US2739129A - Cleaning composition - Google Patents
Cleaning composition Download PDFInfo
- Publication number
- US2739129A US2739129A US235100A US23510051A US2739129A US 2739129 A US2739129 A US 2739129A US 235100 A US235100 A US 235100A US 23510051 A US23510051 A US 23510051A US 2739129 A US2739129 A US 2739129A
- Authority
- US
- United States
- Prior art keywords
- water
- cleaning
- soluble
- powder
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 30
- 238000004140 cleaning Methods 0.000 title description 27
- 239000000843 powder Substances 0.000 description 21
- 239000002245 particle Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 229910052500 inorganic mineral Inorganic materials 0.000 description 11
- 235000010755 mineral Nutrition 0.000 description 11
- 239000011707 mineral Substances 0.000 description 11
- 238000005498 polishing Methods 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 238000009991 scouring Methods 0.000 description 7
- 239000013543 active substance Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- -1 fatty alcohol sulfonates Chemical class 0.000 description 5
- 230000007935 neutral effect Effects 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000008262 pumice Substances 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 3
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 208000028990 Skin injury Diseases 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- 235000019983 sodium metaphosphate Nutrition 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 229940048086 sodium pyrophosphate Drugs 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- OGNVQLDIPUXYDH-ZPKKHLQPSA-N (2R,3R,4S)-3-(2-methylpropanoylamino)-4-(4-phenyltriazol-1-yl)-2-[(1R,2R)-1,2,3-trihydroxypropyl]-3,4-dihydro-2H-pyran-6-carboxylic acid Chemical compound CC(C)C(=O)N[C@H]1[C@H]([C@H](O)[C@H](O)CO)OC(C(O)=O)=C[C@@H]1N1N=NC(C=2C=CC=CC=2)=C1 OGNVQLDIPUXYDH-ZPKKHLQPSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000015241 bacon Nutrition 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- QHDUJTCUPWHNPK-UHFFFAOYSA-N methyl 7-methoxy-2h-indazole-3-carboxylate Chemical compound COC1=CC=CC2=C(C(=O)OC)NN=C21 QHDUJTCUPWHNPK-UHFFFAOYSA-N 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000004552 water soluble powder Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
Definitions
- the invention relates to cleaning compositions, and more particularly. to scouring, cleansing, and polishing powders, of which the mechanically cleansing waterunsoluble components are of-such a fineness .that they will pass completely through a sieve having a mesh size of .3 mm.
- such compositions comprise a major part of water-insoluble mineral particles and a minor part of water-soluble particles.
- Powders of said type are frequently used for the cleansing and polishing of metals as well as for the cleaning of dirty hands.
- the mineral particles must be of a small grain size, as otherwise skin injuries, or scratches on shiny metal surfaces would occur.
- cleaning compositions a grain size under 0.3 mm. of the alkaline reaction, various phosphates, and soaps or synthetic capillary activematerials.
- These combinations of various substances have been heretofore, as usual in the manufacture of washing agents, frequently brought into powder form by spraying a mixture of the starting materials in form of a warm aqueous pasty mass having a high content of solids. This method is less a drying of the paste but rather a crystallizing out, on cooling, of the inorganic components dissolved by heating.
- neutral salts as, e. g. sodium sulfate or sodium chloride, which result from the preparation of fatty alcohol sulfonates, alkylaryl sulfonates, parai'lin sulfonates or other synthetic capillary active agents, form large and relatively sharply-edged crystals, and often coarsen the finely granulated cleaning compositions in an undesired manner.
- Such powders are especially suitable as water-soluble ingredients of scouring, cleansing, and polishing compositions which are prepared by spray-drying of solutions, in which the starting materials are dissolved as completely as possible.
- the liquid droplets finely distributed in the warm air current, dry to a fine powder without allowing the formation of large crystals. The more diluted the solution, and the finer the distribution by the spray nozzles is, the softer and the more finely granulated is the obtained powder.
- the selection of the water-insoluble components of a particle size under 0.3 depends on the intended use of the powder. Quartz dust has been found suitable for cleansing purposes, but it may also be incorporated in polishing powders if a particularly finely granulated prodnet is used or if the proportion of the water-soluble components is increased.
