US2781320A - All purpose - Google Patents
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- Publication number
- US2781320A US2781320A US2781320DA US2781320A US 2781320 A US2781320 A US 2781320A US 2781320D A US2781320D A US 2781320DA US 2781320 A US2781320 A US 2781320A
- Authority
- US
- United States
- Prior art keywords
- sodium
- weight
- water
- bar
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 claims description 82
- -1 ALKYLBENZENE SULFATES Chemical class 0.000 claims description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 54
- 239000011780 sodium chloride Substances 0.000 claims description 46
- 150000003839 salts Chemical class 0.000 claims description 32
- 229910052783 alkali metal Inorganic materials 0.000 claims description 22
- 150000001340 alkali metals Chemical class 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 150000003871 sulfonates Chemical class 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 10
- 150000007513 acids Chemical class 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 10
- 101700018994 ARYL Proteins 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims 2
- 239000000344 soap Substances 0.000 description 42
- 239000011734 sodium Substances 0.000 description 36
- 239000000306 component Substances 0.000 description 34
- 229910052708 sodium Inorganic materials 0.000 description 32
- 125000004432 carbon atoms Chemical group C* 0.000 description 26
- 125000000217 alkyl group Chemical group 0.000 description 24
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 24
- MRTOHWYKOIAOSC-UHFFFAOYSA-N 1,2-di(propan-2-yl)naphthalene;sodium Chemical compound [Na].C1=CC=CC2=C(C(C)C)C(C(C)C)=CC=C21 MRTOHWYKOIAOSC-UHFFFAOYSA-N 0.000 description 14
- 210000003491 Skin Anatomy 0.000 description 14
- 239000000203 mixture Substances 0.000 description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 14
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 12
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 12
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 12
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 12
- CDFWDLTWTVIPBT-UHFFFAOYSA-N 1,4-dioxo-1,4-dipentoxybutane-2-sulfonic acid;sodium Chemical compound [Na].CCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCC CDFWDLTWTVIPBT-UHFFFAOYSA-N 0.000 description 10
- 125000001931 aliphatic group Chemical group 0.000 description 10
- 125000005907 alkyl ester group Chemical group 0.000 description 10
- 239000001768 carboxy methyl cellulose Substances 0.000 description 10
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 10
- 229910052700 potassium Inorganic materials 0.000 description 10
- 239000011591 potassium Substances 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 8
- 238000005336 cracking Methods 0.000 description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 description 8
- 235000011152 sodium sulphate Nutrition 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 239000003760 tallow Substances 0.000 description 8
- 229920002472 Starch Polymers 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000003801 milling Methods 0.000 description 6
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 235000019832 sodium triphosphate Nutrition 0.000 description 6
- 239000008234 soft water Substances 0.000 description 6
- 235000019698 starch Nutrition 0.000 description 6
- ULUAUXLGCMPNKK-UHFFFAOYSA-N (±)-Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 4
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 4
- GHNRTXCRBJQVGN-UHFFFAOYSA-N 4-dodecan-6-ylbenzenesulfonic acid Chemical class CCCCCCC(CCCCC)C1=CC=C(S(O)(=O)=O)C=C1 GHNRTXCRBJQVGN-UHFFFAOYSA-N 0.000 description 4
- 229920002261 Corn starch Polymers 0.000 description 4
- PAFZNILMFXTMIY-UHFFFAOYSA-N Cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 4
- 229940060367 Inert Ingredients Drugs 0.000 description 4
- 239000004166 Lanolin Substances 0.000 description 4
- 229940039717 Lanolin Drugs 0.000 description 4
- 229940067606 Lecithin Drugs 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L MgCl2 Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 150000008051 alkyl sulfates Chemical class 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000008120 corn starch Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 239000003974 emollient agent Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 229920000591 gum Polymers 0.000 description 4
- 239000008233 hard water Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- SUMDYPCJJOFFON-UHFFFAOYSA-M isethionate Chemical compound OCCS([O-])(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-M 0.000 description 4
- 235000019388 lanolin Nutrition 0.000 description 4
- 239000000787 lecithin Substances 0.000 description 4
- 235000010445 lecithin Nutrition 0.000 description 4
- 229920005610 lignin Polymers 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000006011 modification reaction Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 235000002639 sodium chloride Nutrition 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000271 synthetic detergent Substances 0.000 description 4
- 229940104261 taurate Drugs 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- RSWGJHLUYNHPMX-HNBVOPMISA-N (1R,4aR,4bS,10aR)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical class C([C@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-HNBVOPMISA-N 0.000 description 2
- FXZAUBIBKADOBA-UHFFFAOYSA-N 1,4-bis(2-methylpropoxy)-1,4-dioxobutane-2-sulfonic acid;sodium Chemical compound [Na].CC(C)COC(=O)CC(S(O)(=O)=O)C(=O)OCC(C)C FXZAUBIBKADOBA-UHFFFAOYSA-N 0.000 description 2
- YUCTUWYCFFUCOR-UHFFFAOYSA-N 1,4-dihexoxy-1,4-dioxobutane-2-sulfonic acid;sodium Chemical compound [Na].CCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCC YUCTUWYCFFUCOR-UHFFFAOYSA-N 0.000 description 2
- OXLXSOPFNVKUMU-UHFFFAOYSA-N 1,4-dioctoxy-1,4-dioxobutane-2-sulfonic acid Chemical compound CCCCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCCCC OXLXSOPFNVKUMU-UHFFFAOYSA-N 0.000 description 2
- HJYITXYOCDILBF-BQASJOSNSA-O 2-[2,3-bis[[(E)-nonadec-9-enoyl]oxy]propoxy-hydroxyphosphoryl]oxyethyl-trimethylazanium Chemical compound CCCCCCCCC\C=C\CCCCCCCC(=O)OCC(COP(O)(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C\CCCCCCCCC HJYITXYOCDILBF-BQASJOSNSA-O 0.000 description 2
- UKIMGCJPCFNHHF-UHFFFAOYSA-N 2-methylpropyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCC(C)C)=CC=CC2=C1 UKIMGCJPCFNHHF-UHFFFAOYSA-N 0.000 description 2
- RGVIYLQXUDJMCP-UHFFFAOYSA-N 2-tridecylphenol Chemical compound CCCCCCCCCCCCCC1=CC=CC=C1O RGVIYLQXUDJMCP-UHFFFAOYSA-N 0.000 description 2
- ZRGXFRPXHJVPCM-UHFFFAOYSA-N 3-butyl-2-phenylphenol;sodium Chemical compound [Na].CCCCC1=CC=CC(O)=C1C1=CC=CC=C1 ZRGXFRPXHJVPCM-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N Behenic acid Chemical class CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- RMEXQHBEFYDOAE-UHFFFAOYSA-N C(CCC(C)C)OS(=O)(=O)C1=CC=CC=C1.[Na] Chemical compound C(CCC(C)C)OS(=O)(=O)C1=CC=CC=C1.[Na] RMEXQHBEFYDOAE-UHFFFAOYSA-N 0.000 description 2
