US2643959A - Process for the protective treatment of iron - Google Patents
Process for the protective treatment of iron Download PDFInfo
- Publication number
- US2643959A US2643959A US165109A US16510950A US2643959A US 2643959 A US2643959 A US 2643959A US 165109 A US165109 A US 165109A US 16510950 A US16510950 A US 16510950A US 2643959 A US2643959 A US 2643959A
- Authority
- US
- United States
- Prior art keywords
- iron
- aluminum
- mixture
- hydrogen
- anhydrous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/06—Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases
- C23C10/08—Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases only one element being diffused
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/06—Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases
- C23C10/14—Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases more than one element being diffused in one step
Definitions
- This invention relates to a process for the protective treatment of iron and has particular relation to a process of this type in which metallic aluminum is applied to and alloys with the iron surface to be protected.
- the main object of the present invention is to provide an improved process for the protective treatment of iron by the application of aluminum chloride in the vapor phase to the surface to be protected in order to obtain a more efiicient and durable protection of the iron, than obtainable by the hitherto known processes using aluminum.
- Another object of my invention is to provide an anhydrous gaseous mixture, in which vaporized aluminum chloride is present in intimate mixture with hydrogen and which is particularly adapted to react quickly with the iron and to produce an improved corrosion-resistant surface layer.
- a further object of my invention consists in providing a process for the protective treatment of iron with a mixture of aluminum and copper.
- the iron surface to be protected is treated with a gaseous mixture which contains vaporized AlCls and hydrogen and has been obtained by reactingmetallic aluminum with completely dry H01 gas in the manner described further below.
- the AlCls is used in dry condition and is applied to the iron in the absence of water or moisture in an atmosphere of hydrogen. Both conditions must be observed, as the absence of water, steam or moisture as well as the presence of a hydrogen atmosphere are essential.
- dry gaseous HCl gas is caused to pass at a temperature between 300 and 600 C. over a mixture of aluminum, which may be present for example in the form of shavings or grit, with aluminum oxide (A1203) and small coal.
- the aluminum oxide may be used in an amount of 10% by weight and the coal likewise in an amount of 10% by weight based on the amount of aluminum.
- the aluminum is subjected to the action of HCl as in mixture with aluminum oxide and coal in order to prevent sticking together of the metal particles.
- the coal prevents oxidation and combines with water vapor if the latter is present.
- the aluminum chloride is split into Al and C1, the aluminum forming an alloy with the surface layer of the iron, while the Cl is converted into iron chloride.
- the thickness of the alloy layer formed depends upon the temperature and duration of the treatment of the iron with the gaseous stream of aluminum chloride and hydrogen.
- the protective efiect of my process can be increased by using the aluminum in combination with copper.
- This can be done for example by using a mixture of aluminum shavings and copper shavings or by using an alloy of aluminum and copper in the reaction with dry gaseous HCl.
- a gaseous mixture containing hydrogen, aluminum chloride and copper chloride is formed and in the treatment of the heated iron with such mixture in the above described manner, in addition to aluminum, copper is also deposited in the iron and increases the resistance of the iron to corrosion.
- the duration and temperature of the treatment according to my invention depends on the requirements of resistance of the iron to corro sion. I have found that treatments with the gaseous AlCh-containing mixture at 900 to 1000 C. during to 60 minutes give satisfactory results. In order to decrease the brittleness of protective layers in iron treated according to the process of my invention, the latter may be subjected to a thermal after-treatment at about 1000 C. in an atmosphere of hydrogen or air. Such treatment causes the aluminum to diiluse deeper into the iron so that concentration of aluminum in the top layer of iron decreases and said layer becomes softer.
- I have found that a, completely dry stream of I-ICl gas can be obtained with advantage by reacting silicon tetrachloride with an alkanol, for example ethyl alcohol, methyl alcohol, propyl alcohol, butyl alcohol, whereby a completely dry stream of H01 gas and a compound for example of the formula Si(OC2H5) 4 is obtained which can be used in a manner known by itself for the preparation of silicone resins.
- an alkanol for example ethyl alcohol, methyl alcohol, propyl alcohol, butyl alcohol
- HCl gas prepared in any other suitable manner may also be used in carrying out my invention, provided that it is in a substantially anhydrous condition.
- the iron is treated with a gaseous mixture obtained by the reaction of metallic aluminum and dry HCl gas.
- a process for the protective treatment of iron comprising causing iron to react at 700 to 1000 C. with an anhydrous gaseous medium consisting of hydrogen and aluminum chloride and obtained by the reaction, at 300 to 600 C'., of anhydrous HCl gas and a mixture of aluminum, aluminum oxide, and coal, until a coating of aluminum is deposited on the surface of the iron treated.
