US20150336169A1 - Cooling system for molding fixtures, particularly for foundry molds - Google Patents
Cooling system for molding fixtures, particularly for foundry molds Download PDFInfo
- Publication number
- US20150336169A1 US20150336169A1 US14/654,534 US201314654534A US2015336169A1 US 20150336169 A1 US20150336169 A1 US 20150336169A1 US 201314654534 A US201314654534 A US 201314654534A US 2015336169 A1 US2015336169 A1 US 2015336169A1
- Authority
- US
- United States
- Prior art keywords
- water
- air
- cooling system
- compressed air
- treated water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000001816 cooling Methods 0.000 title claims abstract description 67
- 238000000465 moulding Methods 0.000 title claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 129
- 238000001914 filtration Methods 0.000 claims description 5
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 238000005115 demineralization Methods 0.000 claims description 2
- 230000002328 demineralizing effect Effects 0.000 claims description 2
- 238000005086 pumping Methods 0.000 claims description 2
- 238000001223 reverse osmosis Methods 0.000 claims description 2
- 239000012530 fluid Substances 0.000 description 4
- 238000005266 casting Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000004512 die casting Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 229910001234 light alloy Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010120 permanent mold casting Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/06—Permanent moulds for shaped castings
- B22C9/065—Cooling or heating equipment for moulds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D30/00—Cooling castings, not restricted to casting processes covered by a single main group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
- B22D17/20—Accessories: Details
- B22D17/22—Dies; Die plates; Die supports; Cooling equipment for dies; Accessories for loosening and ejecting castings from dies
- B22D17/2218—Cooling or heating equipment for dies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D46/00—Controlling, supervising, not restricted to casting covered by a single main group, e.g. for safety reasons
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/72—Heating or cooling
- B29C45/73—Heating or cooling of the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/72—Heating or cooling
- B29C45/73—Heating or cooling of the mould
- B29C45/7337—Heating or cooling of the mould using gas or steam
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/023—Water in cooling circuits
Definitions
- the present invention relates to a cooling system for molding fixtures, and particularly for foundry molds.
- the invention also relates to a device for mixing air and treated water, and for the controlled ejection of atomized water under pressure.
- such a system is applied on molds for the production of castings of light alloys, permanent-mold castings, low-pressure or high-pressure die castings, but it should be understood that it can be applied to molding fixtures in general.
- cooling circuits which comprise coils that are provided in the areas of the fixture where an effective and rapid reduction of the temperature is required during the solidification of the casting.
- the fluid circulating in such cooling circuits is compressed air, which is blown into the coils and is adapted to remove a preset quantity of heat, and is then dispersed in the environment.
- the coils are normally incorporated into the molding fixture.
- a first drawback is the thermal shock generated by the passage of the fluid inside the adapted channels and the adapted slots which are often provided in the body of the mold.
- the heated water that exits from the mold or from the system associated with it must be suitably treated for its disposal or reuse.
- the aim of the present invention is to provide a cooling system for molding fixtures in foundries, which is capable of overcoming the above-mentioned drawbacks of conventional cooling circuits and cooling systems.
- an object of the invention is to provide a cooling system that is capable of combining the advantages of air systems with the effectiveness of water circuits.
- Another object of the invention is to provide a cooling system that can also be fitted on existing molding fixtures.
- Another object of the invention is to provide a cooling system that does not produce thermal shocks in the mold with which it is associated, and which is immune to leaks owing to problems of excess pressure.
- Another object of the invention is to provide a cooling system for molding fixtures, and particularly for foundry molds, which can be provided with conventional technologies.
- a cooling system for molding fixtures and particularly for foundry molds, characterized in that it comprises:
- FIG. 1 schematically illustrates a cooling system according to the invention
- FIG. 2 is a diagram of the water treatment means of a system according to the invention.
- FIG. 3 is a diagram of the pressurization means of a system according to the invention.