- RIXLIAYYGCYMPR-UHFFFAOYSA-M CC(C)CCCCCS([O-])(=O)=O Chemical compound CC(C)CCCCCS([O-])(=O)=O RIXLIAYYGCYMPR-UHFFFAOYSA-M 0.000 description 2
- 241000543381 Cliftonia monophylla Species 0.000 description 2
- 240000007170 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- KWKXNDCHNDYVRT-UHFFFAOYSA-N Dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 2
- 240000001327 Echinochloa stagnina Species 0.000 description 2
- 235000001418 Echinochloa stagnina Nutrition 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 101700015827 FYPP3 Proteins 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N Hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- JJWLVOIRVHMVIS-UHFFFAOYSA-N Isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N Maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Chemical class CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 235000019483 Peanut oil Nutrition 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N Propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 235000003434 Sesamum indicum Nutrition 0.000 description 2
- 240000003670 Sesamum indicum Species 0.000 description 2
- 241000687904 Soa Species 0.000 description 2
- 241000529895 Stercorarius Species 0.000 description 2
- 229940033134 Talc Drugs 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J Tetrasodium pyrophosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- LLZRNZOLAXHGLL-UHFFFAOYSA-J Titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 2
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 description 2
- 229940045136 Urea Drugs 0.000 description 2
- 229940093612 Zein Drugs 0.000 description 2
- 229920002494 Zein Polymers 0.000 description 2
- DYWHAGUHISAWBU-UHFFFAOYSA-N [Na].CCCCC1=CC=CC=C1C1=CC=CC=C1 Chemical compound [Na].CCCCC1=CC=CC=C1C1=CC=CC=C1 DYWHAGUHISAWBU-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive Effects 0.000 description 2
- 235000010443 alginic acid Nutrition 0.000 description 2
- 229920000615 alginic acid Polymers 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 125000004104 aryloxy group Chemical group 0.000 description 2
- 125000004429 atoms Chemical group 0.000 description 2
- SATZVFKUEAMFPB-UHFFFAOYSA-N azanium;sodium;chloride Chemical compound [NH4+].[Na].[Cl-] SATZVFKUEAMFPB-UHFFFAOYSA-N 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 235000012970 cakes Nutrition 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 235000011148 calcium chloride Nutrition 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 229960000539 carbamide Drugs 0.000 description 2
- 125000005587 carbonate group Chemical group 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910052570 clay Inorganic materials 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000005687 corn oil Nutrition 0.000 description 2
- 239000002285 corn oil Substances 0.000 description 2
- 230000000875 corresponding Effects 0.000 description 2
- 235000012343 cottonseed oil Nutrition 0.000 description 2
- 239000002385 cottonseed oil Substances 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- UZILCZKGXMQEQR-UHFFFAOYSA-N decylbenzene Chemical compound CCCCCCCCCCC1=CC=CC=C1 UZILCZKGXMQEQR-UHFFFAOYSA-N 0.000 description 2
- 230000001627 detrimental Effects 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 2
- 229940042397 direct acting antivirals Cyclic amines Drugs 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 235000001797 dul Nutrition 0.000 description 2
- 235000001803 dul Nutrition 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N ethyl amine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000009432 framing Methods 0.000 description 2
- 230000000855 fungicidal Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 230000002070 germicidal Effects 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 230000000266 injurious Effects 0.000 description 2
- 238000004900 laundering Methods 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000001050 lubricating Effects 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 235000011147 magnesium chloride Nutrition 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 159000000003 magnesium salts Chemical class 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 229940113083 morpholine Drugs 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 2
- 231100000344 non-irritating Toxicity 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic Effects 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical class C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000004006 olive oil Substances 0.000 description 2
- 235000008390 olive oil Nutrition 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical class C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000312 peanut oil Substances 0.000 description 2
- 101700004450 phpP Proteins 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- LBCVFLWDOITWFP-UHFFFAOYSA-N propan-2-yl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OC(C)C)=CC=CC2=C1 LBCVFLWDOITWFP-UHFFFAOYSA-N 0.000 description 2
- 230000001105 regulatory Effects 0.000 description 2
- 150000003385 sodium Chemical class 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 description 2
- 235000011008 sodium phosphates Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- IXYACKYHUWCLAM-UHFFFAOYSA-M sodium;2-ethylhex-1-ene-1-sulfonate Chemical compound [Na+].CCCCC(CC)=CS([O-])(=O)=O IXYACKYHUWCLAM-UHFFFAOYSA-M 0.000 description 2
- VQOIVBPFDDLTSX-UHFFFAOYSA-M sodium;3-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC(S([O-])(=O)=O)=C1 VQOIVBPFDDLTSX-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 235000014347 soups Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000000576 supplementary Effects 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- RWRDLPDLKQPQOW-UHFFFAOYSA-N tetrahydropyrrole Substances C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 230000003245 working Effects 0.000 description 2
- 239000005019 zein Substances 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/126—Acylisethionates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
Definitions
- This invention relates to the production-ofa deter-gent bar or. cake and more particularly to an-all purpose detergent bar suitable foruse insoft. water, hard Water and seawater.
- AlLingredients in the. bar should-have approximately the same rate of. solubility or dispersibility in order to prevent pitting, grittiness, and the-like. 31 The rate of solubility. should be approximately the same in cold water as itis. in hot water, andshould not beun'dul'y high. in order to prevent rapid dissolution when left in water;
- a still fu'rfne'r object of this invention is to provide a detergent har capable of satisfactory performance inwater of any degree of hardhess-from-ze-ro to'the hardness of sea water and: at any teinperatureof from 0 C. to C. for washing dishware and kitchen utensils and. the like, for hand laundering ofclothing, for useas a'general purpose toilet soap, and for. shavingpur-poses.
- Still another object of this invention is to provide a'd'etergent barhaving the properties-ofa good grade of soft water toilet soap.