- Other suitable mineral agents are,
- Suitable water soluble agents are especially salts having alkaline reaction, such as sodium carbonate, sodium bicarbonate, dior tri-sodium phosphate, but also sodium pyrophosphate, sodium metaphosphate, sodium tripolyphosphate or sodium hexarnetaphosphate may be used.
- the action of these salts is assisted by an addition of capillary active substances, such as soap, alkylaryl sulfonates, olefinic or parafiinic sulfonates, and others.
- the cleaning composition can be prepared in various ways; for instance, the alkali salts which are to be incorporated can be brought to the desired fineness by prolonged grinding, sieving and/ or sifting. Especially if vibrating mills are used, a particularly finely ground product is obtained.
- the water-soluble ingredients may be ground also in the presence of moderate amounts of water-insoluble mineral ingredients; this procedure is especially recommended when very hard mineral ingredients such as quartz dust, areemployed. In this case the mineral powder assists in a very efiicient way the grinding operation, so as to produce a finely granulated powder in a shorter time.
- scouring and polishing compositions contain often as water-soluble ingredients combinations of materials which may consist of salts having an ever, with a suitable operation of the spraying apparatus, even substantially saturated'starting solutions, which contain no more undissolved solids, yield a powder which is completely satisfactory for the requirements of the method according to the invention. If a small amount of fine mineral powder is blown into the tower, an intimate mixture of the two ingredients is obtained which can be mixedreadily with the main amount of the mineral ingredient and which produces already after a short miX- ingperiod a very homogeneous powder.
- the present invention is by no means limited to polishing and scouring compositions of which the water-soluble component has an a kaline reaction; also substances of neutral or acid reaction can be successfully used.
- acid components are amidosuli'onic acid, urea nitrate, oxalic acid as well as organic, especially aromatic aminosulfonic acids; also other solid substances of acid reaction of similar or other groups, as e. g. sodium bisulfate, can be used together with finely powdered mineral components, particularly for the removal of acid-soluble stains.
- the neutral or acid polishing and scouring compositions may contain, in addition to the anion active ingredients, also cation active or electro-neutral wetting or foaming agents. Beside the acid resistant anion active wetting agents, certain cation active substances are particularly suitable as admixtures to acid polishing and scouring compositions, since they display in addition to the disinfecting action desired in a hand cleaning composition, also an inhibitive action in the metal treatment. it is, of course, also possible to incorporate other disinfecting substances into acid, neutral or alkaline cleaning compositions.
- novel cleansing, securing, and polishing compositions of the invention are of advantage not only in dry but also in wet cleaning.
- dry cleaning which is particularly recommended for the cleansing of aluminum, or copper
- the fine abrasive particles are embedded in the finer water-soluble components, in such a way that the cleaning composition applied to the base assumes already after a few strokes a surface of smooth appearance and displays a conspicuous polishing effect after the removal of superficial stains from the metal surface.
- This effect becomes especially apparent on relatively soft, transparent plastics, such as, for instance, Plexiglas.
- a cleaning composition containing 17 per cent of water-soluble components, having a particle size equal to the size of the quartz powder leaves theron a great number of microscopic fine scratches, which render the material dull.
- the mechanical cleaning action of the abrasive agents shall be assisted by the chemical action of the components dissolved in water; therefore, a high solution rate of the soluble admixtures is desired.
- Powders of a particle size of a .3 mm. have a relatively high rate of solution in water, and an increase of the cleaning action by a further decrease of the particle size could not be expected; nevertheless, I have observed a considerably increased cleaning action of such cleaning compositions.
- the explanation for this effect may be found in the particular conditions of diffusion and solution obtaining in wet cleaning. Whereas the dissolution of a water-soluble substance of .3 mm.
- the great advantage of the cleaning compositions according to the invention is due to the fact that the very fine water-soluble components are dissolved very quickly and yield a relatively concentrated cleaning liquid, which is capable of assisting very efficiently the mechanical cleaning action of the insoluble components. This results in a dissolution of the stains at the first strokes.
- Example 2 25 parts of alkyl sulfonate or alkyl aryl sulfonate in the form of a 20-30 per cent paste containing neutral salts are mixed with 35 parts of calcined soda. To this paste, hot water is added in such an amount that a complete dissolution of the substances is obtained. The solution contains'about 40 to 45 per cent of solids.
- the composition of this mixture may be changed.