- FIG. 4 is a diagram of the compressed air generation means and of the associated mixing and ejection means of a system according to the invention
- FIG. 5 shows a second embodiment of the water treatment means and treated water pressurization means of a system according to the invention
- FIG. 6 is a cross-sectional view of the mixing and ejection device of a system according to the invention.
- a cooling system for molding fixtures, and particularly for foundry molds, according to the invention is generally designated with the reference numeral 10 .
- Such cooling system 10 comprises:
- the water treatment means 11 as shown in schematic form in FIG. 2 , comprise a water treatment unit 17 , of the reverse osmosis or demineralization type, to which the water is supplied by a water mains 18 .
- the demineralized water that exits from the water treatment unit 17 passes through a duct 19 into a tank 20 , which is kept at a constant level as subsequent means 22 of supplying the treated water draw the treated water from the tank 20 and transfer it to the means for pressurizing the treated water 13 .
- the supply means 22 for the treated water are constituted by a supply pump 21 , which is adapted to provide pressurized treated water to the water pressurization means 13 .
- Such water treatment means 11 comprise a first stopcock 23 between the treatment unit 17 and the tank 20 , and a second stopcock 24 at the exit from the supply pump 21 .
- the means 13 of pressurizing the treated water comprise, in sequence on the same line, a pressure reduction device 25 , a tank 26 , and a filtering device 27 , after which the water reaches the mixing and ejection device 14 .
- stopcocks There are two stopcocks, a first stopcock 28 between the pressure reduction device 25 and the tank 26 , and a second stopcock 29 at the exit from the pressure reduction device 25 .
- the compressed air generation means 12 comprise a compressed air system 30 , which is usually already fitted for molding fixtures with which the cooling system 10 is associated, for example a press, and thus of a conventional type, one branch 31 of which has a pressure reduction device 32 , with a solenoid control valve 33 upstream.
- the value of the pressure of the treated water that exits from the water pressurization means 13 is one bar higher than the pressure of the air that exits from the compressed air generation means 12 .
- the air and water lines are very different from each other, and each of them has a different length, with curves and areas at different temperatures, and these differences determine different drops in pressure in the two circuits, with the consequence that if the same operating pressure is used both for the water and for the air, the mixing is neither constant nor repeatable, since sometimes the water flow predominates, and sometimes the air flow predominates, and thus the cooling obtained in the circuit of the molding fixture is inconsistent and thus is not satisfactory.
- the mixing and ejection device 14 comprises a pneumatic valve 34 that actuates the opening of the water circuit, i.e., the line connected to the water pressurization means 13 , the pneumatic valve 34 being actuated by the passage of the air between the solenoid control valve 33 of the compressed air generation means 12 and the air pressure reduction device 32 .
- the treated water under pressure is caused to pass, downstream of the pneumatic valve 34 , through a calibrated nozzle 35 .
- Such calibrated nozzle 35 has a calibrated water exit hole 37 with a diameter 38 of for example 0.3 millimeters, which is calculated to have approximately 110 milliliters per minute of water under a pressure of 5 bar, in contrast to the 4 bar on the air line, a preset flow-rate that is calculated to be optimal for most cooling circuits already fitted to foundry molding fixtures known today.
- the treated water under pressure originating from the water pressurization means 13 and the air under pressure exiting from the compressed air generation means 12 both pass through a three-way connector 36 , and are mixed inside it.
- the cooling circuit 16 of which, already integrated, is of the type that works with air
- the diameter 38 of the hole 37 of the nozzle 35 must not be larger than 0.3 millimeters.
- Such three-way connector 36 is of a conventional type and available on the market.
- FIG. 5 shows a second embodiment of the water treatment means, designated with the reference numeral 111 , and of the water pressurization means 113 which are connected to them.
- the water treatment means 111 simply comprise a container of demineralized water 150 , and thus is used if the molding fixture on which the system according to the invention is applied is not equipped with the water treatment means 11 described above for the first embodiment of the cooling system according to the invention 10 described above, and normally already provided on the molding fixture.
