US20160318822A1 - Iron (III) Oxide Containing Soil-Binding Composition - Google Patents
Iron (III) Oxide Containing Soil-Binding Composition Download PDFInfo
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- US20160318822A1 US20160318822A1 US15/106,344 US201415106344A US2016318822A1 US 20160318822 A1 US20160318822 A1 US 20160318822A1 US 201415106344 A US201415106344 A US 201415106344A US 2016318822 A1 US2016318822 A1 US 2016318822A1
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- weight
- iron
- soil
- composition
- iii
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- 239000000203 mixture Substances 0.000 title claims abstract description 76
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 title claims abstract description 23
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims description 21
- 239000002689 soil Substances 0.000 claims abstract description 62
- 239000000463 material Substances 0.000 claims abstract description 28
- 235000010263 potassium metabisulphite Nutrition 0.000 claims abstract description 16
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 claims abstract description 14
- 229940043349 potassium metabisulfite Drugs 0.000 claims abstract description 14
- 239000000080 wetting agent Substances 0.000 claims abstract description 9
- 230000008635 plant growth Effects 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 20
- 229910052742 iron Inorganic materials 0.000 claims description 15
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 11
- 239000000600 sorbitol Substances 0.000 claims description 11
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 9
- 235000010356 sorbitol Nutrition 0.000 claims description 9
- 235000013379 molasses Nutrition 0.000 claims description 8
- 239000011859 microparticle Substances 0.000 claims description 7
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 6
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 claims description 6
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 6
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 6
- 239000001527 calcium lactate Substances 0.000 claims description 5
- 235000011086 calcium lactate Nutrition 0.000 claims description 5
- 229960002401 calcium lactate Drugs 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 230000003389 potentiating effect Effects 0.000 abstract description 3
- 230000002708 enhancing effect Effects 0.000 abstract description 2
- 239000004297 potassium metabisulphite Substances 0.000 abstract description 2
- 241000196324 Embryophyta Species 0.000 description 49
- 238000012360 testing method Methods 0.000 description 33
- 241000220259 Raphanus Species 0.000 description 18
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 15
- 230000000694 effects Effects 0.000 description 15
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 14
- 238000011282 treatment Methods 0.000 description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
- 240000008042 Zea mays Species 0.000 description 12
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 10
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 10
- 235000009973 maize Nutrition 0.000 description 10
- 230000035784 germination Effects 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- 238000010790 dilution Methods 0.000 description 7
- 239000012895 dilution Substances 0.000 description 7
- 230000002401 inhibitory effect Effects 0.000 description 7
- 244000046052 Phaseolus vulgaris Species 0.000 description 6
- 229960005191 ferric oxide Drugs 0.000 description 6
- 235000013980 iron oxide Nutrition 0.000 description 6
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- 239000012141 concentrate Substances 0.000 description 5
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- 244000005700 microbiome Species 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 4
- 241000209140 Triticum Species 0.000 description 4
- 235000021307 Triticum Nutrition 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000003906 humectant Substances 0.000 description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000011161 development Methods 0.000 description 3
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- 208000024891 symptom Diseases 0.000 description 3
- 230000004584 weight gain Effects 0.000 description 3
- 235000019786 weight gain Nutrition 0.000 description 3
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 2
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 2
- 240000008384 Capsicum annuum var. annuum Species 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
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- 150000001875 compounds Chemical class 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
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- 239000000835 fiber Substances 0.000 description 2
- 229960005150 glycerol Drugs 0.000 description 2
- -1 glycols Chemical class 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 150000002506 iron compounds Chemical class 0.000 description 2
- 159000000014 iron salts Chemical class 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 235000011056 potassium acetate Nutrition 0.000 description 2
- 229960004109 potassium acetate Drugs 0.000 description 2
- PHZLMBHDXVLRIX-UHFFFAOYSA-M potassium lactate Chemical compound [K+].CC(O)C([O-])=O PHZLMBHDXVLRIX-UHFFFAOYSA-M 0.000 description 2