- the soda may be replaced, wholly or in part, by orthophosphatcs or by anhydric phosphates, such as ym-phosphates, metaphosphates, or polyphcsphates. Salts of polycarboxyamines may be added.
- the hot solution is sprayed by means of a nozzle, which produces fine droplets, in a countercurrent of hot air.
- a very fine powder is obtained of approximately the following composition: 20% of capillary active substance, 35% of NazCOs, 23 of water; the balance is N212SO4 and/ or NaCl.
- the cleaning composition in accordance with the invention is obtained, which may contain 5 to 25 per cent of the water-soluble powder recited hereinabove.
- a powdered, water-insoluble inorganic abrasive selected from the group consisting of quartz, kaolin, pumice and marble dust, and a water soluble salt selected from the group consisting of sodium sulfate, sodium carbonate, sodium bicarbonate, (ii-sodium phosphate, sodium pyrophosphate, sodium metaphosphate, sodium tripolyphosphate and sodium hexametaphosphate, said water insoluble abrasive having a particle size passing completely through a sieve having meshes of .3 mm., said water soluble salts having a particle size smaller than that of said water-insoluble abrasive, and being present in an amount ranging from about 5% to about 33% by weight of said water-soluble abrasive.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP13333A DE860981C (de) | 1948-10-02 | 1948-10-02 | Scheuer- und Handreinigungsmittel |
| DE300950X | 1950-09-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2739129A true US2739129A (en) | 1956-03-20 |
Family
ID=25784261
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US235100A Expired - Lifetime US2739129A (en) | 1948-10-02 | 1951-07-03 | Cleaning composition |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2739129A (enrdf_load_stackoverflow) |
| BE (1) | BE503818A (enrdf_load_stackoverflow) |
| CH (1) | CH300950A (enrdf_load_stackoverflow) |
| DE (1) | DE860981C (enrdf_load_stackoverflow) |
| GB (1) | GB711356A (enrdf_load_stackoverflow) |
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2945815A (en) * | 1957-01-02 | 1960-07-19 | Colgate Palmolive Co | Abrasive detergent compositions |
| US3053897A (en) * | 1959-01-29 | 1962-09-11 | Purex Corp Ltd | Process for forming alkali alcoholates of trialkanolamines |
| US3079344A (en) * | 1957-09-27 | 1963-02-26 | Henkel & Cie Gmbh | Detergent composition including dust inhibiting agent |
| US3149078A (en) * | 1960-06-27 | 1964-09-15 | Colgate Palmolive Co | Liquid abrasive cleanser |
| US3210285A (en) * | 1960-06-27 | 1965-10-05 | Colgate Palmolive Co | Liquid abrasive cleanser containing sodium chloride |
| US3884824A (en) * | 1972-02-17 | 1975-05-20 | Ricoh Kk | Method and composition of mixed baso' 4 'and srso' 4 'for polishing a photoconductor surface |
| US4576730A (en) * | 1985-03-18 | 1986-03-18 | Touchstone Corporation | Method and composition for cleaning and protecting metal |
| US4615821A (en) * | 1984-09-25 | 1986-10-07 | The Procter & Gamble Company | Benzyl alcohol for improved powdered cleansers |
| US4687591A (en) * | 1986-08-22 | 1987-08-18 | Antonio Castaldo | Cleaning composition for cymbals |
| US4718942A (en) * | 1985-08-08 | 1988-01-12 | Witco Corporation | Thixotropic overbased alkaline earth metal inorganic-organic compositions containing alkoxylated oxidized petrolatums |
| US4755223A (en) * | 1986-08-22 | 1988-07-05 | Antonio Castaldo | Liquid composition for cleaning and polishing cymbals comprising kaolin clay |
| US5234505A (en) * | 1991-07-17 | 1993-08-10 | Church & Dwight Co., Inc. | Stabilization of silicate solutions |
