US3179596A - Soap bar for dry skin - Google Patents
Soap bar for dry skin Download PDFInfo
- Publication number
- US3179596A US3179596A US30469A US3046960A US3179596A US 3179596 A US3179596 A US 3179596A US 30469 A US30469 A US 30469A US 3046960 A US3046960 A US 3046960A US 3179596 A US3179596 A US 3179596A
- Authority
- US
- United States
- Prior art keywords
- soap
- skin
- bar
- petrolatum
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000344 soap Substances 0.000 title claims description 76
- 206010013786 Dry skin Diseases 0.000 title claims description 11
- 230000037336 dry skin Effects 0.000 title claims description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 66
- 239000004264 Petrolatum Substances 0.000 claims description 31
- 229940066842 petrolatum Drugs 0.000 claims description 31
- 235000019271 petrolatum Nutrition 0.000 claims description 31
- 239000003921 oil Substances 0.000 claims description 15
- 239000004166 Lanolin Substances 0.000 claims description 12
- 229940039717 lanolin Drugs 0.000 claims description 12
- 235000019388 lanolin Nutrition 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 150000004665 fatty acids Chemical class 0.000 claims description 9
- 239000000470 constituent Substances 0.000 claims description 8
- 239000003760 tallow Substances 0.000 claims description 7
- 239000003925 fat Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 5
- 235000003441 saturated fatty acids Nutrition 0.000 claims description 5
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000000151 deposition Methods 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 4
- BILPUZXRUDPOOF-UHFFFAOYSA-N stearyl palmitate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC BILPUZXRUDPOOF-UHFFFAOYSA-N 0.000 claims 1
- 210000003491 skin Anatomy 0.000 description 29
- 235000011187 glycerol Nutrition 0.000 description 22
- 239000000203 mixture Substances 0.000 description 19
- 125000004432 carbon atom Chemical group C* 0.000 description 17
- 235000019198 oils Nutrition 0.000 description 13
- 239000000047 product Substances 0.000 description 10
- 239000003599 detergent Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 238000001035 drying Methods 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 235000019864 coconut oil Nutrition 0.000 description 5
- 239000003240 coconut oil Substances 0.000 description 5
- 235000019197 fats Nutrition 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000002671 adjuvant Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 210000004927 skin cell Anatomy 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 238000012935 Averaging Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000002285 radioactive effect Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 2
- 229940001584 sodium metabisulfite Drugs 0.000 description 2
- 235000010262 sodium metabisulphite Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- 101100321000 Mus musculus Ypel3 gene Proteins 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 210000002919 epithelial cell Anatomy 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000002888 oleic acid derivatives Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000015541 sensory perception of touch Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/24—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/265—Organic compounds, e.g. vitamins containing oxygen containing glycerol
Definitions
- a milled and plodded toilet soap bar comprises 70-80% sodium salt of higher fatty acids of 8 to 20 carbon atoms, of which acids 90- 75% thereof is of fatty acids of 16 to 20 carbon atoms and 1025% thereof is of saturated fatty acids of 8 to 14 carbon atoms, 4 to 7% of a mixture of hydrocarbons of about 16 to 32 carbon atoms and a glycerol content of 30 to 70% of the hydrocarbon weight.
- a bar of this description is particularly suitable for cleansing dry skin and simultaneously deposits oleaginous soap bar constituent on the skin.
- a milled and plodded toilet soap bar comprises 78% settled white sodium soap derived from a mixture of about 20 parts coconut oil and 80 parts tallow, about petrolatum, 2.5% glycerol, 1.5% lanolin, 12% Water and 1% adjuvants.
- the soap employed is one from which substantially all inorganic salts, unreacted fats and oils and glycerol have been removed.
- the product has been found to deposit petrolatum on the skin in normal washing, leading to a higher lipophilic 'ice content thereof and improving the appearance and feel of the skin, as well as counteracting the tendency to drying of the skin after washing.
- the water soluble soap which is the major constituent of this product and contributes most to its desirable physical properties, such as cleaning power, satisfactory solubility, processability and appearance, as well as other use characteristics associated with good toilet soaps, is a mixture of sodium salts of higher fatty acids of 8 to 20 carbon atoms.
- the proportion of soaps containing 8 to 14 carbon atoms should be kept low in this bar, intended primarily for use in the cleansing of skin deficient in natural oils. Soaps of 8l4 carbon atoms are less unctuous in feel than the higher and unsaturated soaps and thereby give some users the impression that their application is drying to the skin.