- a detergent bar comprising (A) a-syntheticorganic anionicdetergent selected from the groupbonsisting of the water-soluble alkali metal and ainine salts of higheraliphatic sulfates and sulf-onates eontaining a hydrocarbon radicalwith at least ll carbon ato'ms in a straight chain, and alkyl aryl sulfates and sulfonates containing at least one-alkylside chain radical of at least 8 carbo'natoms, B) a synthetic organic anionic lathering agent selected from the group consisting of'tiie water soluble alkali metal and" amine salts of lower alkyl aryl sulfates and sulfonat'es containing" at least one alkyl side chain radical of from 2' to 6 carbon atoms, and (C) a syntheticorganic anioniclathen ing
- long chain alkyl aryl sulfonates such as sodium o'c'tyl nonyl dodecyl, decyl -and tetra'decylbenzene sulfonat'es
- the correspond ing' acyl ethyltauratesslong chainalkyloxyethylene sulfates such asisodium: or.
- potassium laurylpo'lyoxyethylene sulfate sodium laurylmonoonyethylene: sulfate, sodium octadecylpolyoxyethylenesulfate, and sodiumcetylpolyoxyethylene sulfate, long chain alkyl' aryl oxy'ethylene sulfates suchraslammonium, sodium, or potassium nony-L, octyl-, and tridecylphenol monoand polyoxyethylene.
- sulfates, long chain alkyl sulfates such.
- Component A may be used in quan- 3 tities varying fromabout 5 to 90 percent, and preferably from about 5 to 50 percent by weight of the bar.
- component B As the lower alkyl aryl lathering agent suitable for use as component B in the instant invention there may be mentioned sodium diisopropyl naphthalene sulfonate, sodium isopropyl naphthalene sulfonate, sodium diisobntyl naphthalene sulfonate, sodium isobutyl naphthalene sulfonate, sodium isohexylbenzene sulfonate, monobutyl biphenyl sodium monosulfonate, monobutylphenylphenol sodium monosulfonate, dibutylphenylphenol sodium disulfonate, and the like.
- Component B may be used in quantities varying from about 2.5 to 75 percent but more preferably from about 5 to percent by weight of the bar.
- the lower alkyl sulfates and sulfonates such as the sodium sulfate derivative of 2-ethyl hexanol-l, sodium 2-ethyl-1-hexenyl sulfonate, sodium isooctyl sulfonate, sodium isononyl (also triisopropylene) sulfonate, lower alkyl esters of aliphatic sulfopolycarboxylic acids such as sodium diamyl sulfosuccinate, sodium diisobutyl sulfosuccinate, sodium dihexyl sulfosuccinate, sodium dioctyl sulfosuccinate, sodium triamyl sulfotricarballylate, sodium triisobutyl sulfotricarballylate, and sodium tri-n-butyl sulf
- soap which is preferably employed in the detergent bar of the instant invention, there may be mentioned the water soluble salts of myristic, palmitic, stearic, behenic, oleic, lauric, abietic, capric, caproic, ricinoleic, linoleic, hydrogenated and dehydrogenated abietic acids, and the surface active hydrolysis products of tallow, cocoanut oil, cottonseed oil, soy-bean oil, peanut oil, sesame, linseed oil, olive oil, corn oil, castor oil and the like. While soap is not essential in the formulation, it is preferable to have from about 25 to 75 percent by weight of the bar present for the purpose of improving the feel, appearance, working properties and the like.
- water-soluble sodium salts of the aforementioned detergents, lathering agents, and soaps are generally preferred, other alkali metal and amine salts may be employed, as for example those with potassium, ammonium, lower alkyl amines such as methylamine, ethylamine, propylamine, and isopropyl amine, lower alkylolamines such as mono-, diand triethanoland isopropanolamines, cyclic amines such as cyclohexylamine, morpholine, and-pyrrolidine, and the like.
- lower alkyl amines such as methylamine, ethylamine, propylamine, and isopropyl amine
- lower alkylolamines such as mono-, diand triethanoland isopropanolamines
- cyclic amines such as cyclohexylamine, morpholine, and-pyrrolidine, and the like.
- Suitable additive e. g. binders, fillers, builders and the like may be added to the detergent bar of the instant invention to provide properties regarded as desirable in any particular instance.
- These may include carboxymethyl cellulose, polyethylene glycol, starch (substituted, degraded or undegraded) lignin, alginates, copolymers of maleic anhydride with styrene and polyvinyl alkyl ethers and the like, urea, zein, lecithin, lanolin, talc, salts such as borax, calcium chloride, magnesium chloride, sodium sulfate, sodium phosphate, tetrasodium pyrophosphate, and sodium tripolyphosphate, oxides and hydroxides such as magnesium oxide, sodium hydroxide, potassium hydroxide and titanium hydroxide, dyes, pigments, perfumes and the like.
- supplementary agents may be used to control the rate of solubility of the bar, improve slip and feel, stabilize it against changes in humidity which cause softening or drying out, improve its appearance and odor, serve as builders and thelike. Their use however must be carefully regulated to prevent undesirable and disadvantageous properties from resulting.
- some inorganic salts are too soluble and are leached out of the bar, mak ing it rough. Others are insoluble or only slightly soluble so that they are left as rough gritty particles on the surface of the bar when the more soluble portions are dissolved out. Many crystallize out on the surface of the bar during storage. Some are too hygroscopic, causing excessive softening of the bar on storage in humid conditions. Most of them make a very hard and dense bar.
- inorganic salts such as sodium sulfate, sodium chloride, ammonium chloride and the like are present in certain of the surfactants employed in the bar as manufactured, but generally and preferably such amounts total no more than about 25 percent by weight of the bar. Bars containing clay, bentonite or rosin usually have a gritty feel and insufficient slip. Some are very dark in color making a very unattractive bar.
- Starches, gums and dextrines are unsatisfactory in large amounts in that they tend to reduce the slip of the bar and dry out, causing cracking and crumbling of the bar. Those of low solubility are preferred since they reduce the rate of consumption of the bar.
- the detergent bar contains a mononuclear long chain alkyl aryl sulfonate, more specifically sodium dodecyl benzene sulfonate, as component A, a lower alkyl naphthalene sulfonate, more specifically sodium diisopropyl naphthalene sulfonate as component B, a salt of a lower alkyl ester of an aliphatic sulfopolycarboxylic acid, more specifically sodium diamyl sulfosuccinate, as component C, and a water-soluble soap such as sodium tallow soap, in addition to small amounts of carboxymethylcellulose and perfume.
- a mononuclear long chain alkyl aryl sulfonate more specifically sodium dodecyl benzene sulfonate
- component A a lower alkyl naphthalene sulfonate
- a bar manufactured in accordance with this preferred embodiment has highly satisfactory properties for handwashing, shaving, dishwashing, and cotton detergency in soft, hard or sea water. After more than twenty months of storage through humid summer and dry winter conditions, it still had a smooth soap-like appearance, with no evidence of blooming or cracking, and at no time during this period did it exhibit undue softness or brittleness. When used for washing and shaving, it likewise does not exhibit undesirable pitting, blooming, slushing, or cracking.
