US2752323A - Reinforcing filler for the rubber industry - Google Patents

Reinforcing filler for the rubber industry Download PDF

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Publication number
US2752323A
US2752323A US331489A US33148953A US2752323A US 2752323 A US2752323 A US 2752323A US 331489 A US331489 A US 331489A US 33148953 A US33148953 A US 33148953A US 2752323 A US2752323 A US 2752323A
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US
United States
Prior art keywords
rubber
reinforcing filler
rubber industry
illites
minerals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US331489A
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English (en)
Inventor
Anfinset Hans Monrad
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Individual
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Individual
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Publication of US2752323A publication Critical patent/US2752323A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/20Mica; Vermiculite
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S524/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S524/925Natural rubber compositions having nonreactive materials, i.e. NRM, other than: carbon, silicon dioxide, glass titanium dioxide, water, hydrocarbon or halohydrocarbon

Definitions

  • the reinforcing filler which I have found particularly suitable for this purpose consists principally of hydrous mica specifically these are the illites.
  • Illites are a group of mica-resembling hydrolyzed minerals usually formed from the primary minerals felspar, mica and/or chlorite. As described in the text (pages 156 and 157) X-Ray Identification and Crystal Structures of Clay Minerals, by G. W. Brindley, London 1951, the hydrous micas lie between two well-defined groups of minerals, the well-crystallized micas and the expanding minerals, vermiculite and the montmorillonoids.
  • the intermediates between the non-expanding clay micas, the illites, and the expanding minerals are the mixed-layer minerals which consist of inter-layered mixtures of mica layers and vermiculite layers in some cases and mica layers and montrnorillonoid layers in others.
  • the hydrous micas are a well-defined mineral group and are classified according to their alkali content which is a measure of the charge per layer as well as in the crystal series, dioctahedral and trioctahedral.
  • the illites are intermediate in alkali content between the higher alkali value in the mica and the lower alkali value in the vermiculite. This decrease in alkali content is a measure of the decrease in the negative charge on the layer.
  • a mixture containing by volume of natural rubber, about 25% by volume of carbon black and about 25 by volume of illites (1 micron or less) plus necessary additional materials can easily be worked for instance on a rolling mill obtaining a continuous sheet while corresponding mixtures where the illite is replaced by other special fillers do not produce a continuous sheet.
  • hydromica as a reinforcing filler it is possible to use relatively small quantities of sulphur and accelerator(s) and still obtain relatively great tensile strength and elongation or break considerably greater than when using other first class fillers.
  • hydrous mica as a filler provides a processing advantage and during the working homogeneous mixtures are formed from the raw ingredients more quickly than when known fillers are used so that the cycle of compounding (time for mixing) is reduced by 20 to 35% and consequently the capacity of the rubber-mixing machinery is increased correspondingly.
  • caoutchouc As well as synthetic rubber products, for example rubber-like products obtained by the polymerisation of isoprene or its derivatives.
  • a composition consisting essentially of (a) a member selected from the group consisting of natural rubber and isoprene polymer rubber, and of (b) a finely-divided inorganic mineral filler consisting of illite in an amount of up to 50% by volume based upon said rubber, and of (0) carbon black in an amount up to 50% by volume based upon said rubber.
  • composition as claimed in claim 1 wherein said illite has a particle size of less than 1 micron.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
US331489A 1952-01-19 1953-01-15 Reinforcing filler for the rubber industry Expired - Lifetime US2752323A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE2752323X 1952-01-19

Publications (1)

Publication Number Publication Date
US2752323A true US2752323A (en) 1956-06-26

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ID=20427151

Family Applications (1)

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US331489A Expired - Lifetime US2752323A (en) 1952-01-19 1953-01-15 Reinforcing filler for the rubber industry

Country Status (4)

Country Link
US (1) US2752323A (de)
BE (1) BE517022A (de)
FR (1) FR1069911A (de)
LU (1) LU31965A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5444127A (en) * 1992-10-19 1995-08-22 Henkel Corporation Tertiary amine derivatives as components of polymer forming systems

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2381163A (en) * 1943-02-15 1945-08-07 Jefferson Electric Co Electrical insulating material
US2626941A (en) * 1949-08-15 1953-01-27 Wingfoot Corp Water impermeable, water vapor permeable coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2381163A (en) * 1943-02-15 1945-08-07 Jefferson Electric Co Electrical insulating material
US2626941A (en) * 1949-08-15 1953-01-27 Wingfoot Corp Water impermeable, water vapor permeable coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5444127A (en) * 1992-10-19 1995-08-22 Henkel Corporation Tertiary amine derivatives as components of polymer forming systems

Also Published As

Publication number Publication date
LU31965A1 (de)
BE517022A (de)
FR1069911A (fr) 1954-07-13

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