- soaps have been reported to be harsher to the skin than those of higher fatty acids but, when mixed with higher soaps, as in the present bars, no significant change in mildness was observed.
- Some lower saturated fatty acids of 8 to 14 carbon atoms should be present to give the soap a balanced mixture of detergents which is more amorphous, foams more quickly and better removes various types of dirt and soil from the skin. It has been found that at least 10% is desirable for these purposes and it is preferable that no more than 25% of the saturated soaps of 8 0t 14 carbon atoms should be present.
- the balance of the soap constituent is a mixture derived from fatty acids of 16 to 20 carbon atoms.
- Such a mixture will contain predominant proportions of stearic, oleic and palmitic acid soaps with minor proportions of palmitoleic and arachidic soaps sometimes present.
- These higher fatty acid soaps give the bar a slip and oily feel to the skin when they are employed in the described proportions in a toilet soap of this composition and such a slip or lubricity is desirable in the present bars.
- C -C 90 015-020 soap ranges a commercially acceptable and proven soap is obtained which can be manufactured easily and has the desirable combination of properties which suit it for use in a product primarily intended for cleansing dry skin.
- composition of this invention is primarily a soap bar with additional desirable characteristics resulting from the presence of the other recited constituents.
- the amount of sodium soap present should be within the range of 7080% of the bar.
- the sodium soaps in the present bars may be made by the usual soap making techniques which result in a product essentially free of inorganic salt, glycerol, unsaponified and unsaponifiable materials. It is preferred to use settled white kettle soap of good quality, which has been dried into the usual ribbon or chip form.
- the oil charge employed to obtain such a soap of higher fatty acid content specified is preferably composed of coconut oil and tallow. It is preferred to use parts tallow and 20 parts coconut oil but the proportions may be varied from 94:10 to 75:25.
- a bar containing only soap and the proportion of petrolatum recited is significantly different in some respects from a soap bar and, in general, the comparison of physical and processing properties, apart'from 'superfatting effect, is unfavorable to the petrolatum-containing detergent.
- the petrolatum or hydrocarbon oil mixture tends to soften the soap and make it more difficult to process. It also affects the performance and feel of a wetted bar, tending to slow down the development of good lathering and to reduce the desirable slipperiness of the bar.
- glycerol a sufficient quantity of glycerol, in accordance with this invention, has a benficial result on the product performance and helps it to be efficiently made in standard soap manufacturing equipment.
- the percentage of glycerol employed should be about half as much as that of petrolatum and preferably 2.5% glycerol is used.
- the glycerol content may be between 30 and 70% of the petrolatum weight.
- lanolin preferably 1.5%
- the lanolin more closely approximating the chemical nature of the sebum, supplements the petrolatum and improves conditioning of the skin.
- Lanolin usually has a very detrimental effect on lathering power of soap, even more so than petrolatum, but
- small percentages of adjuvants may be used to give the bar special desired properties and to improve its stability.
- the proportion of adjuvants is preferably kept low to maintain the essential soap-like characteristics of the bar.
- the adjuvants employed may be mentioned perfume, fluorescent dyes, stabilizers, antioxidants, solvents, pigmeuts and coloring agents.
- Sodium metabisulfite in the formula even only at 0.1 to 0.2%, significantly improves the bar color on storage and is a preferred stabilizing and bleaching agent.
- the solvents polyethylene glycol is preferably employed to dissolve bactericide, e.g., tetrachlorsalicylanilide, and better distribute it through the bar, when it is in the formula.
- the content of additives will be less than 5 and preferably less than 2%.
- the formula given above was made with 6.0% petrolatum, instead of the combination of petrolatum and lanolin, other constituents remaining constant, except for a compensating increase in soap content.
- the bar made was made according to the same method, was tested and was found to be satisfactory but the lanolin-petrolatumglycerine combination is preferable. Subjects with dry skin conditions, who employed these bars, noted with approval the better feel of the skin and an increase in softness and suppleness, together with an improvement in appearance.
