US2813833A - Method of and apparatus for breaking down of froth - Google Patents

Method of and apparatus for breaking down of froth Download PDF

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Publication number
US2813833A
US2813833A US362305A US36230553A US2813833A US 2813833 A US2813833 A US 2813833A US 362305 A US362305 A US 362305A US 36230553 A US36230553 A US 36230553A US 2813833 A US2813833 A US 2813833A
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US
United States
Prior art keywords
froth
chamber
gas
discharge
vortex
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US362305A
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English (en)
Inventor
Leonardus J Revallier
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Stamicarbon BV
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Stamicarbon BV
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    • C—CHEMISTRY; METALLURGY
    • C13—SUGAR INDUSTRY
    • C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
    • C13B25/00—Evaporators or boiling pans specially adapted for sugar juices; Evaporating or boiling sugar juices
    • C13B25/02—Details, e.g. for preventing foaming or for catching juice
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01J—MANUFACTURE OF DAIRY PRODUCTS
    • A01J11/00—Apparatus for treating milk
    • A01J11/02—Appliances for preventing or destroying foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01B—BOILING; BOILING APPARATUS ; EVAPORATION; EVAPORATION APPARATUS
    • B01B1/00—Boiling; Boiling apparatus for physical or chemical purposes ; Evaporation in general
    • B01B1/02—Preventing foaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/02—Foam dispersion or prevention
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/10—Mixing by creating a vortex flow, e.g. by tangential introduction of flow components
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05B—PHOSPHATIC FERTILISERS
    • C05B1/00—Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
    • C05B1/10—Apparatus for the manufacture of superphosphates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S261/00—Gas and liquid contact apparatus
    • Y10S261/54—Venturi scrubbers

