US2820263A - Device for ultrasonic treatment of molten metal - Google Patents

Device for ultrasonic treatment of molten metal Download PDF

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US2820263A
US2820263A US508246A US50824655A US2820263A US 2820263 A US2820263 A US 2820263A US 508246 A US508246 A US 508246A US 50824655 A US50824655 A US 50824655A US 2820263 A US2820263 A US 2820263A
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ultrasonic
molten metal
ultrasonic treatment
ladle
handle
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US508246A
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Fruengel Frank
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/10Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/08Shaking, vibrating, or turning of moulds

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  • the present invention relates to ultrasonic treatment of molten metal and has as one of its objects to provide simple means for such treatment being beneficial in degassing the metal and in obtaining a finer grain in the finished casting.
  • the invention provides for ultrasonic treatment of molten metal on its Way between crucible and mold, i. e., directly in the pouring ladle and provides therefor a special ladle having an ultrasonic generator or transducer in its long handle.
  • Fig. 1 is a diagrammatic view of a pouring ladle having a long handle in which ultrasonic shock Wave generating means are arranged;
  • Fig. 2 is a similar view showing magnetostrictive means for producing ultrasonic vibration in the handle of a pouring ladle.
  • the ladles 10, shown in their conventional form as half-spherical bowls, are provided with long handles 11 to which electrical connections are made in the form of cables 12.
  • Pouring ladles are generally not provided with a refractory inner lining, but are coated with a graphite preparation which is a good conductor for ultra sound. Therefore, it is readily possible to subject the molten metal 13 in the ladle to ultrasonic vibration which can be generated in the long handle of the ladle itself.
  • Such ultrasonic generating means may include, as shown in Fig. l, a storage condenser 14 to which one conductor 15 of cable 12 is connected through an impedance 16. The other terminal of condenser 14 and the other conductor of the cable are grounded to the handle and complete a circuit to which an external source of voltage impulses can be connected for charging condenser 14, whereby impedance 16 serves to limit the charging rate.
  • a discharge circuit of condenser 14 includes a spark gap 17 preferably arranged in a sealed chamber 20 filled with water or other liquid.
  • Fig. 1 The arrangement depicted in Fig. 1 is very effective, rugged and reliable in operation, but it is not the only means of producing ultrasonic vibration in a pouring ladle and magnetrostrictive transducers can also be employed as indicated in Fig. 2.
  • high-frequency current is fed through cable 12 to a coil 18 wound around a handle extension 19 of magnetostrictive material such as, for instance, nickel.
  • handle extension 19 being preferably designed for a harmonic natural frequency, will execute ultrasonic vibration which will be imparted on the content 13 of the ladle and will effect ultrasonic treatment thereof.
  • handle extension 19 being preferably designed for a harmonic natural frequency, will execute ultrasonic vibration which will be imparted on the content 13 of the ladle and will effect ultrasonic treatment thereof.
  • the arrangement shown is of simple construction since the coil can operate with low voltage and is not exposed to excessive heat.
  • Suitable frequencies for magnetostrictive transducers lie in the range from 5,000 to 150,000 cycles per second. It is, however, advantageous to operate ladles according to this invention, particularly for industrial application, with a frequency of about 10,000 cycles per second, because generating sets for this frequency are extensively used in the field of induction heating, are therefore commercially available, and deliver high-frequency energy at resonable cost.
  • ultrasonic treatment Whenever for certain alloys ultrasonic treatment must be extended for longer periods, it may become necessary to apply heat to the ladle in order to prevent excessive cooling of its content before actual casting.
  • Such heating can be provided for by electric heating elements or the ladle can be put on a heater surface for the duration of ultrasonic treatment.
  • Current for heating elements provided in the ladle can be fed through the same cable as the high-frequency or voltage impulse current necessary for producing the ultrasonic energy.
  • a projection of magnetostrictive material can be secured to the bottom or any other part of the ladle proper, which then for the period of ultrasonic treatment can be temporarily inserted in a conveniently located stationary coil excited by current of proper frequency.