- the bar in accordance with the instant invention may be produced in well known manner by a framing, milling or similar process.
- frame bars all the ingredients are mixed at elevated temperatures in a crutcher with sufiicient water to permit easy stirring.
- the mass is then poured into wooden frames to cool, solidify and partially dry after which the frame is removed, and the soap block cut into pieces and stamped in a soap press.
- detergent bar as employed herein and the appended"claims'includes any Table Detergent Latherlng agents 7 Soup, Ex. A B- parts Additional components Type Parts Type Parts Type Parts Type Parts,
- the parts of sodium dodecylbenzene sulfonate shown in the table comprise about 85 percent of active ingredient and 15 percent of inert ingredients such as sodium sulfate.
- the parts of sodium diisopropyl naphthalene sulfonate shown in the table comprise about 55 percent of active ingredient and percent of inert ingredients such as sodium sulfate Gum No. 198 is a degraded corn starch.
- STPP is sodium tripolyphosphate.
- CMC and Carbose D are carboxymethyl cellulose.
- Indulin C is lignin.
- Nu- Film is a substituted starch.
- Alcolec S is lecithin.
- Nadex 360 is a corn starch.
- a detergent bar comprising (A) about 5 to 50% by Weight of a synthetic organic anionic detergent selected from the group consisting of the water soluble alkali metal and amine salts of higher aliphatic sulfates and sulfonates containing a hydrocarbon radical with at least 11 carbon atoms in a straight chain, and alkylbenzene sulfates and sulfonates containing at least one alkyl side chain radical of at least 8 carbon atoms, (B) about 5 to 25% by weight of a synthetic organic anionic lathering agent selected from the group consisting of the water solu- 7 .ble alkali metal'and amine salts of alkyl-arylsulfates and sulfonates containing at least one alkyl side chain radical of from 2 to 6 carbon atoms and devoid of alkyl side chain radicals of more than 6 carbon atoms, (C) about 5 to 25% by weight of a synthetic organic anionic lather- -7.
- ing agent selected from the group consisting of the water soluble alkali metal and amine salts of lower branched chain aliphatic sulfates and lower alkyl esters of lower aliphatic sulfopolycarboxylic acids containing an open chain hydrocarbon radical of from 3 to 9 carbon atoms, and from about 25 to 75% by weight of a water-soluble salt of a higher aliphatic monocarboxylic acid.
- component A is an alkyl benzene sulfonate salt containing an alkyl side chain radical of at least 8 carbon atoms.
- a detergent bar comprising (A) about 5 to 50% by Weight of a water-soluble alkyl benzene sulfonate salt containing an alkyl side chain radical of at least 8 carbon atoms, (B) about 5 to 25% by weight of a water-soluble alkyl naphthalene sulfonate salt containing an alkyl side chain radical of from 2 to 6 carbon atoms and devoid of alkyl side chain radicals of more than 6 carbon atoms, ((1) about 5 to by weight of a water-soluble salt of a lower alkyl ester of sulfosuccinic acid, and from about 25 to 75% by weight of a water-soluble salt'of a higher aliphatic monocarboxylic acid.
- a detergent bar comprising about 5 to by weight of sodium dodecylbenzene sulfonate, about 5 to 25% by Weight of sodium diisopropyl naphthalene sulfonate, about 5 to 25 by weight of sodium diamyl sulfosuccinate, and from about 25 to by weight of a water-soluble salt of a higher aliphatic monocarboxylic acid.
- a detergent bar comprising about 20 parts by weight of sodium dodecylbenzene sulfonate, about 20 parts by weight of sodium diisopropyl naphthalene sulfonate, about 10 parts by weight of sodium diamyl sulfosuccinate, about 47 parts by weight of a water soluble salt of a higher aliphatic monocarboxylic acid, and about 2 parts 'by weight of carboxymethyl cellulose.
- a detergent bar comprising about 20 parts by weight of sodium dodecylbenzene sulfonate, about 20 parts by weight of sodium diisopropyl naphthalene sulfonate, about 12 parts by weight of sodium isonony-l sulfonate, and about 45 parts by weight of a water soluble salt of a higher aliphatic monocarboxylic acid.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
ALL PUnPosnnnrERon-NnnAa CharlesfF. Jelinek, Parkwootl, Easton, Pa, Raymond L.
Mayhew, Phillipsliurg, N. L, and John A. Yeager, Easton, Pat, assignors to'General Aniline a; Film Cor poration, New York, N. Y., a corporation-of Delaware No Drawing. Application May 12,1953, Serial No. 354,646
11' Ciaims. (Cl; 252-121) This invention relates to the production-ofa deter-gent bar or. cake and more particularly to an-all purpose detergent bar suitable foruse insoft. water, hard Water and seawater.
It is known. that either hard' water or sea water seriously impairs 'the-eflicie'ncy of soap in regard to detergency and lat-hering due to' the-precipitation: of. the calcium and magnesium. salts of soaps. The additicniof synthetic detergents to soap to improve performance in hard and sea water is an art that has: been: practiced for many years but themajor objection .tosuclr combinations is poor lather. On the other hand, uon-soap-cont ain'ing synthetic detergent bars are not satisfactory due to high cost, hygroscopicity, unsatisfactory solubility characteristics, defatting actionron the skin, lack of lubricating effect-and slipperyrfeel usually associatedwith soap, poor working; properties; standard. soap machinery, brittle ness and poor. cohesion of the barzitself'. A large number'ofibinders andfillers have been used' in conjunction with synthetic; detergentsin. an attempt to obtain a detergentzbar-zresemhling in. activity theusual toilet soap bar Whenused in: soft Water; However, although a con-siderable amount of WOIk.l'1218- beenidone to provide an all purpose detergent bar, none has been truly satisfactory. The followingimay. beconsidered to b'e:the major propcrties: desirable insa; good all purpose detergent bar;
-1.. Good. deter-gency onrthehuman; skim-and fabrics and hard surfaces. in allkindsof water including-hard, soft, sea coldiand hot;
"2; Good soap-like lathering qualities intall types. of water, particularly when used on the skin.
3. Mild'and'non-injurious to-the skin.
4; little or-no tendency towards softening, blooming, crystall-izing, cracking, drying or decomposingunder ordiw nary use and storage conditions.
'55 Pleasing-appearance, feel and' odor.
6. Ability to be produced in standard soa'p mixing equipment.
Attemptg to provide an all purposedetergent' haruvith the aforementioned proper-ties are complicatedand rendered difiiculti by the following facts.