Definitions

  • a froth which is difiicult to break I may mention the froth obtained in the decomposition of phosphate rock by means of a strong acid such as H2804 or HNOs.
  • the gas evolution during this decomposition is chiefly due to the presence of rather large amounts of calcium carbonate; the stability of the froth is highly increased by the presence of colloidal clay in the raw rock.
  • a further object of my invention is to provide a method of breaking down froth without the use of chemical froth inhibitors in such instances where said use is customarily desirable but hardly admissible.
  • a still further object of my invention is to provide a method of breaking down froths with an unusual high liquid content.
  • Another object of my invention is to provide simple and efficient apparatus for carrying out my new process.
  • My invention is applicable in the breaking down of froths encountered in many different technological fields, e. g. the breaking of froth formed in fermentation processes, in the processing of milk, potato starch water and solutions of capillary active substances, and in the breaking of the very corrosive froth encountered when decomposing rock phosphates with a strong acid.
  • the froth is broken down by subjecting it to the forces obtaining in a gas vortex, generated in an auxiliary gas.
  • gas vortex designates a body of gas in rotational movement with a current moving spirally inwards towards the axis of rotation so that the angular velocity increases from the periphery towards the core of the body.
  • a gas vortex is established in a rotation chamber of suitable form by feeding the gas into the chamber at a 2,813,833 t e-dented Nov. 19, 1957 suitable velocity, then given an adequate discharge rate from the chamber, if a froth is introduced into the core of the vortex through an axial feed aperture, the froth is broken, presumably by the centrifugal forces and shearthe discharging gas.
  • rotation chamber designates a radially symmetrical cham-- ber with one axially located discharge aperture in onepassages disposed sotherethrough at a suit-- commences to rotate in the chamber in a path of greater radius than the radius of the discharge: aperture and forms in the chamber a vortex from which: gas continuously discharges through the discharge aper-- end thereof and one or more feed that a gas fed into the chamber able velocity,
  • the rotation: chamber is preferably of that type having a discharge end.
  • the method according to my invention of breaking down froth comprises introducing the froth into the core of a gas vortex which is established in a rotation chamber of the kind defined by feeding gas continuously into such a chamber, the velocity of the said feed and the area of the rotation chamber discharge aperture being such that the froth after entering the chamber is broken down and the liquid from the froth is precipitated on the chamber wall, flows along the said wall and passes through the discharge aperture of the chamber in unfrothed condition, e. g. in the shape of big drops.
  • a rotation chamber with one or more feed passages in substantially tangential relation to the chamber, but a chamber may be used in which the feed takes place axially, e. g., through an annular slot which is provided with guiding members Which impart the rotary motion to the gas.
  • the rotation chamber may have an axially located feed aperture formed by or connected with a feed pipe.
  • the feed aperture may be located in the end of the chamber opposite the discharge end or the feed pipe may intrude axially into the chamber.
  • the froth may be introduced into the chamber under the aspirating effect of a depression in the core of the vortex, which depression occurs if the dimensions of the rotation chamber are adequately selected. Otherwise, the froth may be supplied under an only slight overpressure. In order to aspirate the froth into the chamber it is essential for the diameter of the froth feed aperture to be smaller than the diameter of the discharge aperture.
  • the dimensions of the rotation chamber may be chosen with regard to the nature of the froth and the quantity to be broken down in a given time. It is impotrant to remember, however, that the pressure drop necessary to create a gas vortex giving the desired result is greater the larger the rotation chamber. On account of this fact it may be advantageous in order to attain the desired capacity to use a plurality of small rotation chambers connected to operate in parallel, instead of a single large rotation chamber.
  • the pressure drop necessary for causing the gas to flow through the rotation chamber at the required velocity can be produced either by. supplying the gas under pressure or by connecting the discharge aperture of the rotation chamber to a suction line.
  • the difference between the pressure at the entrance and at the discharge required for breaking the froth need not be great, the latter method is very useful in practice.
  • the actual pressure drop to be employed in a given rotation chamber, to give the desired result is determined empirically. If the gas velocity is too high the liquid on the wall of the chamber, instead of flowing to the discharge aperture, becomes dispersed in the gas. It is found that the froth breaking action is attained at relatively low velocities, so that it is easy to avoid causing this dispersal of the liquid.
  • the area of the discharge aperture in relation tothe feed aperture area is also a factor which influences the result, since this will affect, in addition to the maximum angular velocities obtaining in the chamber, the rate of discharge and hence the period of time during which the precipitated liquid remains in the chamber and in contact with the rotating gas. To give an adequate rate of discharge and to avoid unduly high angular velocities the area of the discharge aperture is preferably larger than the area of the feed aperture or the aggregate feed aperture area in the event that there is more than one feed aperture.
  • the process may be carried on with the rotation chamber orientated in any desired manner.
  • the chamber may be placed with its discharge aperture uppermost or lowermost.
  • a collecting chamber is preferably suitably positioned in receiving relation to the discharge aperture of the rotation chamber, the said collecting chamber being provided with a gas outlet and a liquid outlet.
  • Such outlets may be combined if desired, but in this case, due care should be taken to ensure that the gas velocity in the combined outlet is not so high that an intensive mixing, and hence possibly a new froth formation occurs.
  • a collecting chamber of a radially symmetrical form located coaxially with respect to the rotation chamber. This arrangement makes it possible for the rotary motion of the gas discharging from the rotation chamber to continue within the collecting chamber, so that the thorough separation of the precipitated liquid from the gas is promoted by the continuing centrifugal accelerations.
