US2487569A - Antistain baths for color photographic materials - Google Patents

Antistain baths for color photographic materials Download PDF

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Publication number
US2487569A
US2487569A US40010A US4001048A US2487569A US 2487569 A US2487569 A US 2487569A US 40010 A US40010 A US 40010A US 4001048 A US4001048 A US 4001048A US 2487569 A US2487569 A US 2487569A
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US
United States
Prior art keywords
color
film
water
baths
silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US40010A
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English (en)
Inventor
Mackey E Scudder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAF Chemicals Corp
Original Assignee
General Aniline and Film Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE490235D priority Critical patent/BE490235A/xx
Application filed by General Aniline and Film Corp filed Critical General Aniline and Film Corp
Priority to US40010A priority patent/US2487569A/en
Priority to GB14278/49A priority patent/GB659362A/en
Priority to FR990966D priority patent/FR990966A/fr
Priority to DEP49482A priority patent/DE857738C/de
Priority to CH291226D priority patent/CH291226A/fr
Application granted granted Critical
Publication of US2487569A publication Critical patent/US2487569A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/3046—Processing baths not provided for elsewhere, e.g. final or intermediate washings

Definitions

  • This inv n io relates to ph to a ic e sta n ba hs, to .antiestain 'ba hs mp oyed in mu ti lay r color p to raphy, a d esp c l y final rinse baths for the washing of multi-layer colo p oto aph c material .o in th fixin trea me t-s a to pr ent t iorma ion 0i stai I s vknown tha in he rocessing o mul color reversible an mum-colo re ersible White op qu the ex osed mm r exnosedr h te opaque, is first developed with a normal black and white developer to produce a negative image.
  • the black and white negative material After development, the black and white negative material, without being fixed, is exposed to general illumination, followed by a second development with a color forming developer. Duringthe first and second development, the silver-halides in all the layers are reduced to metallic silver. After the s c nd develo n he m i is cleared in running'water, hardened in an aqueous solution consisting of either alum or potassium c om a um andt n as in unning water- Aiter the latter treatment, the silver present all the layers formed during the first and second d elo men is co v ted i a sa by and 9f the known silver-salt formers, as bleaching baths, and the silver-salt $11311 iormedis then removed by dissolvingitin a silver-.- salt solvent such as, for example, hypo. The material is then washed for .a long period of timeand then dried.
  • a silver-.- salt solvent such as,
  • a iii-1 K 53? obj ct at th in ent n is finalrinee bath which clears undesirable matter from a multi-color photographic material in a short time while avoiding staining.
  • alkyl i. e., methyl, ethyl, propyl, isopropyl, butyl, etc.
  • alkylene i. e., l-butenyl, etc aryl, i. e., phenyl, naphthyl, etc., and aralkyl, -i. e., benzyl, methylbenzyl, ethylbenzyl, etc.
  • 'InFormula 2 Z represents hydrogen, amino, alkyl, 1. e., methyl, ethyl,'-butyl, etc., p'henyl, phenylenahydroxy, alkox-y, i.
  • alkylthio alkyl-S-
  • X is hydrogen or a primary amino and I hydrazino, "phenyl, hydroxy, alkoxy, i. e., butoxy, etc,, or an alkylthio (alkyl-S-i group, i. e., methylthio, ethylthio, propylthio, etc.
  • the water-soluble addition products of formaldehyde and an azine characterized by Formula 1 are prepared according to the methods described in United States Patent 2,197,357.
  • the water-soluble products while utilizing the azines of Formulae 2 and 3 are prepared according to the methods described in United States Patents, 2,211,? 10 and 2,211,709, respectively.
  • the concentration of the addition products required may vary from as little as 0.5%, an amount which in general has been found to eliminate stain for the most part, to as much as 5%, an amount which is an assurance that stain formation will not ensue. Amounts higher than 5% give little improvement. Concentrations ranging from between 2 and 4% are most desirable from a commercial standpoint.
  • the photographic multi-layer materials which may be processed with the anti-stain bath of the present invention, are color reversible film, color negative film, color reversible white printing material coated on an opaque base, and color positive printing material coated on paper, irrespective of whether the dyestuff images are produced with color formers present in the emulsion, or by a selective second exposure followed by development with developing solutions containing color formers and color developing agents.
  • the color reversible film consists of an integral tripack emulsion coated on the usual clear cellulose acetate or nitrate film base. Each of the emulsion are sensitized to one of the primary colors of light, namely, blue, green, and red.
  • the top layer is blue sensitive.
  • a filter layer, yellow in color and blue absorbing, lies under the top layer. Below this filter layer, lies a green sensitive emulsion layer, and below this is a red sensitive emulsion layer.
