US20180236600A1 - Methods for joining two blanks and blanks and products obtained - Google Patents

Methods for joining two blanks and blanks and products obtained Download PDF

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Publication number
US20180236600A1
US20180236600A1 US15/954,329 US201815954329A US2018236600A1 US 20180236600 A1 US20180236600 A1 US 20180236600A1 US 201815954329 A US201815954329 A US 201815954329A US 2018236600 A1 US2018236600 A1 US 2018236600A1
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Prior art keywords
laser beam
blank
spot
blanks
spots
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US15/954,329
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Inventor
Elisenda VILA I FERRER
Pedro RUBIO
Mireia ILLANA GREGORI
Antoine RIQUELME
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Autotech Engineering SL
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Autotech Engineering SL
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Application filed by Autotech Engineering SL filed Critical Autotech Engineering SL
Assigned to AUTOTECH ENGINEERING A.I.E. reassignment AUTOTECH ENGINEERING A.I.E. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ILLANA GREGORI, Mireia, Vila I Ferrer, Elisenda, RIQUELME, Antoine, RUBIO, Pedro
Publication of US20180236600A1 publication Critical patent/US20180236600A1/en
Assigned to AUTOTECH ENGINEERING S.L. reassignment AUTOTECH ENGINEERING S.L. CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: AUTOTECH ENGINEERING A.I.E.
Priority to US16/748,235 priority Critical patent/US20200156185A1/en
Priority to US18/201,646 priority patent/US20230294202A1/en
Abandoned legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00—Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/06—Shaping the laser beam, e.g. by masks or multi-focusing
    • B23K26/0604—Shaping the laser beam, e.g. by masks or multi-focusing by a combination of beams
    • B23K26/0608—Shaping the laser beam, e.g. by masks or multi-focusing by a combination of beams in the same heat affected zone [HAZ]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00—Working by laser beam, e.g. welding, cutting or boring
    • B23K26/20—Bonding
    • B23K26/21—Bonding by welding
    • B23K26/211—Bonding by welding with interposition of special material to facilitate connection of the parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00—Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/06—Shaping the laser beam, e.g. by masks or multi-focusing
    • B23K26/067—Dividing the beam into multiple beams, e.g. multifocusing
    • B23K26/0676—Dividing the beam into multiple beams, e.g. multifocusing into dependently operating sub-beams, e.g. an array of spots with fixed spatial relationship or for performing simultaneously identical operations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00—Working by laser beam, e.g. welding, cutting or boring
    • B23K26/20—Bonding
    • B23K26/21—Bonding by welding
    • B23K26/24—Seam welding
    • B23K26/26—Seam welding of rectilinear seams
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0222—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in soldering, brazing
    • B23K35/0233—Sheets, foils
    • B23K35/0238—Sheets, foils layered
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • B23K35/0261—Rods, electrodes, wires
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24—Selection of soldering or welding materials proper
    • B23K35/28—Selection of soldering or welding materials proper with the principal constituent melting at less than 950 degrees C
    • B23K35/282—Zn as the principal constituent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24—Selection of soldering or welding materials proper
    • B23K35/28—Selection of soldering or welding materials proper with the principal constituent melting at less than 950 degrees C
    • B23K35/286—Al as the principal constituent
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2101/00—Articles made by soldering, welding or cutting
    • B23K2101/18—Sheet panels
    • B23K2101/185—Tailored blanks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2101/00—Articles made by soldering, welding or cutting
    • B23K2101/34—Coated articles, e.g. plated or painted; Surface treated articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00—Materials to be soldered, welded or cut
    • B23K2103/02—Iron or ferrous alloys
    • B23K2103/04—Steel or steel alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00—Materials to be soldered, welded or cut
    • B23K2103/08—Non-ferrous metals or alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00—Materials to be soldered, welded or cut
    • B23K2103/08—Non-ferrous metals or alloys
    • B23K2103/10—Aluminium or alloys thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00—Working by laser beam, e.g. welding, cutting or boring
    • B23K26/0093—Working by laser beam, e.g. welding, cutting or boring combined with mechanical machining or metal-working covered by other subclasses than B23K
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite

Definitions

  • the present disclosure relates to methods for joining two blanks, and methods for obtaining products after joining two blanks.