  • a discharge conduit for the gas which extends axially intothe collecting chamber, and to provide a peripheral discharge outlet for the liquid which flows down the wall of the said chamber.
  • This liquid outlet may take the form of a conduit provided in such tangential relation to the collecting chamber that the liquid which spirals downwards along the wall of the collecting-chamber, flows into thedischarge conduit as it continues its spiral movement. The liquid may be removed from thiscollecting' chamber continuously or discontinuously.
  • My invention may be used for dealing with f'roths of widely differing compositions and properties. Froth with a high liquid content can be broken down without diificulty. If desired a separation may be effected beforehand between a liquid and a froth.
  • a froth to be broken down if a froth to be broken down is so stiff that itis very difiicult or even impossible to convey it along a froth feed conduit to the axial feed aperture1 by application of pressure, it may be fed into the core of the vortex by means of a screw conveyor.
  • a rotation chamber for this purpose, may have a comparatively wide froth feed conduit and associated axial feed aperture, and a screw conveyor may be arranged within the said feed conduit. It may be necessary for dealing with such froths, to make the vortex current of suitably greater power than is normally required, butsubject to this requirement a rapid and complete breakage of the froth can be attained.
  • auxiliary gas for breaking the froth may be open to objection in'some cases, e. g., when a dilution of the gas phase occurring in the froth is undesirable.
  • a gas of the same composition as the gas phase in the froth may be used as the auxiliary gas to form the vortex. If necessary this gas may be recycled after separation therefrom of the liquid precipitated from the froth.
  • Figure 1 shows apparatus, comprising a vessel in which e. g., phosphate rock may be decomposed, and associated apparatus for breaking down the froth which is formed during the decomposition.
  • FIG. 2 shows a preferred form of the rotation chamber to be used in greater detail.
  • Figure 3 shows another assembly in which apparatus according to my invention is incorporated.
  • Figures 4 and 5 illustrate a very compact construction of rotation chamber and a conjoined collecting vessel.
  • Figure 4 shows a longitudinal cross section of the apparatus and Figure 5 an end view of the same.
  • the decomposition vessel 1 has a stirring element 2 and is closed by a cover plate 3.
  • the filling opening of the vessel 1 is provided with a charging hopper 4.
  • the rotation chamber is mounted in the mouth of a I radially symmetrical collecting chamber 10 which is provided'with an axially arranged gas discharge pipe 11 and a tangentially disposed liquid outlet pipe 12. If air is passed into the rotation chamber at a suitable velocity through the pipe 7, for instance from a low pressure air line, an air vortex is set up in the rotation chamber and the depression at the core of the vortex aspirates the froth out of the vessel 1.
  • 26 is a rotation chamber which is disposed with its discharge aperture 28 uppermost.
  • the rotation chamber is provided with a froth supply pipe 25which discharges axially into the chamber.
  • the rotation chamber is mounted in the wall of a radially symmetricalcollecting vessel 30 so that it'is'coaxial with the said vessel.
  • the vessel 39 has an outlet 31 for the gas and a tangential outlet 32 for the resultant liquid.
  • the outlet 32 opens into' a further vessel 33 provided with a gas discharge conduit 34 which is connected to a gas delivery pipe 35. If pipe 35 is connected to a suction conduit in which a depression of cm.
  • the suction is sufiicient to cause continuous feed of gas into the rotation chamber 26 through the pipe 27, at a velocity such that a vortex is established in the rotation chamber and such that by the action of this vortex froth is aspirated into the rotation chamber through the pipe and is broken down, the separated liquid being forced out of the discharge aperture 28 by the gas discharging from the rotation chamber and being flung against the wall of the vessel 30.
  • the liquid subsequently flows off through the pipe 32 into the vessel 33.
  • the rotation chamber 53 is formed by the combination of a hollowed-out lock 40 and a connected cylindrical part 41.
  • This part 41 is provided with a tangential gas inlet conduit 44, discharging at 45, and with an axial froth supply conduit 42 the discharge end 43 of which is narrowed.
  • a radially symmetrical collecting chamber 54 Connected to the discharge aperture 46 of the rotation chamber 53 is a radially symmetrical collecting chamber 54 formed by the combination with the block 40 of the cylindrical part 47.
  • the cylindrical part 47 is provided with an axially disposed discharge pipe 48 for the gas and a tangential discharge pipe 51 for the liquid obtained from the broken froth.
  • the discharge pipe 51 is provided with a regulating cock 52 by means of which the gas can be prevented from leaving through the said pipe.
  • a method of breaking down froth which comprises the steps of continuously flowing an auxiliary gas tangen tially into a radially symmetrical space to generate a gas vortex therein, continuously discharging said auxiliary gas axially from said vortex, and introducing froth into the core of said vortex, the forces prevailing in said vortex being effective to break down said froth and discharge the liquid separated from the froth in liquid form along with said auxiliary gas.
  • auxiliary gas is of the same composition as the gas occluded in the froth to be broken.
  • Apparatus for breaking down froth comprising a radially symmetrical rotation chamber, a circular axial discharge aperture in said chamber, at least one feed conduit for an auxiliary gas discharging tangentially into said chamber on a radius exceeding the radius of said discharge aperture, and a froth feed conduit discharging axially into said chamber opposite said discharge aperture, the outlet diameter of said froth feed conduit being less than the diameter of said discharge aperture, and a radially symmetrical receiving vessel joined coaxially to said rotation chamber and enclosing the discharge aperture thereof, said receiving vessel being provided with a gas discharge conduit projecting axially thereinto opposite the discharge opening of said rotation chamber.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biochemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Animal Husbandry (AREA)
  • Environmental Sciences (AREA)
  • Degasification And Air Bubble Elimination (AREA)
US362305A 1952-06-19 1953-06-17 Method of and apparatus for breaking down of froth Expired - Lifetime US2813833A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL170454 1952-06-19