- a milled and plodded toilet soap bar particularly suitable for cleansing dry skin and depositing oleaginous soap bar constituent on the skin comprising 70-80% of soap substantially free of inorganic salts, unreacted fats and oils and glycerol, the soap being of higher fatty acids of 8 to 20 carbon atoms predominantly of 16 to 18 carbon atoms, 10-25% of the soap being of saturated fatty acids of 8 to 14 carbon atoms and 90-75% of 16 to 20 carbon atoms, being that derived from an oil charge of 10 to coconut oil and 90-75% tallow, 4 to 7% petrolatum, to of the petrolaturn of glycerol, 1 to 2.5% lanolin and 10 to 16% water.
- a milled and plodded toilet soap bar particularly suitable for cleansing dry skin and depositing petrolatum on the skin comprising about 78% settled White sodium soap derived from a mixture of about 20 parts coconut oil and 80 parts tallow, which soap is substantially free of inorganic salts, unreacted fats and oils and glycerol, about 5% petrolatum, about 2.5% glycerol, about 1.5% lanolin and about 12% water.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE604013D BE604013A (xx) | 1960-05-20 | ||
NL264887D NL264887A (xx) | 1960-05-20 | ||
IT649802D IT649802A (xx) | 1960-05-20 | ||
US30469A US3179596A (en) | 1960-05-20 | 1960-05-20 | Soap bar for dry skin |
US47925A US3224976A (en) | 1960-05-20 | 1960-08-08 | Detergent bar |
GB16722/61A GB941807A (en) | 1960-05-20 | 1961-05-08 | Detergent bars |
CH555261A CH408259A (de) | 1960-05-20 | 1961-05-13 | Riegelseife |
DK199561AA DK107434C (da) | 1960-05-20 | 1961-05-15 | Rensemiddel i stykform. |
DEC24113A DE1165191B (de) | 1960-05-20 | 1961-05-15 | Stueckfoermige Toiletteseife |
FR862088A FR1290558A (fr) | 1960-05-20 | 1961-05-17 | Pain détergent |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US30469A US3179596A (en) | 1960-05-20 | 1960-05-20 | Soap bar for dry skin |
US47925A US3224976A (en) | 1960-05-20 | 1960-08-08 | Detergent bar |
Publications (1)
Publication Number | Publication Date |
---|---|
US3179596A true US3179596A (en) | 1965-04-20 |
Family
ID=26706077
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US30469A Expired - Lifetime US3179596A (en) | 1960-05-20 | 1960-05-20 | Soap bar for dry skin |
US47925A Expired - Lifetime US3224976A (en) | 1960-05-20 | 1960-08-08 | Detergent bar |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US47925A Expired - Lifetime US3224976A (en) | 1960-05-20 | 1960-08-08 | Detergent bar |
Country Status (8)
Country | Link |
---|---|
US (2) | US3179596A (xx) |
BE (1) | BE604013A (xx) |
CH (1) | CH408259A (xx) |
DE (1) | DE1165191B (xx) |
DK (1) | DK107434C (xx) |
GB (1) | GB941807A (xx) |
IT (1) | IT649802A (xx) |
NL (1) | NL264887A (xx) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3941712A (en) * | 1972-01-10 | 1976-03-02 | Ferrara Peter J | Soap composition and process of producing such |
US4169066A (en) * | 1977-07-15 | 1979-09-25 | Colgate-Palmolive Company | Process of incorporating poly(ethylene oxide) into soap |
US4169067A (en) * | 1977-07-15 | 1979-09-25 | Colgate-Palmolive Company | Bar product |
US4405492A (en) * | 1982-03-22 | 1983-09-20 | The Procter & Gamble Company | Process for making high-glycerin soap bars |
US4547307A (en) * | 1981-09-17 | 1985-10-15 | Udo Hoppe | Cake of soap with deodorizing action |
US4647394A (en) * | 1981-04-07 | 1987-03-03 | Mitsubishi Chemical Industries Limited | Soap composition |
US4707496A (en) * | 1984-07-19 | 1987-11-17 | Simmons Nominees Pty. Ltd. | Insect repellent soap composition |
US4808322A (en) * | 1988-03-10 | 1989-02-28 | Mclaughlin James H | Skin cleansing-cream conditioning bar |
US4941990A (en) * | 1988-03-10 | 1990-07-17 | Mclaughlin James H | Skin cleansing-cream conditioning bar |