  • the very simplest arrangement for taking advantage of ultrasonic treatment for molten casting material would be a ladle of conventional construction provided with a flat bottom portion which can be brought in close contact with the plane surface of an ultrasonic transducer or can be immersed in a bath which in turn is excited by ultrasonic vibration.
  • the transducer is mounted stationary and can be combined with the heating means probably required for keeping the metal melt of temperature.
  • a device for ultrasonic treatment of molten metal comprising in combination a metal pouring ladle having a long handle, electric means for producing vibration of ultrasonic frequency arranged in said handle, and connecting means for supplying electric energy in suitable form to said vibration producing means.
  • a device for ultrasonic treatment of molten metal comprising in combination a metal pouring ladle having a long handle, a storage condenser accommodated in said handle, means for connecting said condenser to a source of voltage impulses for charging the condenser, a discharge circuit for said condenser arranged in said handle and including spark gap means designed for a breakdown voltage lower than the peak of said charging impulses, said spark gap means arranged in a chamber formed in said handle and filled with a liquid, whereby a spark discharge is caused in said liquid whenever the impulse voltage surpasses the breakdown voltage of said spark gap means, said spark giving rise to ultrasonic shock wave radiation exciting said pouring ladle for ultrasonic treatment of its content.
  • said vibration producing means include a spark gap means, handle portions forming a chamber filled with a liquid in which said spark gap means is submerged, and means for causing electric discharges across said spark gap means.
  • a device for treatment of molten metal comprising in combination a metal pouring ladle having a long handle, electric energy storage means accommodated in said handle, connecting means for supplying electric energy to said storage means from an external source, a discharge circuit for said storage means arranged in said handle, handle portions forming a chamber filled with a liquid, said discharge circuit including spark gap means within the liquid filling of said chamber, the breakdown References Cited in the file of this patent UNITED STATES PATENTS 726,515 Day Apr. 28, 1903 1,318,740 Fessenden Oct. 14, 1919 1,689,196 Dunn Oct. 30, 1928 1,939,712 Mahoux Dec. 19, 1933 2,419,373 Schrumn Apr.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Description

Jan. 21, 1958 F.-FRUENGEL 2,820,263.
DEVICE FOR ULTRASONIC TREATMENT OF MOLTEN METAL Filed my 13. 1955 INVENTOR.
FRANK FRUENGEL BY M404 0- K0456 United States Patent DEVICE FOR ULTRASONIC TREATMENT OF MOLTEN METAL Frank Fruengel, Hamburg-Rissen, Germany Application May 13, 1955, Serial No. 508,246 In Germany October 1, 1948 Public Law 619, August 23, 1954 Patent expires October 1, 1968 4 Claims. (CI. 22-86) The present invention relates to ultrasonic treatment of molten metal and has as one of its objects to provide simple means for such treatment being beneficial in degassing the metal and in obtaining a finer grain in the finished casting.
In the prior art there have been disclosed various methods aiming at introducing ultrasonic energy into a batch of molten metal, but none of these methods could gain widespread recognition because there is not available an ultrasonic transducer that could safely be inserted directly in molten metal. It was necessary to insert long intermediate members, such as rods of tungsten or porcelain between ultrasonic transducer and molten metal, which members caused considerable loss of ultrasonic energy particularly on account of high absorption at vibration frequencies not inherent in members of such material; or it was necessary to excite the crucible, holding the molten metal, by a suitable transducer, which latter practice requires great amounts of ultrasonic energy due to considerable size of the crucible and the thickness of its lining. Besides, an ultrasonic transducer is hard to apply on a crucible of conventional form.
It is a purpose of this invention to provide a simple device and a method for employing ultrasonic vibration in connection with conventional foundry and casting equipment causing little additional expenses.
With this purpose in view, the invention provides for ultrasonic treatment of molten metal on its Way between crucible and mold, i. e., directly in the pouring ladle and provides therefor a special ladle having an ultrasonic generator or transducer in its long handle.