.1-.. Detergents whichr foamr'poorly at the lower concentrations commonlytusedt in'standardifoamz test-s frequently lather; copiously when used atihigher; concentrations such as i uobtained in washing thehands 2.. AlLingredients in the. bar should-have approximately the same rate of. solubility or dispersibility in order to prevent pitting, grittiness, and the-like. 31 The rate of solubility. should be approximately the same in cold water as itis. in hot water, andshould not beun'dul'y high. in order to prevent rapid dissolution when left in water;
4. Some detergents leave sticky or other objectionable residues on the skin.
5: Calcium and magnesiumsalts of'fatty acids formed in situ will seriously impair the lather of many surfactants in certain concentration ranges.
Q6 Patented Feb;
6. Many surfactantstwhich have satisfactory detergent and lathering properties when. used in soft water; have unsatisfactory properties in hard water and 'sea water. This also applies. to soap.
7. Many surfactants which have good detergent and foaming properties by themselves are? unsatisfactory when mixed with soap and certain other surfactants.
it is an object of this invention to provide an all 'p'urposerdeterg'entzbarwhichiwill possess substantially all of the above mention'edvmajor: propertiesdes'lrable in a-good all purpose detergent bar. It is another object of this invention to provide'a detergenfbar capable of p'roducing a satisfactory lather in hot 'an'd cold, soft, hard and sea Water. It is stillanother object of this invention to provide anall purposedetergent bar which will-be nontoxic and non irritating 't'otliehum'anskin; A still fu'rfne'r object of this invention is to provide a detergent har capable of satisfactory performance inwater of any degree of hardhess-from-ze-ro to'the hardness of sea water and: at any teinperatureof from 0 C. to C. for washing dishware and kitchen utensils and. the like, for hand laundering ofclothing, for useas a'general purpose toilet soap, and for. shavingpur-poses. Still another object of this invention is to provide a'd'etergent barhaving the properties-ofa good grade of soft water toilet soap. Other objects and advantages-will appear as the description proceeds.-
The above objects are a-ttained by the instant invention which is directed to-the production of a detergent bar comprising (A) a-syntheticorganic anionicdetergent selected from the groupbonsisting of the water-soluble alkali metal and ainine salts of higheraliphatic sulfates and sulf-onates eontaining a hydrocarbon radicalwith at least ll carbon ato'ms in a straight chain, and alkyl aryl sulfates and sulfonates containing at least one-alkylside chain radical of at least 8 carbo'natoms, B) a synthetic organic anionic lathering agent selected from the group consisting of'tiie water soluble alkali metal and" amine salts of lower alkyl aryl sulfates and sulfonat'es containing" at least one alkyl side chain radical of from 2' to 6 carbon atoms, and (C) a syntheticorganic anioniclathen ingagent selectedfrom' the groupconsi sting'of the water soluble alkali metal and amine salts' of lower aliphatic sulfates and sulfonate'scontaining an open (straight or branched) chain hydrocarbonradical'of from 3' to9car bon atoms; The aforementioned detergent liar jmay 'optionally and preferably co'ntaina water-soluble soap se' lected from 'thagroup consisting of"the water-soluble alkali metal and amineisalts ofihigher aliphatic mono"- carbox-yli-c acids. The detergent bar may also. contain suitable binders, fillers, perfumes-, salts, colors, fungicides, germicides; antiseptios and thelike;
As the-longcliain' detergents suitable for use as component'A-in theinstantirivention, there maybe mentioned long chain alkyl aryl sulfonates' such as sodium o'c'tyl nonyl dodecyl, decyl -and tetra'decylbenzene sulfonat'es, Nlong chain acylv N alkyl taurates such as'sodium oleoyl methyltaurate,='sodium pal'niitoyl methyl taurate, sodium or potassium lauroyl methyl taurate, and the correspond ing' acyl ethyltauratesslong chainalkyloxyethylene sulfates such asisodium: or. potassium laurylpo'lyoxyethylene sulfate, sodium laurylmonoonyethylene: sulfate, sodium octadecylpolyoxyethylenesulfate, and sodiumcetylpolyoxyethylene sulfate, long chain alkyl' aryl oxy'ethylene sulfates suchraslammonium, sodium, or potassium nony-L, octyl-, and tridecylphenol monoand polyoxyethylene. sulfates, long chain alkyl sulfates such. as sodium laur'y l and steanylsulfates, long ehain alkylisethionatessuch.-as sodiumoleic isethionate, sodiiun lauric isethionate and the like. Miiitures of the above mentioneddetergents may also be employed. Component A may be used in quan- 3 tities varying fromabout 5 to 90 percent, and preferably from about 5 to 50 percent by weight of the bar.
As the lower alkyl aryl lathering agent suitable for use as component B in the instant invention there may be mentioned sodium diisopropyl naphthalene sulfonate, sodium isopropyl naphthalene sulfonate, sodium diisobntyl naphthalene sulfonate, sodium isobutyl naphthalene sulfonate, sodium isohexylbenzene sulfonate, monobutyl biphenyl sodium monosulfonate, monobutylphenylphenol sodium monosulfonate, dibutylphenylphenol sodium disulfonate, and the like. Component B may be used in quantities varying from about 2.5 to 75 percent but more preferably from about 5 to percent by weight of the bar.
As the lower aliphatic lathering agent suitable for use as component C in the instant invention there may be mentioned the lower alkyl sulfates and sulfonates such as the sodium sulfate derivative of 2-ethyl hexanol-l, sodium 2-ethyl-1-hexenyl sulfonate, sodium isooctyl sulfonate, sodium isononyl (also triisopropylene) sulfonate, lower alkyl esters of aliphatic sulfopolycarboxylic acids such as sodium diamyl sulfosuccinate, sodium diisobutyl sulfosuccinate, sodium dihexyl sulfosuccinate, sodium dioctyl sulfosuccinate, sodium triamyl sulfotricarballylate, sodium triisobutyl sulfotricarballylate, and sodium tri-n-butyl sulfotricarballylate, and the like. Component C may be used in quantities varying from about 2.5 to 75 percent, but more preferably from about 5 to 25 percent by weight of the bar.
As the soap which is preferably employed in the detergent bar of the instant invention, there may be mentioned the water soluble salts of myristic, palmitic, stearic, behenic, oleic, lauric, abietic, capric, caproic, ricinoleic, linoleic, hydrogenated and dehydrogenated abietic acids, and the surface active hydrolysis products of tallow, cocoanut oil, cottonseed oil, soy-bean oil, peanut oil, sesame, linseed oil, olive oil, corn oil, castor oil and the like. While soap is not essential in the formulation, it is preferable to have from about 25 to 75 percent by weight of the bar present for the purpose of improving the feel, appearance, working properties and the like.