- 239000001521 potassium lactate Substances 0.000 description 2
- 235000011085 potassium lactate Nutrition 0.000 description 2
- 229960001304 potassium lactate Drugs 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- 229960004249 sodium acetate Drugs 0.000 description 2
- 239000001540 sodium lactate Substances 0.000 description 2
- 235000011088 sodium lactate Nutrition 0.000 description 2
- 229940005581 sodium lactate Drugs 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 2
- FOGYNLXERPKEGN-UHFFFAOYSA-N 3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfopropyl)phenoxy]propane-1-sulfonic acid Chemical compound COC1=CC=CC(CC(CS(O)(=O)=O)OC=2C(=CC(CCCS(O)(=O)=O)=CC=2)OC)=C1O FOGYNLXERPKEGN-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 206010021033 Hypomenorrhoea Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010022971 Iron Deficiencies Diseases 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000589180 Rhizobium Species 0.000 description 1
- 241000190070 Sarracenia purpurea Species 0.000 description 1
- 239000000877 Sex Attractant Substances 0.000 description 1
- 239000000589 Siderophore Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 229920004890 Triton X-100 Polymers 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 229960005069 calcium Drugs 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 229950008138 carmellose Drugs 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012364 cultivation method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
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- 238000000151 deposition Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 239000000797 iron chelating agent Substances 0.000 description 1
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- 230000003050 macronutrient Effects 0.000 description 1
- 235000021073 macronutrients Nutrition 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
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- 238000012423 maintenance Methods 0.000 description 1
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- 239000011572 manganese Substances 0.000 description 1
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- 235000021049 nutrient content Nutrition 0.000 description 1
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- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
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- 239000005871 repellent Substances 0.000 description 1
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- 239000012047 saturated solution Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
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- 244000000000 soil microbiome Species 0.000 description 1
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- 229940088594 vitamin Drugs 0.000 description 1
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- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- C05G3/04—
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/70—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting wettability, e.g. drying agents
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
Definitions
- the invention relates to compositions for retaining soil moisture and improving plant growth in dry soils, which, together with one or more moisture retaining materials (humectants) and wetting agents, comprises iron(III)oxides and optionally potassium metabisulfite [bor ⁇ acute over (k) ⁇ en (HU), E224] as potentiating agent. Further, the invention relates to binding the moisture content of soils, as well as composition for use in enhancing the efficacy of soil retaining compositions.
- a number of methods for inhibiting the decrease of soil moisture-content have been provided, one form of which is the introduction of the most different humectants in the soil.
- the common characteristic of these materials is that they easily bind the moisture while decrease the fast flow-out of the moisture from the area and the treated area, respectively.
- Such materials have a characteristic equilibrium point.
- Such materials are mainly organic compounds, such as glycols, polihydroxy alcohols, like glycerol and sorbitol.
- compositions in the form of liquid concentrated solution for improved water supply of plant roots which essentially consist of an organic humectants, binding agent, wetting agent and water.
- humectants for example sorbitol, molasses, potassium lactate, sodium lactate, glycerol, potassium acetate, sodium acetate may be used.
- the composition may contain preferably a thickener, such as a cellulose ether derivative, hydroxyethyl cellulose, carboxymethyl propylcellulose and the like.
- WO 90/13598 discloses a sprayable composition for covering, among others, soil, refuse at a dump site and other dangerous materials, which contains a water-soluble cellulose polymer forming a water-resisting layer after application, clay and a carrier, wherein the composition forms a tough, water-repellent and flexible layer, without penetrating in the soil.
- a sprayable composition for covering, among others, soil, refuse at a dump site and other dangerous materials, which contains a water-soluble cellulose polymer forming a water-resisting layer after application, clay and a carrier, wherein the composition forms a tough, water-repellent and flexible layer, without penetrating in the soil.
- the presence of iron oxide is mentioned.