Publications (1)

Publication Number Publication Date
US2813833A true US2813833A (en) 1957-11-19

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Application Number Title Priority Date Filing Date
US362305A Expired - Lifetime US2813833A (en) 1952-06-19 1953-06-17 Method of and apparatus for breaking down of froth

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US (1) US2813833A (en, 2012)
CH (1) CH314629A (en, 2012)
DE (1) DE1022189B (en, 2012)
ES (1) ES209827A1 (en, 2012)
FR (1) FR1084313A (en, 2012)
GB (1) GB734459A (en, 2012)
NL (1) NL75693C (en, 2012)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2838543A (en) * 1957-11-29 1958-06-10 Upjohn Co 6-fluoro steroids and process
US3161490A (en) * 1960-11-01 1964-12-15 Edmund F Dudek Gas-liquid separator
US3345803A (en) * 1965-01-07 1967-10-10 Fmc Corp Method and apparatus for degassing viscose
US3420450A (en) * 1965-05-03 1969-01-07 Svenska Cellulosa Ab Nozzle means for breaking foam
US3830041A (en) * 1971-10-20 1974-08-20 Environeering Foam breaker
US4111829A (en) * 1975-07-31 1978-09-05 Societe Nationale Elf Aquitaine (Production) Device for destroying foam
EP0314015A1 (en) * 1987-10-23 1989-05-03 Tecno-Bio Co., Ltd. Method for introducing and bonding gas into water, apparatus for carrying out the method and water produced by the method
US5015273A (en) * 1990-03-16 1991-05-14 Camco International Inc. Foam breaker and method
US5194814A (en) * 1991-05-22 1993-03-16 Tremetrics, Inc. Electrolytic conductivity detector
US20070006735A1 (en) * 2005-07-11 2007-01-11 David Olsen Separation of liquid and gas from froth
US20110067568A1 (en) * 2008-05-15 2011-03-24 Outotec Oyj Apparatus and method for mechanical deaeration
CN109277068A (zh) * 2018-11-27 2019-01-29 河钢股份有限公司承德分公司 常温常压下钒铬共提的反应装置及反应方法
EP4382184A1 (en) * 2022-12-06 2024-06-12 Yara International ASA System for breaking a liquid foam and method of operating thereof

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1168868B (de) * 1958-11-11 1964-04-30 Waldhof Zellstoff Fab Verfahren zum Zerstoeren von Schaeumen
DE1083201B (de) * 1958-12-11 1960-06-15 phil Karl Rolf Dietrich Frankfurt/M Dr Zyklonentschäumer für Nährsubsrate zum Züchten von Mikroorganismen
DE1271677B (de) * 1959-10-08 1968-07-04 Standard Messo Duisburg Vorrichtung zum Vermeiden von Schaumbildung bei einer unter Vakuum stehenden Fluessigkeit
DE3635713A1 (de) * 1986-10-21 1988-04-28 Voith Gmbh J M Verfahren zur entschaeumung
DE3900170C2 (de) * 1989-01-05 1994-02-17 Kammerer F Gmbh Verfahren und Vorrichtung zur Verminderung des Schaumvolumens über einer Flüssigeit in einem Behälter
FR2661450A1 (fr) * 1990-04-30 1991-10-31 Total Petroles Procede et dispositif pour le cassage de mousses chargees de deblais provenant du forage de puits et pour la recuperation de la phase liquide de ces mousses.

Citations (8)

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Publication number Priority date Publication date Assignee Title
GB104183A (en) * 1916-02-16 1918-02-15 Rasmussen & Ernst G M B H Process and Apparatus for Separating Air or Gases from Liquids.
US1440808A (en) * 1920-06-02 1923-01-02 Sullivan Machinery Co Separator
CH136359A (de) * 1927-11-15 1929-11-15 Harald Ledin Sven Verfahren und Apparat zum Austausch von Wärme zwischen Flüssigkeit und Gasen oder Dämpfen oder zum Reinigen und Absorbieren von Gasen.
DE615004C (de) * 1933-12-31 1935-06-24 Hartmann A G Maschf Fliehkraft-Staubabscheider
US2118167A (en) * 1935-12-12 1938-05-24 Micromatic Hone Corp Separator
US2353833A (en) * 1941-07-28 1944-07-18 Garman O Kimmell Separator for treating foamy oil
US2447119A (en) * 1944-06-30 1948-08-17 Harold J Goodyer Device for separating liquid or foreign matter in suspension from fluid under pressure
US2653801A (en) * 1950-10-13 1953-09-29 Stamicarbon Process and apparatus for dispersing a substance in a liquid

