US3241970A - Preparation of photographic emulsions - Google Patents
Preparation of photographic emulsions Download PDFInfo
- Publication number
- US3241970A US3241970A US143290A US14329061A US3241970A US 3241970 A US3241970 A US 3241970A US 143290 A US143290 A US 143290A US 14329061 A US14329061 A US 14329061A US 3241970 A US3241970 A US 3241970A
- Authority
- US
- United States
- Prior art keywords
- complex
- silver
- solution
- preparation
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000839 emulsion Substances 0.000 title claims description 24
- 238000002360 preparation method Methods 0.000 title claims description 14
- -1 SILVER HALIDE Chemical class 0.000 claims description 30
- 229910052709 silver Inorganic materials 0.000 claims description 26
- 239000004332 silver Substances 0.000 claims description 26
- 239000002904 solvent Substances 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 17
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 claims description 13
- 229910021612 Silver iodide Inorganic materials 0.000 claims description 13
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 claims description 13
- 229940045105 silver iodide Drugs 0.000 claims description 13
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 56
- 239000000243 solution Substances 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 108010010803 Gelatin Proteins 0.000 description 8
- 229920000159 gelatin Polymers 0.000 description 8
- 239000008273 gelatin Substances 0.000 description 8
- 235000019322 gelatine Nutrition 0.000 description 8
- 235000011852 gelatine desserts Nutrition 0.000 description 8
- 150000004820 halides Chemical class 0.000 description 8
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 7
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 5
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000012876 carrier material Substances 0.000 description 3
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 125000001477 organic nitrogen group Chemical group 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 150000003378 silver Chemical class 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- BYBCDPXQFQGGTR-UHFFFAOYSA-L disilver;bromide;iodide Chemical compound [Br-].[Ag+].[Ag+].[I-] BYBCDPXQFQGGTR-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229960004592 isopropanol Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- HAAYBYDROVFKPU-UHFFFAOYSA-N silver;azane;nitrate Chemical compound N.N.[Ag+].[O-][N+]([O-])=O HAAYBYDROVFKPU-UHFFFAOYSA-N 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- IZWPGJFSBABFGL-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS([O-])(=O)=O IZWPGJFSBABFGL-GMFCBQQYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/015—Apparatus or processes for the preparation of emulsions
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C2200/00—Details
- G03C2200/06—Additive
Definitions
- This invention relates to a novel process for the preparation of silver halide photographic emulsions. More particularly, this invention relates to a novel process for the preparation of silver bromide, silver iodide and mixed silver bromide-silver iodide photographic emulsions.
- the instant invention is based on the discovery that silver bromide, silver iodide, or mixtures of the two, complex with the aforesaid solvent in the presence of excess bromide ions.
- the complex is soluble in the solvent up to 20% by weight.
- the solution of this complex is colorless and is not sensitive to light. It should become immediately obvious that such a complex is particularly adapted to the photographic emulsion art when the silver halide or halides can be made to precipitate out of the complex onto a suitable carrier so that they will become light sensitive again.
- the complex is conveniently prepared simply by adding silver bromide, silver iodide or mixtures of the two to the normally liquid nitrogen containing solvent in the presence of excess bromide ions and stirring.
- Suitable solvents for my purpose are dimethyl forrnamide, pyrrolidone, pyriconvenient source of bromide ions is hydrobromic acid so that this acid is preferred as a bromide source.
- the photographic emulsions can be prepared simply by adding the silver halide complex to a suitable carrier contained in a material which acts both as a solvent for the carrier and as a precipitate for the complex.
- suitable carrier contained in a material which acts both as a solvent for the carrier and as a precipitate for the complex.
- the solvent-precipitants which can be employed include water, the lower molecular weight aliphatic alcohols, i.e. methanol, propanol, iso propanol, butanol, amyl alcohol and other organic solvents which are miscible with the normally liquid nitrogen containing complexing agent.
- the preferred solvents are water and aliphatic alcohols of from 1-5 carbon atoms, with water being particularly preferred.
- the complex can be added to the solvent-precipitant which contains dissolved in place of the carrier an anionic, cationic, nonionic or amphoteric dispersing agent such as sodium lauryl sulfate, iso-octyl phenoxy polyoxyethylene ethanol, sodium N-methyl N-oleoyl taurate, sodium N-lauroyl sarcosinate.
- an anionic, cationic, nonionic or amphoteric dispersing agent such as sodium lauryl sulfate, iso-octyl phenoxy polyoxyethylene ethanol, sodium N-methyl N-oleoyl taurate, sodium N-lauroyl sarcosinate.
- My invention offers the special advantage that all operations up to the re-precipitation can be carried out in full light, only the subsequent steps requiring the use of a dark room.