- compositions for stimulating plant growth which are applicable of energy introduction. These compositions comprise carbon source, a water-soluble macronutrient component providing nitrogen and phosphorous, and vitamin/cofactor component, optionally together with a micronutrient component, which latter may contain zinc, iron and manganese source.
- iron source iron(II)oxide is mentioned.
- US publication 2005/0111924 describes soil binding and revegetation compositions useful for inhibiting the erosion of soil, which comprises water, carbohydrate, protein, iron compound and a strong base, as well as a fibrous material comprising at least two different types of fibers; the pH-value of the compositions is strongly basic, characteristically 9 to 13, preferably 10 to 12,8.
- iron compound iron(II) and iron(III)oxides and other iron salts are mentioned.
- compositions contain binding materials, like lignosit, which is a hygroscopic adhesive and contains maize or potato dextrin, or alternatively, ligno-sulfonic acid calcium, sodium or ammonium salt may also be used.
- wetting agent compounds known per se are mentioned, such as Triton products (Triton 101, Triton X100, Ninol II-CN, Igepal 60630, nonylphenol-(9-15)ethoxylate and the like.
- soils contain iron in an amount of 1 to 5%, which is the fourth most occurring element in the Earth. Most part of the iron is present in silicate stones or as iron oxide or hydroxide, that is in forms which are hardly accessible for plants. In the soils the iron is present in Fe ++ and Fe +++ form, wherein especially the latter can be very difficult to be utilized by the plant, though it is essential for these.
- the iron supply may be provided in traditional methods, by adding simple inorganic iron salts or complex iron compounds, this solution, however, needs frequent treatments as most of the materials used become lost, partly by being washed into and depositing in the deep layers of soil, and partly by taken up fast, mostly in an amount higher than required by the plant. It is especially important in case of dry soils.
- iron deficiency of plants is difficult to correct as the iron present in the different nutritients (fertilizers) transform rapidly into a form unavailable for the plants in the soil.
- some iron chelates proved to be useful, but very few chelates remain stable in a relatively broad pH range.
- a small change in the moisture content results in a substantial change of pH value; thus, such methods are difficult to use.
- a further advantage of the new solution according to the invention is the influence of the siderophore production by the plants and the microorganisms present in the soil in an indirect way, thus providing a more steady iron uptake for the plants.
- microparticle iron(III)oxide also influences the soil bacterium activity in a preferable effect as not only the plants, but also the microorganisms utilize from the same source (pool). Increase of the microbiological activity provides additional benefit at the same time, as the mobility of other nutritient elements (such as phosphorous, nitrogen) is also increases thereby.
- the subject of the invention is a method for improving the growth and development of plants living or being cultivated in dry soils, wherein on the locus of the plants or in the and/or to the roots of plants microparticle iron oxide is applied and administered, respectively.
- Another subject of the invention is a plant growth regulating composition, which, as essential component, comprises microparticle iron(III)oxide.
- a composition for binding and retaining the humidity of dry soils is provided, which, besides known moisture retaining and humidity retaining compositions, further comprise iron(III)oxide.
- a further subject of the invention is the improvement of the compositions comprising the iron(III)oxide and the methods applying the same as mentioned above, wherein as effect improving agent, potassium metabisulfite is used.