US20070021314A1 (en) * | 2005-06-18 | 2007-01-25 | Salvador Charlie R | Cleansing bar compositions comprising a high level of water |
US20070155639A1 (en) * | 2005-06-18 | 2007-07-05 | Salvador Charlie R | Cleansing bar compositions comprising a high level of water |
US8129327B2 (en) | 2006-12-01 | 2012-03-06 | The Procter & Gamble Company | Packaging for high moisture bar soap |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3431207A (en) * | 1965-06-28 | 1969-03-04 | Malmstrom Chem Corp | Water-insoluble bacteriostats in soap and detergent solutions |
US3326808A (en) * | 1965-08-25 | 1967-06-20 | Pfizer & Co C | Antiseptic detergent composition |
US3494869A (en) * | 1966-07-11 | 1970-02-10 | Lever Brothers Ltd | Superfatted soap bars and process for their preparation |
US3622517A (en) * | 1968-03-06 | 1971-11-23 | Marathon Oil Co | Synthetic detergent compositions |
US3639286A (en) * | 1968-05-28 | 1972-02-01 | Mario Ballestra | Synthetic detergent in bar or cake form and the method to manufacture same |
US3538217A (en) * | 1969-04-02 | 1970-11-03 | Grace W R & Co | Phenolic germicidal compositions |
BE756790A (fr) * | 1969-10-01 | 1971-03-29 | Henkel & Cie Gmbh | Detergent faconne a base de surfactifs synthetiques |
GB1492938A (en) * | 1974-01-11 | 1977-11-23 | Procter & Gamble Ltd | Low sudsing detergent compositions |
US4867899A (en) * | 1987-11-30 | 1989-09-19 | Colgate-Palmolive Company | Sodium monoglyceride sulfate detergent composition bar and process for manufacture thereof |
GB9106959D0 (en) * | 1991-04-03 | 1991-05-22 | Unilever Plc | Detergent composition |
US5254334A (en) * | 1992-05-04 | 1993-10-19 | Imaginative Research Associates, Inc. | Anhydrous foaming composition containing low concentrations of detergents and high levels of glycerin amd emollients such as oils and esters |
US5409706A (en) * | 1992-05-04 | 1995-04-25 | Imaginative Research Associates, Inc. | Anhydrous foaming composition containing low concentrations of detergents and high levels of glycerin and emollients such as oils and esters |
US5312559A (en) * | 1992-07-07 | 1994-05-17 | The Procter & Gamble Company | Personal cleanser with moisturizer |
US5451338A (en) * | 1993-08-06 | 1995-09-19 | Avon Products, Inc. | Mar resistant soap formulations |
DE4432366A1 (de) * | 1994-09-12 | 1996-03-14 | Henkel Kgaa | Milde Detergensgemische |
WO1997022684A1 (en) * | 1995-12-20 | 1997-06-26 | The Procter & Gamble Company | Pour molded personal cleansing bar |
GB2459093B (en) * | 2008-04-08 | 2013-01-02 | Unilever Plc | Extruded soap bars comprising a starch-polyol structuring system |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB444165A (en) * | 1934-06-08 | 1936-03-16 | Victor Boulez | A process of manufacturing soap |
GB639630A (en) * | 1948-02-06 | 1950-07-05 | Peter Lunt & Company Ltd | Improvements in or relating to detergent compositions |
GB760210A (en) * | 1953-12-31 | 1956-10-31 | Monsanto Chemicals | Antiseptic detergent compositions |
US2795554A (en) * | 1952-04-21 | 1957-06-11 | Monsanto Chemicals | Antiseptic soap composition |
CA564080A (en) * | 1958-09-30 | Swift And Company | Toilet soap composition | |
US2894986A (en) * | 1956-07-23 | 1959-07-14 | Monsanto Chemicals | Diphenyl urea derivatives |
US2948684A (en) * | 1957-05-10 | 1960-08-09 | Lever Brothers Ltd | Disinfectant and deodorant soap composition |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2781320A (en) * | 1957-02-12 | All purpose | ||
BE378069A (xx) * | 1930-04-08 | |||
US2438169A (en) * | 1945-07-12 | 1948-03-23 | Allied Chem & Dye Corp | Manufacture of detergents |
US2494580A (en) * | 1947-05-24 | 1950-01-17 | Procter & Gamble | Detergent composition |
US2749315A (en) * | 1951-04-28 | 1956-06-05 | Colgate Palmolive Co | Toilet detergent bar and process of preparing same |