- a mixture of 450 cubic centimeters of water and 3.5 grams of gelatin was placed in a constant temperature bath at 70 C. and stirred. To this was added the complex and the entire mixture was stirred for three minutes. The mixture was ripened for ten minutes, precipitated and washed. After several washings the silver halide crys tals were redispersed at 40 C. by the addition of 48 grams of gelatin dissolved in 475 cubic centimeters of water. The resulting emulsion was after-ripened and coated on a suitable film base.
- the resulting emulsion was of excellent quality, was low in fog and was comparable in speed to normal positive type film.
- EXAMPLE II Ammonia type emulsion A mixture of 83.0 grams of silver bromide and 1.6 grams of silver iodide was added to 120 cubic centimeters of dimethyl formamide and stirred for one minute. 80 cubic centimeters of a 48% solution of hydrobromic acid was then added with stirring. 300 cubic centimeters of dimethyl formamide was then added in two portions of cubic centimeters each, stirring for a few minutes after the first addition and until dissolved after the second. The resulting complex was then added to a solution maintained at 56 C. of 6.5 grams of gelatin, 260.0 cubic centimeters of water and 70.0 cubic centimeters of a 28% solution of ammonium hydroxide. After stirring for nineteen minutes and digesting for ten minutes, the emulsion was precipitated and washed several times with cold water.
- dimethyl formamide in the examples may be replaced by any other of the enumerated complexing agents, e.g. pyrrolidone, pyridine, butylamine, N-dimethylaniline, dibutylamine, etc.
- complexing agents e.g. pyrrolidone, pyridine, butylamine, N-dimethylaniline, dibutylamine, etc.
- My invention can also be carried out by dissolving a colloidal carrier material such as gelatin in the solution containing the silver halide complex and adding this solution to the precipitating medium.
- a colloidal carrier material such as gelatin
- the solution of the complex may be sprayed into a chamber containing steam.
- the steam can be brought into the chamber flowing in the form of a counter current to the direction of travel of the silver complex spray.
- a process for the preparation of photographic emulsions which comprises adding a silver halide selected from the group consisting of silver bromide, silver iodide and mixtures of the two to a normally liquid organic nitrogen containing solvent in the presence of excess bromide ions so as to form a complex soluble in said solvent, and then adding the resulting solution of said complex to a solution of carrier, the solvents used in the preparation of the carrier solution being miscible with the said nitrogen containing solvent and capable of breaking the complex, thereby forming a dispersion of silver halide in the solution of the carrier.
- the normally liquid nitrogen containing solvent is selected from the class consisting of dimethyl formamide, pyridine, pyrrolidone, N-dimethylaniline, butylamine and dibutyla- 4 mine.
- a process for the preparation of photographic emulsions which comprises adding mixtures of silver bromide and silver iodide to dimethyl formamide and hydrobromic acid to form a complex soluble in dimethyl formamide and then adding the resulting solution of said complex in dimethyl formamide to an aqueous solution of gelatin.
- a process for the preparation of photographic emulsions which comprises adding a silver halide selected from the group consisting of silver bromide, silver iodide, mixtures of the two and silver bromoiodide to a normally liquid organic nitrogen containing solvent in the presence of excess bromide ions so as to form a complex soluble in said solvent, and then adding the resulting solution of said complex in said solvent to a solution of surfactant in a solvent miscible with said nitrogen containing solvent, thereby re-forming the silver halide, and admixing to the dispersion thus obtained a colloidal carrier material so as to form a light sensitive silver halide emulsion.
- a process which comprises adding a silver halide selected from the group consisting of silver bromide, silver iodide and mixtures of the two to dimethyl formamide in the presence of excess bromide ions so as to form a complex soluble in dimethyl formamide.
- a process which comprises adding a mixture of silver bromide and silver iodide to dimethyl formamide in the presence of hydrobromic acid to form a complex soluble in dimethyl formamide.
- a process which comprises mixing together silver bromide, dimethyl formamide and hydrobromic acid so as to form a complex soluble in dimethyl formamide.
- a process which comprises mixing together silver iodide, dimethyl formamide and hydrobromic acid so as to form a complex soluble in dimethyl formamide.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE623226D BE623226A (fi) | 1961-10-06 | ||
US143290A US3241970A (en) | 1961-10-06 | 1961-10-06 | Preparation of photographic emulsions |
GB35482/62A GB1023578A (en) | 1961-10-06 | 1962-09-18 | Improvements in or relating to the preparation of photographic emulsions and complexes therefor |
DEG36086A DE1171736B (de) | 1961-10-06 | 1962-10-05 | Verfahren zur Herstellung photographischer Emulsionen |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US143290A US3241970A (en) | 1961-10-06 | 1961-10-06 | Preparation of photographic emulsions |
Publications (1)
Publication Number | Publication Date |
---|---|
US3241970A true US3241970A (en) | 1966-03-22 |
Family
ID=22503421
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US143290A Expired - Lifetime US3241970A (en) | 1961-10-06 | 1961-10-06 | Preparation of photographic emulsions |
Country Status (4)
Country | Link |
---|---|
US (1) | US3241970A (fi) |
BE (1) | BE623226A (fi) |
DE (1) | DE1171736B (fi) |
GB (1) | GB1023578A (fi) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3907573A (en) * | 1970-08-21 | 1975-09-23 | Minnesota Mining & Mfg | Silver halide photographic emulsions with improved physical characteristics |
US3941600A (en) * | 1973-07-27 | 1976-03-02 | Polaroid Corporation | Method of forming a photographic emulsion layer |
US4076539A (en) * | 1973-07-23 | 1978-02-28 | Fuji Photo Film Co., Ltd. | Process for preparing silver halide dispersions |
US4370412A (en) * | 1978-09-14 | 1983-01-25 | Eastman Kodak Company | Aqueous hydrophilic colloid coating composition containing a combination of anionic surfactants |
EP0881533A1 (en) * | 1997-05-30 | 1998-12-02 | Eastman Kodak Company | Preparation and use of a dimethylamine silver chloride complex as a single source precursor for nucleation of silver chloride crystals |
EP0881532A1 (en) * | 1997-05-30 | 1998-12-02 | Eastman Kodak Company | Preparation and use of a dimethylamine silver bromo-iodide complex as a single source precursor for iodide incorporation in silver bromide crystals |
EP0881534A1 (en) * | 1997-05-30 | 1998-12-02 | Eastman Kodak Company | Preparation and use of a dimethylamine silver bromide complex as a single source precursor for nucleation of silver bromide crystals |
EP0881530A1 (en) * | 1997-05-30 | 1998-12-02 | Eastman Kodak Company | A high chloride emulsion prepared with dimethylamine silver chloro-iodide and antifoggants |
EP0881531A1 (en) * | 1997-05-30 | 1998-12-02 | Eastman Kodak Company | Preparation and use of a dimethylamine silver chloro-iodide complex as a single source precursor for iodide incorporation of silver chloride crystals |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB471366A (fi) * | ||||
US2875052A (en) * | 1949-08-06 | 1959-02-24 | Weyde Edith | Photographic material for the direct production of positive photographic images |
US3031304A (en) * | 1958-08-20 | 1962-04-24 | Albert J Oliver | Fine grain nuclear emulsion |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE151752C (fi) * |
-
0
- BE BE623226D patent/BE623226A/xx unknown
-
1961
- 1961-10-06 US US143290A patent/US3241970A/en not_active Expired - Lifetime
-
1962
- 1962-09-18 GB GB35482/62A patent/GB1023578A/en not_active Expired
- 1962-10-05 DE DEG36086A patent/DE1171736B/de active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB471366A (fi) * | ||||
US2875052A (en) * | 1949-08-06 | 1959-02-24 | Weyde Edith | Photographic material for the direct production of positive photographic images |
US3031304A (en) * | 1958-08-20 | 1962-04-24 | Albert J Oliver | Fine grain nuclear emulsion |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3907573A (en) * | 1970-08-21 | 1975-09-23 | Minnesota Mining & Mfg | Silver halide photographic emulsions with improved physical characteristics |
US4076539A (en) * | 1973-07-23 | 1978-02-28 | Fuji Photo Film Co., Ltd. | Process for preparing silver halide dispersions |
US3941600A (en) * | 1973-07-27 | 1976-03-02 | Polaroid Corporation | Method of forming a photographic emulsion layer |
US4370412A (en) * | 1978-09-14 | 1983-01-25 | Eastman Kodak Company | Aqueous hydrophilic colloid coating composition containing a combination of anionic surfactants |
EP0881533A1 (en) * | 1997-05-30 | 1998-12-02 | Eastman Kodak Company | Preparation and use of a dimethylamine silver chloride complex as a single source precursor for nucleation of silver chloride crystals |
EP0881532A1 (en) * | 1997-05-30 | 1998-12-02 | Eastman Kodak Company | Preparation and use of a dimethylamine silver bromo-iodide complex as a single source precursor for iodide incorporation in silver bromide crystals |
EP0881534A1 (en) * | 1997-05-30 | 1998-12-02 | Eastman Kodak Company | Preparation and use of a dimethylamine silver bromide complex as a single source precursor for nucleation of silver bromide crystals |
EP0881530A1 (en) * | 1997-05-30 | 1998-12-02 | Eastman Kodak Company | A high chloride emulsion prepared with dimethylamine silver chloro-iodide and antifoggants |
EP0881531A1 (en) * | 1997-05-30 | 1998-12-02 | Eastman Kodak Company | Preparation and use of a dimethylamine silver chloro-iodide complex as a single source precursor for iodide incorporation of silver chloride crystals |
Also Published As
Publication number | Publication date |
---|---|
DE1171736B (de) | 1964-06-04 |
BE623226A (fi) | |
GB1023578A (en) | 1966-03-23 |
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