- FIG. 1 is the view of plants obtained with tomato plants in withering-treatment tests
- FIG. 2 is the view of plants obtained with maize plants in withering-treatment tests
- FIG. 3 shows the effect exerted on maize sprouts and root in tests for soil moisture retaining effect
- FIG. 4 is the diagram of water-retaining capacity of soil in tests for soil moisture retaining effect
- FIG. 5 is the diagram of wet sprout and wet root weights in comparative tests for soil moisture retaining effect
- FIG. 6 shows the weight of water retained in the soil in comparative tests for soil moisture retaining effect
- FIG. 7 shows the results of germination-inhibiting tests performed on filter-paper with maize
- FIG. 8 is the view of germination of maize seeds during the germination-inhibiting tests
- FIG. 9 shows the results of germination-inhibition tests carried out on filter-paper with wheat
- FIG. 10 is the view of wheat seeds during germination-inhibiting tests
- FIG. 11 is the protocol of radish drought resistance ability tests
- FIG. 12 shows the total watering in the radish drought resistance ability tests
- FIG. 13 is the summary of the mean radish bunch weights in the radish drought resistance ability tests
- FIG. 14 is the summary of the individual radish bunch weights in the radish drought resistance ability tests
- FIG. 15 is the summary of the individual radish plant weights in the radish drought resistance ability tests
- FIG. 16 is the summary of the mean radish plant weights in the radish drought resistance ability tests
- FIG. 17 shows the effect of iron(III)oxide, iron(III)oxide+POTASSIUM METABISULFITE and FeSO 4 additives on bean plants.
- the iron(III)oxide may be applied as such or formulated in an appropriate form.
- the iron supply can be of need in the first line on dry soils, and not only for the iron supply but also in respect of the moisture retaining, such formulations may suitably comprise the known components of compositions used for binding and retaining of humidity.
- composition of the invention comprises known moisture binding agent, known wetting agent, iron(III)oxide, optionally potassium metabisulfite and water.
- a number of agents useful as moisture retaining agent are known. Special property of these materials is that they keep steady moisture content in air in contact with the saturated solution thereof. At a certain temperature, the solution releases moisture in the air, wherein the relative moisture content is below the characteristic equilibrium point of the said material. Thus, as moisture retaining material, such materials are called which, at a specified moisture content easily absorbs moisture, thus decreasing the degree of moisture emission of the material treated.
- Such moisture retaining materials or mixtures thereof have specific moisture index.
- Certain organic materials for example some glycols and polyalcohols, such as glycerol and sorbitol, show similar moisture retaining effect and moisture equilibrium index. Consequently, their solutions inhibit the evaporation in the air and the moisture from the air at a relative humidity beyond their equilibrium point.
- moisture retaining materials preferred are for example the sorbitol, molasses, potassium lactate, sodium lactate, glycerol, potassium acetate, sodium acetate, vegetable fats, oligofructose, carmellose syrup, magnesium carbonate, cocoa fibre and the like.
- sorbitol molasses, potassium lactate, sodium lactate, glycerol, potassium acetate, sodium acetate, vegetable fats, oligofructose, carmellose syrup, magnesium carbonate, cocoa fibre and the like.
- the composition according to the invention comprises 10 to 80 weight % moisture binding agent, 0.5 to 5 weight % wetting agent, 0.1 to 0.5 weight % iron(III)oxide, 0 to 0.5 weight % potassium metabisulfite and about 20 to 85 weight % water. It is especially preferred when the composition, besides the iron(III)oxide, contains potassium metabisulfite as well.
- composition according to the invention have excellent soil moisture retaining effect, even in loose structure soils.
- the preferred composition according to the invention comprises 10 to 50 weight % molasses, about 0.5 weight % calcium lactate, 5 to 30 weight % sorbitol, 0.5 to 5 weight % Tween 20, 0.1 to 0.5 weight % iron(III)oxide and 0.005 to 0.5 weight % potassium metabisulfite.
- the iron(III)oxide is present in the form of Fe 2 O 3 and Fe 3 O 4 or the mixture thereof.
- the iron oxide is in miocroparticle form, wherein the particle size is suitably at most 50 micrometer, preferably 20 to 40 micrometer.
- compositions of the invention are suitable in the form of concentrates. Obviously, during application, dilution is necessary, which cannot cause any problem for one skilled in the application technology. For use in small area, the dilution is suitably 10 to 1000-fold, suitably 50 to 150-fold.
- the composition is applied on the locus in the form of concentrate or dilute solution/suspension, before or after planting, pre-emergently or post-emergently.
