 1908-10-06 Franz Salzer Process for producing an electrolytic deposit of metallic chromium.
US1922853A (en) * 1927-12-01 1933-08-15 United Chromium Inc Process for the electrolytic deposition of chromium
US2768104A (en) * 1952-03-25 1956-10-23 Heintz Mfg Co Method for coating iron
US2882189A (en) * 1954-10-20 1959-04-14 Parker Rust Proof Co Alkali metal phosphate coating method for metals and article produced thereby
US2846342A (en) * 1955-09-30 1958-08-05 Leo P Curtin Bonding coats for metal
US2911332A (en) * 1956-05-25 1959-11-03 Kelsey Hayes Co Process of coating metal and resulting articles
US3094441A (en) * 1958-09-03 1963-06-18 Curtin Leo Vincent Chromic phosphate bonding coats for metal
US3063877A (en) * 1960-10-10 1962-11-13 Amchem Prod Method and solutions for treating metal surfaces

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3501352A (en) * 1965-08-02 1970-03-17 Hooker Chemical Corp Composition and method for treating zinc surfaces
US4161409A (en) * 1978-03-06 1979-07-17 Louis Schiffman Corrosion inhibitive pigment
US4230770A (en) * 1978-10-06 1980-10-28 The Goodyear Tire & Rubber Company Metal photopolymer substrates
US4539051A (en) * 1983-03-02 1985-09-03 Parker Chemical Company Process for producing phosphate coatings
US5368655A (en) * 1992-10-23 1994-11-29 Alchem Corp. Process for chromating surfaces of zinc, cadmium and alloys thereof
US5433773A (en) * 1994-06-02 1995-07-18 Fremont Industries, Inc. Method and composition for treatment of phosphate coated metal surfaces
US5472523A (en) * 1994-06-02 1995-12-05 Fremont Industries, Inc. Method and composition for treatment of phosphate coated metal surfaces
US6537678B1 (en) 2000-09-20 2003-03-25 United Technologies Corporation Non-carcinogenic corrosion inhibiting additive
EP1493846A1 (de) 2003-06-30 2005-01-05 United Technologies Corporation Korrosionsinhibirendes Additiv und Korrosionsinhibirender Überzug
US7341677B2 (en) 2003-06-30 2008-03-11 United Technologies Corporation Non-carcinogenic corrosion inhibiting additive
US20070228332A1 (en) * 2006-04-04 2007-10-04 United Technologies Corporation Chromate free waterborne corrosion resistant primer with non-carcinogenic corrosion inhibiting additive
US7972533B2 (en) 2006-04-04 2011-07-05 United Technologies Corporation Chromate free waterborne corrosion resistant primer with non-carcinogenic corrosion inhibiting additive
US20090004486A1 (en) * 2007-06-27 2009-01-01 Sarah Arsenault Corrosion inhibiting additive
US10774428B2 (en) 2007-06-27 2020-09-15 Raytheon Technologies Corporation Method for corrosion inhibiting additive
US20130078382A1 (en) * 2010-05-26 2013-03-28 Atotech Deutschland Gmbh Process for forming corrosion protection layers on metal surfaces
US9738790B2 (en) * 2010-05-26 2017-08-22 Atotech Deutschland Gmbh Process for forming corrosion protection layers on metal surfaces

Also Published As

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DE1295961B (de) 1969-05-22
US3222226A (en) 1965-12-07
ES290121A1 (es) 1963-08-16
GB988985A (en) 1965-04-14
BE634984A (de)

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