US20190194550A1 - Treatment Method for Reducing Contaminating Agents in Liquid Mixtures of Substituted Hydrocarbons Used as Fuels - Google Patents

Treatment Method for Reducing Contaminating Agents in Liquid Mixtures of Substituted Hydrocarbons Used as Fuels Download PDF

Info

Publication number
US20190194550A1
US20190194550A1 US16/328,185 US201616328185A US2019194550A1 US 20190194550 A1 US20190194550 A1 US 20190194550A1 US 201616328185 A US201616328185 A US 201616328185A US 2019194550 A1 US2019194550 A1 US 2019194550A1
Authority
US
United States
Prior art keywords
fuels
fuel
hydrocarbons used
hydrocarbons
treatment method
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US16/328,185
Other languages
English (en)
Inventor
José Jorge Torres Álarez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of US20190194550A1 publication Critical patent/US20190194550A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/16—Metal oxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24—Mixing, stirring of fuel components
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel

Definitions

  • Liquid hydrocarbons used as fuel such as gasoline, gas oil or diesel, jet fuel, or kerosene, are toxic and highly flammable. Vapors produced by their evaporation and substances created when burnt, such as carbon monoxide, nitrous oxides, non-burnt hydrocarbons, etc., contribute to air pollution. Also, burning these fuels additionally produces carbon dioxide, a greenhouse gas directly related to global climate change.
  • This invention pertains to a method of refining and catalyzing liquid hydrocarbons used as fuel that eliminates sulfur, aromatic compounds, benzenes, xylenes, toluenes, in addition to oxidizing available octanes to act as an oxidizer during the hydrocarbon combustion processes, which provides better burning and greater energy availability for industrial fuel uses.
  • the disclosed method is applicable to mixed fuels in the final stage of hydrocarbon refining, i.e., fuels that, in current state of the art, are used as final products available for sale to consumers.
  • the disclosed method comprises mixing small solid ferrous oxide particles with water vapor until a heterogeneous mixture is achieved. This heterogeneous mixture is then poured into a container with substituted hydrocarbons used as fuel, and is combined and mixed constantly for a few minutes.
  • Hydrocarbons used in commerce as fuel carry high concentrations of sulfur, aromatic compounds, benzenes, xylenes, toluenes, and others. Burning these fuels in internal combustion engines is not efficient enough to burn all of these compounds, so they are released into the atmosphere.
  • a treatment method for reducing polluting agents in liquid substituted hydrocarbons used as fuel comprising blending a heterogeneous mixture of ferrous oxide in water with said fuel, mixing or constantly combining the solution, allowing the mixture to settle, and removing the aqueous solution of ferrous oxide and water by decanting.
  • the fuel obtained as a result of applying the disclosed method contains a lower count of polluting compounds containing sulfur, aromatic compounds, benzenes, xylenes, toluenes, and others. Additionally, it increases fuel burning efficiency because, during the chemical reaction, hydrocarbons gain additional oxygen atoms that help as an oxidizer.
  • FIG. 1 is the graphic result of the GC-FID analysis of a commercially available diesel sample, in which the X axis shows minutes lapsed, and the Y axis shows voltage in mV.
  • FIG. 2 is the graphic result of the GC-FID analysis of a commercially available diesel sample, treated with the claimed compound and method, in which the X axis shows minutes lapsed, and the Y axis shows voltage in mV, and the hydrocarbon reduction is appreciated.
  • FIG. 3 is the graphic result of the GC-FID analysis of a commercially available gasoline sample, in which the X axis shows minutes lapsed, and Y axis shows voltage in V.
  • FIG. 4 is the graphic result of the GC-FID analysis of a commercially available gasoline sample, treated with the claimed compound and method, in which the X axis shows minutes lapsed, and the Y axis shows voltage in mV, and the hydrocarbon reduction is appreciated.
  • FIG. 5 is the graphic result of the GC-FID analysis of a commercially available jet fuel sample, in which the X axis shows minutes lapsed, and Y axis shows voltage in mV.
  • FIG. 6 is the graphic result of the GC-FID analysis of a commercially available jet fuel sample, treated with the claimed compound and method, in which the X axis shows minutes lapsed, and Y axis shows voltage in mV, and the hydrocarbon reduction is appreciated.
  • the process is achieved by supersaturating ferrous oxide in water.
  • the ferrous oxide supersaturation process has been described by (MARTIN, Scot T. Precipitation and dissolution of iron and manganese oxides. Environmental Catalysis, 2005, p. 61-81). This supersaturated solution serves as catalyzer for refining fuel.
  • the supersaturated ferrous oxide solution is mixed with the fuel. It is well known that the ferrous oxide supersaturated solution may be used in a proportion of up to 70% of said solution against 30% fuel. However, in the preferred embodiment, the mixture is done with 10% solution to 90% fuel (e.g., 100 liters of supersaturated ferrous oxide solution for each 1,000 liters of fuel to be refined).
  • the supersaturated solution must be mixed by constant fluid blending, either by agitation, fluid recirculation, or barometric variation. In the preferred embodiment, 1 liter of this mixture must be mixed for at least one minute.
  • FIG. 1 shows a graphic result of gas chromatography of a commercially available diesel sample.
  • the first spike belongs to the dichloromethane used as control solvent.
  • FIG. 2 shows a graphic result of gas chromatography of a commercially available diesel after treatment with the claimed method. As can be seen in accordance with the retention time shown in FIG. 2 , the amount of linear hydrocarbons has decreased, which demonstrates the refining capabilities of the method.
  • FIG. 3 shows the graphic result of gas chromatography of a commercially available gasoline sample.
  • the first spike belongs to the dichloromethane used as control solvent.
  • FIG. 4 shows the graphic result of gas chromatography of the same commercially available gasoline sample after being treated with the claimed method. It will be appreciated that the quantity of cyclic hydrocarbons has also decreased.
  • FIG. 5 corresponds to the analysis of commercially available jet fuel
  • FIG. 6 corresponds to the analysis of the same jet fuel after being treated with the claimed method. The results are similar to those of diesel and gasoline.
  • This method is applicable to any industry in which fuel is used and there is a desire to reduce polluting combustion byproducts and improve fuel efficiency.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Liquid Carbonaceous Fuels (AREA)
US16/328,185 2016-08-31 2016-08-31 Treatment Method for Reducing Contaminating Agents in Liquid Mixtures of Substituted Hydrocarbons Used as Fuels Abandoned US20190194550A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2016/055210 WO2017093816A1 (es) 2016-08-31 2016-08-31 Método de tratamiento para reducción de agentes contaminantes en mezclas líquidas de hidrocarburos sustituidos usados como combustibles