  • the present disclosure further relates to products obtained by or obtainable by any of these methods.
  • ultra-high-strength steels which exhibit an optimized maximal strength per weight unit and advantageous formability properties.
  • These steels are designed to attain a microstructure after heat treatment, which confers good mechanical properties and makes them especially suited for the hot stamping process used to form steel blanks into particular automobile parts. Since during the hot stamping process the blank is subjected to aggressive atmospheres, the steel is usually coated to avoid corrosion and oxidation.
  • components may be made of a composite metal blank which is obtained by welding several blanks with optionally different thicknesses, different materials, size and properties. At least theoretically, using this kind of technique the use of material may be optimized. Blanks of different thickness may be joined or a steel blank may be joined with a blank of a different material for example, using the specific properties of each material where they are needed.
  • Tailored welded blanks may be used for structural components such as doors, B-Pillars, beams, floor, bumpers, etc.
  • 22MnB5 steel An example of steel used in the automotive industry is 22MnB5 steel.
  • the composition of 22MnB5 is summarized below in weight percentages (rest is iron (Fe) and impurities):
  • the 22MnB5 may contain approximately 0.23% C, 0.22% Si, and 0.16% Cr.
  • the material may further comprise Mn, Al, Ti, B, N, Ni in different proportions.
  • UHSS Various other steel compositions of UHSS may also be used in the automotive industry. Particularly, the steel compositions described in EP 2 735 620 A1 may be considered suitable. Specific reference may be had to table 1 and paragraphs 0016-0021 of EP 2 735 620, and to the considerations of paragraphs 0067-0079. In some examples the UHSS may contain approximately 0.22% C, 1.2% Si, and 2.2% Mn.
  • Steel of any of these compositions may be supplied with a coating in order to prevent corrosion and oxidation damage.
  • This coating may be e.g. an aluminum-silicon (AlSi) coating or a coating mainly comprising zinc or a zinc alloy.
  • Patchwork blanks and tailored blanks may also be used or useful in other industries.
  • Usibor® 1500P is supplied in a ferritic-perlitic condition.
  • the mechanical properties are related to this structure. After heating, hot stamping, and subsequent rapid cooling (quenching), a martensitic microstructure is obtained. As a result, maximal strength and yield strength increase noticeably.
  • Usibor® 1500P may be supplied with an aluminum-silicon (AlSi) coating in order to prevent corrosion and oxidation damage.
  • AlSi aluminum-silicon
  • this coating has a significant effect related to its weld behavior. If Usibor® 1500P blanks are welded without any further measures, aluminum of the coating may enter into the weld area and this can cause an important reduction of the mechanical properties of the resulting component and increase the possibility of fracture in the weld zone.
  • US20080011720 proposes a process for laser welding at least one metal workpiece by a laser beam, said workpiece having a surface containing aluminum, characterized in that the laser beam is combined with at least one electric arc so as to melt the metal and weld said workpiece(s).
  • the laser in front of the arc allows the use of a flux-cored wire or the like containing elements inducing the gamma-phase (Mn, Ni, Cu, etc,) favourable to maintaining an austenitic structure throughout the melted zone.
  • the filler material may not distribute homogeneously in the welding zone. This may cause material accumulation (“bumps”) in certain areas thus affecting locally the behaviour of the welding zone. That is, the mechanical properties of the welding zone may vary.
  • Another problem may be that the filler material may need to be preheated before applied because the electric arc may not be capable of melting it otherwise.
  • a blank may be regarded as an article which has yet to undergo one or more processing steps (e.g. deformation, machining, surface treatment or other).
  • processing steps e.g. deformation, machining, surface treatment or other.
  • These articles may be substantially flat plates or have more complicated shapes.