- the composition is preferably applied on the ground in a way that it does not contact with the plant parts above ground.
- Application may also be accomplished by dressing the propagation material, wherein the propagation material is coated in methods known per se with the concentrate, followed by drying. Dressing methods are well-known from the art.
- compositions of the invention substantially improve the water retaining ability of the soil while enhance the drought resistance of the plants as well and enhance the yield on dry soils. These effects have been shown both in greenhouse and open-air experiments. It has further been observed that—contrary to many plant protection and plant-retaining compositions—the compositions according to the invention have not influenced the germination ability of the seeds.
- compositions and the treatments according to the invention are illustrated in the following examples.
- composition assembled according to U.S. Pat. No. 5,865,869 was used, while the compositions according to the invention ware different variants supplemented with different amounts of iron(III)oxide and optionally with potassium metabisulfite.
- compositions are specified in Table I.
- the amounts of materials are expressed in weight % calculated from the total weight of the compositions.
- tomato seeds were germinated in usual way and the seedlings were watered with a 60 ⁇ dilution (59 ml water+1 ml concentrate) of the compositions by using 15 ml for watering.
- the control vessels were watered with 15 ml water.
- the tomato seedlings were watered for one month with reduced amount of water, only enough for avoiding total withering with a total of 70 ml water per vessel, while the normal water claim of the plants would have been 370 ml during the period.
- the plants started to wither, the control plant perished after 15 days, while the sample treated with HTC7 and HTC22 started to present withering symptoms only after 21 days, which could be reversed with minimal watering (5 ml).
- the process was irreversible.
- the plants of tests are shown in FIG. 1 . It can unanimously be seen that both HTC7 (labeled as “Ricsi” on the Figure) and HTC22 provided much better grown plants; in case of HTC22, the root is longer and more hairy than in case of HTC7.
- the plants were watered for one month+10 days with reduced amount of water, only enough for avoiding total withering with a total of 40 ml water per vessel, while the normal water claim of the plants would have been 290 ml during the period.
- the plants started to wither, in case of the control plants as well.
- the HTC7 started to present withering symptoms after one month, the HTC22 as last, started to present withering symptoms only after one month and 10 days.
- the plants of tests are shown in FIG. 2 . It can unanimously be seen that compared to the control, both HTC7 (labeled as “Ricsi” on the Figure) and HTC22 provided much more developed plants; in case of HTC22, the root is longer and more hairy than in case of HTC7.
- the soil was treated at the plantation of the maize seedling (from the mixture of 59 ml water+1 ml solution 15 ml to a 200 ml vessel; the control was watered with 15 ml water).
- the maize plants were grown in greenhouse for 6 weeks while receiving water according to needs, a total of 290 ml water during the 6 weeks period, both the control and treated plants.
- FIG. 3 shows the results obtained with five parallel trials.
- the above test was also carried out by examining the HTC7 and HTC22 compositions beside the control.
- the test results are shown on FIGS. 5 and 6 . It has been observed that both the wet sprout weights and wet root weights of the plants were substantially higher than in case of the control (see FIG. 5 , the term “USA” means the HTC7 composition); HTC22 shows better result at the wet sprout weight than the HTC7 treatment.
- FIG. 7 it can be seen that the soil moisture retaining ability was significantly increased by the HTC22 composition compared to both the control and the HTC composition (labeled as “USA” on the Fig).
- the germination-inhibiting side-effect was tested on 5 plants, in two media in 5 parallels.
- Soil was filled in Petri-dishes or instead of soil, filter papers were used; on the surface thereof 20-22 seeds were placed.
- To the Petri-dishes provided with the filter papers each 10 ml of the 60x dilution were poured, the control was 10 ml water.
- the soil was watered with the mixture of 20 ml solution and 20 ml water; as control, 40 ml water was used.
- compositions according to the invention have not inhibited the germination of green pepper, tomato, maize, sunflower and wheat; even more, the germination of maize and green pepper have been stimulated.