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2016/055210 A-371-Of-International WO2017093816A1 (es) 2016-08-31 2016-08-31 Método de tratamiento para reducción de agentes contaminantes en mezclas líquidas de hidrocarburos sustituidos usados como combustibles

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US15/929,274 Continuation US20200318017A1 (en) 2016-08-31 2020-04-21 Treatment Method for Reducing Contaminating Agents in Liquid Mixtures of Substituted Hydrocarbons Used as Fuels

Publications (1)

Publication Number Publication Date
US20190194550A1 true US20190194550A1 (en) 2019-06-27

Family

ID=58796394

Family Applications (2)

Application Number Title Priority Date Filing Date
US16/328,185 Abandoned US20190194550A1 (en) 2016-08-31 2016-08-31 Treatment Method for Reducing Contaminating Agents in Liquid Mixtures of Substituted Hydrocarbons Used as Fuels
US15/929,274 Abandoned US20200318017A1 (en) 2016-08-31 2020-04-21 Treatment Method for Reducing Contaminating Agents in Liquid Mixtures of Substituted Hydrocarbons Used as Fuels

Family Applications After (1)

Application Number Title Priority Date Filing Date
US15/929,274 Abandoned US20200318017A1 (en) 2016-08-31 2020-04-21 Treatment Method for Reducing Contaminating Agents in Liquid Mixtures of Substituted Hydrocarbons Used as Fuels

Country Status (7)

Country Link
US (2) US20190194550A1 (zh)
EP (1) EP3508558A4 (zh)
CN (1) CN110234741A (zh)
CO (1) CO2019002973A2 (zh)
MX (1) MX2019002220A (zh)
RU (1) RU2717834C1 (zh)
WO (1) WO2017093816A1 (zh)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040108252A1 (en) * 2002-12-10 2004-06-10 Petroleo Brasileiro S.A. - Petrobras Process for the upgrading of raw hydrocarbon streams