Some preferred examples of embodiments of this in vention will now be described with reference to the accompanying drawing in which:
Fig. 1 is a diagrammatic view of a pouring ladle having a long handle in which ultrasonic shock Wave generating means are arranged; and
Fig. 2 is a similar view showing magnetostrictive means for producing ultrasonic vibration in the handle of a pouring ladle.
The ladles 10, shown in their conventional form as half-spherical bowls, are provided with long handles 11 to which electrical connections are made in the form of cables 12. Pouring ladles are generally not provided with a refractory inner lining, but are coated with a graphite preparation which is a good conductor for ultra sound. Therefore, it is readily possible to subject the molten metal 13 in the ladle to ultrasonic vibration which can be generated in the long handle of the ladle itself. Such ultrasonic generating means may include, as shown in Fig. l, a storage condenser 14 to which one conductor 15 of cable 12 is connected through an impedance 16. The other terminal of condenser 14 and the other conductor of the cable are grounded to the handle and complete a circuit to which an external source of voltage impulses can be connected for charging condenser 14, whereby impedance 16 serves to limit the charging rate.
2,820,263 Patented Jan. 21, 1958 A discharge circuit of condenser 14 includes a spark gap 17 preferably arranged in a sealed chamber 20 filled with water or other liquid. When now the peaks of the condenser charging pulses are higher than the breakdown voltage of the spark gap, sparks will jump through the gap and cause ultrasonic shock waves in the liquid imparting in turn ultrasonic vibration to the content of the ladle.
The arrangement depicted in Fig. 1 is very effective, rugged and reliable in operation, but it is not the only means of producing ultrasonic vibration in a pouring ladle and magnetrostrictive transducers can also be employed as indicated in Fig. 2. Here high-frequency current is fed through cable 12 to a coil 18 wound around a handle extension 19 of magnetostrictive material such as, for instance, nickel. When coil 18 is energized by a current of suitable frequency, handle extension 19, being preferably designed for a harmonic natural frequency, will execute ultrasonic vibration which will be imparted on the content 13 of the ladle and will effect ultrasonic treatment thereof. The arrangement shown is of simple construction since the coil can operate with low voltage and is not exposed to excessive heat.
Suitable frequencies for magnetostrictive transducers lie in the range from 5,000 to 150,000 cycles per second. It is, however, advantageous to operate ladles according to this invention, particularly for industrial application, with a frequency of about 10,000 cycles per second, because generating sets for this frequency are extensively used in the field of induction heating, are therefore commercially available, and deliver high-frequency energy at resonable cost.
Whenever for certain alloys ultrasonic treatment must be extended for longer periods, it may become necessary to apply heat to the ladle in order to prevent excessive cooling of its content before actual casting. Such heating can be provided for by electric heating elements or the ladle can be put on a heater surface for the duration of ultrasonic treatment. Current for heating elements provided in the ladle can be fed through the same cable as the high-frequency or voltage impulse current necessary for producing the ultrasonic energy.
In another arrangement for magnetostrictive excitation of the ladle, a projection of magnetostrictive material can be secured to the bottom or any other part of the ladle proper, which then for the period of ultrasonic treatment can be temporarily inserted in a conveniently located stationary coil excited by current of proper frequency.
The very simplest arrangement for taking advantage of ultrasonic treatment for molten casting material would be a ladle of conventional construction provided with a flat bottom portion which can be brought in close contact with the plane surface of an ultrasonic transducer or can be immersed in a bath which in turn is excited by ultrasonic vibration. For such operation, the transducer is mounted stationary and can be combined with the heating means probably required for keeping the metal melt of temperature.
It will be understood that other arrangements and construction of parts essential for ultrasonic treatment of molten metal in a pouring ladle are possible without departing from the spirit and scope of the invention.
What is claimed is:
1. A device for ultrasonic treatment of molten metal comprising in combination a metal pouring ladle having a long handle, electric means for producing vibration of ultrasonic frequency arranged in said handle, and connecting means for supplying electric energy in suitable form to said vibration producing means.
