US2188287A - Wetting agent for alkaline mercerizing solutions - Google Patents

Wetting agent for alkaline mercerizing solutions Download PDF

Info

Publication number
US2188287A
US2188287A US163920A US16392037A US2188287A US 2188287 A US2188287 A US 2188287A US 163920 A US163920 A US 163920A US 16392037 A US16392037 A US 16392037A US 2188287 A US2188287 A US 2188287A
Authority
US
United States
Prior art keywords
acid
wetting agent
solutions
parts
mercerizing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US163920A
Other languages
English (en)
Inventor
Munz Ferdinand
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Aniline Works Inc
Original Assignee
General Aniline Works Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Aniline Works Inc filed Critical General Aniline Works Inc
Application granted granted Critical
Publication of US2188287A publication Critical patent/US2188287A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/392—Nitroso compounds; Nitro compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/06—Protein or carboxylic compound containing

Definitions

  • My invention relates to wetting agents for alkaline mercerizing solutions, consisting of a phenolic body, a compound of a particular wetting effect, but insoluble in mercerizing solutions, and a reaction product of nitric acid on an unsaturated fatty acid.
  • wetting agents are used as consist of mixtures of ingredients, on the one hand, of phenolic bodies used as solvents such as phenol, homologous cresols, xylenols or substitution products of phenols, such as ehlorocresols or chloroxylenols, and, on the other hand, of compounds of a particular wetting effect, but which as such are insoluble in mercerizing solutions.
  • solvents such as phenol, homologous cresols, xylenols or substitution products of phenols, such as ehlorocresols or chloroxylenols
  • wet ting agents for mercerizing solutions are obtained which are distinguished by an essentially better solubility and stronger effect than that of the hitherto known agents.
  • nitric acid acts on the unsaturated fatty acid in two directions, namely on the one hand by'o-xidizing decomposition, on the other hand by introducing nitro groups, which latter may, in addition, be acted upon in various ways, for instance, by reduction boiling with the addition of an acid or an alkali, by the action of a sulfite, without changing the characteristic properties.
  • the nitric acid employed which may be used alone or in admixture with a dehydrating agent such as sulfuric acid, and also according to the conditions of working and the kind of the unsaturated fatty acid (oleic acid, linoleic acid, ricinoleic acid and the various technical mixtures), substances of differing constitution and effects are obtained.
  • a dehydrating agent such as sulfuric acid
  • the unsaturated fatty acid oleic acid, linoleic acid, ricinoleic acid and the various technical mixtures
  • the fats themselves may be used, since they are split up by the action of the hot nitric acid.
  • Example 1 A mixture of '76 parts of crude cresol, 4 parts of cyclohexanol and 20 parts of a nitration prodnot of oleic acid may be used as Wetting agent for mercerizing solutions.
  • the aforesaid nitration product has been prepared as follows. To 1500 parts of nitric acid of 40 B. during 8 to 10 hours at about '75 to 80, 1000 parts of oleic acid are added, then the reaction mixture is slowly heated to about 100 and kept for some hours at this temperature.
  • Example 2 The reaction product of nitric acid, on oleic acid as described in the foregoing example, is reated for some hours with sulfurous acid with the addition of a small amount of water, in order to remove nitro groups which can be easily split off, and then the reaction product thus obtained is separated from the aqueous layer.
  • sulfurous acid with the addition of a small amount of water
  • second component which has a particular wetting eflect, but is insoluble in mercerizing solutions
  • di-iso butylsulfaminic acid cf. my application. Ser. No. 71,875, filed March 31, 1936, now U. S. Patent No. 2,116,583 dated May 10, 1938, yielding an increased wetting effect, compared with that of the above mixture.
  • An improved wetting agent for an alkaline mercerizing solution which comprises a phenolic compound and a wetting agent which is as such FERDINAND

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Treatment Of Fiber Materials (AREA)
US163920A 1936-10-02 1937-09-15 Wetting agent for alkaline mercerizing solutions Expired - Lifetime US2188287A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE201595X 1936-10-02

Publications (1)

Publication Number Publication Date
US2188287A true US2188287A (en) 1940-01-23

Family

ID=5767017

Family Applications (1)

Application Number Title Priority Date Filing Date
US163920A Expired - Lifetime US2188287A (en) 1936-10-02 1937-09-15 Wetting agent for alkaline mercerizing solutions

Country Status (6)

Country Link
US (1) US2188287A (en:Method)
BE (1) BE423798A (en:Method)
CH (1) CH201595A (en:Method)
FR (1) FR827181A (en:Method)
GB (1) GB486973A (en:Method)
NL (1) NL48407C (en:Method)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2050810A3 (en) * 2007-10-18 2011-02-16 Petróleo Brasileiro S.A. Petrobras Method for production of cetane-index improvement additive for diesel oil

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2050810A3 (en) * 2007-10-18 2011-02-16 Petróleo Brasileiro S.A. Petrobras Method for production of cetane-index improvement additive for diesel oil

Also Published As

Publication number Publication date
GB486973A (en) 1938-06-14
CH201595A (de) 1938-12-15
NL48407C (en:Method)
FR827181A (fr) 1938-04-20
BE423798A (en:Method)

Similar Documents

Publication Publication Date Title
US2174762A (en) Condensation products derived from amines and method of producing them
US2945818A (en) Process for preparing surface active compositions
US2185163A (en) Polyoxyalkylene ammonium compounds and process of preparing them
US2164431A (en) Production of etherg suitable as dis
DE1041003B (de) Oberflaechenaktive Mittel
US2188287A (en) Wetting agent for alkaline mercerizing solutions
US3222286A (en) Dry cleaning composition
US1985747A (en) Ether-like constituted compound
US2200603A (en) Method for the improving of goods
US1851914A (en) Manufacture and use of new wetting preparations
US2083482A (en) Carbocyclic compounds containing acid salt-forming groups
US2195194A (en) Treatment of fibrous materials
US2806007A (en) Production of resins from formaldehyde and reaction product of phenol and alginic acid
DE642744C (de) Verfahren zur Herstellung von ester- und saeureamidartigen Kondensationsprodukten aus Oxyaminen
US2345036A (en) Mercerizing penetrant
US2214629A (en) Products for fixing tanning agents and a method of carrying out this fixing
US2185480A (en) Nitrogenous condensation products and process of producing the same
US2038947A (en) Process of manufacturing methyl ether of tertiary butyl meta cresol
US2574541A (en) Certain para-cyclohexylcyclohexanol ethers of certain glycols
US1852820A (en) Soap manufacture
DE1520353B2 (de) Verfahren zur Herstellung von wasserlöslichen, Phosphor enthaltenden, oberflächenaktiven Polykondensationsprodukten
US1929654A (en) Mercerizing liquor
US2213139A (en) Increasing the wetting power of strong alkaline lyes
AT125234B (de) Verfahren zur Herstellung von Oxyalkyläthern der Cellulose.
US2295705A (en) Process of preparing terpine hydrate