US2575895A - Method of making fibrous products - Google Patents

Method of making fibrous products Download PDF

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Publication number
US2575895A
US2575895A US117247A US11724749A US2575895A US 2575895 A US2575895 A US 2575895A US 117247 A US117247 A US 117247A US 11724749 A US11724749 A US 11724749A US 2575895 A US2575895 A US 2575895A
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US
United States
Prior art keywords
glue
dispersion
parts
weight
fibrous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US117247A
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English (en)
Inventor
Gerrit Johannes Sluiter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NL FABRIEK VAN CELLA PRODUCTEN
Original Assignee
NL FABRIEK VAN CELLA PRODUCTEN
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Publication of US2575895A publication Critical patent/US2575895A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/02—Cellulose; Modified cellulose
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C08L7/02—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08—Cellulose derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L89/00—Compositions of proteins; Compositions of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse

Definitions

  • cellulose derivati-ve agglutinants such as tylose (methyl cellulose), gums and resins (such as gum tragacanth) included, aswell as ofanimal origin such as the meat-, fishand bone-glues substantially consisting of fibrous mater-ial, glue and the caseinand albumin-glues, and also of and rubber'latex. synthetic origin.
  • FIGs. 1 to 8 are fragmentary perspective views before the whole is worked'up-with aids and apof coverings made in accordance with the pliances into a uniform fibrous pap from which invention. the artificial products are to be manufactured. Without restricting theinvention to the recipe It is found that by application of this process following hereafter, an example for the preparaa 'much' better uniformdistribution-of the fibres tion of a uniform suspension of fibres in aqueous through the pap; from which the artificial prodglue is now given.
  • Emmple 1 Preferably the fibrous suspension is left to itself for a period of the order of several hours, 525 parts by weight of glue, for example the "for'example duringa day,' before the fibres are Swedish naturalstarch product known under "beaten through the glue dispersion. the registered trade-mark fAlkasit, stirred In the process according to the invention 1:10 with water.
  • the mass is thoroughly mixed chemically free cellulose in a more or less pure and then preferably left forswelling durin some condition in the form of pulpor 'wadding. of time, for example la-1 hour.
  • the thus obtained -wood, straw, or 'thelike canadvantageously. be 40 thick uniform paste is'diluted with water, 1:1.
  • the glue was added irrespectively of whether example during a day. Thereupon the fibres fibrous fillers were used or not, and naturally are thoroughly beaten u h the lu disperthe applied percentage of glue was not specifically sion until a uniformpap is obtained.
  • fibrous suspensioncan-adterial adapted to the applied amount of-fibrous ma-
  • the thus obtained fibrous suspensioncan-adterial vantageously be applied for mixing with rubber
  • the latex can be of vegetable origin; such as'vegetable dry fibres such as cellulose with latexwithout 'protein glue,starch products fromigluten ('zeine), coagulation unless the latex isstabilized very starch derivative agglutinants (dextrin; swelled lthoroughly fibrous suspensions obtained accordfibres, glue, aids and appliances.
  • cream latex that is latex which is concentrated to about 60 percent by weight of solids
  • revertex which is concentrated to amply '70 percent by weight of solids
  • Latices containing more water, such as latex with about 38-40 percent by weight of solids will give a pap that is too thin for some objects if the ratio of solids in the pap is wanted to bemaintained.
  • Natural rubber latex as well as synthetic latices can be used.
  • the latices may contain self .vulcanizing agents and accelerators.
  • Example 1 125 parts by weight of cream latex containing stabilizer, anti-oxidant and preservator is added under stirring to the pap obtained accordingly to the preceding Example 1.
  • a pap which, according to the composition, can be worked up by brushing up, bulking, casting, spraying and the A plurality of coverings made in accordance;
  • Fig. 1 shows a covering consisting of a layer I made from the final pap only and thus substantially consisting of rubber
  • Fig. 3 shows a covering consisting of two layers I with an intermediate supporting layer 3.
  • Fig. 4 illustrates the removal of the underlayer 2 from the layer I of the covering shown in Fig. 2.
  • Figs. 5 to 8 correspond to Figs. 1 to 4 respectively and show the coverings thereof provided with a relief 4.
  • Fillers may be added to increase the hardness of the products manufactured with the pap.
  • Very suitable for this purpose is, for example chalk, of which according to the desired increase of the hardness, more or less is added (for example 125-300 parts by weight), mixed with water in a ratio that is dependent i. e. on the filler quality.
  • the ratio lies mostly at about 1:1. The most uniformdistribution is obtained by adding these fillers to the glue dispersion, i. e. prior to the addition of the fibre mass.
  • Still harder products can be obtained by incorporation of gyps (plaster), cement or similar fast-hardening materials, for example 100 parts by weight in 50 parts of water.
  • gyps plaster
  • Fig. 2 shows 'weight in 60-70 parts of water.
  • water glass is generally added, for example 30 parts by This may be done during the beating of the fibres through the glue dispersion, or the water glass may be added later on, even simultaneously with the addition of the latex.
  • Pigments maybe added to any of the components of the pap," or to the semi-manufactured or final product.
  • Preferably latex dye is used for this purpose as only a small quantity thereof is necessary thanks to its strong colouring power.
  • the products obtained from the pap are poorly inflammable, it can be useful in special cases, such as for wall coverings in ships, theatres and the like to decrease the inflammability by addition of powdered asbestos, alum and the like, preferably to the fibrous material prior to the addition of the latter to the glue dispersion.
  • the pap can be made as a sprayable pap.
  • the water ratio is higher thanfor the spreadable pap.
  • a satisfactorily sprayable product can be obtained for example by addition of a suitable amount of Water to the spreadable pap or by addition of this extra water during one or more stepsof the preparation of the pap.
  • Another suitable sprayable pap can be obtained according to the following example.
  • Example 1 To parts by weight of a solution of caseinate glue and borax in water in a ratio by weight of 101%:80 a preservator is admixed. Half of this bath is added to 167 parts by weight of cream latex together with vulcanisation dispersion. The remaining half is added to the pap obtained according to Example 1, during the preparation of which 200 parts by weight of chalk in 400 parts of water and 30 parts by weight of water glass in 70 parts of water are added. Thereupon the latex liquid and the pap are mixed under stirring.
  • a frother such as a special soap.
  • the spraying can be carried out i. c. with the aid of a special motar gun with compressor.
  • a process for preparing a fibrous composition containing cellulose fibres, glue and a rubber in aqueous dispersed form which comprises adding 70-80 parts, by weightof loosely cohering fibrous cellulose flock to a uniform aqueous dispersion of 5-25 parts by weight of glue, intimately mixing said fibrous cellulose flock with said glue dispersion, allowing said mixture of cellulose flock and glue dispersion to stand for a period of several hours, thereafter beating the fiber glue dispersion to efiect uniform suspension of loose fibers in the glue dispersion, and mixing said suspension with 75-100 parts by weight of rubber solids in latex form, whereby to form a uniform composition adapted to be shaped and dried to form flexible articles.
  • a flexible product obtained by removing water from a uniform fibrous composition comprising, in intimate admixture, 75-100 parts of a rubber in the form of a latex and an aqueous glue dispersion containing 5-25 parts by weight of glue, and 70-80 parts by weight of loose cellulose fibers suspended therein, said loose cellulose fibers being derived from cellulose flock.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US117247A 1948-09-30 1949-09-22 Method of making fibrous products Expired - Lifetime US2575895A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL142579A NL74868C (id) 1948-09-30 1948-09-30