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4811321B1 (zh) * 1967-02-16 1973-04-12
RU2159666C1 (ru) * 1999-11-24 2000-11-27 Дыкман Аркадий Самуилович Способ очистки промышленных газовых выбросов
US7309416B2 (en) * 2003-07-11 2007-12-18 Aspen Products Group, Inc. Methods and compositions for desulfurization of hydrocarbon fuels
CN101067100B (zh) * 2006-12-22 2011-05-18 毕舒 清洁环保燃料的制备方法及制得的燃料
TWI414592B (zh) * 2010-11-05 2013-11-11 Ind Tech Res Inst 油品改質的方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040108252A1 (en) * 2002-12-10 2004-06-10 Petroleo Brasileiro S.A. - Petrobras Process for the upgrading of raw hydrocarbon streams

Also Published As

Publication number Publication date
EP3508558A1 (en) 2019-07-10
EP3508558A4 (en) 2020-04-01
CN110234741A (zh) 2019-09-13
MX2019002220A (es) 2019-09-23
US20200318017A1 (en) 2020-10-08
CO2019002973A2 (es) 2019-08-30
RU2717834C1 (ru) 2020-03-26
WO2017093816A1 (es) 2017-06-08

Similar Documents

Publication Publication Date Title
Zhu et al. One-pot extraction combined with metal-free photochemical aerobic oxidative desulfurization in deep eutectic solvent
CA2837269C (en) Glycerol containing fuel mixture for direct injection engines
Amais et al. A simple dilute-and-shoot procedure for Si determination in diesel and biodiesel by microwave-induced plasma optical emission spectrometry
Zhao et al. Extractive desulfurization of dibenzothiophene by a mixed extractant of N, N-dimethylacetamide, N, N-dimethylformamide and tetramethylene sulfone: optimization by Box–Behnken design
US7959690B1 (en) Nanoparticles for soot reduction
Zhao et al. Design rules of ionic liquids tasked for highly efficient fuel desulfurization by mild oxidative extraction
Wang et al. One-pot extraction and aerobic oxidative desulfurization with highly dispersed V 2 O 5/SBA-15 catalyst in ionic liquids
EP3441442B1 (en) A process for the reduction of the sulphur content of fuels
Souza et al. Determination of refractory elements in used lubricating oil by ICPOES employing emulsified sample introduction and calibration with inorganic standards
Lim et al. Comparative effects of oxygenates-gasoline blended fuels on the exhaust emissions in gasoline-powered vehicles
JP2009235406A (ja) 燃料油の酸化的脱硫
US20200318017A1 (en) Treatment Method for Reducing Contaminating Agents in Liquid Mixtures of Substituted Hydrocarbons Used as Fuels
CN104830381B (zh) 一种cfmv车用清洁燃料及制备方法
Ahmad et al. Desulfurization of oils; produced from pyrolysis of scrap tires
Dyachkova et al. Chemical preparation of samples of dead automobile catalyzers for subsequent determination of platinum, palladium, and rhodium using atomic emission spectrometry with inductively coupled plasma
Jamolovich et al. Modern methods of reducing the content of aromatic hydrocarbons in gasoline
Mohammed et al. Desulfurization of diesel fuel by oxidation and solvent extraction
Sun et al. Organic pollutant removal from marine diesel engine off-gases under electron beam and hybrid electron beam and wet scrubbing process
US8888994B2 (en) Method for deep desulphurization of hydrocarbon fuels
Shishov et al. Ultrasound Assistant Deep-Eutectic-Solvent-Based Liquid–Liquid Microextraction for the Determination of Transesterification Catalyst in Biodiesel Samples
Vorobiev et al. The Unique Composition and Stability of Water-Fuel Emulsion
Kolhe et al. Desulphurization of Jet Fuel using Merox Process: A Review
TWI398512B (zh) 複合燃料乳劑，及該乳劑與水乳化所製備之複合燃料乳液，以及該乳劑及該乳液之製備方法及其應用
JPS60169660A (ja) デイ−ゼルエンジン燃料の燃焼性改良方法
Piccinin Catalytic application of carbon nanotubes obtained from plastic solid waste in the removal of quinoline from isooctane by selective oxidation with hydrogen peroxide

Legal Events

Date Code Title Description
STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION