US2245620A - Binder for glass fiber threads - Google Patents
Binder for glass fiber threads Download PDFInfo
- Publication number
- US2245620A US2245620A US284100A US28410039A US2245620A US 2245620 A US2245620 A US 2245620A US 284100 A US284100 A US 284100A US 28410039 A US28410039 A US 28410039A US 2245620 A US2245620 A US 2245620A
- Authority
- US
- United States
- Prior art keywords
- binder
- glass fiber
- threads
- fiber threads
- adhesives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011230 binding agent Substances 0.000 title description 15
- 239000003365 glass fiber Substances 0.000 title description 6
- 239000001993 wax Substances 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920001353 Dextrin Polymers 0.000 description 3
- FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000010775 animal oil Substances 0.000 description 2
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 2
- -1 collodium Polymers 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000000899 Gutta-Percha Substances 0.000 description 1
- 240000000342 Palaquium gutta Species 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 229920000588 gutta-percha Polymers 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/40—Organo-silicon compounds
Definitions
- the binder according to the invention consists of diluted aqueous solutions of animal, vegetable or mineral oils, tats, waxes and the like or mixtures thereof, to which a water-soluble adhesive may be added for increasing the adhesiveness oi the binder.
- emulsions can be prepared in the usual manner practised in the art of making emulsions with the use of suitable emulsifying agents.
- a glass fiber thread or strand sized with a binder according to the invention after the setting of the binder is well closed, soft and supple and has a brilliant, slightly fatty surface which renders it highly suited for textile treatments.
- the setting of the binder may be accelerated by artificial drying.
- the binder can be readily removed again by the. common textile washing media, such as aqueous soap solutions or the like.
- binders according to the invention are composed as follows:
- the emulsions may also contain up to 5% Without afiecting the possibility of removin the binder from the finished, products by washing, the binder may be given either a more pronounced binding efiect or a more. pronounced lubricating eflect as desired in accordance with the purpose for which it is used by a proper selection oi various oils or by ,suitablymixins oils and tats, adding waxes and using suitable 0 emulsiiyini asents.
- a binder for glass fiber threads and the like consisting or a diluted aqueous emulsion containing 3 to 10% Iatty acid sulphonate, 3 to 10% 40 oil and 3 to 10% dextrine.
Description
Patented- June 17, 1941 UNITED STATES PATENT OFFICE ammo BINDER FOR GLASS m THREADS Hana summit. Germany, assimi- Owens Corning Fiber-glee Corporation, '1 Ohio No Drawing. Apt liclflmllbmmiiflerialho.
284,100. In July 14, 10;.
s (0.1. leez) In the art of making threads or strands or B glass fibers and like fibers. it is well-known to I 7 Parts bind the fibers by means of adhesives such as Special w 10 gutta-percha, collodium, rubber solutions, var- Wax emulsifying agent.....-,. 2 nish, shellac, waxes or like substances. Although 5 Water 88 these adhesives have a good bindins D W? Hid fully close the threads, they possess numerous M disadvantages. Threads etli'lesiziiet l' wietlili m6 water 80w adhesives do not lend th ves w e v treatments such weaving mmnlfit-$8.?? .2212 22.1 a to their surface is not sumciently smooth and their v Animal or vegetable oii---..--.- 3 to 5 ability to slide is unsatisfactory. Moreover, the Gelatin, y 3 to 5 said adhesives either cannot be removed any more from the finished fabrics or they can only D be removed therefrom by the aid of organic sol- Parts vents, such as alcohol, benzine, ether, carbospecial 10 sulphide or the like, some of which are infiam- Wax 8111mm u mable or explosive. 3 2
However, in many cases it is necessary to remove the binder again from the finished glass fiber products because the favorable electrical and thermal properties of the glass are more or less reduced by the said adhesives.
It is the object of the present invention to provide a binder for glass fibers and. threads without the above-said disadvantages, i. e. a binder which has a high binding eifect and at the same time iubricates the threads or strands and can easily be washed out without having to use inflammable solvents for this purpose.
