US3185653A - Multi-color coating compositions and methods of preparation thereof - Google Patents
Multi-color coating compositions and methods of preparation thereof Download PDFInfo
- Publication number
- US3185653A US3185653A US208920A US20892062A US3185653A US 3185653 A US3185653 A US 3185653A US 208920 A US208920 A US 208920A US 20892062 A US20892062 A US 20892062A US 3185653 A US3185653 A US 3185653A
- Authority
- US
- United States
- Prior art keywords
- emulsion
- coating composition
- dispersed
- globules
- phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000008199 coating composition Substances 0.000 title claims description 76
- 238000000034 method Methods 0.000 title claims description 20
- 238000009500 colour coating Methods 0.000 title description 20
- 238000002360 preparation method Methods 0.000 title description 2
- 239000000839 emulsion Substances 0.000 claims description 100
- 239000012071 phase Substances 0.000 claims description 89
- 239000008346 aqueous phase Substances 0.000 claims description 30
- 239000002904 solvent Substances 0.000 claims description 29
- 239000004215 Carbon black (E152) Substances 0.000 claims description 28
- 229930195733 hydrocarbon Natural products 0.000 claims description 28
- 150000002430 hydrocarbons Chemical class 0.000 claims description 28
- 239000003381 stabilizer Substances 0.000 claims description 24
- 229920001971 elastomer Polymers 0.000 claims description 23
- 239000005060 rubber Substances 0.000 claims description 23
- 230000001804 emulsifying effect Effects 0.000 claims description 20
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000000049 pigment Substances 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 13
- 230000000694 effects Effects 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 230000001680 brushing effect Effects 0.000 claims description 5
- 238000004040 coloring Methods 0.000 claims description 5
- 239000000243 solution Substances 0.000 description 27
- 239000003973 paint Substances 0.000 description 16
- 125000001931 aliphatic group Chemical group 0.000 description 15
- 239000003086 colorant Substances 0.000 description 15
- 238000000576 coating method Methods 0.000 description 14
- 238000003756 stirring Methods 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 13
- 239000002585 base Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000006185 dispersion Substances 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
- 239000003208 petroleum Substances 0.000 description 9
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 210000004209 hair Anatomy 0.000 description 8
- 238000013019 agitation Methods 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229920000058 polyacrylate Polymers 0.000 description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 3
- 239000002174 Styrene-butadiene Substances 0.000 description 3
- 241000779819 Syncarpia glomulifera Species 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- -1 gums Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000001739 pinus spp. Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000011115 styrene butadiene Substances 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 229940036248 turpentine Drugs 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000870659 Crassula perfoliata var. minor Species 0.000 description 2
- 241000519995 Stachys sylvatica Species 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 239000010459 dolomite Substances 0.000 description 2
- 229910000514 dolomite Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241001274197 Scatophagus argus Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 238000010073 coating (rubber) Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229960002900 methylcellulose Drugs 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- UJRBOEBOIXOEQK-UHFFFAOYSA-N oxo(oxochromiooxy)chromium hydrate Chemical compound O.O=[Cr]O[Cr]=O UJRBOEBOIXOEQK-UHFFFAOYSA-N 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
- B05D5/061—Special surface effect
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S260/00—Chemistry of carbon compounds
- Y10S260/26—Multicolor
Definitions
- bi-color coating compositions consisting of an unstable emulsion of two different colored phases, an internal phase being of aqueous nature, and containing cellulose-containing fibre materials Patented May 25, 1965 and an external phase being of non-aqueous nature.
- a coating composition When such a coating composition is applied to a wall, a wallpaper-like coating patterned in two colors with an appearance similar to paper is obtained. This effect is due to the presence of cellulose-containing fibres to protect the globules of the emulsion so that the coating composition may be applied by brush.
- a coating composition can only be used when a wallpaper-like coating is wanted. Further, this emulsion is unstable, and the coating composition can be stored only for a very short time.
- a well known type of coating composition is the socalled emulsion paints.
- a paint consists of an emulsion of a disperse phase in a continuous'aqueous phase, which disperse phase as binder comprises polymeric materials, preferably of polystyrene type, styrene-butadiene type, poly(vinyl acetate) type and polyacrylic type, conf. for example Encyclopedia of Chemical Technology, First Supplement Volume, The Interscience Encyclopedia, Inc., New York, 1957.
- a further object of my invention is to provide a method of preparing a coating composition of the kind stated above.
- My invention is based on the discovery that a useful emulsion coating composition overcoming the above disadvantages by the known coating compositions adapted to produce spotted color efifects may be obtained when a coating composition having a binder consisting of a solution of cyclized rubber in a hydrocarbon solvent selected from the group consisting of aliphatic, cycloaliphaticand aromatic hydrocarbons is emulgated in an emulsion'paint in which further a hydrocarbon solvent of the same group is emulgated, provided said emulsion coating composition, further comprises a colloidal stabilizing agent.