While the water-soluble sodium salts of the aforementioned detergents, lathering agents, and soaps are generally preferred, other alkali metal and amine salts may be employed, as for example those with potassium, ammonium, lower alkyl amines such as methylamine, ethylamine, propylamine, and isopropyl amine, lower alkylolamines such as mono-, diand triethanoland isopropanolamines, cyclic amines such as cyclohexylamine, morpholine, and-pyrrolidine, and the like.
Suitable additive, e. g. binders, fillers, builders and the like may be added to the detergent bar of the instant invention to provide properties regarded as desirable in any particular instance. These may include carboxymethyl cellulose, polyethylene glycol, starch (substituted, degraded or undegraded) lignin, alginates, copolymers of maleic anhydride with styrene and polyvinyl alkyl ethers and the like, urea, zein, lecithin, lanolin, talc, salts such as borax, calcium chloride, magnesium chloride, sodium sulfate, sodium phosphate, tetrasodium pyrophosphate, and sodium tripolyphosphate, oxides and hydroxides such as magnesium oxide, sodium hydroxide, potassium hydroxide and titanium hydroxide, dyes, pigments, perfumes and the like.
These supplementary agents may be used to control the rate of solubility of the bar, improve slip and feel, stabilize it against changes in humidity which cause softening or drying out, improve its appearance and odor, serve as builders and thelike. Their use however must be carefully regulated to prevent undesirable and disadvantageous properties from resulting. Thus, some inorganic salts are too soluble and are leached out of the bar, mak ing it rough. Others are insoluble or only slightly soluble so that they are left as rough gritty particles on the surface of the bar when the more soluble portions are dissolved out. Many crystallize out on the surface of the bar during storage. Some are too hygroscopic, causing excessive softening of the bar on storage in humid conditions. Most of them make a very hard and dense bar. Those with a negative heat of solution make the bar feel cold on the skin during use. Varying amounts of inorganic salts such as sodium sulfate, sodium chloride, ammonium chloride and the like are present in certain of the surfactants employed in the bar as manufactured, but generally and preferably such amounts total no more than about 25 percent by weight of the bar. Bars containing clay, bentonite or rosin usually have a gritty feel and insufficient slip. Some are very dark in color making a very unattractive bar.
Small amounts of waxes, oils, fats and greases improve milling of the ingredients by plasticizing the mixture. They also serve as lubricants in aiding release of the bar from the dye in the stamping operation. Residues left on the skin after washing act as emollients to overcome the defatting efiect of the detergents. However, they have a serious defoaming effect on the surfactants in the composition particularly when employed in too large an amount. Carboxymethylcellulose may be added to improve whiteness retention for fabric -detergency and as a foam stabilizer and skin beneficient. Similarly, lanolin when used in emollient amounts to overcome the defatting effect of the detergents, has a detrimental effect on lathering properties.
Starches, gums and dextrines are unsatisfactory in large amounts in that they tend to reduce the slip of the bar and dry out, causing cracking and crumbling of the bar. Those of low solubility are preferred since they reduce the rate of consumption of the bar.
In the preferred embodiment of this invention, the detergent bar contains a mononuclear long chain alkyl aryl sulfonate, more specifically sodium dodecyl benzene sulfonate, as component A, a lower alkyl naphthalene sulfonate, more specifically sodium diisopropyl naphthalene sulfonate as component B, a salt of a lower alkyl ester of an aliphatic sulfopolycarboxylic acid, more specifically sodium diamyl sulfosuccinate, as component C, and a water-soluble soap such as sodium tallow soap, in addition to small amounts of carboxymethylcellulose and perfume. A bar manufactured in accordance with this preferred embodiment has highly satisfactory properties for handwashing, shaving, dishwashing, and cotton detergency in soft, hard or sea water. After more than twenty months of storage through humid summer and dry winter conditions, it still had a smooth soap-like appearance, with no evidence of blooming or cracking, and at no time during this period did it exhibit undue softness or brittleness. When used for washing and shaving, it likewise does not exhibit undesirable pitting, blooming, slushing, or cracking.
The bar in accordance with the instant invention may be produced in well known manner by a framing, milling or similar process. In making frame bars, all the ingredients are mixed at elevated temperatures in a crutcher with sufiicient water to permit easy stirring. The mass is then poured into wooden frames to cool, solidify and partially dry after which the frame is removed, and the soap block cut into pieces and stamped in a soap press. In the milling process all of the materials for making the bar are mixed in an amalgamator, preferably passed through a roller mill for one or more times to assure a thorough mixing while adding sufiicient water to provide the proper viscosity, and the milled mass then compressed and extruded from a plodder into long bars which are cut into suitable lengths and stamped into the desired shape and size.
The examples in the following table, in which parts are by weight, are illustrative of the compositions of the detergent bars made in accordance with the instant invention. It will be understood thatthe'invention is not limited thereby:
It will be-understood: that the term detergent bar as employed herein and the appended"claims'includes any Table Detergent Latherlng agents 7 Soup, Ex. A B- parts Additional components Type Parts Type Parts Type Parts Type Parts,
1 Na dodecylbenzene sul- 10 Nadiisopropylnaphtha- 10 Na dlamylsuliosucci- 5 50. .Gum No.1iJ8 15 innate. lene sulfonate. 'nate. I i
' Gum N0. 198.... 13 do 5 50 STPB 10 10 50v 7: 50 7 60 5 '50 5 30 15 do... s- 42 Nadihexylsulfosuccinate- 10 47 20 Na dlisobutyl sulfo- 6 51 A succinate. i v 20 Na isooetyl sulfonate.-.- 20. i 37 20 Na lsononylsulfonate'...' 12 45' 20 Nadlamylsulfosueel- 10 37 nate. 20 -do 10 20 -do... 10 "37 20 do. 10 37 20 do 1O 27 20 Na2-ethyl-l-hexenylsul- 10, 5G
fonate. 20 Na dlamyl sulfosucel 10 -40 10 hate: V 20. .....do 10, i8 20 d0 10 j '45- 2 20. 10 -1qas ,3 10 20 d0 10 28 2 10 10 20 d0 10 28 2 10 7 20 -.-do 10 25 10 10 15 do 7 30 5 12 do 20 -do 20 Na, tri-isobutyl sulfo- 10 45 CarboseD 2 carballylate. do 20 d0 20 Na tri-n-butyl sulfo- 10 45 do 2 iii i 1: o b D 2 3. am y su osuceiar ose 20 20 na 10 47 Pine perfume... 11 0 do 20 -.d0 10 do 5 2g 2 ..do 40 -.--.d0 40 ---do 20 NHlnonyl phenol 10 d0 10 d0 5 (C2H40)4 sulfate. H Nadodeeylbenzenesul- 20 Na dusobutylnaphtha- 20 do 1o 47 fonate. lene sulfonate.
