US2871140A - Metal treating process - Google Patents

Metal treating process Download PDF

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Publication number
US2871140A
US2871140A US499575A US49957555A US2871140A US 2871140 A US2871140 A US 2871140A US 499575 A US499575 A US 499575A US 49957555 A US49957555 A US 49957555A US 2871140 A US2871140 A US 2871140A
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molten
wire
metal
temperature
reaction
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US499575A
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Norman P Goss
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Diamond Shamrock Corp
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Diamond Alkali Co
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Priority to LU34289D priority Critical patent/LU34289A1/xx
Priority to BE546758D priority patent/BE546758A/xx
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Priority to US499575A priority patent/US2871140A/en
Priority to GB10167/56A priority patent/GB792421A/en
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/70—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using melts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C9/00—Cooling, heating or lubricating drawing material

Definitions

  • One type of prior metal treatment contemplates a descaling treatment, followed by acid pickling and lime treatment, with or without a subsequent glyceride coating.
  • Processes of this type while used commercially, involve a relatively large number of operations and have certain inherent disadvantages, including the additional process control required and costs involved. Additionally, in many processes of this type, organic solvents are employed as carriers for any lubricant coating applied. These solvents generally must be removed and often leave an objectionable greasy residue on the metal.
  • Another prior process involves passing wire, or other metal to be treated, through a molten salt, for example, molten caustic, followed by either aqueous washing, without further treatment, or by aqueous washing together with additional metal treatments.
  • a molten salt for example, molten caustic
  • Such processes in some instances, are satisfactory.
  • any coating or film thereby formed on the metal is but a surface layer which can be relatively easily removed.
  • the intermediate aqueous washings remove much of any such surface coating.
  • a third type of metal treatment contemplates passing wire or other metal through a molten bath comprising the reaction product of caustic soda and a fatty acid. This procedure thus involves passing the metal through a molten soap, generally in the presence of caustic. Again, while a soap film is applied to the surface of the metal by this technique, the coating comprises a preformed soap which may be relatively easily removed from the metal surface.
  • the present invention has forv its principal object the provision of a new and improved metal treating process which avoids the difiiculties heretofore encountered in conditioning metal prior to deep drawing operations.
  • a further object of the invention is the provision of a new and improved adherent, protective lubricant for metals.
  • a stillv further object of the invention is to provide a atent 2371,1140 Patented Jan. 27, 1959 tion will appear more fully from the following descrip- Eli tion.
  • the present invention is based upon the discovery that a singularly adherent and durable surface diffusion layer can be provided on metal by contacting such metal successively with a first bath comprising at least one molten alkali metal'hyd'roxide and a second bath comprising at least one molten substance, such as a molten fatty acid, capable of chemical reaction with said hydroxide to form a strongly adherent, protective, lubricant surface diffusion zone at and beneath the metal surface.
  • the molten alkali metal hydroxide provides a penetrating and cleansing action on the metal being treated. Further, this beneficial action of the alkali metal hydroxide establishes the alkali metal hydroxide in highly reactive form, both at the metal surface and deep within the pores of the metal.
  • a chemical reaction occurs not only at the surface of the metal, but after penetrating or diffusing into the metal within the metal pores as well to establish what is herein referred to as a surface diffusion zone. Accordingly, the resultant reaction product surface diffusion zone is extremely difficult to remove by abrasion, as well as by such handling metal receives in industry prior to further treatment.
  • reaction product comprising the surface diffusion zone essentially is a soap or other lubricant soap-like material; not only are excellent lubricant characteristics provided, but removal of this surface difiusion zone, when desired, may be accomplished readily by washing with water or steam without an elaborate or costly cleaning procedure.
  • the preferred practice of the invention at present contemplates first preheating metal to an elevated temperature, above the temperature of the molten alkali metal hydroxide employed, quenching the thus-heated metal in the first molten bath comprising molten alkali metal hydroxide, and passing the metal into a second molten bath, containing a fatty acid or other substance capable of reacting with the molten hydroxide, as indicated above.