- the water pressurization means 113 comprise a pressurization tank 126 , which is provided with a level indicator 151 , and a filtering device 127 at the exit point from the pressurization tank 126 .
- a first stopcock 128 is arranged upstream of the pressurization tank 126 , and a second stopcock is arranged downstream of the filtering device 127 .
- the supply means 122 for the treated water are constituted by an air pumping device 152 , for example a compressed air line that is already operational and used for the molding fixture 15 , followed by an air pressure reduction device 153 , which is adapted to propel air into the pressurization tank 126 , so that the demineralized water that exits from it is available to the mixing and ejection device 14 at the optimal preset pressure.
- an air pumping device 152 for example a compressed air line that is already operational and used for the molding fixture 15
- an air pressure reduction device 153 which is adapted to propel air into the pressurization tank 126 , so that the demineralized water that exits from it is available to the mixing and ejection device 14 at the optimal preset pressure.
- the invention also relates to a device 14 for mixing air and treated water, and for the controlled ejection of atomized water under pressure toward a cooling circuit 16 of a molding fixture 15 , as described above.
- Such device 14 is characterized in that it comprises
- the device 14 comprises a pneumatic valve 34 that actuates the opening of a water line that is connected to water pressurization means 13 , the pneumatic valve 34 being actuated by the passage of air between a solenoid control valve 33 of compressed air generation means 12 and an air pressure reduction device 32 .
- a cooling system is provided that combines the advantages of air systems with the effectiveness of water circuits.
- such cooling system according to the invention thanks to the water pressurization means and to the compressed air generation means, which are conveniently mixed as described above, makes it possible to achieve the ejection of humidified air containing a low percentage of water, approximately 110 milliliters per minute, which is sufficient to constantly achieve the precise and repeatable cooling of the molding fixture on which it is applied.
- Another important object of the invention is to provide a cooling system that can also be fitted on existing molding fixtures, thanks to the ability to be connected to the compressed air system of the molding fixture on which it is applied for the supply of compressed air, and thanks to the ability to inject the humidified air produced into the cooling circuits that are already defined in the molding fixture.
- a cooling system is provided that makes it possible to use a pressure on the air line, 4 bar, which is lower than the pressure used in the standard compressed air circuit, 7-9 bar, that is already provided on molding fixtures with compressed air cooling circuits; in fact compressed air alone removes much less heat than humidified air, and as a consequence the use of humidified air, or atomized water, makes it possible to adopt a much lower operating pressure, with consequent energy saving for the compressor.
- a cooling system is provided that, thanks to the humidified air, makes it possible to shorten cooling times, with consequent reduction of molding cycle times and better yield in terms of productivity of the molding fixture.
- the cooling system according to the invention is capable of serving a plurality of cooling circuits in parallel.
- a cooling system which does not produce thermal shocks in the mold with which it is associated, since the passage of humidified air in the cooling circuit causes less sudden thermal rushes, and which is immune against leaks owing to problems of excess pressure.
- a device is also provided for mixing air and treated water and for ejection, which optimizes the operation of the system according to the invention.
- a cooling system is provided for molding fixtures, and particularly for foundry molds, and a device is provided for mixing air and treated water, and for the controlled ejection of atomized water under pressure toward a cooling circuit of a molding fixture, which can both be provided with conventional technologies.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Moulding By Coating Moulds (AREA)
- Casting Devices For Molds (AREA)
- Nozzles (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITPD2012A000402 | 2012-12-21 | ||
IT000402A ITPD20120402A1 (it) | 2012-12-21 | 2012-12-21 | Impianto di raffreddamento per attrezzature di stampaggio, in particolare per stampi da fonderia, con dispositivo di miscelazione di aria ed acqua trattata, e di eiezione controllata di acqua nebulizzata in pressione per tale impianto |
PCT/IB2013/061150 WO2014097216A1 (en) | 2012-12-21 | 2013-12-19 | Cooling system for molding fixtures, particularly for foundry molds |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2013/061150 A-371-Of-International WO2014097216A1 (en) | 2012-12-21 | 2013-12-19 | Cooling system for molding fixtures, particularly for foundry molds |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US16/202,125 Continuation US10702917B2 (en) | 2012-12-21 | 2018-11-28 | Cooling system for molding fixtures, particularly for foundry molds |
Publications (1)
Publication Number | Publication Date |
---|---|
US20150336169A1 true US20150336169A1 (en) | 2015-11-26 |
Family
ID=47749943
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US14/654,534 Abandoned US20150336169A1 (en) | 2012-12-21 | 2013-12-19 | Cooling system for molding fixtures, particularly for foundry molds |
US16/202,125 Active US10702917B2 (en) | 2012-12-21 | 2018-11-28 | Cooling system for molding fixtures, particularly for foundry molds |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US16/202,125 Active US10702917B2 (en) | 2012-12-21 | 2018-11-28 | Cooling system for molding fixtures, particularly for foundry molds |
Country Status (12)
Country | Link |
---|---|
US (2) | US20150336169A1 (pl) |
EP (1) | EP2934848B1 (pl) |
JP (1) | JP6331039B2 (pl) |
CN (1) | CN104981334B (pl) |
BR (1) | BR112015014962B1 (pl) |
CA (1) | CA2895634C (pl) |
IT (1) | ITPD20120402A1 (pl) |
MX (1) | MX368506B (pl) |
PL (1) | PL2934848T3 (pl) |
RU (1) | RU2657035C2 (pl) |
TR (1) | TR201910905T4 (pl) |
WO (1) | WO2014097216A1 (pl) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101779151B1 (ko) * | 2016-03-15 | 2017-09-18 | 주식회사 포스코 | 처리수 공급 장치 및 이를 포함하는 스케일 처리 설비 |
JP2018202324A (ja) * | 2017-06-05 | 2018-12-27 | いすゞ自動車株式会社 | 噴射試験装置 |
CN107855490A (zh) * | 2017-12-19 | 2018-03-30 | 上海震界自动化设备制造有限公司 | 压铸件自动循环水冷装置 |
CN108995160B (zh) * | 2018-08-09 | 2020-11-06 | 钟小二 | 一种塑料注塑模具用冷却装置 |
CN108973057A (zh) * | 2018-09-21 | 2018-12-11 | 深圳市创信力合科技有限公司 | 一种注塑模具 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5285841A (en) * | 1992-02-12 | 1994-02-15 | Ryobi Ltd. | Metal mold cooling device |
US6412288B1 (en) * | 1998-08-06 | 2002-07-02 | Aga Aktiebolag | Point cooling |
US20090315231A1 (en) * | 2006-07-26 | 2009-12-24 | Yuichi Furukawa | Cooling system for forming mold and method of cooling forming mold |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
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US4637451A (en) * | 1984-02-22 | 1987-01-20 | Dbm Industries Limited | Die casting mold |
US4779400A (en) * | 1986-10-20 | 1988-10-25 | Moore Push-Pin Company | Method and apparatus for forming, filling and sealing bags made from continuous plastic sheets |
