US2907096A - Shaped polyacrylonitrile structures - Google Patents
Shaped polyacrylonitrile structures Download PDFInfo
- Publication number
- US2907096A US2907096A US36368353A US2907096A US 2907096 A US2907096 A US 2907096A US 36368353 A US36368353 A US 36368353A US 2907096 A US2907096 A US 2907096A
- Authority
- US
- United States
- Prior art keywords
- filament
- filaments
- temperature
- lustrous
- coagulating bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
- Y10T428/2975—Tubular or cellular
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
Definitions
- the invention -relates to the manufacture of shaped structures from polymers and copolymers of acrylonitrile.
- the critical temperature range is to a certain eXtent a function of the composition of the polymer but is always between 15 and 70 C. If a solution of polyacrylonitrile in nitric acid is spun, and if the coagulating bath has a temperature below l C., the filaments are lustrous and have a silky character. If, however, the temperature is raised above 15 C., the filaments assume with rising temperature more and more a dull and white aspect. Of course, the transitions from a lustrous and clear filament to a dull and white filament, which are produced by raising the temperature of the coagulating bath, are not abrupt but gradual, and the transition temperatures Vary as a function of Vthe composition and type of filament.
- Some polymers show the described e'fiect already at bath temperatures of 15 to 20 C.
- the lower temperature limit is generally above 20 C., i.e'. from this temperature on the effect .becomes visible for the naked eye.
- the upper temperature limit is defined by the spinnability of the filaments.
- nitric acid solution into warm water a filament is obtained the interior of which presents over the whole length of the filament a very fine regular porous structure; this makes it possible to spin and Stretch the filaments without difliculties. This behavior appears to be typical for nitric acid solutions. So far, it has not been possible to accomplish similar efi'ects with other solvents.
- the upper temperature limit is controlled by the spinnability and elongation. As distinctly shown in the preparation of films on glass plates, the size of the cavities increases with increasing temperature until the Spinning of a fine filament becomes impossible, Though for coarser deniers it is possible to Work still 'at 70 C., the matting effect is already at 30 to 40 C. a maximum.
- the critical temperature range in its broadest aspect may, therefore, be defined as lying between 15 to 70 C.; the optimum range is between 25 and 50 C.
- a filament produced within the critical temperature range has, for the same titer, a larger diameter than a filament spun below said range.
- the cross section of the filaments are usually circular; whereas, for instance, a filament of 3 denier which had been pro- Vduced at temperatures of the coagulating bath between 5 and 15 C., has a diameter of 19 to 20/t, a similar filament produced otherwise under the same conditions but in a coagulating bath having a temperature of 35 to 40 C., had a diameter of 24 to 29,11..
- Fig. l is taken from a lustrous filament, wherein the fibrils have a diameter of 19,u, and
- Fig. 2 is a corresponding cross section taken from a dull filament according to the invention, wherein the fibrils are larger and have, due to the enclosed air bubbles, a diameter of 24/4.
- the microscopic picture of stretched filaments shows the lustrous filaments clear and transparent, whereas the mat filaments appear even in thin cross sections opaque and dull, though inhomogenities proper, e.g. air bubbles, cannot be made out. But if the filament is examined in unstretched condition, i.e. in the state as it leaves the coagulating bath after rinsing with water and drying, innumerable bubbles can be detected which are just visible. Otherwise, the filament in this unfinished, i.e. unstretched state constitutes the same unstable structure as the lustrous filament. Surprisingly, however, the mechanical properties and the strength of the mat porous filaments in the stretched state are at least not inferior to those of the transparent lustrous filaments.
- My ,novel method allows of producing instead of lustrous filaments of dense structure dull filaments of porous structure merely by modifying the temperature of the coagulating bath.
- the degree of porosity can be controlled by adjusting the rise of temperature.
- the mat filaments produced according to the invention have a better heat retaining capacity than lustrous filaments.
- Polymers or copolymers of acrylonitrile can be used for carrying out the novel process; if copolymers are used, they must contain at least 80 percent by weight of acrylonitrile, the rest being another polymerizable compound such as vinyl acetate, arcylic or methacrylic acid or esters or amides thereof.
- the nitric acid content of the coagulating bath depends on the rate of feed and is between 1 and 40 percent by weight. i
- the following examples illustrate the method and results obtained in controlling the temperature of the coagulating bath, whereby the first example is carried out at a temperature below the critical temperature and the following examples above the critical temperature.
- Example I 100 g. of polyacrylonitrile having an average molecular Weight of 60,000 and l g. of urea are dissolved at 20 C. in 700 ⁇ g. of 59%l nitric acid. The solution is filtered through a Nichrome Wire net with 50,1l meshes and stored at a temperature of to C. At this temperature, the solution is stable for at least 100 hours, i.e. after said time the polymer can be quantitatively recovered with substantially the same nitrogen content by precipitation with water. The solution has a viscosity of 450 poise at C. It is extruded into a coagulating bath at a rate of 36 cc. per hour through a spinneret having 10 holes of .1 mm. diameter.
- the coagulating bath has a temperature of 10 to 15 C. and consists of 10% nitric acid.
- the filament travels through the bath for a distance of 150 mm. and is then rinsed With distilled water in countercurrent in a washing trough having a length of 500 mm.
- the filament is then wound on a take-up bobbin revolving at a circurnferential speed of 8 m./min. From this bobbin, the filament passes through a water bath of 90 to 95 C., which contains 0.l% of phosphoric acid, 02% of polyvinyl alcohol, and 02% of glycerol; in this bath, the filament gives olf the main amount of its Water content.
- the filament passes over a guide roller into a drying chamber, where it is dried with air of about 100 C., and then over a bobbin heated to 150 C. and revolving at a circumferential speed of 10'm./min to the collecting bobbin, which revolves at a circumferential speed at 30 m./rnin.
- a 30 denier fiber consisting of 10 filaments, which has a tensile strength of 120 to 150 g.
- the fiber is lustrous and colorless; its cross-section is Circular and has a diameter of 19 to ZOM.
- Example 2 The procedure was exactly the same as in the first example with the sole difference that the temperature in the coagulating bath was maintained at 35 to 40 C. instead of at 10' to 15 C. There was also obtained a 30 denier fiber which consisted of 10'individual ⁇ filaments and. had a tensilestrength of 120 to 150 g. However,
- the fiber had dull lustre and a snow White color.
- the cross section was Circular, and the diameter was 22 to 2411..
- Example 3 As in Example 1, a solution of g. of polyacrylonitrile having an average molecular weight of 65000 and 800 g. of 59% nitric acid is prepared at 20 C. The solution has a viscosity of 400 poisc at 15 C. It is spun as described in Example l, with the following modifications. The spinneret has 10 holes of .2 mm. diameter and is fed With 40 ccm. of solution per hour. The spinning speed is 3 m./min at the spi'nneret and 30 Iin/min on the take-up bobbin. The temperature in the coagulating bath is maintained at 40 to 45 C. The fiber has a total titre of 30 d. and a tensile strength of g. It is dull and white. The cross section of the fiber is circular and has a diameter of 25 to 28.
- Example 4 Acrylonitfile and Vinyl acetate are polymerized in a known manner to a copolymer containing 5 percent of Vinyl acetate and having a molecular weight of 70,000.
- the polymer is connninuted to a particle size of less than a diameter.
- 100 parts of this copolymer are ground to a suspension with 350 parts of a nitric acid containing 53 percent by weight of HNO3. This suspension is degassed at reduced pressure. Then 1 g. of urea and 350 parts of 65% nitric acid are introduced with stirring. Within a few minutes, the suspension changes to a clear solution. Said solution is filtered through a finely porous filter of a polyvinyl chloride fabric and then degassed in vacuo.
- the Spinning process can be carried out up to' temperatures of 35 to 40 C. in the coagulati'ng bath' Without disturbances; at a further increase of the temperature of the coagulating bath, however, the filament easily tends to break before it is sufliciently strengthen'ed by' stretching.
- line A indicates the tensile strength in grams'perv 1 denier
- line B the diameter of the filament in microns
- line C the aspect of the filament.
- filaments can be Washed first With Water, and subsequently they can be treated With hot water of more than 70 C. to remove the greater part of the absorbed Water; the Washed filaments are then heated to about 70 to 100 C., for instance in Water, and stretched by at least about 30 percent, and these prestretched filaments are subsequently stretched again at temperatures above 100 C. by to 250%. Or the swollen filaments can be heated to 70 to 100 C., for instance by passing them over a heated support, to remove the greater part of the absorbed water in liquid form, and the recovered hot water may, if desired, be used for treating the freshly spun filaments at temperatur-es of 70 to 100" C.
- the after-stretching can also be carried out in a water bath Which contains traces of a strong acid, and after the wet stretching, the filament may be subjected to a finishing treatment by which small amounts of a strong acid and a lubricating agent are applied.
- a delustered filament composed of an acrylonitrile polymer selected from the group consisting of polyacrylonitrile and copolymers containing at least 80 percent by weight of acrylonitrile monomer units, the balance being polymers of compounds copolymerizable With acrylonitrile, said polymer being soluble in nitric acid, the interior of said filament being honeycombed With a great number of small cavities, said filament having throughout a dull to White appearance and being stretchable without impairment of its mechanical and strength properties to the same extent as a corresponding transparent lustrous filament of the same composition.
- a delustered stretched filamentV composed of an acrylonitrile polymer selected from the group consisting of polyacrylonitrile and copolymers containing at least 80 percent by weight of acrylonitrile monomer units, the balance being polymers of compounds copolymerizable with acrylonitrile, said polymer being soluble in nitric acid, the interior of said filament being honeycombed with a great number of small cavities, said filament having throughout its cross-section a dull to white appearance, the mechanical and strength properties of said delustered filament being at least the same as those of, and the heat retaining capacity of said delustered filament being considerably improved over that of a corresponding transparent lustrous filament of the same composition. 3.
- a delustered filament composed of an acrylonitrile polymer selected from the group consisting of polyacrylonitrile and copolymers containing at least percent by weight of acrylonitrile monomer units, the balance being polymers of compounds selected from the group consisting of vinyl acetate, acrylic acid, methacrylic acid, and esters and amides of said acids, said polymer being Soluble in nitric acid, the interior of said filament being honeycombed with a great number of small cavities, said filament having throughout its cross-section a dull to White appearance and being stretchable Without impairment of its mechanical and strength properties to the same eXtent as a corresponding transparent lustrous filament of the same composition.
- a delustered filament composed of polyacrylonitrile soluble in nitric acid, the interior of said filament being honeycombed With a great number of small cavities, said filament having throughout its cross-section a dull to White appearance and being stretchable Without impairment of its mechanical and strength properties to the same extent as a corresponding transparent lustrous filament of the same composition.
- a delustered stretched filament composed of polyacrylonitrile soluble in nitric acid, the interior of said filament being honeycombed With a great number of small cavities, said filament having throughout its crosssection a dull to white appearance, the mechanical and strength properties of said delustered filament being substantially the same as those of, andthe heat retaining capacity of said delustered filament being considerably improved over that of, a corresponding transparent lustrous filament of the same composition.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH741847X | 1952-06-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2907096A true US2907096A (en) | 1959-10-06 |
Family
ID=4533225
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US36368353 Expired - Lifetime US2907096A (en) | 1952-06-28 | 1953-06-23 | Shaped polyacrylonitrile structures |
Country Status (5)
Country | Link |
---|---|
US (1) | US2907096A (de) |
BE (1) | BE520876A (de) |
CH (1) | CH308184A (de) |
GB (1) | GB741847A (de) |
NL (2) | NL105850C (de) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3088188A (en) * | 1960-01-04 | 1963-05-07 | Monsanto Chemicals | Manufacture of shaped objects of acrylonitrile polymer by wet spinning |
US3118161A (en) * | 1963-03-13 | 1964-01-21 | E B & A C Whiting Company | Foamed polypropylene filaments |
US3127298A (en) * | 1964-03-31 | Method and products thereof | ||
US3246067A (en) * | 1962-05-14 | 1966-04-12 | Du Pont | Wet-spinning of aromatic polyester filament of high opacity |
US3322611A (en) * | 1962-10-19 | 1967-05-30 | Du Pont | Porous fibers and processes of preparing same |
US3871950A (en) * | 1972-04-28 | 1975-03-18 | Asahi Chemical Ind | Hollow fibers of acrylonitrile polymers for ultrafilter and method for producing the same |
US3933653A (en) * | 1972-04-28 | 1976-01-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Membranes of acrylonitrile polymers for ultrafilter and method for producing the same |
US4559268A (en) * | 1983-07-04 | 1985-12-17 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Filament for brushmaking |
