US2026816A - Soap preparation - Google Patents
Soap preparation Download PDFInfo
- Publication number
- US2026816A US2026816A US566809A US56680931A US2026816A US 2026816 A US2026816 A US 2026816A US 566809 A US566809 A US 566809A US 56680931 A US56680931 A US 56680931A US 2026816 A US2026816 A US 2026816A
- Authority
- US
- United States
- Prior art keywords
- soap
- salt
- water soluble
- combination
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000344 soap Substances 0.000 title description 84
- 238000002360 preparation method Methods 0.000 title description 4
- 239000000203 mixture Substances 0.000 description 36
- 150000003839 salts Chemical class 0.000 description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
- -1 sulphuric acid ester Chemical class 0.000 description 24
- 239000002253 acid Substances 0.000 description 21
- 239000001117 sulphuric acid Substances 0.000 description 16
- 235000011149 sulphuric acid Nutrition 0.000 description 16
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 15
- 239000008233 hard water Substances 0.000 description 12
- 238000001556 precipitation Methods 0.000 description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 9
- 239000004359 castor oil Substances 0.000 description 5
- 235000019438 castor oil Nutrition 0.000 description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 5
- 239000003599 detergent Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 150000003138 primary alcohols Chemical class 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 208000004434 Calcinosis Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910001389 inorganic alkali salt Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000005404 monopole Effects 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
Definitions
- This invention relates to a soap composition having as its total or principal ingredients a soap of any kind and a salt of an acid sulphuric acid ester of a higher aliphatic alcohol, especially of a normal primary alcohol.
- the principal object of the invention is to provide a soap composition which is totally stable in the presence of hard, strongly alkaline or acid waters, producing no insoluble precipitates whatever.
- a further object is to produce a soap composition possessing very excellent cleansing, purifying and foaming powers, its properties being comparable only to the action of soap in completely softened water.
- the soap in the composition may be of any kind. Soaps found to be particularly suitable include all kinds of soluble soaps, such as curd soaps; rosin curd soaps; soft soaps; sulphonated oil soap, such as sulphonated castor oil soap, and similar or related soaps.
- soluble soaps such as curd soaps; rosin curd soaps; soft soaps; sulphonated oil soap, such as sulphonated castor oil soap, and similar or related soaps.
- sulphonated oil soap such as sulphonated castor oil soap, and similar or related soaps.
- a suitable sulionated castor oil soap called monopol soap is described in German Patent No. 113,433. It is of course understood that only soluble soaps are applicable.
- salts of sulphuric acid esters found suitable in compositions of the present invention there are particularly those of the acid sulphuric acid esters of lauryl alcohol, cetyl alcohol and stearyl alcohol, and/or mixtures of the acid sulphuric acid esters of higher normal primary alcohols derived from the fatty acids contained in coconut oil by replacement of the carboxyl group by the group CHzOH.
- soap-addition products such as solvents for fats, washing agents or bleaching agents including hydrocarbons, halogenated hydrocarbons, lower alcohols, cyclohexanol, glycerin; soluble phosphates, borax, waterglass; and persalts, such as sodium perborate.
- composition is compounded forms no part of the present invention.
- Such may conveniently be accomplished, for example, by mixing the soap with the dry salt of the sulphuric acid ester of the aliphatic alcohol, and pressing the mixture.
- the soap in a melted condition may be mixed with the solid salt or with a solution of the salt.
- the resulting mixture if not already in powdered form may be reduced to such state, if desired.
- the proportions of the soap and salt to be used in making up the compositions depend entirely upon the use to which the same is to be put, and principally upon the nature of the water with which the same is to be used. To be taken into consideration is its hardness, its salt content, or its degree of acidity. A mixture of 75% soap with 25% of the salt of the sulphuric acid ester of the fatty alcohol has been found extremely satisfactory for many purposes.
- the salts employed are those of a soluble nature, in particular, the alkali metal salts such as sodium salt.
- Example Melted grain soa in a quantity of 150 kgs. is thoroughly mixe y stirring with 50 kgs. of dodecyl sodium sulphate (the sodium salt of the acid sulphuric acid ester of lauryl alcohol).
- a soap composition for use in hard water comprising in combination essentially a water soluble soap and a water soluble salt of an acid sulphuric acid ester of a higher aliphatic alcohol in proportions which prevent precipitation of the soap during use in hard water.
- a soap composition comprising in combination curd soap and a water soluble salt of an acid sulphuric acid ester of a higher aliphatic alcohol, said salt being used in a proportion which prevents precipitation of the soap during use in hard water.
- a stable soap composition comprising in combination rosin curd soap and a water soluble salt of an acid sulphuric acid ester of a higher aliphatic alcohol, said salt being used in a proportion which retains in undiminished amount the cleansing power of the soap.
- a stable soap composition comprising in combination soft soap and a water soluble salt of an acid sulphuric acid ester of a higher aliphatic alcohol, said salt being used in a proportion which retains in undiminished amount the cleansing power of the soap.
- a stable soap composition comprising in combination essentially a sulphonated castor oil soap and a water soluble salt of an acid sulphuric acid ester of a higher aliphatic alcohol, said salt being used in a proportion which prevents precipitation of the soap during use in hard water.
- a stable soap composition comprising in combination sulphonated castor oil soap and a water soluble salt of an acid sulphuric acid ester of a higher normal primary aliphatic alcohol, said salt being used in a proportion which prevents precipitation of the soap during use in hard water.
- a stable soap composition comprising in combination a water soluble soap and a water soluble salt of an acid sulphuric acid ester of lauryl alcohol.
- a soap composition comprising in combination, a water soluble soap and a water soluble salt of an acid sulphuric acid ester of cetyl alcohol in a proportion of about 75% to 25%, respectively.