  • the invention provides a method for joining a first blank and a second blank, at least one of the first and second blanks comprising at least a layer of aluminum, of an aluminum alloy, of zinc or of a zinc alloy.
  • the method comprises selecting a first portion of the first blank to be joined to the second blank, and selecting a second portion of the second blank to be joined to the first portion, melting the first portion to the second portion, while supplying a filler wire to a weld zone using a first and a second laser beams.
  • the first laser beam melts the filler wire in the weld zone during welding, and the first portion and the second portion of the blanks are melted and mixed with the melted filler wire using the second laser beam.
  • the characteristics of the beams may be the power of the laser beam or the dimension of the spots.
  • the filler wire may require a different power to melt than the portions of the blanks.
  • Another example may be the width of the weld zone compared with the size of the filler wire; each one may require a different spot size.
  • the Marangoni effect (also called the Gibbs-Marangoni effect) is the mass transfer along an interface between two fluids due to surface tension gradient.
  • the Marangoni effect is a fluid flow created in the “weld pool” due to a temperature distribution in the weld pool.
  • the surface tension is dependent on temperature and therefore, these temperature differences create a surface tension gradient on the surface of the weld pool. That is, the melted part of the substrate and the melted part of the filler material that are closer to the surface—and are therefore hotter—will be drawn from the region of lower surface tension (higher temperature) to the region of higher surface tension (lower temperature).
  • a fluid flow (fluid being the melted part of the substrate and the melted part of the filler—reinforcement—material) is created in such a way that the height distribution and the penetration of the filler material in the welding zone is increased.
  • the fluid flow may resemble a spiraling downward movement from the upper hotter layers of the welding zone towards its lower cooler layers.
  • using the second laser beam may comprise displacing the second laser beam in an oscillating manner to mix the first portion and the second portion of the blanks with the melted filler wire.
  • the oscillating movement of the laser beam may cause the materials in the weld pool to mix more homogeneously as a result (or in part as a result) of the Marangoni effect.
  • Such an oscillating movement may comprise different beam motions such as a spiraling or circular movement around a central point, a wobbling movement or a weaving (zig-zag) movement along the weld direction, or a combination thereof.
  • using the second laser beam may comprise generating a twin-spot to melt the first portion and the second portion and to mix the first portion and the second portion of the blanks with the melted filler wire.
  • Two sub-beams may be generated with twin-spot laser optics, each sub-beam generating one of the two spots of the twin-spot.
  • the use of a twin-spot may also mix the materials in the weld pool more homogeneously, again (partially) as a result of the Marangoni effect.
  • the first laser beam used for melting the filler wire may have a spot having a size corresponding (e.g. equal or greater) to the filler wire diameter. Therefore, it may accurately and precisely concentrate all its energy for the purpose of melting the filler wire.
  • the second laser beam used for melting the first portion to the second portion and for mixing the melted filler wire may generate a spot or a twin-spot having a size corresponding to a size of the weld zone. More specifically, in case of a single spot, a size (e.g. width) of the weld zone may be equal or greater than the size of the spot. In case of a twin-spot, a size (e.g.
  • the width of the weld zone may be equal or greater to the aggregate size of the two spots of the twin-spot.
  • the size of the weld zone may be a size of the desired welding. It may correspond to known tolerances of the blanks so that any gaps between the blanks to be appropriately filled during the welding.
  • the two laser beams may be generated by a single laser head. This may facilitate alignment and improve the speed of the welding.
  • the first laser beam may be generated by a first laser head and the second laser beam may be generated by a second laser head. This may allow for easier individual control of the beam characteristics (e.g. shape, power) of the two beams.
  • the two laser beams may generate spots arranged substantially in line with a welding direction.
  • the spot or spots generated by the second laser beam may precede or follow the spot of the first laser beam. Therefore, the first laser beam may generate one spot and the second laser beam may generate one or more spots, and the spots of the first and the second laser beam may be arranged substantially in line with a welding direction.
  • the spot of the first laser beam may be arranged before, after or between the spots of the twin-spot generated from the second laser beam.