All of the detergent bars described in the above table have satisfactory hand Washing lathering properties in tap water and as good or better lathering properties in sea water. The soap employed was in all instances, except in Example 2, a sodium tallow soap. In said Example 2, potassium tallow soap was used.
The parts of sodium dodecylbenzene sulfonate shown in the table comprise about 85 percent of active ingredient and 15 percent of inert ingredients such as sodium sulfate. The parts of sodium diisopropyl naphthalene sulfonate shown in the table comprise about 55 percent of active ingredient and percent of inert ingredients such as sodium sulfate Gum No. 198 is a degraded corn starch. STPP is sodium tripolyphosphate. CMC and Carbose D are carboxymethyl cellulose. Indulin C is lignin. Nu- Film is a substituted starch. Alcolec S is lecithin. Nadex 360 is a corn starch.
While all of the detergent bars described in the table are satisfactory, those of Examples 3 and 29 containing the preferred components, as described above, possess superior properties. The bars of Examples 12 and 31 also have highly satisfactory properties.
detergent composition in a solid, cohesive state in any size or shape. Similarly the recitation of an alkyl or hydrocarbon radical containing a specified number of car bon atoms is to be considered as also including a mixture of radicals of the same type averaging the specified number of carbon atoms. Various modifications and variations of this invention will be obvious to the person skilled in the art and it is to be understood that such modifications and variations are to be included within the purview of this application and the spirit and scope of the appended claims.
What is claimed is:
l. A detergent bar comprising (A) about 5 to 50% by Weight of a synthetic organic anionic detergent selected from the group consisting of the water soluble alkali metal and amine salts of higher aliphatic sulfates and sulfonates containing a hydrocarbon radical with at least 11 carbon atoms in a straight chain, and alkylbenzene sulfates and sulfonates containing at least one alkyl side chain radical of at least 8 carbon atoms, (B) about 5 to 25% by weight of a synthetic organic anionic lathering agent selected from the group consisting of the water solu- 7 .ble alkali metal'and amine salts of alkyl-arylsulfates and sulfonates containing at least one alkyl side chain radical of from 2 to 6 carbon atoms and devoid of alkyl side chain radicals of more than 6 carbon atoms, (C) about 5 to 25% by weight of a synthetic organic anionic lather- -7. A detergent bar as defined in claim 5, in which'component B is sodium diisopropyl naphthalene sulfonate.
8. A detergent bar as defined in claim 5 in which com- -ponent C is sodium diamyl sulfosuccinate.
ing agent selected from the group consisting of the water soluble alkali metal and amine salts of lower branched chain aliphatic sulfates and lower alkyl esters of lower aliphatic sulfopolycarboxylic acids containing an open chain hydrocarbon radical of from 3 to 9 carbon atoms, and from about 25 to 75% by weight of a water-soluble salt of a higher aliphatic monocarboxylic acid.
2. A detergent bar as defined in claim 1 in which component A is an alkyl benzene sulfonate salt containing an alkyl side chain radical of at least 8 carbon atoms.
3. A detergent bar as defined in claim 1 in which com ponent B is an alkyl naphthalene sulfonate salt containing an alkyl side chain radical of from 2 to 6 carbon atoms.
4. A detergent bar as defined in claim 1 in which component.C is a salt of a lower alkyl ester of sulfosuccinic acid.
5. A detergent bar comprising (A) about 5 to 50% by Weight of a water-soluble alkyl benzene sulfonate salt containing an alkyl side chain radical of at least 8 carbon atoms, (B) about 5 to 25% by weight of a water-soluble alkyl naphthalene sulfonate salt containing an alkyl side chain radical of from 2 to 6 carbon atoms and devoid of alkyl side chain radicals of more than 6 carbon atoms, ((1) about 5 to by weight of a water-soluble salt of a lower alkyl ester of sulfosuccinic acid, and from about 25 to 75% by weight of a water-soluble salt'of a higher aliphatic monocarboxylic acid.
6. A detergent bar as defined in claim 5, in which component A is sodium dodecylbenzene sulfonate.
9. A detergent bar comprising about 5 to by weight of sodium dodecylbenzene sulfonate, about 5 to 25% by Weight of sodium diisopropyl naphthalene sulfonate, about 5 to 25 by weight of sodium diamyl sulfosuccinate, and from about 25 to by weight of a water-soluble salt of a higher aliphatic monocarboxylic acid.
10. A detergent bar comprising about 20 parts by weight of sodium dodecylbenzene sulfonate, about 20 parts by weight of sodium diisopropyl naphthalene sulfonate, about 10 parts by weight of sodium diamyl sulfosuccinate, about 47 parts by weight of a water soluble salt of a higher aliphatic monocarboxylic acid, and about 2 parts 'by weight of carboxymethyl cellulose.
l1.'A detergent bar comprising about 20 parts by weight of sodium dodecylbenzene sulfonate, about 20 parts by weight of sodium diisopropyl naphthalene sulfonate, about 12 parts by weight of sodium isonony-l sulfonate, and about 45 parts by weight of a water soluble salt of a higher aliphatic monocarboxylic acid.
References Cited in the file of this patent UNITED STATES PATENTS 1,906,484 Nues slein May 2, 1933 2,176,423 Jaeger Oct. 17, 1939 2,438,169 Hoyt Mar. 23, 1948 2,617,772 Keenan Nov. 11, 1952 2,631,980 Lewis Mar. l7, 1 953
Claims (1)
1. A DETERGENT BAR COMPRISING (A) ABOUT 5 TO 50% BY WEIGHT OF A SYNTHETIC ORGANIC ANIONIC DETERGENT SELECTED FROM THE GROUP CONSISTING OF THE WATER SOLUBLE ALKALI METAL AND AMINE SALTS OF HIGHER ALIPHATIC SULFATES AND SULFONATES SCOTAINING A HYDROCARBON RADICAL WITH AT LEAST 11 CARBON ATOMS IN A STRAIGHT CHAIN, AND ALKYLBENZENE SULFATES AND SULFONATES CONTAINING AT LEAST ONE ALKYL SIDE CHAIN RADICAL OF AT LEAST 8 CARBON ATOM, (B) ABOUT 5 TO 25% BY WEIGHT OF A SYNTHETIC ORGANIC ANIONIC LATHERING AGENT SELECTED FROM THE GROUP CONSISTING OF THE WATER SOLUBLE ALKALI METAL AND AMINE SALTS OF ALKYL ARYL SULFATES AND SULFONATES CONTAINING AT LEAST ONE ALKYL SIDE CHAIN RADICAL OF FROM 2 TO 6 CARBON ATOMS AND DEVOID OF ALKYL SIDE CHAIN RADICALS OF MORE THAN 6 CARBON ATOMS, (C) ABOUT 5 TO 25, BY WEITHT OF A SYNTHETIC ORGANIC ANIONIC LATHERING AGENT SELECTED FROM THE GROUP CONSISTING OF THE WATER SOLUBLE ALKALI METAL AND AMINE SALTS OF LOWER BRANCHED CHAIN ALIPHATIC SULFATES AND LOWER ALKYL ESTERS OF LOWER ALIPHATIC SULFOPOLYSCARBOXYLIC ACIDS CONTAINING AN OPEN CHAIN HYDROCARBON RADICAL OF FROM 3 TO 9 CARBON ATOMS, AND FROM ABOUT 25 TO 75% BY WEIGHT OF A WATER-SOLUBLE SALT OF A HIGHER ALIPHATIC MONOCARBOXYLIC ACID.