- a soap composition comprising in combination, a water soluble soap and a water soluble salt of an acid sulphuric acid ester of stearic alcohol in proportions which prevent precipitation of the soap during use in hard water.
- a soap composition comprising in combination, a water soluble soap and a water soluble salt of sulphuric acid esters of higher normal primary aliphatic alcohols, said salt being used in a proportion which imparts to the composition powers comparable to soap in completely softened water.
- a stable soap composition comprising in combination, a water soluble soap, a water soluble salt of an acid sulphuric acid ester of a higher aliphatic alcohol and an organic solvent of fats in proportions which prevent precipitation of the soap during use in hard water.
- a stable soap composition comprising in combination, a water soluble soap, a water soluble salt of an acid sulphuric acid ester of a higher aliphatic alcohol and an inorganic alkali salt having detergent properties in proportions which prevent precipitation of the soap during use in hard water.
- a soap composition comprising in combination, a water soluble soap, a water soluble salt of an acid sulphuric acid ester of a higher aliphatic alcohol andanagent commonly used for Bleaclrirrg fibegsfb'y means of'oxyg'e ,said salt being employed in a proportionwhich prevents precipitation oi the soap during use.
- a stable soap composition comprising in combination, curd soap and dodecyl sodium sulphate.
- a stable soap composition comprising in combination, a water soluble soap and a soluble salt of acid sulphuric acid esters of higher normal primary alcohols derived from the fatty acids contained in coconut oil by replacement of the carboxyl group by the group CHzOH.
- a soap composition comprising in combination a preponderating amount of a water soluble soap and a lesser amount of an alkali metal salt of a sulfate of a higher aliphatic alcohol.
- An alkali metal soap containing in combination a water soluble salt of a sulfuric acid ester of a higher aliphatic primary alcohol in suflicient proportion to prevent precipitation of the soap during use in hard water.
- a stable soap composition comprising in combination, a water soluble soap, a water soluble salt of an acid sulfuric acid ester of a higher aliphatic alcohol, and borax having detergent properties, in proportions which prevent precipitation of the soap during use in hard water.
- a stable soap composition comprising in combination, a water soluble soap, a water soluble salt of an acid sulfuric acid ester of a higher aliphatic alcohol, and water glass having detergent properties, in proportions which prevent precipitation of the soap during use in hard water.
- a stable soap composition comprising in combination, a water soluble soap, a water soluble salt of an acid sulfuric acid ester of a higher aliphatic alcohol, and soluble phosphates having detergent properties, in proportions which prevent precipitation of the soap during use in hard water.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE379534X | 1930-10-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2026816A true US2026816A (en) | 1936-01-07 |
Family
ID=6344704
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US566809A Expired - Lifetime US2026816A (en) | 1930-10-06 | 1931-10-03 | Soap preparation |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2026816A (en(2012)) |
| BE (1) | BE383121A (en(2012)) |
| FR (1) | FR723775A (en(2012)) |
| GB (1) | GB379534A (en(2012)) |
| NL (1) | NL35101C (en(2012)) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2494580A (en) * | 1947-05-24 | 1950-01-17 | Procter & Gamble | Detergent composition |
| US2527076A (en) * | 1947-02-24 | 1950-10-24 | Procter & Gamble | Detergent composition |
| US2527077A (en) * | 1947-06-02 | 1950-10-24 | Procter & Gamble | Detergent composition |
| US2527078A (en) * | 1947-05-24 | 1950-10-24 | Procter & Gamble | Detergent composition |
| US2527075A (en) * | 1947-02-24 | 1950-10-24 | Procter & Gamble | Detergent composition |
| US2567645A (en) * | 1947-05-16 | 1951-09-11 | Shell Dev | Process of producing a detergent composition |
| US3353927A (en) * | 1961-11-15 | 1967-11-21 | Calgon Corp | Dissolving rock salt containing calcium sulfate in the presence of an anionic organic wetting agent |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL66298C (en(2012)) * | 1946-11-01 | |||
| US2674580A (en) * | 1950-07-20 | 1954-04-06 | Colgate Palmolive Co | Liquid shampoo |
-
0
- BE BE383121D patent/BE383121A/xx unknown
- NL NL35101D patent/NL35101C/xx active
-
1931
- 1931-09-25 GB GB26825/31A patent/GB379534A/en not_active Expired
- 1931-10-01 FR FR723775D patent/FR723775A/fr not_active Expired
- 1931-10-03 US US566809A patent/US2026816A/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2527076A (en) * | 1947-02-24 | 1950-10-24 | Procter & Gamble | Detergent composition |
| US2527075A (en) * | 1947-02-24 | 1950-10-24 | Procter & Gamble | Detergent composition |
| US2567645A (en) * | 1947-05-16 | 1951-09-11 | Shell Dev | Process of producing a detergent composition |
| US2494580A (en) * | 1947-05-24 | 1950-01-17 | Procter & Gamble | Detergent composition |
| US2527078A (en) * | 1947-05-24 | 1950-10-24 | Procter & Gamble | Detergent composition |
| US2527077A (en) * | 1947-06-02 | 1950-10-24 | Procter & Gamble | Detergent composition |
| US3353927A (en) * | 1961-11-15 | 1967-11-21 | Calgon Corp | Dissolving rock salt containing calcium sulfate in the presence of an anionic organic wetting agent |
Also Published As
| Publication number | Publication date |
|---|---|
| GB379534A (en) | 1932-09-01 |
| BE383121A (en(2012)) | |
| FR723775A (fr) | 1932-04-14 |
| NL35101C (en(2012)) |
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