US5032456A (en) * | 1987-09-11 | 1991-07-16 | Newell Operating Company | Microcellular synthetic paintbrush bristles |
US5786087A (en) * | 1995-02-22 | 1998-07-28 | Specialty Filaments, Inc. | Honeycomb brush bristles and brush made therefrom |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1057285B (de) * | 1955-08-18 | 1959-05-14 | Dr Paul Halbig | Verfahren zur Herstellung von Faeden oder Fasern aus Polymerisaten |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1427330A (en) * | 1922-05-08 | 1922-08-29 | Rousset Jules | Manufacture of hollow artificial textile articles |
US2268160A (en) * | 1939-06-21 | 1941-12-30 | Du Pont | Spongy superpolymer |
US2385890A (en) * | 1943-03-31 | 1945-10-02 | Du Pont | Spinning process |
US2476293A (en) * | 1944-10-03 | 1949-07-19 | American Viscose Corp | Artificial fiber |
US2530962A (en) * | 1948-09-24 | 1950-11-21 | Du Pont | Formation of shaped articles from acrylonitrile polymers |
US2531409A (en) * | 1946-12-13 | 1950-11-28 | Ind Rayon Corp | Interiolymers of acrylonitrile and fumarodinitrile |
US2531408A (en) * | 1946-12-13 | 1950-11-28 | Ind Rayon Corp | Interpolymers of acrylonitrile and itaconic acid |
US2555300A (en) * | 1947-02-13 | 1951-06-05 | Du Pont | Wet-spinning process |
US2572931A (en) * | 1947-11-01 | 1951-10-30 | American Viscose Corp | Cellular products comprising acrylonitrile polymers |
US2579451A (en) * | 1948-12-31 | 1951-12-18 | Du Pont | Polymeric materials |
US2628945A (en) * | 1949-03-24 | 1953-02-17 | Du Pont | Process for obtaining cellular polymeric materials |
-
0
- NL NLAANVRAGE7907039,A patent/NL179065B/xx unknown
- BE BE520876D patent/BE520876A/xx unknown
- NL NL105850D patent/NL105850C/xx active
-
1952
- 1952-06-28 CH CH308184D patent/CH308184A/de unknown
-
1953
- 1953-06-23 US US36368353 patent/US2907096A/en not_active Expired - Lifetime
- 1953-06-23 GB GB1743253A patent/GB741847A/en not_active Expired
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1427330A (en) * | 1922-05-08 | 1922-08-29 | Rousset Jules | Manufacture of hollow artificial textile articles |
US2268160A (en) * | 1939-06-21 | 1941-12-30 | Du Pont | Spongy superpolymer |
US2385890A (en) * | 1943-03-31 | 1945-10-02 | Du Pont | Spinning process |
US2476293A (en) * | 1944-10-03 | 1949-07-19 | American Viscose Corp | Artificial fiber |
US2531409A (en) * | 1946-12-13 | 1950-11-28 | Ind Rayon Corp | Interiolymers of acrylonitrile and fumarodinitrile |
US2531408A (en) * | 1946-12-13 | 1950-11-28 | Ind Rayon Corp | Interpolymers of acrylonitrile and itaconic acid |
US2555300A (en) * | 1947-02-13 | 1951-06-05 | Du Pont | Wet-spinning process |
US2572931A (en) * | 1947-11-01 | 1951-10-30 | American Viscose Corp | Cellular products comprising acrylonitrile polymers |
US2530962A (en) * | 1948-09-24 | 1950-11-21 | Du Pont | Formation of shaped articles from acrylonitrile polymers |
US2579451A (en) * | 1948-12-31 | 1951-12-18 | Du Pont | Polymeric materials |
US2628945A (en) * | 1949-03-24 | 1953-02-17 | Du Pont | Process for obtaining cellular polymeric materials |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3127298A (en) * | 1964-03-31 | Method and products thereof | ||
US3088188A (en) * | 1960-01-04 | 1963-05-07 | Monsanto Chemicals | Manufacture of shaped objects of acrylonitrile polymer by wet spinning |
US3246067A (en) * | 1962-05-14 | 1966-04-12 | Du Pont | Wet-spinning of aromatic polyester filament of high opacity |
US3322611A (en) * | 1962-10-19 | 1967-05-30 | Du Pont | Porous fibers and processes of preparing same |
US3118161A (en) * | 1963-03-13 | 1964-01-21 | E B & A C Whiting Company | Foamed polypropylene filaments |
US3871950A (en) * | 1972-04-28 | 1975-03-18 | Asahi Chemical Ind | Hollow fibers of acrylonitrile polymers for ultrafilter and method for producing the same |
US3933653A (en) * | 1972-04-28 | 1976-01-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Membranes of acrylonitrile polymers for ultrafilter and method for producing the same |
US4559268A (en) * | 1983-07-04 | 1985-12-17 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Filament for brushmaking |
US5032456A (en) * | 1987-09-11 | 1991-07-16 | Newell Operating Company | Microcellular synthetic paintbrush bristles |
US5786087A (en) * | 1995-02-22 | 1998-07-28 | Specialty Filaments, Inc. | Honeycomb brush bristles and brush made therefrom |
Also Published As
Publication number | Publication date |
---|---|
CH308184A (de) | 1955-06-30 |
GB741847A (en) | 1955-12-14 |
NL179065B (nl) | |
NL105850C (de) | 1900-01-01 |
BE520876A (de) | 1900-01-01 |
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