| US5234506A (en) * | 1991-07-17 | 1993-08-10 | Church & Dwight Co., Inc. | Aqueous electronic circuit assembly cleaner and method |
| US5261967A (en) * | 1991-07-17 | 1993-11-16 | Church & Dwight Co, Inc. | Powdered electric circuit assembly cleaner |
| US5264047A (en) * | 1991-07-17 | 1993-11-23 | Church & Dwight Co., Inc. | Low foaming effective hydrotrope |
| US5264046A (en) * | 1991-07-17 | 1993-11-23 | Church & Dwight Co., Inc. | Aqueous electronic circuit assembly cleaner and cleaning method |
| US5312562A (en) * | 1991-07-17 | 1994-05-17 | Church & Dwight Co., Inc. | Aqueous electronic circuit assembly cleaner and method |
| US5423909A (en) * | 1994-05-10 | 1995-06-13 | Gullickson; Larry L. | Slip-resistant composition and method |
| US5431847A (en) * | 1991-07-17 | 1995-07-11 | Charles B. Barris | Aqueous cleaning concentrates |
| US5433885A (en) * | 1991-07-17 | 1995-07-18 | Church & Dwight Co., Inc. | Stabilization of silicate solutions |
| USRE35017E (en) * | 1991-07-17 | 1995-08-15 | Church & Dwight Co., Inc. | Method for removing soldering flux with alkaline salts, an alkali metal silicate and anionic polymer |
| USRE35045E (en) * | 1991-07-17 | 1995-10-03 | Church & Dwight Co., Inc. | Method for removing soldering flux with alkaline metal carbonate salts and an alkali metal silicate |
| USRE35115E (en) * | 1991-07-17 | 1995-12-12 | Church & Dwight Co. Inc. | Low foaming effective hydrotrope |
| US20050278881A1 (en) * | 2004-06-18 | 2005-12-22 | John-Son Huang | Bag for cleaning oil film on windshield of vehicle |
| CN113235093A (zh) * | 2021-05-20 | 2021-08-10 | 深圳市高新昌科技有限责任公司 | 用于镀锌及锌合金及铝及铝合金的出光粉及其制备方法 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1168589B (de) * | 1956-07-27 | 1964-04-23 | Dalli Werke Maeurer & Wirtz | Scheuermittel fuer Reinigungszwecke |
| BE638431A (enrdf_load_stackoverflow) * | 1962-10-10 | |||
| US4051056A (en) | 1974-09-09 | 1977-09-27 | The Procter & Gamble Company | Abrasive scouring compositions |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2020228A (en) * | 1933-11-13 | 1935-11-05 | Victor Chemical Works | Method of cleaning |
| US2191199A (en) * | 1937-09-17 | 1940-02-20 | Hall Lab Inc | Abrasive detergent composition |
| US2257545A (en) * | 1937-12-24 | 1941-09-30 | Monsanto Chemicals | Detergent composition |
| US2296690A (en) * | 1940-03-02 | 1942-09-22 | J B Ford Company | Abrasive scouring powder |
| US2489848A (en) * | 1947-10-10 | 1949-11-29 | Wyandotte Chemicals Corp | Abrasive scouring powder |
| US2555285A (en) * | 1951-05-29 | Detergent composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2035940A (en) * | 1934-07-17 | 1936-03-31 | John K Berresford | Detergent composition |
-
0
- BE BE503818D patent/BE503818A/xx unknown
-
1948
- 1948-10-02 DE DEP13333A patent/DE860981C/de not_active Expired
-
1951
- 1951-05-30 GB GB12650/51A patent/GB711356A/en not_active Expired
- 1951-06-27 CH CH300950D patent/CH300950A/de unknown
- 1951-07-03 US US235100A patent/US2739129A/en not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2555285A (en) * | 1951-05-29 | Detergent composition | ||
| US2020228A (en) * | 1933-11-13 | 1935-11-05 | Victor Chemical Works | Method of cleaning |
| US2191199A (en) * | 1937-09-17 | 1940-02-20 | Hall Lab Inc | Abrasive detergent composition |
| US2257545A (en) * | 1937-12-24 | 1941-09-30 | Monsanto Chemicals | Detergent composition |
| US2296690A (en) * | 1940-03-02 | 1942-09-22 | J B Ford Company | Abrasive scouring powder |
| US2489848A (en) * | 1947-10-10 | 1949-11-29 | Wyandotte Chemicals Corp | Abrasive scouring powder |
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2945815A (en) * | 1957-01-02 | 1960-07-19 | Colgate Palmolive Co | Abrasive detergent compositions |