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE541226C (de) * 1925-10-18 1932-01-07 Metallgesellschaft Ag Verfahren und Vorrichtung zum Eindampfen von dampf- oder gasentbindenden Fluessigkeiten
DE817441C (de) * 1948-10-02 1951-10-18 Chemische Werke Huels G M B H Verfahren und Vorrichtung zum Entschaeumen von Fluessigkeiten
BE493152A (en, 2012) * 1949-01-07
DE855686C (de) * 1949-11-30 1952-11-17 Rosenblads Patenter Ab Vorrichtung zur Begrenzung der Schaumhoehe von Fluessigkeiten

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB104183A (en) * 1916-02-16 1918-02-15 Rasmussen & Ernst G M B H Process and Apparatus for Separating Air or Gases from Liquids.
US1440808A (en) * 1920-06-02 1923-01-02 Sullivan Machinery Co Separator
CH136359A (de) * 1927-11-15 1929-11-15 Harald Ledin Sven Verfahren und Apparat zum Austausch von Wärme zwischen Flüssigkeit und Gasen oder Dämpfen oder zum Reinigen und Absorbieren von Gasen.
DE615004C (de) * 1933-12-31 1935-06-24 Hartmann A G Maschf Fliehkraft-Staubabscheider
US2118167A (en) * 1935-12-12 1938-05-24 Micromatic Hone Corp Separator
US2353833A (en) * 1941-07-28 1944-07-18 Garman O Kimmell Separator for treating foamy oil
US2447119A (en) * 1944-06-30 1948-08-17 Harold J Goodyer Device for separating liquid or foreign matter in suspension from fluid under pressure
US2653801A (en) * 1950-10-13 1953-09-29 Stamicarbon Process and apparatus for dispersing a substance in a liquid

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2838543A (en) * 1957-11-29 1958-06-10 Upjohn Co 6-fluoro steroids and process
US3161490A (en) * 1960-11-01 1964-12-15 Edmund F Dudek Gas-liquid separator
US3345803A (en) * 1965-01-07 1967-10-10 Fmc Corp Method and apparatus for degassing viscose
US3420450A (en) * 1965-05-03 1969-01-07 Svenska Cellulosa Ab Nozzle means for breaking foam
US3830041A (en) * 1971-10-20 1974-08-20 Environeering Foam breaker
US4111829A (en) * 1975-07-31 1978-09-05 Societe Nationale Elf Aquitaine (Production) Device for destroying foam
AU604584B2 (en) * 1987-10-23 1990-12-20 Harrier Gmbh Method for introducing and bonding gas into water, apparatus for carrying out the method and water produced by the method
WO1989003724A1 (en) * 1987-10-23 1989-05-05 ''harrier Gmbh'' Gesellschaft Für Den Vertrieb Med Method for introducing and bonding gas into water, apparatus for carrying out the method and water produced by the method
EP0314015A1 (en) * 1987-10-23 1989-05-03 Tecno-Bio Co., Ltd. Method for introducing and bonding gas into water, apparatus for carrying out the method and water produced by the method
US5391328A (en) * 1987-10-23 1995-02-21 Tecno-Bio Co., Ltd. Apparatus for introducing and bonding gas into water
US5015273A (en) * 1990-03-16 1991-05-14 Camco International Inc. Foam breaker and method
US5194814A (en) * 1991-05-22 1993-03-16 Tremetrics, Inc. Electrolytic conductivity detector
US20070006735A1 (en) * 2005-07-11 2007-01-11 David Olsen Separation of liquid and gas from froth
US7449051B2 (en) 2005-07-11 2008-11-11 Hewlett-Packard Development Company, L.P. Separation of liquid and gas from froth
US20110067568A1 (en) * 2008-05-15 2011-03-24 Outotec Oyj Apparatus and method for mechanical deaeration
CN109277068A (zh) * 2018-11-27 2019-01-29 河钢股份有限公司承德分公司 常温常压下钒铬共提的反应装置及反应方法
CN109277068B (zh) * 2018-11-27 2023-09-22 河钢股份有限公司承德分公司 常温常压下钒铬共提的反应装置及反应方法
EP4382184A1 (en) * 2022-12-06 2024-06-12 Yara International ASA System for breaking a liquid foam and method of operating thereof

Also Published As

Publication number Publication date
NL75693C (en, 2012)
DE1022189B (de) 1958-01-09
ES209827A1 (es) 1953-12-16
CH314629A (de) 1956-06-30
FR1084313A (fr) 1955-01-18
GB734459A (en) 1955-08-03

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