  • Each of the three silver-halide emulsion layers contain dye-forming compounds which unite during the development of a silver image in an aromatic amine developing agent to form a dye with the oxidation product of the developing agent, or may be free from color formers in which case the film is processed with the color formers in the color developers by the selective second exposure and color development method as described in United States Patents 1,897,866, 1,900,870, 1,928,709 and 1,980,941.
  • a yellow dye is formed in the blue sensitive emulsion; a magenta dye is formed in the green sensitive emulsion; and a cyan dye is formed in the red sensitive emulsion. Combinations of these 4 three printing primaries will produce all of the other colors in the finished film or print.
  • the color negative film is made up in the same: manner as the color reversible film with the ex-- ception that it may contain a layer of clear" gelatin between the red sensitive layer and the green sensitive layer.
  • the color reversible white opaque material is prepared in the same manner as color reversible film and the color negative film with the exception that the base consists of an opaque white film.
  • the color paper is also constructed in the same manner as the color reversible film and the color negative film, with the exception that the emulsion is coated on a baryta coated paper base. Suitable methods for the preparation of photographic multi--layer materials have been described in the literature relating to color photography and are, therefore, not described here.
  • Example I A 4" x 5" full color transparency sheet of color.” film was printed by contact on two 4" x 5" sheets of color reversible white opaque film.
  • the film was washed for two minutes in running water 68 F. and re-exposed to white light.
  • the re-exposed film was color developed for fifteen minutes at 68 F. in a developer of the following composition:
  • Example II Example III Example I was repeated with the exception that the colored material employed was a color transparency sheet and the final rinse bath consisted of 97 parts by weight of water and 3 parts by weight of a water-soluble addition product of formaldehyde and melamine, trimethylolmelamine, prepared according to Example VI of United States Patent 2,197,357. After fixing and washing, the color print washed in water showed objectionable stains, while the color print treated with the aqueous solution containing the addition product was clear and unstained.
  • the colored material employed was a color transparency sheet and the final rinse bath consisted of 97 parts by weight of water and 3 parts by weight of a water-soluble addition product of formaldehyde and melamine, trimethylolmelamine, prepared according to Example VI of United States Patent 2,197,357.
  • Example IV Example IV was repeated with the exception that the final rinse consisted of 98 parts by weight of water and 2 parts by weight of trimethylolmelamine available commercially under the brand name of "I a-rial: MR1! and having the fol-lowing formula:
  • the treated and untreated prints of Examples 11 to IV inclusive were stored for several months.
  • the untreated prints showed marked staining during storage and the color balance after storage was completely ruined by yellow stains, whereas no stains were evident on the treated prints and the color balance was unafiected.
  • water-soluble addition products of formaldehyde and an azine in aqueous solutions as a final rinse bath, they may be incorporated into gelatin solutions in a concentration ranging from 25% and such gelatin solutions utilized as a surface coating for the processed multi-layer photographic material.
  • At least one Y is an amino group having at least one reactive hydrogen atom, the remaining Ys being a radical selected from the group consisting of hydrogen, hydroxyl, halogen, alkyl, alkylene, aryl and aralkyl
  • Z represents a member selected from the group consisting of hydrogen amino, hydroxy, alkyl, alkoxy, phenyl, phenylene, mercapto, alkylthio and hydrazino, at least two Zs being a member selected from the class consisting of amino and hydrazino group
  • X represents a member selected from the groupconsisting of hydrogen and a primary amino group
  • R represents a member of the group consisting of halogen, hydroxy, hydrazino, alkoxy, phenyl, and alkylthio groups.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
US40010A 1948-07-21 1948-07-21 Antistain baths for color photographic materials Expired - Lifetime US2487569A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BE490235D BE490235A (en)) 1948-07-21
US40010A US2487569A (en) 1948-07-21 1948-07-21 Antistain baths for color photographic materials
GB14278/49A GB659362A (en) 1948-07-21 1949-05-27 Anti-stain baths for color photographic materials
FR990966D FR990966A (fr) 1948-07-21 1949-07-19 Perfectionnements aux procédés de production d'images photographiques en couleurs
DEP49482A DE857738C (de) 1948-07-21 1949-07-21 Verfahren zur Verhinderung von Fleckenbildungen auf Farbbildern
CH291226D CH291226A (fr) 1948-07-21 1949-07-21 Procédé pour empêcher, dans la photographie en couleurs, la formation de taches.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US40010A US2487569A (en) 1948-07-21 1948-07-21 Antistain baths for color photographic materials

Publications (1)

Publication Number Publication Date
US2487569A true US2487569A (en) 1949-11-08

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Family Applications (1)

Application Number Title Priority Date Filing Date
US40010A Expired - Lifetime US2487569A (en) 1948-07-21 1948-07-21 Antistain baths for color photographic materials

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US (1) US2487569A (en))
BE (1) BE490235A (en))
CH (1) CH291226A (en))
DE (1) DE857738C (en))
FR (1) FR990966A (en))
GB (1) GB659362A (en))

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2629660A (en) * 1950-12-01 1953-02-24 Gen Aniline & Film Corp Antifading baths for photographic black-and-white prints
US2647057A (en) * 1950-10-31 1953-07-28 Pavelle Color Inc Protecting color pictures exposed to high humidities against fading and staining
DE960517C (de) * 1950-07-12 1957-03-21 Agfa Ag Fuer Photogabrikation Verfahren zur Herstellung haltbarer subtraktiver farbenphotographischer Bilder
US2976207A (en) * 1959-02-27 1961-03-21 Standard Oil Co Dihydroxy-aminotriazine insecticides
US2980678A (en) * 1958-01-06 1961-04-18 Ici Ltd Pyrimidines
US2983611A (en) * 1957-09-16 1961-05-09 Eastman Kodak Co Gelatin compositions containing hardeners
US2994637A (en) * 1957-11-13 1961-08-01 Diamond Alkali Co Aminopyrimidines as fungicides
US3053656A (en) * 1954-07-01 1962-09-11 Polaroid Corp Photographic silver halide developers containing triazine rings
US3083097A (en) * 1957-04-26 1963-03-26 Agfa Ag Bleaching silver images in the formation of printing plates
US3249603A (en) * 1960-08-09 1966-05-03 Hoffmann La Roche Novel pyrimidine sulfanilamides and processes for their preparation
US3325287A (en) * 1963-11-26 1967-06-13 Fuji Photo Film Co Ltd Photographic gelatin hardening composition
US3391019A (en) * 1964-02-21 1968-07-02 Ici Ltd Process for coating shaped hydrophobic polymeric materials with reaction product of halogenotriazine and polymer containing hydroxyl, amino or mercapto group
US3429878A (en) * 1967-01-31 1969-02-25 Smithkline Corp 6-amino-5-methyleneaminopyrimidines
US3461461A (en) * 1965-11-01 1969-08-12 Upjohn Co 6-amino-4-(substituted amino)-1,2-dihydro-1-hydroxy-2-iminopyrimidines
US3464987A (en) * 1966-02-21 1969-09-02 Upjohn Co 1,2-dihydro-1-hydroxy-2-imino-6-(lower alkyl)pyrimidines
US3473929A (en) * 1965-09-09 1969-10-21 Eastman Kodak Co Method of inhibiting discoloration of color photographs
US4046503A (en) * 1975-04-12 1977-09-06 Henkel & Cie Gmbh Developer-coupler hair dyes based on alkoxy-triamino-pyrimidines
US4150228A (en) * 1976-05-14 1979-04-17 Polaroid Corporation Thioether substituted silver halide solvents
US4255574A (en) * 1973-02-26 1981-03-10 Hoffmann-La Roche Inc. Process for preparing 2,4-diamino-pyrimidines
US4336254A (en) * 1981-03-24 1982-06-22 Smithkline Corporation Guanidinopyrimidine compounds, compositions and method of using as a diuretic
US4336255A (en) * 1981-03-24 1982-06-22 Smithkline Corporation Pharmaceutical compositions containing guanidinopyrimidines
US4555479A (en) * 1983-05-25 1985-11-26 Fuji Photo Film Co., Ltd. Color photographic light-sensitive material
US4786583A (en) * 1987-06-22 1988-11-22 Eastman Kodak Company Stabilizing bath for use in photographic processing
US4797352A (en) * 1984-06-08 1989-01-10 Konishiroku Photo Industry Co., Ltd. Method of processing a silver halide photographic light-sensitive material
US5217852A (en) * 1990-12-07 1993-06-08 Fuji Photo Film Co., Ltd. Color image-stabilization processing solution used for processing a silver halide color photographic material and a processing method using the same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE563764A (en)) * 1957-01-10

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2384658A (en) * 1943-07-10 1945-09-11 Eastman Kodak Co Color photography
US2440954A (en) * 1945-08-23 1948-05-04 Du Pont Process for eliminating stain from color-yielding elements by treatment with aromatic aldehydes containing an acyl group

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2384658A (en) * 1943-07-10 1945-09-11 Eastman Kodak Co Color photography
US2440954A (en) * 1945-08-23 1948-05-04 Du Pont Process for eliminating stain from color-yielding elements by treatment with aromatic aldehydes containing an acyl group

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE960517C (de) * 1950-07-12 1957-03-21 Agfa Ag Fuer Photogabrikation Verfahren zur Herstellung haltbarer subtraktiver farbenphotographischer Bilder
US2647057A (en) * 1950-10-31 1953-07-28 Pavelle Color Inc Protecting color pictures exposed to high humidities against fading and staining
US2629660A (en) * 1950-12-01 1953-02-24 Gen Aniline & Film Corp Antifading baths for photographic black-and-white prints
US3053656A (en) * 1954-07-01 1962-09-11 Polaroid Corp Photographic silver halide developers containing triazine rings
US3083097A (en) * 1957-04-26 1963-03-26 Agfa Ag Bleaching silver images in the formation of printing plates
US2983611A (en) * 1957-09-16 1961-05-09 Eastman Kodak Co Gelatin compositions containing hardeners
US2994637A (en) * 1957-11-13 1961-08-01 Diamond Alkali Co Aminopyrimidines as fungicides
US2980678A (en) * 1958-01-06 1961-04-18 Ici Ltd Pyrimidines
US2976207A (en) * 1959-02-27 1961-03-21 Standard Oil Co Dihydroxy-aminotriazine insecticides
US3249603A (en) * 1960-08-09 1966-05-03 Hoffmann La Roche Novel pyrimidine sulfanilamides and processes for their preparation
US3325287A (en) * 1963-11-26 1967-06-13 Fuji Photo Film Co Ltd Photographic gelatin hardening composition
US3391019A (en) * 1964-02-21 1968-07-02 Ici Ltd Process for coating shaped hydrophobic polymeric materials with reaction product of halogenotriazine and polymer containing hydroxyl, amino or mercapto group
US3473929A (en) * 1965-09-09 1969-10-21 Eastman Kodak Co Method of inhibiting discoloration of color photographs
US3461461A (en) * 1965-11-01 1969-08-12 Upjohn Co 6-amino-4-(substituted amino)-1,2-dihydro-1-hydroxy-2-iminopyrimidines
US3464987A (en) * 1966-02-21 1969-09-02 Upjohn Co 1,2-dihydro-1-hydroxy-2-imino-6-(lower alkyl)pyrimidines
US3429878A (en) * 1967-01-31 1969-02-25 Smithkline Corp 6-amino-5-methyleneaminopyrimidines
US4255574A (en) * 1973-02-26 1981-03-10 Hoffmann-La Roche Inc. Process for preparing 2,4-diamino-pyrimidines
US4046503A (en) * 1975-04-12 1977-09-06 Henkel & Cie Gmbh Developer-coupler hair dyes based on alkoxy-triamino-pyrimidines
US4150228A (en) * 1976-05-14 1979-04-17 Polaroid Corporation Thioether substituted silver halide solvents
US4336254A (en) * 1981-03-24 1982-06-22 Smithkline Corporation Guanidinopyrimidine compounds, compositions and method of using as a diuretic
US4336255A (en) * 1981-03-24 1982-06-22 Smithkline Corporation Pharmaceutical compositions containing guanidinopyrimidines
US4555479A (en) * 1983-05-25 1985-11-26 Fuji Photo Film Co., Ltd. Color photographic light-sensitive material
EP0127162A3 (en) * 1983-05-25 1987-02-25 Fuji Photo Film Co., Ltd. Color photographic light-sensitive material
US4797352A (en) * 1984-06-08 1989-01-10 Konishiroku Photo Industry Co., Ltd. Method of processing a silver halide photographic light-sensitive material
US4786583A (en) * 1987-06-22 1988-11-22 Eastman Kodak Company Stabilizing bath for use in photographic processing
US5217852A (en) * 1990-12-07 1993-06-08 Fuji Photo Film Co., Ltd. Color image-stabilization processing solution used for processing a silver halide color photographic material and a processing method using the same
US5348845A (en) * 1990-12-07 1994-09-20 Fuji Photo Film Co., Ltd. Color image-stabilization processing solution used for processing a silver halide color photographic material and a processing method using the same

Also Published As

Publication number Publication date
FR990966A (fr) 1951-09-28
CH291226A (fr) 1953-06-15
BE490235A (en))
GB659362A (en) 1951-10-24
DE857738C (de) 1952-12-01

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