  • the two spots of the twin-spot may be arranged perpendicularly to the welding direction.
  • the two spots of the twin-spot may be arranged collinearly to the welding direction.
  • the two spots of twin-spot of the second laser beam may precede or follow the spot of the first laser beam.
  • the spot of the first laser beam may be arranged collinearly between the spots of the twin-spots.
  • the two spots of the twin-spot of the second laser beam may precede or follow the spot of the first laser beam.
  • the spot of the first laser beam may be arranged collinearly between the spots of the twin-spots.
  • the choice of spot arrangement may depend on the characteristics of the coating, the filler material, the desired welding or of a combination thereof.
  • the first and second blanks might be butt-jointed
  • the first portion might be an edge of the first blank
  • the second portion might be the edge of the second blank.
  • a square butt-joint (without machining or beveling of the edges) may be used.
  • a closed square butt weld may be used.
  • the first and/or the second blank comprises a steel substrate with a coating comprising the layer of aluminum or of an aluminum alloy or the layer of zinc or of a zinc alloy.
  • steel substrate of the first and/or the second blank might be an ultra-high strength steel, in particular a 22MnB5 steel.
  • a method for forming a product comprises forming a blank including a method of joining a first and a second blank according to any of the methods described herein, heating the blank, and hot deforming and subsequent quenching of the heated blank.
  • Nd-YAG Neodymium-doped yttrium aluminum garnet
  • CO2 laser with sufficient power
  • Nd-YAG lasers are commercially available, and constitute a proven technology. This type of laser may also have sufficient power to melt the portions (together with the arc) of the blanks and allows varying the width of the focal point of the laser and thus of the weld zone. Reducing the size of the “spot” increases the energy density.
  • the filler wire used may comprise gammagenic elements to stabilize the austenitic phase. Austenitic stabilizing elements counteract the ferrite stabilizing effect of Al or Zn, thus minimizing (or avoiding) ferrite in the final weld joint.
  • aluminum (or zinc) may be present in the weld zone, but it does not lead to worse mechanical properties after hot deformation processes such as hot stamping when the filler wire comprises gammagenic elements, which stabilizes the austenitic phase.
  • austenite gamma phase iron, ⁇ -Fe
  • austenite gamma phase iron, ⁇ -Fe
  • Gammagenic elements are herein to be understood as chemical elements promoting the gamma-phase, i.e. the austenite phase.
  • the gammagenic elements may be selected from a group comprising Nickel (Ni), Carbon (C), Manganese (Mn), Copper (Cu) and Nitrogen (N).
  • ferrite stabilizer elements may counteract the action of “austenitic stabilizer elements”, optionally these “ferrite stabilizer elements” can still be suitable components when other factors are also taken into account for the composition of the filler.
  • Molybdenum (Mo) could be a suitable element and e.g. for corrosion resistance Silicon (Si) and Chromium (Cr) could be suitable components.
  • Aluminum alloys are herein to be understood as metal alloys in which aluminum is the predominant element.
  • Zinc alloys are herein to be understood as metal alloys in which zinc is the predominant element.
  • the amount of gammagenic elements in the filler wire is sufficient to compensate for the presence of alphagenic elements such as Cr, Mo, Si, Al and Ti (Titanium).
  • alphagenic elements such as Cr, Mo, Si, Al and Ti (Titanium).
  • Alphagenic elements promote the formation of alpha-iron (ferrite). This may lead to reduced mechanical properties as the microstructure resulting after hot stamping and quenching may comprise martensite-bainite and ferrite.
  • the filler may contain a austenite stabilizing elements and may have a composition in weight percentages of 0%-0.3% of carbon, 0%-1.3% of of silicon, 0.5%-7% of manganese, 5%-22% of chromium, 6%-20% of nickel, 0%-0.4% of molybdenum, 0%-0.7% of Niobium, and the rest iron and unavoidable impurities.
  • the metal filler material may be stainless steel AlSi 316L, as commercially available from e.g. Hoganäs®.
