US20160340618A1 - Compositions and methods for removing soil from surfaces - Google Patents

Compositions and methods for removing soil from surfaces Download PDF

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Publication number
US20160340618A1
US20160340618A1 US15/227,729 US201615227729A US2016340618A1 US 20160340618 A1 US20160340618 A1 US 20160340618A1 US 201615227729 A US201615227729 A US 201615227729A US 2016340618 A1 US2016340618 A1 US 2016340618A1
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United States
Prior art keywords
composition
rinse aid
detergent
catalyst
oxygen source
Prior art date
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Abandoned
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US15/227,729
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English (en)
Inventor
Tobias Neil Foster
Dirk Kullwitz
Beana Pathicheril
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Ecolab USA Inc
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Ecolab USA Inc
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Application filed by Ecolab USA Inc filed Critical Ecolab USA Inc
Publication of US20160340618A1 publication Critical patent/US20160340618A1/en
Assigned to ECOLAB USA INC. reassignment ECOLAB USA INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: PATHICHERIL, BEANA, KULLWITZ, DIRK, FOSTER, Tobias Neil
Priority to US17/305,888 priority Critical patent/US11566207B2/en
Priority to US18/068,268 priority patent/US12221594B2/en
Priority to US19/015,066 priority patent/US20250223522A1/en
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04—Cleaning involving contact with liquid
    • B08B3/041—Cleaning travelling work
    • B08B3/042—Cleaning travelling work the loose articles or bulk material travelling gradually through a drum or other container, e.g. by helix or gravity
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D11/0023—
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/168—Organometallic compounds or orgometallic complexes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C11D3/3917—Nitrogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3945—Organic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

Definitions

  • Removing food soils with respect to the exemplary example of removing starch soils comprises both the removal of starch from ware and the prevention of the build-up of starch layers on ware.
  • the objective of starch removal is met by using a highly caustic detergent, while preventing the built-up of starch layers by spraying a highly alkaline solution or an acid directly onto the ware. This kind of procedure is known under the expression X-Streamclean technology.
  • WO 2012/107187 A1 describes the use of manganese or iron complexes in washing and cleaning compositions in the form of granules or powder or solution or suspension for bleaching of coloured stains on hard surfaces, such as for dishwashing detergents.
  • a detergent may further comprise hydrogen peroxide.
  • the detergent mixture for forming the composition may comprise at least
  • the aqueous composition which is formed from a detergent mixture with a peroxidation catalyst and rinse aid with an oxygen source may provide the advantage of significantly improving removal of soil and particularly removing of starch containing soil with short washing times, an easy and cost-saving procedure, and an environmentally friendly oxidizing system based on oxygen.
  • the compositions of the present invention particularly provide an improved cleaning performance.
  • a method for removing soil from a surface to be cleaned comprises applying to the surface to be cleaned a composition like described above. Therefore, the method mainly comprises the step of providing a composition according to the invention optionally having one or more of the afore-mentioned optional features and applying this composition to the surface to be cleaned. Accordingly, the peroxidation catalyst is provided in a detergent mixture and the oxygen source is provided in a rinse fluid, wherein the detergent mixture and the rinse fluid are added to water, this mixture coming in contact with the surface to be cleaned.
  • cleaning and particularly “washing” refers to a method or process used to facilitate or aid in soil removal, bleaching, microbial population reduction, and any combination thereof.
  • the catalyzed degradation of food soil components in water can significantly be enhanced, such as the removal from even baked starch from plates.
  • the oxygen source is thereby particularly advantageous for allowing a superb performance of the peroxidation catalyst thereby degrading food soil under alkaline conditions.
  • the composition is thereby capable of degrading food soil components, reducing the formation of foam and further for reducing redeposition of soil on cleaned ware.
  • the composition in case the composition is in a steady state, it may be provided that fresh rinse aid is added subsequently, wherein the soiled ware is wetted with the composition and thus with catalyst.
  • This allows providing fresh rinse aid and thus fresh oxygen source and bringing this in contact directly on the surface of the ware. This allows an especially effective cleaning procedure such an especially effective starch degradation.
  • composition may be formed by using a single detergent that is highly effective against starch at a lowest possible alkalinity and without any third product sprayed directly onto the ware.
  • This may be particularly advantageous due to the reduced amount of required chemicals and thus reduced costs as well as reduced amount of time due to one step being omitted.
  • An additional benefit is the usage of the environmental friendly oxidizing system based on oxygen. Thereby it is referred to the reactivity of the oxygen source in contact with the catalyst in higher concentrations, for example providing both components at once. Without using a third component this challenge is addressed to.
  • inventive concept arose by providing a concept with bringing the catalyst into the sump by means of the detergent and oxygen source by the rinse aid.
  • surfaces to be cleaned include hard and soft surfaces, for example of upper outer and/or inner outer surfaces of materials such as ceramic, metal, plastic and/or glass, surface that came into contact with beverages and/or food, beverages such alcoholic or non-alcoholic beverages such as beer or milk, food such as meat, vegetables and/or grain-products, coffee tea and particularly starch containing beverages and/or food.
  • beverages such as alcoholic or non-alcoholic beverages such as beer or milk
  • food such as meat, vegetables and/or grain-products, coffee tea and particularly starch containing beverages and/or food.
  • oxygen source refers to any composition capable of generating oxygen especially in situ and in a soil, as well as in solution.
  • the active oxygen source is a compound capable of providing oxygen in situ on and in the soil upon contact with the peroxidation catalyst.
  • the compound may be organic, or inorganic.
  • amino alcohols include 2-amino-2-methyl-1-propanol, 2-amino-1-butanol, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-ethyl-1,3-propanediol, hydroxymethyl aminomethane, and the like.
  • Savinase® a protease derived from Bacillus lentus type, such as Maxacal®, Opticlean®, Durazym®, and Properase®
  • a protease derived from Bacillus licheniformis such as Alcalase®
  • Detersive proteases are described in patent publications including: GB 1,243,784, WO 9203529 A (enzyme/inhibitor system), WO 9318140 A, and WO 9425583 (recombinant trypsin-like protease) to Novo; WO 9510591 A, WO 9507791 (a protease having decreased adsorption and increased hydrolysis), WO 95/30010, WO 95/30011, WO 95/29979, to Procter & Gamble; WO 95/10615 ( Bacillus amyloliquefaciens subtilisin) to Genencor International; EP 130,756 A (protease A); EP 303,761 A (protease B); and EP 130,756 A.
  • cellulase enzymes examples include those sold under the trade names Carezyme® or Celluzyme® by Novo; under the tradename Cellulase by Genencor; under the tradename Deerland Cellulase 4000 or Deerland Cellulase TR by Deerland Corporation; and the like. A mixture of cellulases can also be used.
  • Suitable zwitterionic surfactants include, for example, betaines, imidazolines, and propinates.
  • a potassium hydroxide having a concentration of from about 1 to about 50 wt % can be used.
  • the phosphonic acid can be dissolved or suspended in an aqueous medium and the potassium hydroxide can then be added to the phosphonic acid for neutralization purposes.
  • the concentrated detergent composition may include the water conditioning polymer in an amount of 0.1 to 20% by weight based on the total weight of the concentrated detergent composition, preferably 0.2 to 5% by weight.
  • the composition can include an anti-redeposition agent for facilitating sustained suspension of soils in a cleaning solution and preventing the removed soils from being redeposited onto the substrate being cleaned.
  • suitable anti-redeposition agents include fatty acid amides, fluorocarbon surfactants, complex phosphate esters, styrene maleic anhydride copolymers, and cellulosic derivatives such as hydroxyethyl cellulose, hydroxypropyl cellulose, and the like.
  • the anti-redeposition agent can be included in an amount of 0.5 to 10% by weight based on the total weight of the concentrated detergent composition, preferably 1 to 5% by weight.
  • the components used to form the concentrated detergent composition can include an aqueous medium such as water as an aid in processing. It is expected that the aqueous medium will help provide the components with a desired viscosity for processing. In addition, it is expected that the aqueous medium may help in the solidification process when is desired to form the concentrated detergent composition as a solid.
  • the concentrated detergent composition When the concentrated detergent composition is provided as a solid, it can, for example, be provided in the form of a block or pellet. It is expected that blocks will have a size of at least about 5 grams, and can include a size of greater than about 50 grams. It is expected that the concentrated detergent composition will include water in an amount of 1 to 50% by weight based on the total weight of the concentrated detergent composition, preferably 2 to 20% by weight.
  • the components that are processed to form the concentrated detergent composition are processed into a block, it is expected that the components can be processed by a solidification technique. Then talk about the overall water range that we would expect for the solidification processes, which is 0.001%-40%.
  • a surfactant or mixture of surfactants may be used.
  • the surfactant chosen may be compatible with the surface to be cleaned.
  • a variety of surfactants may be used, including anionic, nonionic, cationic, and zwitterionic surfactants, which are commercially available from a number of sources.
  • Suitable surfactants include nonionic surfactants, for example, low foaming non-ionic surfactants.
  • the composition comprises at least one surfactant selected from the group comprising of a anionic surfactant and/or a non-ionic surfactant, preferably the surfactant can be selected from the group comprising of linear alkyl benzene sulfonates, alcohol sulfonates, amine oxides, alcohol ethoxylates, alkyl phenol ethoxylates, polyethylene glycol esters, EO/PO block copolymers, aminoxides, alkylbenzensulfonates, sodiumlaurylethersulfates and mixtures thereof and most preferred the surfactant can be selected from the group comprising of aminoxides, alkylbenzensulfonates, sodiumlaurylethersulfates and mixtures thereof.
  • the surfactant can be selected from the group comprising of aminoxides, alkylbenzensulfonates, sodiumlaurylethersulfates and mixtures thereof.
  • the level and degree of foaming under the conditions of use and in subsequent recovery of the composition may be a factor for selecting particular surfactants and mixtures of surfactants. For example, in certain applications it may be desirable to minimize foaming and a surfactant or mixture of surfactants that provides reduced foaming may be used. In addition, it may be desirable to select a surfactant or a mixture of surfactants that exhibits a foam that breaks down relatively quickly so that the composition may be recovered and reused with an acceptable amount of down time. In addition, the surfactant or mixture of surfactants may be selected depending upon the particular soil that is to be removed.
  • suitable penetrants include, but are not limited to, alcohols, short chain ethoxylated alcohols and phenol (having 1-6 ethoxylate groups).
  • Organic solvents are also suitable penetrants.
  • suitable organic solvents, for use as a penetrant include esters, ethers, ketones, amines, and nitrated and chlorinated hydrocarbons.
  • the method for cleaning surfaces to be cleaned by using the composition as defined above in detail may comprise the following steps when using it in a dish washer:
  • the steady state concentration of a peroxide containing rinse aid in the sump is sufficient to lead the peroxidation catalyst to achieve catalyzed removal of soils from surfaces such as starch from plates.
  • the steady state, or cyclic steady state particularly comprises a concentration of an oxygen source and a peroxidation catalyst being present after some, particularly after 50, cleaning cycles and thus steps a) to c) in the wash tank of a hood-type dish washer. Therefore, especially step c) is performed under conditions and thus concentrations of the cyclic steady stare.
  • the above method allows bringing this in contact directly on the surface of the ware, which in turn provides an especially effective cleaning procedure. Furthermore, due to the recycling of the washing solution by collecting it in a tank, the catalyst may be used for a huge amount of washing cycles minimizing the amount of catalyst used.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
US15/227,729 2013-10-24 2016-08-03 Compositions and methods for removing soil from surfaces Abandoned US20160340618A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US17/305,888 US11566207B2 (en) 2013-10-24 2021-07-16 Compositions and methods for removing soil from surfaces
US18/068,268 US12221594B2 (en) 2013-10-24 2022-12-19 Compositions and methods for removing soil from surfaces
US19/015,066 US20250223522A1 (en) 2013-10-24 2025-01-09 Compositions and methods for removing soil from surfaces

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2013/072302 WO2015058803A1 (en) 2013-10-24 2013-10-24 Compositions and methods for removing soils from surfaces

Related Parent Applications (2)

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PCT/EP2013/072302 Continuation WO2015058803A1 (en) 2013-10-24 2013-10-24 Compositions and methods for removing soils from surfaces
PCT/EP2013/072302 Continuation-In-Part WO2015058803A1 (en) 2013-10-24 2013-10-24 Compositions and methods for removing soils from surfaces

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US17/305,888 Division US11566207B2 (en) 2013-10-24 2021-07-16 Compositions and methods for removing soil from surfaces

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US15/227,729 Abandoned US20160340618A1 (en) 2013-10-24 2016-08-03 Compositions and methods for removing soil from surfaces
US17/305,888 Active 2036-08-06 US11566207B2 (en) 2013-10-24 2021-07-16 Compositions and methods for removing soil from surfaces
US18/068,268 Active 2033-11-28 US12221594B2 (en) 2013-10-24 2022-12-19 Compositions and methods for removing soil from surfaces
US19/015,066 Pending US20250223522A1 (en) 2013-10-24 2025-01-09 Compositions and methods for removing soil from surfaces

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US17/305,888 Active 2036-08-06 US11566207B2 (en) 2013-10-24 2021-07-16 Compositions and methods for removing soil from surfaces
US18/068,268 Active 2033-11-28 US12221594B2 (en) 2013-10-24 2022-12-19 Compositions and methods for removing soil from surfaces
US19/015,066 Pending US20250223522A1 (en) 2013-10-24 2025-01-09 Compositions and methods for removing soil from surfaces

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US (4) US20160340618A1 (enrdf_load_stackoverflow)
EP (3) EP4276163B1 (enrdf_load_stackoverflow)
JP (1) JP6254693B2 (enrdf_load_stackoverflow)
CN (1) CN105683350B (enrdf_load_stackoverflow)
AU (2) AU2013403675B2 (enrdf_load_stackoverflow)
BR (1) BR112016009177B1 (enrdf_load_stackoverflow)
CA (1) CA2928577C (enrdf_load_stackoverflow)
MX (1) MX395198B (enrdf_load_stackoverflow)
WO (1) WO2015058803A1 (enrdf_load_stackoverflow)

Cited By (2)

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US11028344B2 (en) * 2016-08-16 2021-06-08 Diversey, Inc. Composition for aesthetic improvement of food and beverage containers and methods thereof
US11406849B2 (en) * 2017-04-10 2022-08-09 Kao Corporation Amino alcohol-containing skin cleansing composition for removing keratotic plugs from skin

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CN113604290A (zh) 2015-08-21 2021-11-05 艺康美国股份有限公司 在固体漂洗助剂产品中的吡啶硫酮防腐剂体系
EP3710569A1 (en) 2017-11-14 2020-09-23 Ecolab USA Inc. Solid controlled release caustic detergent compositions
WO2021062143A1 (en) 2019-09-27 2021-04-01 Ecolab Usa Inc. Concentrated 2 in 1 dishmachine detergent and rinse aid
GB202103434D0 (en) * 2021-03-12 2021-04-28 Reckitt Benckiser Finish Bv Composition
CN114149875A (zh) * 2021-12-06 2022-03-08 广东舒洁环境科技有限公司 一种中性环保清洁剂及其制备方法
JP2023088527A (ja) * 2021-12-15 2023-06-27 株式会社クレオ 洗浄装置、洗浄液および洗浄方法

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