- results were of similar character both on wet paper filter and in soil.
- test results obtained with maize are shown on FIGS. 7 and 8 , those with wheat are shown on FIGS. 9 and 10 .
- the mean radish bunch weights and the individual radish bunch weights are shown in FIGS. 13 and 14 , respectively. It can be seen from the Figures that the weight of the treated radish was 98.5% of the control plants.
- Surface-sterilized bean seeds Phaseolus vulgaris var. Rocco were germinated at a temperature of 20 ⁇ 3° C. for 3 days. Thereafter a total of 60, 10 for each treatment, germ plants were planted into each 250 cm 3 sandy soil. The moisture contents were adjusted to 50% with sterile tap water, without additives (control), and with 1:60 dilutions of the soil conditioning composition prepared with sterile tap water, respectively.
- the plants prepared as above were grown in climate chamber under 12/12 hours light period and 22/15° C. temperature. During treatment, 50% of the water supply necessary for the optimal development of the plant was provided. For defense against pests, fly trap containing sex pheromone was placed to the vicinity of the plants. No weed control was necessary during the tests.
- the growth parameters prout length, root length
- the dry weight of the sprout and root were measured. From these data, the mean results relating to the sprout weight according to each treatment are shown in FIG. 17 .
- the components of the test materials are shown in Table 1.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
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- Processing Of Solid Wastes (AREA)
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HUP1300753 | 2013-12-23 | ||
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US15/106,344 Abandoned US20160318822A1 (en) | 2013-12-23 | 2014-12-22 | Iron (III) Oxide Containing Soil-Binding Composition |
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US (2) | US20160318822A1 (fr) |
EP (1) | EP3087044B1 (fr) |
JP (1) | JP2017509570A (fr) |
CN (1) | CN106061925B (fr) |
AP (1) | AP2016009319A0 (fr) |
AU (1) | AU2014372349B2 (fr) |
BR (1) | BR112016014775B1 (fr) |
CA (1) | CA2932980A1 (fr) |
CL (1) | CL2016001608A1 (fr) |
EA (1) | EA031474B1 (fr) |
ES (1) | ES2930040T3 (fr) |
GE (1) | GEP20197054B (fr) |
HU (1) | HUE061026T2 (fr) |
IL (1) | IL246332B (fr) |
MA (1) | MA39112B2 (fr) |
MD (1) | MD20160090A2 (fr) |
MX (1) | MX2016008212A (fr) |
PL (1) | PL3087044T3 (fr) |
PT (1) | PT3087044T (fr) |
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US11168036B2 (en) | 2013-12-23 | 2021-11-09 | Invention Center Kft. | Iron (III) oxide containing soil-binding composition |
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MD1059Z (ro) * | 2016-02-29 | 2017-03-31 | ИНСТИТУТ ЭЛЕКТРОННОЙ ИНЖЕНЕРИИ И НАНОТЕХНОЛОГИЙ "D. Ghitu" АНМ | Procedeu de tratare a seminţelor de pepene galben |
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US3294523A (en) * | 1964-01-29 | 1966-12-27 | Robert P Morningstar | Vegetation growth promoter utilising blood as a major component |
JP2858913B2 (ja) * | 1990-09-26 | 1999-02-17 | オルガノ株式会社 | 中空糸膜を用いる濾過方法 |