2. A device for ultrasonic treatment of molten metal comprising in combination a metal pouring ladle having a long handle, a storage condenser accommodated in said handle, means for connecting said condenser to a source of voltage impulses for charging the condenser, a discharge circuit for said condenser arranged in said handle and including spark gap means designed for a breakdown voltage lower than the peak of said charging impulses, said spark gap means arranged in a chamber formed in said handle and filled with a liquid, whereby a spark discharge is caused in said liquid whenever the impulse voltage surpasses the breakdown voltage of said spark gap means, said spark giving rise to ultrasonic shock wave radiation exciting said pouring ladle for ultrasonic treatment of its content.
3. A device as set forth in claim 1, wherein said vibration producing means include a spark gap means, handle portions forming a chamber filled with a liquid in which said spark gap means is submerged, and means for causing electric discharges across said spark gap means.
4. A device for treatment of molten metal comprising in combination a metal pouring ladle having a long handle, electric energy storage means accommodated in said handle, connecting means for supplying electric energy to said storage means from an external source, a discharge circuit for said storage means arranged in said handle, handle portions forming a chamber filled with a liquid, said discharge circuit including spark gap means Within the liquid filling of said chamber, the breakdown References Cited in the file of this patent UNITED STATES PATENTS 726,515 Day Apr. 28, 1903 1,318,740 Fessenden Oct. 14, 1919 1,689,196 Dunn Oct. 30, 1928 1,939,712 Mahoux Dec. 19, 1933 2,419,373 Schrumn Apr. 22, 1947 FOREIGN PATENTS 456,657 Great Britain Nov. 9, 1936 480,554 Great Britain Feb. 24, 1938 OTHER REFERENCES Crawford, Metallurgia, March 1953, pages 109-113. Bergmann, Ultrasonics, 1938, pp. 5-11, 210-11, 216-17.
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3098533A (en) * 1960-07-05 1963-07-23 Ostrom Cyrus Warren Electric discharge impulse submarine drivers
US3181799A (en) * 1962-09-06 1965-05-04 Goodman Mfg Co Method for loosening frozen ore beds
US3599319A (en) * 1968-03-15 1971-08-17 Martin Weinstein Method and apparatus for producing fine-grained thermoelectric material
US4006707A (en) * 1976-05-10 1977-02-08 Branson Ultrasonics Corporation Ultrasonic coating apparatus
US4582117A (en) * 1983-09-21 1986-04-15 Electric Power Research Institute Heat transfer during casting between metallic alloys and a relatively moving substrate
US4854712A (en) * 1987-06-02 1989-08-08 Chikuma Kouki Co., Ltd. Multi-color luminous stirrer
US20090224443A1 (en) * 2008-03-05 2009-09-10 Rundquist Victor F Niobium as a protective barrier in molten metals
US8574336B2 (en) 2010-04-09 2013-11-05 Southwire Company Ultrasonic degassing of molten metals
US8652397B2 (en) 2010-04-09 2014-02-18 Southwire Company Ultrasonic device with integrated gas delivery system
US9481031B2 (en) 2015-02-09 2016-11-01 Hans Tech, Llc Ultrasonic grain refining
US9528167B2 (en) 2013-11-18 2016-12-27 Southwire Company, Llc Ultrasonic probes with gas outlets for degassing of molten metals
US10022786B2 (en) 2015-09-10 2018-07-17 Southwire Company Ultrasonic grain refining
US10233515B1 (en) 2015-08-14 2019-03-19 Southwire Company, Llc Metal treatment station for use with ultrasonic degassing system
US20220097130A1 (en) * 2020-09-25 2022-03-31 GM Global Technology Operations LLC Aluminum castings using ultrasonic technology

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US726515A (en) * 1901-10-07 1903-04-28 Draper Co Molding apparatus.