| US3079344A (en) * | 1957-09-27 | 1963-02-26 | Henkel & Cie Gmbh | Detergent composition including dust inhibiting agent |
| US3053897A (en) * | 1959-01-29 | 1962-09-11 | Purex Corp Ltd | Process for forming alkali alcoholates of trialkanolamines |
| US3149078A (en) * | 1960-06-27 | 1964-09-15 | Colgate Palmolive Co | Liquid abrasive cleanser |
| US3210285A (en) * | 1960-06-27 | 1965-10-05 | Colgate Palmolive Co | Liquid abrasive cleanser containing sodium chloride |
| US3884824A (en) * | 1972-02-17 | 1975-05-20 | Ricoh Kk | Method and composition of mixed baso' 4 'and srso' 4 'for polishing a photoconductor surface |
| US4615821A (en) * | 1984-09-25 | 1986-10-07 | The Procter & Gamble Company | Benzyl alcohol for improved powdered cleansers |
| US4576730A (en) * | 1985-03-18 | 1986-03-18 | Touchstone Corporation | Method and composition for cleaning and protecting metal |
| US4718942A (en) * | 1985-08-08 | 1988-01-12 | Witco Corporation | Thixotropic overbased alkaline earth metal inorganic-organic compositions containing alkoxylated oxidized petrolatums |
| US4687591A (en) * | 1986-08-22 | 1987-08-18 | Antonio Castaldo | Cleaning composition for cymbals |
| US4755223A (en) * | 1986-08-22 | 1988-07-05 | Antonio Castaldo | Liquid composition for cleaning and polishing cymbals comprising kaolin clay |
| US5264047A (en) * | 1991-07-17 | 1993-11-23 | Church & Dwight Co., Inc. | Low foaming effective hydrotrope |
| US5431847A (en) * | 1991-07-17 | 1995-07-11 | Charles B. Barris | Aqueous cleaning concentrates |
| US5261967A (en) * | 1991-07-17 | 1993-11-16 | Church & Dwight Co, Inc. | Powdered electric circuit assembly cleaner |
| US5234505A (en) * | 1991-07-17 | 1993-08-10 | Church & Dwight Co., Inc. | Stabilization of silicate solutions |
| US5264046A (en) * | 1991-07-17 | 1993-11-23 | Church & Dwight Co., Inc. | Aqueous electronic circuit assembly cleaner and cleaning method |
| US5312562A (en) * | 1991-07-17 | 1994-05-17 | Church & Dwight Co., Inc. | Aqueous electronic circuit assembly cleaner and method |
| US5393448A (en) * | 1991-07-17 | 1995-02-28 | Church & Dwight Co., Inc. | Aqueous electronic circuit assembly cleaner and method |
| US5397495A (en) * | 1991-07-17 | 1995-03-14 | Church & Dwight Co. Inc. | Stabilization of silicate solutions |
| US5549761A (en) * | 1991-07-17 | 1996-08-27 | Church & Dwight Co., Inc. | Method for removing rosin soldering flux from a printed wiring board |
| US5234506A (en) * | 1991-07-17 | 1993-08-10 | Church & Dwight Co., Inc. | Aqueous electronic circuit assembly cleaner and method |
| US5433885A (en) * | 1991-07-17 | 1995-07-18 | Church & Dwight Co., Inc. | Stabilization of silicate solutions |
| USRE35017E (en) * | 1991-07-17 | 1995-08-15 | Church & Dwight Co., Inc. | Method for removing soldering flux with alkaline salts, an alkali metal silicate and anionic polymer |
| USRE35045E (en) * | 1991-07-17 | 1995-10-03 | Church & Dwight Co., Inc. | Method for removing soldering flux with alkaline metal carbonate salts and an alkali metal silicate |
| USRE35115E (en) * | 1991-07-17 | 1995-12-12 | Church & Dwight Co. Inc. | Low foaming effective hydrotrope |
| US5423909A (en) * | 1994-05-10 | 1995-06-13 | Gullickson; Larry L. | Slip-resistant composition and method |
| US20050278881A1 (en) * | 2004-06-18 | 2005-12-22 | John-Son Huang | Bag for cleaning oil film on windshield of vehicle |
| CN113235093A (zh) * | 2021-05-20 | 2021-08-10 | 深圳市高新昌科技有限责任公司 | 用于镀锌及锌合金及铝及铝合金的出光粉及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE860981C (de) | 1955-11-03 |
| BE503818A (enrdf_load_stackoverflow) | |
| CH300950A (de) | 1954-08-31 |
| GB711356A (en) | 1954-06-30 |
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