US5865869A (en) * | 1991-08-02 | 1999-02-02 | Ecologel Usa, Inc. | Solution for plant root watering |
US5762678A (en) * | 1996-08-05 | 1998-06-09 | Hiles; Maurice | Conversion of cellulosic waste to a soil improvement complex |
JPH10291878A (ja) * | 1997-04-21 | 1998-11-04 | River Well:Kk | 乾燥生ごみ防虫防疫有機肥料及びその製造方法 |
US6048377A (en) * | 1999-01-21 | 2000-04-11 | True Pitch, Inc. | Top dressing for gardens and lawns |
JP2001226179A (ja) * | 2000-02-17 | 2001-08-21 | Sanpo Kagaku Kk | 鉄入り肥料の製造法並びに鉄入り肥料 |
NO20021592D0 (no) * | 2002-04-04 | 2002-04-04 | Fmc Biopolymer As | Polysakkaridkapsler og fremgangsmåte ved fremstilling derav |
GB0309585D0 (en) * | 2003-04-26 | 2003-06-04 | Fenwick Richard | Weed suppressant gel |
US7021864B2 (en) * | 2003-11-26 | 2006-04-04 | Sequoia Pacific Research Company, Llc | Soil binding and revegetation compositions and methods of making and using such compositions |
US20050289665A1 (en) * | 2004-06-24 | 2005-12-29 | Hartle Jeffrey E | Method for disinfecting seed |
US8034147B2 (en) * | 2006-11-21 | 2011-10-11 | Chk Group, Inc. | Complete plant growth medium |
AU2007333225B2 (en) * | 2006-12-08 | 2014-06-12 | Massachusetts Institute Of Technology | Delivery of nanoparticles and/or agents to cells |
JP4317580B2 (ja) * | 2007-09-14 | 2009-08-19 | 新日本製鐵株式会社 | 還元鉄ペレットの製造方法及び銑鉄の製造方法 |
CN101366953B (zh) * | 2008-10-08 | 2010-10-27 | 东南大学 | 注射用小分子修饰氧化铁纳米粒冻干粉及制备方法 |
WO2010058425A2 (fr) * | 2008-11-20 | 2010-05-27 | Chetan Navnithlal Shah | Conditionneur de sol |
JP5729163B2 (ja) * | 2011-06-24 | 2015-06-03 | トヨタ自動車株式会社 | 負極活物質及び負極活物質の製造方法 |
EP3087044B1 (fr) | 2013-12-23 | 2022-09-21 | Invention Center Kft. | Composition de stabilisation des sols contenant de l'oxyde de fer (iii) |
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2014
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- 2014-12-22 US US15/106,344 patent/US20160318822A1/en not_active Abandoned
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US11168036B2 (en) | 2013-12-23 | 2021-11-09 | Invention Center Kft. | Iron (III) oxide containing soil-binding composition |
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GEP20197054B (en) | 2019-12-25 |
PL3087044T3 (pl) | 2023-01-16 |
JP2017509570A (ja) | 2017-04-06 |
IL246332B (en) | 2020-05-31 |
MD20160090A2 (ro) | 2016-12-31 |
TN2016000232A1 (en) | 2017-10-06 |
BR112016014775B1 (pt) | 2022-08-16 |
MA39112A1 (fr) | 2017-09-29 |
AU2014372349A1 (en) | 2016-07-21 |
EP3087044A1 (fr) | 2016-11-02 |
CN106061925A (zh) | 2016-10-26 |
EP3087044B1 (fr) | 2022-09-21 |
HUE061026T2 (hu) | 2023-05-28 |
AU2014372349B2 (en) | 2020-05-14 |
CL2016001608A1 (es) | 2017-06-30 |
AP2016009319A0 (en) | 2016-07-31 |
WO2015097486A1 (fr) | 2015-07-02 |
PT3087044T (pt) | 2022-11-02 |
ES2930040T3 (es) | 2022-12-05 |
EA201691316A1 (ru) | 2016-11-30 |
CA2932980A1 (fr) | 2015-07-02 |
US20190084897A1 (en) | 2019-03-21 |
CN106061925B (zh) | 2023-05-23 |
EA031474B1 (ru) | 2019-01-31 |
MA39112B2 (fr) | 2021-10-29 |
BR112016014775A2 (fr) | 2017-09-19 |
MX2016008212A (es) | 2017-03-01 |
US11168036B2 (en) | 2021-11-09 |
WO2015097486A8 (fr) | 2016-07-07 |
IL246332A0 (en) | 2016-08-31 |
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