US2714093A (en) * | 1952-07-02 | 1955-07-26 | Blumenthal Armin | Method of preparing detergent compositions |
US2894912A (en) * | 1954-09-21 | 1959-07-14 | Lever Brothers Ltd | Isethionate detergent bar |
US2921907A (en) * | 1955-01-07 | 1960-01-19 | Monsanto Chemicals | Soap stabilization |
US2982735A (en) * | 1955-09-08 | 1961-05-02 | Procter & Gamble | Detergent milled bar and process of preparing same |
GB799075A (en) * | 1955-10-14 | 1958-07-30 | Unilever Ltd | Improvements in or relating to detergent tablets |
-
0
- IT IT649802D patent/IT649802A/it unknown
- NL NL264887D patent/NL264887A/xx unknown
- BE BE604013D patent/BE604013A/xx unknown
-
1960
- 1960-05-20 US US30469A patent/US3179596A/en not_active Expired - Lifetime
- 1960-08-08 US US47925A patent/US3224976A/en not_active Expired - Lifetime
-
1961
- 1961-05-08 GB GB16722/61A patent/GB941807A/en not_active Expired
- 1961-05-13 CH CH555261A patent/CH408259A/de unknown
- 1961-05-15 DE DEC24113A patent/DE1165191B/de active Pending
- 1961-05-15 DK DK199561AA patent/DK107434C/da active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA564080A (en) * | 1958-09-30 | Swift And Company | Toilet soap composition | |
GB444165A (en) * | 1934-06-08 | 1936-03-16 | Victor Boulez | A process of manufacturing soap |
GB639630A (en) * | 1948-02-06 | 1950-07-05 | Peter Lunt & Company Ltd | Improvements in or relating to detergent compositions |
US2795554A (en) * | 1952-04-21 | 1957-06-11 | Monsanto Chemicals | Antiseptic soap composition |
GB760210A (en) * | 1953-12-31 | 1956-10-31 | Monsanto Chemicals | Antiseptic detergent compositions |
US2894986A (en) * | 1956-07-23 | 1959-07-14 | Monsanto Chemicals | Diphenyl urea derivatives |
US2948684A (en) * | 1957-05-10 | 1960-08-09 | Lever Brothers Ltd | Disinfectant and deodorant soap composition |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3941712A (en) * | 1972-01-10 | 1976-03-02 | Ferrara Peter J | Soap composition and process of producing such |
US4169066A (en) * | 1977-07-15 | 1979-09-25 | Colgate-Palmolive Company | Process of incorporating poly(ethylene oxide) into soap |
US4169067A (en) * | 1977-07-15 | 1979-09-25 | Colgate-Palmolive Company | Bar product |
US4647394A (en) * | 1981-04-07 | 1987-03-03 | Mitsubishi Chemical Industries Limited | Soap composition |
US4547307A (en) * | 1981-09-17 | 1985-10-15 | Udo Hoppe | Cake of soap with deodorizing action |
US4405492A (en) * | 1982-03-22 | 1983-09-20 | The Procter & Gamble Company | Process for making high-glycerin soap bars |
US4707496A (en) * | 1984-07-19 | 1987-11-17 | Simmons Nominees Pty. Ltd. | Insect repellent soap composition |
US4808322A (en) * | 1988-03-10 | 1989-02-28 | Mclaughlin James H | Skin cleansing-cream conditioning bar |
US4941990A (en) * | 1988-03-10 | 1990-07-17 | Mclaughlin James H | Skin cleansing-cream conditioning bar |
US20070021314A1 (en) * | 2005-06-18 | 2007-01-25 | Salvador Charlie R | Cleansing bar compositions comprising a high level of water |
US20070155639A1 (en) * | 2005-06-18 | 2007-07-05 | Salvador Charlie R | Cleansing bar compositions comprising a high level of water |
US8080503B2 (en) | 2005-06-18 | 2011-12-20 | The Procter & Gamble Company | Cleansing bar compositions comprising a high level of water |
US8129327B2 (en) | 2006-12-01 | 2012-03-06 | The Procter & Gamble Company | Packaging for high moisture bar soap |
Also Published As
Publication number | Publication date |
---|---|
DE1165191B (de) | 1964-03-12 |
NL264887A (xx) | |
US3224976A (en) | 1965-12-21 |
GB941807A (en) | 1963-11-13 |
CH408259A (de) | 1966-02-28 |
IT649802A (xx) | |
BE604013A (xx) | |
DK107434C (da) | 1967-05-29 |
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