JPS63299848A (ja) * | 1987-05-29 | 1988-12-07 | Mitsubishi Motors Corp | 金型の冷却方法 |
JPH10109092A (ja) * | 1996-10-04 | 1998-04-28 | Kubota Karaatoronitsuku Kk | 金型温調用水処理装置 |
JPH11188473A (ja) * | 1997-12-25 | 1999-07-13 | Ryobi Ltd | 金型冷却装置 |
DE10113278A1 (de) * | 2001-03-16 | 2002-09-19 | Zahnradfabrik Friedrichshafen | Verfahren zur Aufbereitung von Waschwässern aus der Druckgussimprägnierung und Vorrichtung zur Durchführung des Verfahrens |
JP2005021979A (ja) * | 2003-07-04 | 2005-01-27 | Ryoei Engineering Kk | 金型冷却水循環装置 |
JP2005046846A (ja) * | 2003-07-29 | 2005-02-24 | Dynamo:Kk | ダイカスト金型等の冷却方法及び装置 |
US7476312B2 (en) * | 2004-04-15 | 2009-01-13 | Trojan Technologies Inc. | Fluid treatment system |
US20080185311A1 (en) * | 2006-10-13 | 2008-08-07 | Global Distributors Llc | Rotationally molded plastic refuse container with microbial inhibiting inner surface and method |
DE102007019389B4 (de) * | 2007-04-23 | 2015-01-22 | Single Temperiertechnik Gmbh | Formwerkzeugtemperiersystem, Vorrichtung mit Formwerkzeugtemperiersystem und Verfahren zum Temperieren einer Vorrichtung sowie zur Herstellung der Vorrichtung |
JP2010099698A (ja) * | 2008-10-23 | 2010-05-06 | Die Engineering:Kk | 金型冷却装置 |
IT1402730B1 (it) * | 2010-11-24 | 2013-09-18 | Ind Frigo Srl | Sistema integrato di preriscaldo e di raffreddamento per stampi |
CN102729410B (zh) * | 2012-06-28 | 2015-08-19 | 宁国市华晟塑胶制品有限公司 | 一种带冷却系统的模具 |
-
2012
- 2012-12-21 IT IT000402A patent/ITPD20120402A1/it unknown
-
2013
- 2013-12-19 JP JP2015548855A patent/JP6331039B2/ja active Active
- 2013-12-19 BR BR112015014962-6A patent/BR112015014962B1/pt active IP Right Grant
- 2013-12-19 CN CN201380067003.0A patent/CN104981334B/zh active Active
- 2013-12-19 CA CA2895634A patent/CA2895634C/en active Active
- 2013-12-19 EP EP13828851.9A patent/EP2934848B1/en active Active
- 2013-12-19 TR TR2019/10905T patent/TR201910905T4/tr unknown
- 2013-12-19 PL PL13828851T patent/PL2934848T3/pl unknown
- 2013-12-19 WO PCT/IB2013/061150 patent/WO2014097216A1/en active Application Filing
- 2013-12-19 RU RU2015128756A patent/RU2657035C2/ru active
- 2013-12-19 US US14/654,534 patent/US20150336169A1/en not_active Abandoned
- 2013-12-19 MX MX2015008139A patent/MX368506B/es active IP Right Grant
-
2018
- 2018-11-28 US US16/202,125 patent/US10702917B2/en active Active
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US5285841A (en) * | 1992-02-12 | 1994-02-15 | Ryobi Ltd. | Metal mold cooling device |
US6412288B1 (en) * | 1998-08-06 | 2002-07-02 | Aga Aktiebolag | Point cooling |
US20090315231A1 (en) * | 2006-07-26 | 2009-12-24 | Yuichi Furukawa | Cooling system for forming mold and method of cooling forming mold |
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Also Published As
Publication number | Publication date |
---|---|
TR201910905T4 (tr) | 2019-08-21 |
MX368506B (es) | 2019-10-04 |
BR112015014962B1 (pt) | 2021-04-13 |
CN104981334B (zh) | 2018-03-27 |
CA2895634C (en) | 2020-12-08 |
EP2934848B1 (en) | 2019-04-24 |
CA2895634A1 (en) | 2014-06-26 |
US10702917B2 (en) | 2020-07-07 |
MX2015008139A (es) | 2016-04-25 |
PL2934848T3 (pl) | 2020-03-31 |
CN104981334A (zh) | 2015-10-14 |
EP2934848A1 (en) | 2015-10-28 |
JP6331039B2 (ja) | 2018-05-30 |
US20190091762A1 (en) | 2019-03-28 |
WO2014097216A1 (en) | 2014-06-26 |
JP2016504197A (ja) | 2016-02-12 |
RU2015128756A (ru) | 2017-02-02 |
RU2657035C2 (ru) | 2018-06-08 |
BR112015014962A2 (pt) | 2017-07-11 |
ITPD20120402A1 (it) | 2014-06-22 |
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