- the globules form colored spots seen on the background of the color of the emulsion paint
- the colored globules form colored spots seen on the background of the original color of the surface. It has to be noted that'the globules of the emulsion paint are not protected so that these globules will as in conventional emulsion paints coalesce when the emulsion coating composition is applied to a surface.
- the continuous aqueous phase included a phase comprising a hydrocarbon solvent this is owing thereto that otherwise the continuous aqueous phase alone as Well as together with the second dispersed phase has a tendency to draw the hydrocarbon solvent out of the dispersed phase or phases comprising a solution of cyclized rubber which results in a hardening the surface of the globules of said last named phase and the coating composition becomes unusable. This tendency is eliminated, however, when a hydrocarbon solvent is emulgated in the continuous aqueous phase.
- colloidal stabilizing agent contains a colloidal stabilizing agent.
- a salt preferably an alkali salt of polyacrylic acid, for example ammonium polyacrylate or sodium polyacrylate.
- colloidal stabilizing agent which advantageously may be used, methyl cellulose, carboxy-methyl-cellulose, alginates,
- a one-color coating composition according to my invention the pigment or pigments necessary for producing the color are incorporated only in the dispersed phase containing cyclized rubber and a coating film is obtained showing a great number of discrete color stains in a colorless coating film.
- the greatest difficulty in the manufacture of the present coating composition is to produce the final emulsion since the pigmented solution of cyclized rubber cannot or can at least only with very great difficulty be directly emulsified in the continuous aqueous phase.
- the emulsifying in the pre-emulsion of the second dispersed phase in the continuous aqueous phase of the above stated further pro-emulsion of dispersed phase of the first kind in a solution of colloidal stabilizing agent is most suitably carried out by pouring the last pro-emulsion into a bulk ofthe first pre-emulsion under very gentle agitatation. If too great an amount of the second pre-emulsion is added to the first pre-emulsion'at a time, there is a dangerof separation of the dispersed phase of the first kind from the continuous phase. Even a too powerful agitation during the emulsifying process has been shown to EXAMPLE 1 Bi-color coating composition providing a white base color with black spots A white emulsion paint is made by mixing:
- a black/white coating composition is obtained having a good storage stability.
- the paint can be applied on a support, even on a rough or porous support in thick as well as thin coats by means of a paint brush by any other suitable application method resulting in a coating film having a smooth surface.
- the film will have a white base color on which is scattered a great number of discrete black stains, the pattern of the stains depending mainly on the manner in which the brush or other application device has been manipulated.
- Bi-color coating composition providing a grey base color with green spots are mixed and homogenized in a slowly rotating homogenizer, whereupon 30 parts by weight of an emulsified polymer such as a 55% aqueous dispersion of acrylic acid methyl-butyl ester copolymer (based on 40% methyl acrylate and 60% butyl acrylate and having a mol. wt. of about 1.410 for example an emulsion based on emulsion of the kind sold in the trade as Acronal 14D is added under stirring.
- a pre-emulsion or dispersion is 8 obtained in which 12 parts by weight of petroleum spirit are emulsified by vigorous agitation.
- a paste is made by grinding Parts by weight Chromium oxide hydrate, green 24.0 Dolomite 26.0 60% solution of cyclized rubber in petroleum spirit 50.0
- a white/black coating composition is obtained having approximately the same properties as the compositions according to the foregoing examples.
- coating compositions having more than three colors may be obtained by mixing a suitable number already prepared coating compositions of the kind described each with one or more colors.
- each of these phases is mixed with at least some pre-' emulsion before reaching another of these phases.
- a method of preparing a coating composition comprising a stable emulsion of at least two dispersed phases in a continuous aqueous phase; one of said two dispersed phases comprising a colored solution of cyclized rubber in at least one hydrocarbon solvent selected from the group consisting of aliphatic, cycloaliphatic and aromatic hydrocarbons; the second of said two dispersed phases comprising an emulsified synthetic polymeric material; said method including the steps of emulsifying said second dispersed phase in said continuous aqueous phase, in order to obtain an emulsion component; emulsifying at least one hydrocarbon solvent selected from the group consisting of aliphatic, cycloaliphatic and aromatic hy- 6; A method according to claim 4 in which 100 parts by Weight of said first dispersed phase are emulsified in to 120 parts by weight of said solution of colloidal stabilizing agent for obtaining said second pre-emulsion.
- a hydrocarbon solvent selected from the group consisting of aliphatic, cycloaliphatic and aromatic hydrocarbons
- a method of preparing a coating composition comprising a stable emulsion of at least three dispersed phases in a continuous aqueous phase, a first of said three dispersed phases comprising an emulsified synthetic polymeric material; a second of said dispersed phases comprising a hydrocarbon solvent selected from the group consisting of aliphatic, cycloaliphatic and aromatic hydrocarbons; a third of said three dispersed phases comprising a solution of cyclized rubber in a hydrocarbon solvent selected from the group consisting of aliphatic, cycloaliphatic, and aromatic hydrocarbons, at least one pigment being incorporated in said solution; said method including the steps of emulsifying said first and said second dispersed phase in said continuous aqueous phase, in order to obtain a first pro-emulsion; adjusting the viscosity of said first pre-emulsion to a viscosity to between 10 and secs.
- liquid oil-in-water type emulsion coating composition containing pigmented globules adapted to produce a spotted color effect by brushing on a surface without rupture of the said pigmented globules by the hair of the brush, which comprises at least two dispersed phases in a continuous aqueous phase of said emulsion; one of said two dispersed phases comprising a solution of References Cited by the Examiner UNITED STATES PATENTS 4/52 Zola 106--170 12/53- Van Veersen 260-734 MURRAY TILLMAN, Primary Examiner.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK16358AA DK91633C (da) | 1958-01-18 | 1958-01-18 | Flerfarve-maling samt fremgangsmåde til fremstilling af samme. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3185653A true US3185653A (en) | 1965-05-25 |
Family
ID=8090469
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US208920A Expired - Lifetime US3185653A (en) | 1958-01-18 | 1962-07-10 | Multi-color coating compositions and methods of preparation thereof |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3185653A (enrdf_load_stackoverflow) |
| BE (1) | BE676963A (enrdf_load_stackoverflow) |
| CA (1) | CA656712A (enrdf_load_stackoverflow) |
| CH (1) | CH391159A (enrdf_load_stackoverflow) |
| DK (1) | DK91633C (enrdf_load_stackoverflow) |
| FR (1) | FR1234146A (enrdf_load_stackoverflow) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3370024A (en) * | 1966-02-16 | 1968-02-20 | Zolatone Process Inc | Multicolor coating composition and method of making and packaging same |
| US3635289A (en) * | 1969-08-15 | 1972-01-18 | Woods Res & Dev | Well cementing with a settable water-in-oil emulsion |
| US3956206A (en) * | 1968-06-25 | 1976-05-11 | Keith Sellars | Paints from two or more differently coloured aqueous film-forming polymer emulsions |
| US4009136A (en) * | 1974-06-05 | 1977-02-22 | Rohm And Haas Company | Multicolor coating compositions |
| ITTO20130361A1 (it) * | 2013-05-06 | 2014-11-07 | Candis Srl | Prodotto verniciante per rivestimenti murali |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1370914A (en) * | 1971-07-06 | 1974-10-16 | Ici Ltd | Paint compositions |
| DK152140B (da) * | 1979-02-16 | 1988-02-01 | Kuesters Eduard Maschf | Fremgangsmaade og apparat til moenstring af en fremfoert varebane |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2591904A (en) * | 1947-10-29 | 1952-04-08 | John C Zola | Coating compositions and preparation thereof |
| US2661340A (en) * | 1947-12-31 | 1953-12-01 | Rubber Stichting | Manufacture of cyclized rubber |
-
0
- CA CA656712A patent/CA656712A/en not_active Expired
-
1958
- 1958-01-18 DK DK16358AA patent/DK91633C/da active
-
1959
- 1959-01-14 CH CH6838959A patent/CH391159A/de unknown
- 1959-01-16 FR FR784214A patent/FR1234146A/fr not_active Expired
-
1962
- 1962-07-10 US US208920A patent/US3185653A/en not_active Expired - Lifetime
-
1966
- 1966-02-24 BE BE676963D patent/BE676963A/xx unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2591904A (en) * | 1947-10-29 | 1952-04-08 | John C Zola | Coating compositions and preparation thereof |
| US2661340A (en) * | 1947-12-31 | 1953-12-01 | Rubber Stichting | Manufacture of cyclized rubber |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3370024A (en) * | 1966-02-16 | 1968-02-20 | Zolatone Process Inc | Multicolor coating composition and method of making and packaging same |
| US3956206A (en) * | 1968-06-25 | 1976-05-11 | Keith Sellars | Paints from two or more differently coloured aqueous film-forming polymer emulsions |
| US3635289A (en) * | 1969-08-15 | 1972-01-18 | Woods Res & Dev | Well cementing with a settable water-in-oil emulsion |
| US4009136A (en) * | 1974-06-05 | 1977-02-22 | Rohm And Haas Company | Multicolor coating compositions |
| ITTO20130361A1 (it) * | 2013-05-06 | 2014-11-07 | Candis Srl | Prodotto verniciante per rivestimenti murali |
Also Published As
| Publication number | Publication date |
|---|---|
| CH391159A (de) | 1965-04-30 |
| FR1234146A (fr) | 1960-10-13 |
| DK91633C (da) | 1961-08-28 |
| BE676963A (enrdf_load_stackoverflow) | 1966-07-18 |
| CA656712A (en) | 1963-01-29 |
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