US1318740A (en) * 1919-10-14 Reginald a
US1689196A (en) * 1925-02-10 1928-10-30 Dunn John Struthers Pouring ladle
US1939712A (en) * 1929-08-08 1933-12-19 Mahoux George Treatment of metals and alloys
GB456657A (en) * 1934-05-07 1936-11-09 Rudolf Jahn Process of producing uniformly fine-grained castings from metals and metal alloys
GB480554A (en) * 1936-03-25 1938-02-24 Deutsche Edelstahlwerke Ag Improvements in or relating to the casting of metals and alloys
US2419373A (en) * 1943-09-10 1947-04-22 Metals & Controls Corp Apparatus for vibrating metals during casting

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1318740A (en) * 1919-10-14 Reginald a
US726515A (en) * 1901-10-07 1903-04-28 Draper Co Molding apparatus.
US1689196A (en) * 1925-02-10 1928-10-30 Dunn John Struthers Pouring ladle
US1939712A (en) * 1929-08-08 1933-12-19 Mahoux George Treatment of metals and alloys
GB456657A (en) * 1934-05-07 1936-11-09 Rudolf Jahn Process of producing uniformly fine-grained castings from metals and metal alloys
GB480554A (en) * 1936-03-25 1938-02-24 Deutsche Edelstahlwerke Ag Improvements in or relating to the casting of metals and alloys
US2419373A (en) * 1943-09-10 1947-04-22 Metals & Controls Corp Apparatus for vibrating metals during casting

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3098533A (en) * 1960-07-05 1963-07-23 Ostrom Cyrus Warren Electric discharge impulse submarine drivers
US3181799A (en) * 1962-09-06 1965-05-04 Goodman Mfg Co Method for loosening frozen ore beds
US3599319A (en) * 1968-03-15 1971-08-17 Martin Weinstein Method and apparatus for producing fine-grained thermoelectric material
US4006707A (en) * 1976-05-10 1977-02-08 Branson Ultrasonics Corporation Ultrasonic coating apparatus
US4582117A (en) * 1983-09-21 1986-04-15 Electric Power Research Institute Heat transfer during casting between metallic alloys and a relatively moving substrate
US4854712A (en) * 1987-06-02 1989-08-08 Chikuma Kouki Co., Ltd. Multi-color luminous stirrer
US9327347B2 (en) 2008-03-05 2016-05-03 Southwire Company, Llc Niobium as a protective barrier in molten metals
US8844897B2 (en) 2008-03-05 2014-09-30 Southwire Company, Llc Niobium as a protective barrier in molten metals
US20090224443A1 (en) * 2008-03-05 2009-09-10 Rundquist Victor F Niobium as a protective barrier in molten metals
US9617617B2 (en) 2010-04-09 2017-04-11 Southwire Company, Llc Ultrasonic degassing of molten metals
US8652397B2 (en) 2010-04-09 2014-02-18 Southwire Company Ultrasonic device with integrated gas delivery system
US9382598B2 (en) 2010-04-09 2016-07-05 Southwire Company, Llc Ultrasonic device with integrated gas delivery system
US10640846B2 (en) 2010-04-09 2020-05-05 Southwire Company, Llc Ultrasonic degassing of molten metals
US8574336B2 (en) 2010-04-09 2013-11-05 Southwire Company Ultrasonic degassing of molten metals
US9528167B2 (en) 2013-11-18 2016-12-27 Southwire Company, Llc Ultrasonic probes with gas outlets for degassing of molten metals
US10316387B2 (en) 2013-11-18 2019-06-11 Southwire Company, Llc Ultrasonic probes with gas outlets for degassing of molten metals
US10441999B2 (en) 2015-02-09 2019-10-15 Hans Tech, Llc Ultrasonic grain refining
US9481031B2 (en) 2015-02-09 2016-11-01 Hans Tech, Llc Ultrasonic grain refining
US10233515B1 (en) 2015-08-14 2019-03-19 Southwire Company, Llc Metal treatment station for use with ultrasonic degassing system
US10022786B2 (en) 2015-09-10 2018-07-17 Southwire Company Ultrasonic grain refining
US10639707B2 (en) 2015-09-10 2020-05-05 Southwire Company, Llc Ultrasonic grain refining and degassing procedures and systems for metal casting
US20220097130A1 (en) * 2020-09-25 2022-03-31 GM Global Technology Operations LLC Aluminum castings using ultrasonic technology

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