With this object in view, the binder according to the invention consists of diluted aqueous solutions of animal, vegetable or mineral oils, tats, waxes and the like or mixtures thereof, to which a water-soluble adhesive may be added for increasing the adhesiveness oi the binder.
These emulsions can be prepared in the usual manner practised in the art of making emulsions with the use of suitable emulsifying agents.
A glass fiber thread or strand sized with a binder according to the invention after the setting of the binder is well closed, soft and supple and has a brilliant, slightly fatty surface which renders it highly suited for textile treatments. The setting of the binder may be accelerated by artificial drying. The binder can be readily removed again by the. common textile washing media, such as aqueous soap solutions or the like.
Some examples of binders according to the invention are composed as follows:
s. 80to00 Water Emulsiiying agent such as iatty acid sulphonate.'. Animal or vegetable oil.......--... Yellow dextrine.-e-.--.....----..--
80 The emulsions may also contain up to 5% Without afiecting the possibility of removin the binder from the finished, products by washing, the binder may be given either a more pronounced binding efiect or a more. pronounced lubricating eflect as desired in accordance with the purpose for which it is used by a proper selection oi various oils or by ,suitablymixins oils and tats, adding waxes and using suitable 0 emulsiiyini asents. Thus, various modifications and variations may be resorted to without departing from the spirit and scope of the present invention as defined in the appendedclaims.
Having thus described my invention, what I 5 claim as new and desire Patent is:
1. A binder for glass fiber threads and the like, consisting or a diluted aqueous emulsion containing 3 to 10% Iatty acid sulphonate, 3 to 10% 40 oil and 3 to 10% dextrine.
composed of 10% wax, 2% wax emulsifying agent, 7% dextrine and 81% water.
5.A.blnderi'orgia8fiberthreedsandthelik comprising a diluted aque us emulsion containingstoiovt emulsiir seeenastemitor emuisivesubetaneeeelectedtromthegroupommunzoroiummamendstomamm.
to secure by Letters
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39842141 US2371933A (en) | 1938-07-14 | 1941-06-17 | Binders for glass fiber threads |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2245620X | 1938-07-14 | ||
| US39842141 US2371933A (en) | 1938-07-14 | 1941-06-17 | Binders for glass fiber threads |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2245620A true US2245620A (en) | 1941-06-17 |
Family
ID=32109021
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US284100A Expired - Lifetime US2245620A (en) | 1938-07-14 | 1939-07-12 | Binder for glass fiber threads |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2245620A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2607714A (en) * | 1946-11-01 | 1952-08-19 | Owens Corning Fiberglass Corp | Mats of glass fibers interbonded with readily removable binder |
| US2993872A (en) * | 1957-12-23 | 1961-07-25 | Owens Corning Fiberglass Corp | Aqueous composition comprising werner complex, a starch, hydrogenated vegetable oil and emulsifying agent and method of preparing same |
| US3108891A (en) * | 1961-04-24 | 1963-10-29 | Owens Corning Fiberglass Corp | Amylaceous forming size compositions |
| US4037923A (en) * | 1974-06-25 | 1977-07-26 | Bicc Limited | Optical guides with compressible cellular material |
-
1939
- 1939-07-12 US US284100A patent/US2245620A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2607714A (en) * | 1946-11-01 | 1952-08-19 | Owens Corning Fiberglass Corp | Mats of glass fibers interbonded with readily removable binder |
| US2993872A (en) * | 1957-12-23 | 1961-07-25 | Owens Corning Fiberglass Corp | Aqueous composition comprising werner complex, a starch, hydrogenated vegetable oil and emulsifying agent and method of preparing same |
| US3108891A (en) * | 1961-04-24 | 1963-10-29 | Owens Corning Fiberglass Corp | Amylaceous forming size compositions |
| US4037923A (en) * | 1974-06-25 | 1977-07-26 | Bicc Limited | Optical guides with compressible cellular material |
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