- a process for the protective treatment of iron comprising causing the iron to react at 700 to 1000 C. with an anhydrous gaseous medium consisting of hydrogen and aluminum chloride and obtained by the reaction, at 300 to 600 C., of anhydrous H01 gas and a mixture of metallic aluminum and copper, aluminum oxide, and coal until a coating is deposited on the surface of the iron treated.
- a process for the protective treatment of iron comprising causing iron to react at 700 to 1000 C. with an anhydrous gaseous medium consisting of the reaction product, formed at 300 to 600 C, of anhydrous I-ICl gas and aluminum and copper, in mixture with aluminum oxide and coal, until a coating is deposited on the surface of the iron treated.
- a process for the protective treatment of iron in which the product obtained according to claim 1, is subsequently subjected to heating at about 1000 C.
Description
- Patented June 30, 1953 UNITED STATES NT OFFICE PROCESS FOR THE PROTECTIVE TREATMENT OF IRON York No Drawing. Application May 29, 1950, Serial No. 165,109
Claims. 1
This invention relates to a process for the protective treatment of iron and has particular relation to a process of this type in which metallic aluminum is applied to and alloys with the iron surface to be protected.
The main object of the present invention is to provide an improved process for the protective treatment of iron by the application of aluminum chloride in the vapor phase to the surface to be protected in order to obtain a more efiicient and durable protection of the iron, than obtainable by the hitherto known processes using aluminum.
Another object of my invention is to provide an anhydrous gaseous mixture, in which vaporized aluminum chloride is present in intimate mixture with hydrogen and which is particularly adapted to react quickly with the iron and to produce an improved corrosion-resistant surface layer.
A further object of my invention consists in providing a process for the protective treatment of iron with a mixture of aluminum and copper.
It is also an object of my invention to produce from silicon tetrachloride and suitable organic compounds completely dry gaseous HCl which can be used with advantage in the production of a metal chloride-hydrogen mixture needed in carrying out my invention.
Other objects and the advantages of the invention will be apparent from the appended claims and the following specification, which illustrate by way of example some embodiments of my invention.
It has been previously suggested to apply certain compounds of aluminum, particularly A115, to the surface of iron in order to obtain a corrosion resistant surface coating comprising aluminum and iron. However, it was not hitherto possible to isolate a compound of the formula All and it is doubtful whether such a compound can be prepared at all.
It has also been suggested to place iron articles to be treated in a drum or the like with a mixture of powdered aluminum, aluminum oxide and ammonium chloride, to rotate the drum and heat it in a hydrogen atmosphere in order to provide the articles with a corrosion resistant surface. It has been found that this process does not give satisfactory results.
I have now found that the application of metallic aluminum to iron can be carried out in a satisfactory manner and yields products having a surface of high resistance to corrosion particularly at elevated temperatures by proceeding in the manner described hereinafter.
According to my present invention, the iron surface to be protected is treated with a gaseous mixture which contains vaporized AlCls and hydrogen and has been obtained by reactingmetallic aluminum with completely dry H01 gas in the manner described further below. In carrying out this procedure, the AlCls is used in dry condition and is applied to the iron in the absence of water or moisture in an atmosphere of hydrogen. Both conditions must be observed, as the absence of water, steam or moisture as well as the presence of a hydrogen atmosphere are essential.
In carrying out the process of my invention, dry gaseous HCl gas is caused to pass at a temperature between 300 and 600 C. over a mixture of aluminum, which may be present for example in the form of shavings or grit, with aluminum oxide (A1203) and small coal. The aluminum oxide may be used in an amount of 10% by weight and the coal likewise in an amount of 10% by weight based on the amount of aluminum. The aluminum is subjected to the action of HCl as in mixture with aluminum oxide and coal in order to prevent sticking together of the metal particles. Moreover, the coal prevents oxidation and combines with water vapor if the latter is present. No water is formed by a reaction between A1203 and HCl in the above mentioned temperature range of 300 to 600 C., as such reaction does not set in below 800 C. The HCl gas reacts with the metallic aluminum according to the equation and this reaction provides for the presence of the necessary hydrogen in my process. As the aluminum is present in great excess in the reaction, it is possible that sub-chlorides of the formula AlCl and/or AlClz are also formed to some extent I have found that the anhydrous gaseous mixture obtained in the above described manner and consisting of an anhydrous intimate mixture of vaporized aluminum chloride and hydrogen, can be used with excellent results in the production of a protective layer on iron. In order to obtain such layer, said gaseous mixture is passed over iron heated to at least 700 C. and preferably 900-l000 C. or higher, up to 1200 C. Upon bringing the gaseous mixture in contact with the heated iron, the aluminum chloride is split into Al and C1, the aluminum forming an alloy with the surface layer of the iron, while the Cl is converted into iron chloride. The thickness of the alloy layer formed depends upon the temperature and duration of the treatment of the iron with the gaseous stream of aluminum chloride and hydrogen.