  • the metal filler may have the following composition in weight percentages: 0%-0.03% carbon, 2.0-3.0% of molybdenum, 10%-14% of nickel, 1.0-2.0% of manganese, 16-18% chromium, 0.0-1.0% of silicon, and the rest iron and unavoidable impurities.
  • 431L HC as commercially available from e.g. Hoganäs® may be used.
  • This metal filler has the following composition in weight percentages: 70-80% of iron, 10-20% of chromium, 1.0-9.99% of nickel, 1-10% of silicon, 1-10% of manganese and the rest impurities.
  • the filler has the following composition in weight percentages: 2.1% carbon, 1.2% of silicon, 28% of chromium, 11.5% of nickel, 5.5% of molybdenum, 1% of manganese and the rest iron and impurities.
  • the filler may incorporate any component providing higher or lower mechanical characteristics depending on circumstances.
  • the present disclosure provides a method for forming a product comprising forming a blank including a method of joining a first and a second blank in accordance with any of the herein described welding methods and subsequently heating the blank, and hot deforming of the heated blank and final quenching.
  • Heating may include heat treatment in a furnace prior to deformation.
  • Hot deforming may include e.g. hot stamping or deep drawing.
  • FIGS. 1 a -1 d schematically illustrate examples of joining two blanks
  • FIGS. 2 a -2 c schematically illustrate example arrangements for a welding laser beam and a filler wire melting beam according to various implementations.
  • FIGS. 3 a -3 f schematically illustrate relative positions of welding laser beams and filler wire melting beams.
  • FIG. 4 is a flow diagram of a method of joining blanks.
  • FIGS. 1 a -1 d schematically illustrate examples of methods of joining blanks.
  • a first portion or region A 1 of a first blank A is to be joined to a second portion or region B 2 of a second blank B.
  • the two blanks are to be butt-joined, i.e. an edge-to-edge welding, specifically with straight edges (without special shaping/bevelling of the edges).
  • both blanks A and B may be of coated steel, such as e.g. Usibor® 1500P. Both blanks may comprise a steel substrate 1 upon which a coating 2 may be provided.
  • the coating applied in this example is aluminum-silicon (Al187Si10Fe3). Due to the process of application of the coating, the resulting coating may have a metal alloy layer 4 and an intermetallic layer 3 as illustrated in FIG. 1 b - 1 d.
  • FIGS. 1 b -1 d schematically illustrate a cross-sectional view along the plane defined by the line x-y and the corresponding top view according to some examples of dual laser welding.
  • Such plane defined by the line x-y corresponds to the welding beam C, i.e. the line where the edge of blank A contacts the edge of blank B.
  • blanks A and B may comprise a steel substrate 1 with a coating 2 , which may have a metal alloy layer 4 as the outermost layer and an intermetallic layer 3 arranged between the steel substrate 1 and the metal alloy layer 4 .
  • the coating layer and the steel substrate of the welded portions of blanks A and B, and the filler are mixed in the welding beam.
  • the welding beam does not comprise a defined coating layer.
  • the arrow WD indicates the welding direction in the top view.
  • FIG. 1 b further illustrates a cross-sectional view along the plane defined by the line x-y and the corresponding top view of the method of joining according to an example of dual laser welding.
  • a cross-sectional and top view of a filler metal melting laser 20 having a laser head 21 from which a first laser beam Ll exits.
  • a filler wire 25 may be used as welding material.
  • a laser welder 30 having a laser head 31 from which a second laser beam L 2 exits.
  • the first laser beam L 1 (directly) melts the filler wire.
  • the second laser beam L 2 melts portions of the blanks in a weld pool substantially where the two blanks are to be welded.
  • the melted filler wire is directed in the—common—weld pool and at the same time the melted filler wire mixes with the melted portions of the blanks. As the filler wire melts, any gap between the blanks may be filled and a weld may be created.
  • FIG. 1 b further illustrates a top view of the weld zone 40 created in the zones to be welded of the blanks A and B.
  • Laser beam spot S 1 corresponds to the spot created by the first laser beam L 1
  • laser beam spot S 2 corresponds to the spot created by the second laser beam L 2 .
  • the second laser beam L 2 the laser welder beam
  • the laser welder beam may be moveable in a wobbling manner to mix the material in the weld pool as a consequence of the Marangoni effect.
  • the melted portion of the blanks comprises steel substrate material as well as coating material
  • mixing the weld pool ingredients may avoid any harmful effects attributable to the Al alloy coating and, therefore, mechanical properties of the welded zone may not be affected.
  • a filler wire of suitable composition may ensure that good mechanical properties are obtained after the standard heat treatment for Usibor® and after hot deformation processes such as hot stamping.
  • a standard treatment for Usibor® blanks would be to heat the obtained blank in e.g. a furnace to bring about (among others) austenization of the base steel. Then the blank may be hot stamped to form e.g. a bumper beam or a pillar. During rapid cooling after a hot deformation, martensite which gives satisfactory mechanical characteristics may thus be obtained.
  • the standard treatment is not affected in any manner by the methods of joining proposed herein.
  • a suitable filler wire i.e. filler wire with gammagenic elements
  • a martensite structure can also be obtained in the area of the weld, in spite of the presence of aluminum.
  • FIG. 1 c further illustrates a cross-sectional view along the plane defined by the line x-y and the corresponding top view of a method of joining two blanks according to another example of dual laser welding.
  • a filler metal melting laser 20 having a laser head 21 from which a first laser beam L 1 exits.
  • a filler wire 25 may be used as welding material.
  • a laser welder 30 having a laser head 31 from which two sub-beams L 2 a and L 2 b exit.
  • the laser head 31 may comprise twin-spot laser optics.
  • the laser beams also collaborate to form a weld zone 40 .
  • the first laser beam L 1 melts the filler wire 25 similarly as in the example discussed with reference to FIG. 1 b .
  • the two sub-beams, L 2 a and L 2 b generate a twin-spot that melts portions of the blanks in a weld pool substantially where the two blanks are to be welded.
  • the melted filler wire is directed in the—common—weld pool and at the same time the melted filler wire mixes with the melted portions of the blanks.
  • the twin-spot may warrant the mixing of the melted filler wire material with the melted portions of the blanks without any wobbling of any of the sub-beams L 2 a and L 2 b to be required.
  • FIG. 1 c further illustrates a top view of the weld zone 40 created in the zones to be welded of the blanks A and B.
  • Laser beam spot S 1 corresponds to the spot created by the first laser beam L 1
  • laser beam spot S 2 a and S 2 b corresponds to the spots created by the sub-beams L 2 a and L 2 b respectively.
  • FIG. 1 d represents a variation of the example of FIG. 1 b , having a single laser head 51 and a single laser melting the wire and welding.
  • the melting and welding laser 50 has a single laser head 51 from which a first laser beam L 1 and a second laser beam L 2 exit.
  • FIG. 2 a schematically illustrates a top view of a method of joining two blanks according to an example.
  • a first blank A is to be joined to a second blank B along a weld seam C, wherein a first laser beam spot S 1 may be responsible for melting a filler wire 25 material in the weld seam C zone and a second laser beam spot S 2 may be responsible for melting a portion of the first blank A and a portion of the second blank B as well as mix the melted filler wire material with the melted portions of the blanks.
  • the perforated line circles indicate the circular movement of the second laser beam in order to homogeneously mix the melted materials.
  • FIG. 2 b schematically illustrates a weaving movement of the laser beam spot S 2 while FIG. 2 c schematically illustrates a wobbling movement of the laser beam spot S 2 . The selection of movement may depend on weld zone characteristics.
  • FIGS. 3 a -3 f schematically illustrate the relative positions of the spots generated from the first and second laser beams when a twin-spot laser beam is used for melting the portions of the blanks and for mixing the melted portions of the blanks with the melted filler wire.
  • the arrow indicates the welding direction.
  • the three spots are arranged collinearly along the welding direction.
  • the spots S 2 a and S 2 b of the twin-spot precede the spot of the filler wire melting beam.
  • the spot of the filler wire melting beam S 1 precedes the spots S 2 a and S 2 b of the twin-spot.
  • the spot S 1 of the filler wire melting beam is interpolated between the two spots S 2 a and S 2 b of the twin-spot.
  • the spots S 2 a and S 2 b of the twin-spot precede the spot S 1 of the filler wire melting beam.
  • the two spots of the twin-spot are arranged perpendicularly to the welding direction.
  • the two spots S 2 a and S 2 b of the twin-spot are arranged also perpendicularly to the welding direction, but, contrary to the arrangement of FIG. 3 d , they follow the spot S 1 of the filler wire melting beam.
  • the three spots are arranged along a direction perpendicular to the welding direction where the spot S 1 of the filler wire melting beam is interpolated between the two spots S 2 a and S 2 b of the twin-spot.
  • the two spots may also induce or improve a similar Marangoni effect and the elements of the welding zone may again be homogeneously distributed with the austenite stabilizing elements in the filler reaching the bottom part of the weld. Therefore, the aluminum may not lead to worse mechanical properties in the welding zone after hot deformation processes such as hot stamping.
  • the percentage of ferrite and austenite depends on the amount of aluminum. Adding these austenite stabilizing stainless filler materials may increase the mass content of aluminum necessary for starting the ferrite phase. In other words, thanks to the filler, more aluminum may be allowed in the weld area while still maintaining the desired mechanical properties, i.e. while still ensuring the presence of austenite. Thus, the influence of the aluminum in the welding area may be minimized and a weld joint with good mechanical properties may be obtained.
  • FIG. 4 is a flow diagram of a method of joining blanks according to an example.
  • a first portion of a first blank to be joined to a second blank may be selected.
  • the first blank may comprise at least a layer of aluminum or of an aluminum alloy or a layer of zinc or of a zinc alloy.
  • the first blank might comprise a steel substrate with a coating comprising the layer of aluminum or of an aluminum alloy or the layer of zinc or of a zinc alloy.
  • the steel substrate may be an ultra-high strength steel, in particular the steel may be a boron steel.
  • a second portion of a second blank to be joined to the first portion may be selected.
  • the second blank may also comprise at least a layer of aluminum or of an aluminum alloy or a layer of zinc or of a zinc alloy.
  • the second blank might comprise a steel substrate with a coating comprising the layer of aluminum or of an aluminum alloy or the layer of zinc or of a zinc alloy.
  • the steel substrate may be an ultra-high strength steel and in particular a boron steel.
  • the first portion and the second portion of the blanks may be melted in a weld zone.
  • a filler wire may be supplied and melted to the weld zone using a filler wire melting laser beam.
  • the filler wire melting laser beam corresponds to a first laser beam.
  • Such first laser beam is arranged to melt the filler wire in the weld zone.
  • the laser welding beam may correspond to a second laser beam. Using such second laser beam may comprise displacing the second laser beam in an oscillating manner or using a twin-spot laser.
  • the melted portions of the blanks and the melted filler wire are mixed in the weld zone to produce a weld.
  • the filler along the whole weld zone, i.e. along the whole thickness of the blanks, mechanical properties of the weld can be improved.

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US15/954,329 2015-12-18 2018-04-16 Methods for joining two blanks and blanks and products obtained Abandoned US20180236600A1 (en)

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EP3347158B1 (en) 2019-04-03
EP3347158B8 (en) 2019-06-12
US20200156185A1 (en) 2020-05-21
MX2018007372A (es) 2019-05-16
CA3003221A1 (en) 2017-06-22
US20230294202A1 (en) 2023-09-21
ES2896327T3 (es) 2022-02-24
KR102704154B1 (ko) 2024-09-09
JP2018537288A (ja) 2018-12-20
EP3536438A1 (en) 2019-09-11
ES2730939T3 (es) 2019-11-13
WO2017103149A1 (en) 2017-06-22
RU2018118408A3 (ja) 2020-02-14

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