  • alkali metal hydroxide is intended to'inelude hydroxides of the various alkali metals, e. g. sodium, potassium, rubidium, cesium, and lithium.
  • sodium and potassium hydroxides are, of course, the commonly usedalkali metal hydroxides. Because of its availability and low cost, sodium hydroxide is the preferred material at present, and particular reference will be made hereinafter to sodium hydroxide, although the practice of this invention is not limited thereto.
  • the second molten bath comprising the materialCapable of reacting with the alkali metal hydroxide to form an adherent, protective, lubricant surface dilfusionizone may comprise a variety of materials capable of forming an adherent reaction product upon chemical combina- Caproic, Caprylic,
  • unsaturated fatty acids such as Myristoleic, Palmitoleic, Oleic,
  • Linoleic Linolenic, Linolenic, Elaeostearic, Licanic, Ricinoleic, and Erucic acids.
  • natural oils and fats containing substantial proportions of one or more of such fatty acids also may be employed.
  • Illustrative of such materials are tallow or lard, fish oils, such as whale, menhaden, sardine, herring, and plant oils, such as coconut, palm kernel, ba'bassu, munlmru, palm, rape seed, mustard seed, olive, peanut, sesame, corn, cottonseed, soybean, sunflower, walnut, linseed, perilla, castor, tung, and oiticica oils, as well as certain halogenated derivatives thereof.
  • a fatty substance which, upon reaction with the alkali metal hydroxide, forms a continuous solid reaction product layer and which has a relatively high flash point in order to minimize danger of fire caused by contact with hot metal. Any danger from such flash fires can also be prevented, of course, by blanketing the molten baths with an inert atmosphere.
  • Suitable additives for the molten alkali metal hydroxide bath include substances to lower the melting point of the caustic and/or to improve the cleansing action of the caustic.
  • Additives for the molten fatty substance may include sulfur-containing substances, such as molybdenum disulfide, sodium sulfide, sodium sulfite, as well as other lllibricant-type materials, e. g., mica, graphite, and the l e.
  • Fig. 1 is a schematic flow diagram illustrating one embodiment of the method of this invention
  • Fig. 2 is a schematic flow diagram illustrating another embodiment of the method of this invention.
  • Fig. 3 is a schematic representation of one form of apparatus which may be used in the treatment of wire in accordance with this invention.
  • Fig. 4 illustrates schematically another type of apparatus for the treatment of Wire in accordance with this invention.
  • wire first is passed into molten caustic and then into a molten fatty acid, thereby to form
  • the Wire may be, and at present preferably is, subjected .to a heat treatment, such as annealing at 16001850 F., the temperature depending on the type of wire being processed P1101 to immersion in the molten caustic.
  • a heat treatment such as annealing at 16001850 F.
  • Optimum results are obtained when the wire is heated to a temperature in excess of the temperature of the molten caustic thereby to obtain a quenching effect when the wire is contacted with the molten caustic.
  • This heat treatment preferably provides an inert atmosphere, e. g., nitrogen, carbon dioxide, or the like, surrounding the wire.
  • an inert atmosphere e. g., nitrogen, carbon dioxide, or the like
  • the wire is then passed from the molten caustic d1- rectly into the molten fatty acid without intermediate treatment, although in some instances, it is desirable to accomplish a predetermined amount of cooling intermediate the first and second molten baths, as by passage of the wire over one or more pulleys or spools intermediate the molten baths. Such cooling is only required when it is necessary to minimize danger of igniting the second molten bath, e. g., fatty acid, upon contact with the heated metal.
  • the resultant coated wire may then either be stored or shipped without further treatment, or passed directly through wire-drawing dies.
  • the drawn wire still retains an appreciable thickness of a continuous uniform, protective and lubricating surface layer.
  • it is desirable to remove this layer by treatment with water or, preferably, by steam treatment.
  • this layer is extremely adherent and offers continued protection against rust, corrosion, and abrasion, it is advantageous to ship or store the wire without removal of this layer.
  • Fig. 2 illustrates a modification of the process of this invention which does not involve heat treatment of the wire prior to contact with molten caustic.
  • wire is subjected to surface cleaning prior to caustic treatment.
  • surface cleaning treatments contemplated are such conventional metal cleaning procedures as sand blasting, acid pickling, acid etching, and/ or other abrasive or chemical treatment, including electrolytic metal surface cleaning operations. It should be emphasized that in many applications no pretreatment of the metal is necessary at all, the molten caustic afiording a thorough rust removing and surface cleansing action.
  • the wire is then subjected to the same sequence of operations illustrated in Fig. l, which operations, of course, may or may not include cooling intermediate the molten baths.
  • Fig. 3 illustrates, in schematic form, apparatus par ticularly adapted in the treating of hard drawn wire in accordance with this invention.
  • the apparatus shown in Fig. 3 for treating a wire 10 comprises a storage reel 12, a feed pulley 14, a first tubular heat treating furnace 16, a molten caustic container 18, a guide pulley 20, a molten fatty acid container 22, a discharge pulley 26, and a takeup pulley 28 driven through belt 30 by a motor 32.
  • a variety of types of supporting structures may be employed in utilizing the apparatus shown in Fig. 3.
  • tubular extension 17 having a gas inlet 19 for counter-currently introducing the desired atmospherepr-oviding gas, e. g., nitrogen.
  • the outlet of the furnace 16 and the molten caustic container may be juxtaposed to eliminate exposure of the wire prior to contact with the caustic.
  • the molten caustic container 18 and the molten fatty acid container 22 may be fabricated from nickel, steel, Monel, or other chemicaland temperature-resistant metal or alloy, Each of the containers 18 and 22 preferably comprises a curved tubular. member, e. g., '12 inch radius, having an inlet intermediate its ends, and'a radius of curvature dictated by the minimum bending radius the wire to be processed can withstand.
  • a curved tubular. member e. g., '12 inch radius
  • the containers 18 and 22, having a relatively large radius of curvature permit the processing of hard drawn wire which is capable of only a slight degree of bending without rupture.
  • containers of this type have the additional advantage of permitting the use of relatively small quantities of molten caustic and molten fatty acid.
  • eacn'con'tainer is provided with suitable heating'means, such as a longitudinally extending heating coil comprising an electrical resistance heating element (not shown). It will be appreciated that the necessary heating also may be accomplished, if desired, by utilizing gas or other burners (not shown). In order to minimize heat loss the containers 18 and 22 preferably are suitably covered with asbestos or other insulation.
  • wire is passed continuously from the storage reel 12 over feed pulley 14 through the heat treatment furnace 16 wherein any desired heat treatment in advance of caustic immersion may be provided, through molten caustic in the container 18, over guide pulley 20, through molten fatty acid in container 22, over the discharge pulley 26, and onto take-up pulleyZS.
  • a storage spool 34 which illustrates another form of apparatus which may be used intreating wire 10' in the practice of this invention
  • a storage spool 34 a first heat treatment furnace 36, guide spools 38, 40, 42, 44, and 46, a molten caustic container 56 provided with heating means (not shown), and a molten fatty acid container 58, also provided with heating means (not shown), and a take-up spool 5t) driven through belt 52 by a motor 54.
  • a special atmosphere e. g.,' inert or reducing
  • FIG. 4 There is also provided an inlet 39 for introduction of the desired atmosphere-providing gas, e. g., nitrogen.
  • the desired atmosphere-providing gas e. g., nitrogen.
  • the sequence of operations is as follows: Wire 10' is taken continuously from storage reel 34, passed successively through the first heat treatment furnace 36, through molten caustic in container 56, and'molten fatty acid in container 58, and onto the take-up spool 50.
  • the various heat treatment furnaces indicated in the drawings may comprise different types of apparatus, depending upon the particular application. However, it has been found practicable in most instances to employ a tubular heating chamber having a relatively small diameter, e. g., /z" to 1 /2" or less, thesize, of course, being dictated by the size of wire or other metal processed, and providing adequate heating by a spirally disposed electrical resistance heating element about the tubular heating chamber.
  • a suitable electrical resistance heating element may comprise Nichrome wire
  • the tubular heating chamber may be formed from a heat resistant metal, such as nickel, or other suitable metal or alloy, or, if desired, from a heat-resistant metallic or non-metallic refractory substance, such as glass or other refractory. It is desirable to provide heat-resistant insulation about the heating chamber and heating element, a
  • Example I A non-annealed steel wire 0.081 in diameter, moving at a speed of 10 feet per minute, is first passed through a 3-foot long, A" diameter, electrically heated tubular furnace at a temperature of 1835 F. The wire emerging from the furnace is at red heat and has an approximate temperature of 1475 F. This preheated wire passes continuously into molten sodium hydroxide, which has a temperature of 680 F. The wire then is immersed in molten stearic acid maintained at a temperature of 300 F.
  • the thus-treated wire is then passed through wiredrawing dies wherein, in one pass, it is subjected to a substantial reduction, i. e., 30%, in diameter.
  • the wire draws readily without injury to the die or accumulation of excess coating thereon.
  • the drawn wire retains an adherent protective surface diffusion zone which may be either removed by Water or steam washing, or may be allowed to remain on the wire for protective purposes.
  • Example II The procedure of Example I is repeated using palmitic acid instead of stearic acid. Substantially the same results are obtained.
  • Example III A diameter quartz tube 12" long is heated with 4 gas burners and a stream of nitrogen, previously bubbled through concentrated H is passed continuously through the tube.
  • a length of pre-cleaned, acidetched iron wire is piaced in the tube and heated to a red heat.
  • the wire is then quickly placed in a nickel beaker containing molten sodium hydroxide at a temperature of 650 F.
  • the wire is transferred quickly to a glass beaker containing molten stearic acid at a temperature of 375 F.
  • the thus-treated wire is removed from the molten stearic acid and allowed to cool. There results an adherent, hard saponificationproduct surface diffusion layer on the wire.
  • Example IV The procedure of Example lll'is repeated except that the temperature of the molten stearic acid is 167 F.
  • the resultant surface diffusion layer provides a durable, adherent lubricant surface.
  • Example V Red hot iron wire is successively immersed in molten sodium hydroxide having a temperature of 680 F., and in molten palmitic acid which is maintained at F. There results an adherent saponification product surface diffusion layer having excellent lubricating properties.
  • Example VI Employing apparatus of the type illustrated in Fig. 3, using a tubular furnace having a temperature of 1475" F. and provided with a nitrogen atmosphere, iron wire is heated to red heat and passed successively through molten sodium hydroxide at 680 F, and stearic acid at 212 F. There is obtained a durable, protective and lubricant surface on the wire.
  • Example VII Iron wire is heated to red heat and immediately passed successively through molten potassium hydroxide and molten stearic acid. There results a surface diffusion layer essentially identical to that obtained by using molten sodium hydroxide.
  • Example VIII Separate samples of iron wire are heated to red heat in an-inert atmosphere and then successively passed through 7 molten sodium hydroxide at 660 F. and molten fatty acids at temperatures as indicated below:
  • Example IX To illustrate the use of molten alkali metal hydroxide in combination with other fatty substances, a series of experiments are conducted in the following manner. Iron wire is pickled in 50% hydrochloric acid for minutes, rinsed in water, and then heated to 1350 F. in a quartz tube by gas burners. A nitrogen atmosphere is provided in the furnace.
  • the thus-treated wire is then dipped for 5 seconds in molten sodium hydroxide maintained at a temperature of 680 F. and thereafter immediately dipped into a second molten bath for 5 seconds, the second bath being maintained at a temperature of 300 F.
  • the following table indicates the compositions of the second molten bath and the type of reaction observed:
  • Fatty substance Reaction observed Tung oil Mild reaction. Soybean oil Mild reaction. Menhadden oil Mild reaction. Tall oil Vigorous reaction. Sunflower oil Mild reaction. Olive oil Mild reaction. Cottonseed oil Mild reaction. Linseed oil Mild reaction. Castor oil Mild reaction. Caproic acid Vigorous reaction. Oleic acid Vigorous reaction.
  • Example X The procedure according to Example IX is repeated using somewhat different temperature conditions.
  • the tubular furnace temperatur'e is maintained at 1832 F.
  • the molten sodium hydroxide temperature is 932 F.
  • the fatty substance temperature is 302 F.
  • the reactions observed with specific molten fatty substances are shown in the following table:
  • Soybean oil Mild reaction Menhadden oil Mild reaction. Tall oil Vigorous reaction. Sunflower oil Mild reaction. Olive oil Mild reaction. Cottonseed oil Mild reaction. Linseed oil Mild reaction. Castor oil Mild reaction. Caproic acid Vigorous reaction. -Oleic acid Vigorous reaction.
  • Example XI A further series of experiments are conducted according to the procedure of Example IX, except that after the wire is washed with water, following acid pickling, it is placed in an oven maintained at 212 F. for :15 minutes. The thus-heated wire is then passed through a tubular furnace temperature maintained at 15 62 F. The molten sodium hydroxide temperature is 932 F., and the molten fatty substance temperature is 302 F. The results of such runs using the fatty substances are set forth in the table below:
  • Example XIII A further experiment is conducted by placing a drop of room temperature water on a length of wire treated with molten sodium hydroxide and molten stearic acid. Examination under a microscope reveals that the surface diffusion layer softens under the influence of water and can then readily be removed by wiping. Toluene and carbon tetrachloride are applied in the same manner as the drop of water to an identical coating without appreciable solvent effect.
  • Example XIV 5% mica powder mesh) 50% powdered graphite (Acheson Electric Furnace Graphite grade 38, National Carbon Co., Inc.)
  • the present invention affords an excellent means for binding a finely-divided solid lubricant, e. g., graphite, even a large amount of graphite, on wire prior to drawing.
  • a finely-divided solid lubricant e. g., graphite
  • the term metal of course is intended to include both relatively pure metals per se and alloys.
  • the alkali metal hydroxide is employed in the molten state, it is meant that its temperature may range from the temperature at which the particular alkali metal hydroxide or mixtures thereof become molten, to a temperature limited by the boiling point of such hydroxides.
  • the temperature which, of course, may be varied within this range, depending upon the particular application, is the lowest which provides the desired elfect on the metal being treated.
  • temperatures, using sodium hydroxide are within the range from its melting temperature, i. e., 318.4 C. (606.1 F.), to about 950 F.
  • the temperature of the second molten bath also may range from the melting point to the boiling point of the substance or mixture employed,
  • temperatures as low as possible within this range are employed.
  • Using stearic acid typically practicable temperatures within the range from 2503l0 F., although temperatures as high as 375 F. have been used.
  • the speed at which wire is passed through the molten baths and heat treating furnaces can be varied Widely and is dictated by the type of wire being processed and the particular application intended. However, in smallscale installations employing temperatures of the order indicated hereinbefore, lineal speeds within the range from 10 to feet per minute are typical. It is appreciated that commercial wire drawing operations involve wire speeds often as high as several hundred feet per minute. For example, stainless steel wire drawing speeds generally range from about 80 to 200 feet per minute, while carbon steel wire is often drawn at speeds as high as 500 to 600 feet per minute. Hence, it is generally more practicable to treat wire in accordance with this invention and then separately to draw the treated wire. However, in certain instances, continuous drawing operations wherein wire is first treated by the technique of the present invention can be achieved by proper selection of bath compositions, temperatures, and wire drawing speeds.
  • Metals which can advantageously be treated in accordance with this invention include both ferrous and nonferrous metals and alloys.
  • Illustrative are various irons, steels, including stainless steels, titanium, copper, nickel, cobalt, as well as various alloys containing these or other
  • other metal operations are contemplated as well, e. g., tube drawing, pressing and stamping in suitable dies, deep drawing of sheet metals, wire rolling, and the like.
  • While this invention is applicable in a variety of metal treating operations, those skilled in the art will recognize that it provides an improved method for wire patenting, i. e., heat treating of wire, generally medium or high carbon steel wire, before drawing or between draws, whereby the Wire is heated above its transformation temperature range and then cooled to a temperature above this range.
  • Wire patenting operations heretofore generally have involved successively passing wire through molten lead, acid pickling, lime slurry soaking, lime baking, and sub sequent application of a lubricant.
  • the patenting can be accomplished directly by successive immersion of the wire in molten caustic and a molten fatty acid or other fatty substance as indicated hereinbefore, without resort to a multiplicity of elaborate and relatively costly operations as heretofore required.
  • a metal conditioning process including the successive steps of heating a metal to an elevated temperature, immersing the heated metal in molten alkali metal hydroxide maintained at a lower temperature, removing the thustreated metal from the alkali metal hydroxide, and immersing it in a molten fatty acid thereby to cause in situ reaction of alkali metal hydroxide and fatty acid at and beneath the metal surface, and removing the metal from the molten fatty acid.
  • the improvement which comprises passing said wire continuously through 21 molten alkali metal hydroxide and a molten fatty substance capable of reacting with said hydroxide in situ to form a protective and lubricant soap layer on the wire.
  • a metal treating process including the steps of successively heating metal to an elevated temperature in an inert atmosphere, contacting the said heated metal, while maintained in an inert atmosphere, with molten alkali metal hydroxide maintained at a lower temperature, and transferring the thus-treated metal into a molten fatty substance capable of reacting with said alkali metal hydroxide in situ to form an adherent, protective and lubricant surface diffusion zone at and beneath the surface of said metal.
  • a method of conditioning metal surfaces including the steps of contacting said surface with molten alkali metal hydroxide until the surface attains. the temperature of the molten hydroxide, and then immersing the thus-treated metal surface, without intermediate treatment, into a molten fatty acid and thereafter allowing the thus-formed coating on the metal to cool.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
US499575A 1955-04-06 1955-04-06 Metal treating process Expired - Lifetime US2871140A (en)