I have also found that the protective efiect of my process can be increased by using the aluminum in combination with copper. This can be done for example by using a mixture of aluminum shavings and copper shavings or by using an alloy of aluminum and copper in the reaction with dry gaseous HCl. In this case a gaseous mixture containing hydrogen, aluminum chloride and copper chloride is formed and in the treatment of the heated iron with such mixture in the above described manner, in addition to aluminum, copper is also deposited in the iron and increases the resistance of the iron to corrosion. I use for example a gaseous mixture containing 2% by weight of copper based on the weight of Al in the gaseous mixture, and found that admixtures of copper to Al varying between 1 and 5% give good results.
The duration and temperature of the treatment according to my invention depends on the requirements of resistance of the iron to corro sion. I have found that treatments with the gaseous AlCh-containing mixture at 900 to 1000 C. during to 60 minutes give satisfactory results. In order to decrease the brittleness of protective layers in iron treated according to the process of my invention, the latter may be subjected to a thermal after-treatment at about 1000 C. in an atmosphere of hydrogen or air. Such treatment causes the aluminum to diiluse deeper into the iron so that concentration of aluminum in the top layer of iron decreases and said layer becomes softer.
I have found that a, completely dry stream of I-ICl gas can be obtained with advantage by reacting silicon tetrachloride with an alkanol, for example ethyl alcohol, methyl alcohol, propyl alcohol, butyl alcohol, whereby a completely dry stream of H01 gas and a compound for example of the formula Si(OC2H5) 4 is obtained which can be used in a manner known by itself for the preparation of silicone resins. It will be understood, however, that HCl gas prepared in any other suitable manner may also be used in carrying out my invention, provided that it is in a substantially anhydrous condition.
It is essential in carrying out my invention that the iron is treated with a gaseous mixture obtained by the reaction of metallic aluminum and dry HCl gas.
It will be understood by those skilled in the art that my invention is not limited to the specific steps, conditions and materials described above and may be carried out with various modifications. For example, instead of reacting the aluminum with H01 in the form of shavings or grit, it can be used in the form of powder or other suitable form. and in combination with admixtures other than aluminum oxide and/or coal. The temperature and duration of the treatment of iron with the mixture of vaporized AlCls and hydrogen may be varied and the amount of copper used in combination with aluminum may be varied within the limits stated above. These and other modifications may be made without departing from the scope of the inventionas defined in the appended claims.
What is claimed is:
1. A process for the protective treatment of iron, comprising causing iron to react at 700 to 1000 C. with an anhydrous gaseous medium consisting of hydrogen and aluminum chloride and obtained by the reaction, at 300 to 600 C'., of anhydrous HCl gas and a mixture of aluminum, aluminum oxide, and coal, until a coating of aluminum is deposited on the surface of the iron treated. I
2. A process for the protective treatment of iron, comprising causing the iron to react at 700 to 1000 C. with an anhydrous gaseous medium consisting of hydrogen and aluminum chloride and obtained by the reaction, at 300 to 600 C., of anhydrous H01 gas and a mixture of metallic aluminum and copper, aluminum oxide, and coal until a coating is deposited on the surface of the iron treated.
3. A process for the protective treatment of iron, comprising causing iron to react at 700 to 1000 C. with an anhydrous gaseous medium consisting of the reaction product, formed at 300 to 600 C, of anhydrous I-ICl gas and aluminum and copper, in mixture with aluminum oxide and coal, until a coating is deposited on the surface of the iron treated.
4. A process for the protective treatment of iron, in which the product obtained according to claim 1, is subsequently subjected to heating at about 1000 C.
5. A process for the protective treatment of iron, as claimed in claim 1, in which anhydrous 1161 gas obtained by reacting SiCh with an alcohol, is used.
JOHANNE S FISCHER.
References Cited in the file of this patent UNITED STATES PATENTS OTHER REFERENCES Mellors Modern Inorganic Chemistry, pages 398 and 399.