Publications (1)

Publication Number Publication Date
US2575895A true US2575895A (en) 1951-11-20

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US117247A Expired - Lifetime US2575895A (en) 1948-09-30 1949-09-22 Method of making fibrous products

Country Status (5)

Country Link
US (1) US2575895A (id)
DE (1) DE833703C (id)
FR (1) FR996347A (id)
GB (1) GB676791A (id)
NL (1) NL74868C (id)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2808478A1 (en) * 2013-05-31 2014-12-03 Lee Cheong Construction & Building Materials Limited Degradable environmentally friendly fireproof wooden door plank and environmentally friendly fireproof wooden door
CN114622445A (zh) * 2022-03-29 2022-06-14 江苏博汇纸业有限公司 一种高松厚度白卡纸的制备工艺

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE421541B (sv) * 1978-05-25 1982-01-04 Stein Gasland Forfarande vid framstellning av formade produkter

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1765015A (en) * 1923-08-18 1930-06-17 American Rubber Company Process for treating rubber latex, composition and article formed thereby
US1883106A (en) * 1928-07-25 1932-10-18 North American Chemical Compan Shoe bottom filler
US2127298A (en) * 1936-08-17 1938-08-16 Mone R Isaacs Composition of matter
USRE21575E (en) * 1940-09-17 Container closure and limino
US2215553A (en) * 1939-04-07 1940-09-24 Us Rubber Co Method of making fiber-rubber products
US2278943A (en) * 1938-05-30 1942-04-07 Oesterreich Carl Ernst Willy Process for the production of rubberlike binding agent for fiber substances
US2333265A (en) * 1940-09-13 1943-11-02 Mcintosh Alan Henry Rubber product and method of producing same
US2474801A (en) * 1945-09-15 1949-06-28 Latex Fiber Ind Inc Fibrous sheets formed from an aqueous suspension of a mixture of fibers and butadiene-styrene copolymer

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE21575E (en) * 1940-09-17 Container closure and limino
US1765015A (en) * 1923-08-18 1930-06-17 American Rubber Company Process for treating rubber latex, composition and article formed thereby
US1883106A (en) * 1928-07-25 1932-10-18 North American Chemical Compan Shoe bottom filler
US2127298A (en) * 1936-08-17 1938-08-16 Mone R Isaacs Composition of matter
US2278943A (en) * 1938-05-30 1942-04-07 Oesterreich Carl Ernst Willy Process for the production of rubberlike binding agent for fiber substances
US2215553A (en) * 1939-04-07 1940-09-24 Us Rubber Co Method of making fiber-rubber products
US2333265A (en) * 1940-09-13 1943-11-02 Mcintosh Alan Henry Rubber product and method of producing same
US2474801A (en) * 1945-09-15 1949-06-28 Latex Fiber Ind Inc Fibrous sheets formed from an aqueous suspension of a mixture of fibers and butadiene-styrene copolymer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2808478A1 (en) * 2013-05-31 2014-12-03 Lee Cheong Construction & Building Materials Limited Degradable environmentally friendly fireproof wooden door plank and environmentally friendly fireproof wooden door
CN114622445A (zh) * 2022-03-29 2022-06-14 江苏博汇纸业有限公司 一种高松厚度白卡纸的制备工艺

Also Published As

Publication number Publication date
DE833703C (de) 1952-03-10
NL74868C (id) 1954-01-15
FR996347A (fr) 1951-12-18
GB676791A (en) 1952-08-06

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