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LU34289D LU34289A1 (zh) 1955-04-06
BE546758D BE546758A (zh) 1955-04-06
US499575A US2871140A (en) 1955-04-06 1955-04-06 Metal treating process
GB10167/56A GB792421A (en) 1955-04-06 1956-04-03 Improvements in or relating to the treatment of metal

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2966425A (en) * 1959-02-18 1960-12-27 Montgomery H A Co Drawing lubricant coating methods and compositions
US3222778A (en) * 1962-01-17 1965-12-14 Martin Marietta Corp Process for retaining the ductility of metal
EP0163471A2 (en) * 1983-06-20 1985-12-04 Sumitomo Metal Industries, Ltd. Method for continuous drawing of wire rod
US4688411A (en) * 1984-05-21 1987-08-25 Sumitomo Metal Industries, Inc. Method for continuous drawing of wire rod
US20120031160A1 (en) * 2009-04-24 2012-02-09 Arihant Domestic Appliances Ltd. Low carbon welded tube and process of manufacture thereof
US20180347052A1 (en) * 2017-05-31 2018-12-06 Sanchem, Inc. High molecular mass, saturated hydrocarbon acid based chemical conversion coating composition

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1547539A (en) * 1923-12-08 1925-07-28 Firm Koholyt Ag Process for increasing the life of graphite or carbon electrodes
US2127497A (en) * 1934-05-21 1938-08-23 Standard Oil Co California Lubricating grease
US2218557A (en) * 1939-05-12 1940-10-22 Agnes J Reeves Greer Treatment of metals
US2432784A (en) * 1945-12-07 1947-12-16 Harold F Miller Lubricating and cooling compound for cold reducing mills
US2519127A (en) * 1945-04-23 1950-08-15 American Steel & Wire Co Method of drawing stainless steel wire
US2632347A (en) * 1949-03-30 1953-03-24 Standard Oil Dev Co Lubricant for metal rolling mills
US2662836A (en) * 1950-01-06 1953-12-15 Montgomery H A Co Preparing metal surfaces for drawing operations

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1547539A (en) * 1923-12-08 1925-07-28 Firm Koholyt Ag Process for increasing the life of graphite or carbon electrodes
US2127497A (en) * 1934-05-21 1938-08-23 Standard Oil Co California Lubricating grease
US2218557A (en) * 1939-05-12 1940-10-22 Agnes J Reeves Greer Treatment of metals
US2519127A (en) * 1945-04-23 1950-08-15 American Steel & Wire Co Method of drawing stainless steel wire
US2432784A (en) * 1945-12-07 1947-12-16 Harold F Miller Lubricating and cooling compound for cold reducing mills
US2632347A (en) * 1949-03-30 1953-03-24 Standard Oil Dev Co Lubricant for metal rolling mills
US2662836A (en) * 1950-01-06 1953-12-15 Montgomery H A Co Preparing metal surfaces for drawing operations

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2966425A (en) * 1959-02-18 1960-12-27 Montgomery H A Co Drawing lubricant coating methods and compositions
US3222778A (en) * 1962-01-17 1965-12-14 Martin Marietta Corp Process for retaining the ductility of metal
EP0163471A2 (en) * 1983-06-20 1985-12-04 Sumitomo Metal Industries, Ltd. Method for continuous drawing of wire rod
EP0163471A3 (en) * 1983-06-20 1986-06-18 Sumitomo Metal Industries, Ltd. Method for continuous drawing of wire rod
US4688411A (en) * 1984-05-21 1987-08-25 Sumitomo Metal Industries, Inc. Method for continuous drawing of wire rod
US20120031160A1 (en) * 2009-04-24 2012-02-09 Arihant Domestic Appliances Ltd. Low carbon welded tube and process of manufacture thereof
JP2012524661A (ja) * 2009-04-24 2012-10-18 アリハント ドメスティック アプライアンシーズ リミテッド 低炭素溶接鋼管、システムおよびその製造方法
US20180347052A1 (en) * 2017-05-31 2018-12-06 Sanchem, Inc. High molecular mass, saturated hydrocarbon acid based chemical conversion coating composition

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BE546758A (zh)
GB792421A (en) 1958-03-26

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