Claims (1)
1. A PROCESS FOR THE PROTECTIVE TREATMENT OF IRON, COMPRISING CAUSING IRON TO REACT AT 700* TO 1000* C. WITH AN ANHYDROUS GASEOUS MEDIUM CONSISTING OF HYDROGEN AND ALUMINUM CHLORIDE AND OBTAINED BY THE REACTION, AT 300* TO 600* C., OF ANHYDROUS HCI GAS AND A MIXTURE OF ALUMINUM, ALUMINUM OXIDE, AND COAL, UNTIL A COATING OF ALUMINUM IS DEPOSITED ON THE SURFACE OF THE IRON TREATED.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US165109A US2643959A (en) | 1950-05-29 | 1950-05-29 | Process for the protective treatment of iron |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US165109A US2643959A (en) | 1950-05-29 | 1950-05-29 | Process for the protective treatment of iron |
Publications (1)
Publication Number | Publication Date |
---|---|
US2643959A true US2643959A (en) | 1953-06-30 |
Family
ID=22597458
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US165109A Expired - Lifetime US2643959A (en) | 1950-05-29 | 1950-05-29 | Process for the protective treatment of iron |
Country Status (1)
Country | Link |
---|---|
US (1) | US2643959A (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2772985A (en) * | 1951-08-08 | 1956-12-04 | Thompson Prod Inc | Coating of molybdenum with binary coatings containing aluminum |
US2843506A (en) * | 1955-07-13 | 1958-07-15 | Ohio Commw Eng Co | Process of gas plating an article with light metal |
DE1038372B (en) * | 1954-05-31 | 1958-09-04 | Siemens Planiawerke Ag | Process for the production of aluminum layers or aluminum alloys |
US2867546A (en) * | 1956-02-08 | 1959-01-06 | Ohio Commw Eng Co | Gas plating of aluminum using aluminum trilsobutyl |
US2875090A (en) * | 1953-12-22 | 1959-02-24 | Onera (Off Nat Aerospatiale) | Methods of forming superficial diffusion alloys on metal pieces and especially refractory metal pieces |
US2876137A (en) * | 1955-04-12 | 1959-03-03 | Ohio Commw Eng Co | Method of plating metal with magnesium |
US2880115A (en) * | 1955-07-13 | 1959-03-31 | Ohio Commw Eng Co | Method of gas plating light metals |
US2886469A (en) * | 1954-05-31 | 1959-05-12 | Siemens Planiawerke Ag | Method of coating metallic bodies with aluminum utilizing vaporous sub-chlorides |
DE1078843B (en) * | 1954-04-09 | 1960-03-31 | Belge Produits Chimiques Sa | Process for gas metallizing metallic workpieces |
US3375129A (en) * | 1966-09-22 | 1968-03-26 | Ethyl Corp | Aluminum plating employing amine complex of aluminum hydride |
US3753768A (en) * | 1969-11-01 | 1973-08-21 | Sumitomo Chemical Co | Aliminum plating process |
EP0572150A2 (en) * | 1992-05-26 | 1993-12-01 | General Electric Company | Chemical vapour-deposition of aluminide coatings |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US351181A (en) * | 1886-10-19 | Harvesting-mac mine | ||
US1091057A (en) * | 1913-03-12 | 1914-03-24 | Gen Electric | Process of treating metals. |
US1497417A (en) * | 1919-03-31 | 1924-06-10 | Henry C P Weber | Process of coating metals |
US1711603A (en) * | 1926-06-15 | 1929-05-07 | Lay Emil | Process for production of diffused layers on metals |
US1729065A (en) * | 1927-03-19 | 1929-09-24 | Cole William Howard | Material for use in protecting iron and steel |
US2470306A (en) * | 1946-03-27 | 1949-05-17 | Int Alloys Ltd | Process for the production and refining of metals |
-
1950
- 1950-05-29 US US165109A patent/US2643959A/en not_active Expired - Lifetime
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US351181A (en) * | 1886-10-19 | Harvesting-mac mine | ||
US1091057A (en) * | 1913-03-12 | 1914-03-24 | Gen Electric | Process of treating metals. |
US1497417A (en) * | 1919-03-31 | 1924-06-10 | Henry C P Weber | Process of coating metals |
US1711603A (en) * | 1926-06-15 | 1929-05-07 | Lay Emil | Process for production of diffused layers on metals |
US1729065A (en) * | 1927-03-19 | 1929-09-24 | Cole William Howard | Material for use in protecting iron and steel |
US2470306A (en) * | 1946-03-27 | 1949-05-17 | Int Alloys Ltd | Process for the production and refining of metals |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2772985A (en) * | 1951-08-08 | 1956-12-04 | Thompson Prod Inc | Coating of molybdenum with binary coatings containing aluminum |