Publications (1)
Publication Number | Publication Date |
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US2781320A true US2781320A (en) | 1957-02-12 |
Family
ID=3446333
Family Applications (1)
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US2781320D Expired - Lifetime US2781320A (en) | All purpose |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3043779A (en) * | 1957-03-18 | 1962-07-10 | Lever Brothers Ltd | Detergent tablets |
US3043778A (en) * | 1958-02-20 | 1962-07-10 | Lever Brothers Ltd | Soap bar compositions |
US3070547A (en) * | 1953-07-13 | 1962-12-25 | Procter & Gamble | Soap-synthetic bar |
US3076766A (en) * | 1959-08-12 | 1963-02-05 | Colgate Palmolive Co | Detergent bar |
US3130166A (en) * | 1957-05-16 | 1964-04-21 | United States Borax Chem | Granular soap compositions containing carbamide |
US3224976A (en) * | 1960-05-20 | 1965-12-21 | Colgate Palmolive Co | Detergent bar |
US3226330A (en) * | 1959-08-12 | 1965-12-28 | Colgate Palmolive Co | Detergent bar |
US3275561A (en) * | 1957-03-07 | 1966-09-27 | Dow Chemical Co | Lubricious detergent compositions |
US3278444A (en) * | 1964-06-22 | 1966-10-11 | Kelite Chemicals Corp | Detergent composition |
US3305488A (en) * | 1963-05-10 | 1967-02-21 | Lloyd I Osipow | Detergent compositions |
US4260507A (en) * | 1970-08-18 | 1981-04-07 | Lever Brothers Company | Soap-synthetic detergent tablets |
US4278571A (en) * | 1980-05-28 | 1981-07-14 | The Procter & Gamble Company | Surfactant cake compositions |
US4647394A (en) * | 1981-04-07 | 1987-03-03 | Mitsubishi Chemical Industries Limited | Soap composition |
US4874536A (en) * | 1984-06-29 | 1989-10-17 | The Proctor & Gamble Company | Synthetic surfactant cakes with magnesium chloride |
US5417878A (en) * | 1991-03-07 | 1995-05-23 | Kao Corporation | Solid detergent composition |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1906484A (en) * | 1930-04-08 | 1933-05-02 | Ig Farbenindustrie Ag | Soap preparation |
US2176423A (en) * | 1936-01-13 | 1939-10-17 | American Cyanamid & Chem Corp | Esters of sulphodicarboxylic acids |
US2438169A (en) * | 1945-07-12 | 1948-03-23 | Allied Chem & Dye Corp | Manufacture of detergents |
US2617772A (en) * | 1952-11-11 | Tack-fr ee alkaryl sulfonate | ||
US2631980A (en) * | 1949-07-22 | 1953-03-17 | California Research Corp | Noncaking alkyl aryl sulfonate detergent compositions |
-
0
- US US2781320D patent/US2781320A/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2617772A (en) * | 1952-11-11 | Tack-fr ee alkaryl sulfonate | ||
US1906484A (en) * | 1930-04-08 | 1933-05-02 | Ig Farbenindustrie Ag | Soap preparation |
US2176423A (en) * | 1936-01-13 | 1939-10-17 | American Cyanamid & Chem Corp | Esters of sulphodicarboxylic acids |
US2438169A (en) * | 1945-07-12 | 1948-03-23 | Allied Chem & Dye Corp | Manufacture of detergents |
US2631980A (en) * | 1949-07-22 | 1953-03-17 | California Research Corp | Noncaking alkyl aryl sulfonate detergent compositions |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3070547A (en) * | 1953-07-13 | 1962-12-25 | Procter & Gamble | Soap-synthetic bar |
US3275561A (en) * | 1957-03-07 | 1966-09-27 | Dow Chemical Co | Lubricious detergent compositions |
US3043779A (en) * | 1957-03-18 | 1962-07-10 | Lever Brothers Ltd | Detergent tablets |
US3130166A (en) * | 1957-05-16 | 1964-04-21 | United States Borax Chem | Granular soap compositions containing carbamide |
US3043778A (en) * | 1958-02-20 | 1962-07-10 | Lever Brothers Ltd | Soap bar compositions |
US3226330A (en) * | 1959-08-12 | 1965-12-28 | Colgate Palmolive Co | Detergent bar |
US3076766A (en) * | 1959-08-12 | 1963-02-05 | Colgate Palmolive Co | Detergent bar |
US3224976A (en) * | 1960-05-20 | 1965-12-21 | Colgate Palmolive Co | Detergent bar |
US3305488A (en) * | 1963-05-10 | 1967-02-21 | Lloyd I Osipow | Detergent compositions |
US3278444A (en) * | 1964-06-22 | 1966-10-11 | Kelite Chemicals Corp | Detergent composition |
US4260507A (en) * | 1970-08-18 | 1981-04-07 | Lever Brothers Company | Soap-synthetic detergent tablets |
US4278571A (en) * | 1980-05-28 | 1981-07-14 | The Procter & Gamble Company | Surfactant cake compositions |
US4647394A (en) * | 1981-04-07 | 1987-03-03 | Mitsubishi Chemical Industries Limited | Soap composition |
US4874536A (en) * | 1984-06-29 | 1989-10-17 | The Proctor & Gamble Company | Synthetic surfactant cakes with magnesium chloride |
US5417878A (en) * | 1991-03-07 | 1995-05-23 | Kao Corporation | Solid detergent composition |
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