US2875090A (en) * | 1953-12-22 | 1959-02-24 | Onera (Off Nat Aerospatiale) | Methods of forming superficial diffusion alloys on metal pieces and especially refractory metal pieces |
DE1078843B (en) * | 1954-04-09 | 1960-03-31 | Belge Produits Chimiques Sa | Process for gas metallizing metallic workpieces |
DE1038372B (en) * | 1954-05-31 | 1958-09-04 | Siemens Planiawerke Ag | Process for the production of aluminum layers or aluminum alloys |
US2886469A (en) * | 1954-05-31 | 1959-05-12 | Siemens Planiawerke Ag | Method of coating metallic bodies with aluminum utilizing vaporous sub-chlorides |
US2876137A (en) * | 1955-04-12 | 1959-03-03 | Ohio Commw Eng Co | Method of plating metal with magnesium |
US2843506A (en) * | 1955-07-13 | 1958-07-15 | Ohio Commw Eng Co | Process of gas plating an article with light metal |
US2880115A (en) * | 1955-07-13 | 1959-03-31 | Ohio Commw Eng Co | Method of gas plating light metals |
US2867546A (en) * | 1956-02-08 | 1959-01-06 | Ohio Commw Eng Co | Gas plating of aluminum using aluminum trilsobutyl |
US3375129A (en) * | 1966-09-22 | 1968-03-26 | Ethyl Corp | Aluminum plating employing amine complex of aluminum hydride |
US3753768A (en) * | 1969-11-01 | 1973-08-21 | Sumitomo Chemical Co | Aliminum plating process |
EP0572150A2 (en) * | 1992-05-26 | 1993-12-01 | General Electric Company | Chemical vapour-deposition of aluminide coatings |
EP0572150A3 (en) * | 1992-05-26 | 1993-12-29 | General Electric Company | Chemical vapour-deposition of aluminide coatings |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2643959A (en) | Process for the protective treatment of iron | |
US2351798A (en) | Coating metal articles | |
CN86108935A (en) | The method that on metallic article, prepares silican diffusion coatings | |
US2627451A (en) | Disproportionation of silane derivatives | |
KR920021624A (en) | Manufacturing method of coating composition based on silicone resin and use of coating composition | |
US1718563A (en) | Treatment of metals | |
CN105543776B (en) | A kind of last penetration enhancer of aluminium zinc silicon rare earth composite powder and its technique for applying | |
Takahashi et al. | Low temperature deposition of a refractory aluminium compound by the thermal decomposition of aluminium dialkylamides | |
US3383235A (en) | Silicide-coated composites and method of making them | |
RU2006102204A (en) | METHOD OF PROTECTION AGAINST OXIDATION OF PRODUCTS FROM COMPOSITE MATERIAL CONTAINING CARBON, AND PRODUCT PROTECTED WITH THIS METHOD | |
ES8203106A1 (en) | Method of producing an aluminum-zinc alloy coated ferrous product to improve corrosion resistance. | |
US2529206A (en) | Process for increasing the corrosion resistance of ferrous articles | |
US3015579A (en) | Metal coating process | |
US4178193A (en) | Method of improving corrosion resistance with coating by friction | |
US2899332A (en) | Chromizing method and composition | |
US1850997A (en) | Production of resistant silver surfaces | |
Shulpekov et al. | Self-Propagating High-Temperature Synthesis of Titanium Carbosilicide and Electrically Conductive Composite Coatings on its Basis. | |
US2860118A (en) | Corrosion preventing coating compositions for metals comprising a chlorine containingorganic polymer as film former, a copper compound and a tertiary organic heterocyclic base | |
SU392169A1 (en) | METHOD OF OBTAINING HEAT-RESISTANT COATINGS ON HEAT-RESISTANT ALLOYS | |
SU90351A1 (en) | The way to protect chemical equipment from corrosion | |
SU765396A1 (en) | Composition for boroaluminizing | |
SE7610298L (en) | WITH A PROTECTIVE METAL LAYER COATED ITEMS OF CORRODERABLE METAL AND PROCEDURE FOR THE MANUFACTURE OF THE SAME | |
US1982718A (en) | Anticarburizing compound | |
SU1472458A1 (en) | Method of rendering hydrophobic a silica-base heat-insulating material | |
SU737498A1 (en) | Composition for tungstensilicylation of steel articles |