US20150080529A1 - High modulus urethane adhesive compositions, manufacture and use thereof - Google Patents

High modulus urethane adhesive compositions, manufacture and use thereof Download PDF

Info

Publication number
US20150080529A1
US20150080529A1 US14/391,180 US201314391180A US2015080529A1 US 20150080529 A1 US20150080529 A1 US 20150080529A1 US 201314391180 A US201314391180 A US 201314391180A US 2015080529 A1 US2015080529 A1 US 2015080529A1
Authority
US
United States
Prior art keywords
ple
sam
sample
modulus
samples
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US14/391,180
Other languages
English (en)
Inventor
Huide D. Zhu
Andrew R. Kneisel
Daniel P. Sophiea
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Priority to US14/391,180 priority Critical patent/US20150080529A1/en
Publication of US20150080529A1 publication Critical patent/US20150080529A1/en
Assigned to DOW GLOBAL TECHNOLOGIES LLC reassignment DOW GLOBAL TECHNOLOGIES LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SOPHIEA, DANIEL P., KNEISEL, ANDREW R., ZHU, HUIDE D.
Abandoned legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
    • C08G18/2018—Heterocyclic amines; Salts thereof containing one heterocyclic ring having one nitrogen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2081—Heterocyclic amines; Salts thereof containing at least two non-condensed heterocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic

Definitions

  • the present invention relates to a urethane adhesive composition having high modulus and is pump transferable at room temperature.
  • Urethane adhesive compositions are used in many industries. For example, in the automotive industry, urethane adhesive compositions are used to bond glass objects such as windshield, backlight window and quarter glass into the car body structure. In order to provide adequate rigidity and thus better noise, vibration, and harshness (NVH) performance of a car, it's ideal to have urethane adhesive compositions with high modulus performance after they are cured in place. In addition to high modulus, it is also advantageous if such urethane adhesive composition is usable and is also pump transferable at room temperature. Furthermore, it is ideal if the urethane adhesive composition can be used without the need of a paint primer on the car body structure.
  • NSH noise, vibration, and harshness
  • high modulus urethane adhesive compositions can be achieved through the use of rigid polymer resins, e.g. crystalline polyester resins and/or acrylic resins. These compositions typically need the heating during manufacturing and/or application. Furthermore, these compositions typically have high viscosities and therefore difficult to be pumped at room temperature.
  • the present invention provides a urethane adhesive composition with desirable characteristics.
  • the urethane adhesive composition of the present invention contains a) urethane prepolymer resin; b) aromatic polyisocyanate compounds or a blend of aromatic polyisocyanates and aliphatic polyisocyanates; c) catalysts such as organic amines and metal carboxylates for moisture cure; and d) fillers such as carbon black, inorganic fillers (clay, calcium carbonate etc.).
  • the compositions of the present invention can be produced at room temperature and are pump transferable without the need of heating.
  • FIG. 1 illustrates the_E′ values versus temperature for Samples 4 to 7 and Comparative Sample A.
  • the present invention provides a urethane adhesive composition
  • a urethane adhesive composition comprising a urethane prepolymer resin, a polyisocyanate, a catalyst such as an organic amine or a metal carboxylate compound; and a filler.
  • VoronolTM 220-056 is polyoxypropylene diol, having a number average molecular weight of 2000 and is available from The Dow Chemical Company.
  • VoronolTM 232-036 is polyoxypropylene triol, having a number average molecular weight of 4500 and is available from The Dow Chemical Company.
  • MDI is methylene diphenyl diisocyanate available from The Dow Chemical Company.
  • METACURETM T-9 is a stannous octoate catalyst available from Air Products Inc.
  • DABCOTM DC21 is dibutyl tin dicarboxylate available from Air Products Inc.
  • PlatinolTM N is diisononyl phthalate plasticizer available from BASF Co.
  • JEFFCATTM DMDEE is dimorpholino diethyl ether catalyst available from Huntsman Chemical Co.
  • ELFTEXTM S7100 is a standard carbon black available from Cabot Co. Clay used in the Examples is available from Burgess Pigment Co.
  • DesmodurTM N3300 is hexamethylene diisocyanate trimers, available from Bayer Co.
  • PAPITM 20 is polymeric methylene diphenyl diisocyanate available from The Dow Chemical Company.
  • VestanatTM IPDI is isophorone diisocyanate available from Evonik Degussa Company.
  • BETASEALTM 43532 primer is an isocyanate containing primer available from The Dow Chemical Company.
  • PTSITM is p-Toluenesulfonyl Isocyanate available from VANDEMARK CHEMICAL CO.
  • Carbon black is available from Cabot Company.
  • Urethane prepolymer resins are preferably prepared by the reaction between polyoxypropylene diol, polyoxypropylene triol , and methylene diphenyl diisocyanate in the presence of a catalyst and with dialkyl phthalate as solvent as shown in the example of making Prepolymer 1.
  • the urethane prepolymer resins for use in preparing the composition of the invention have an average isocyanate functionality of at least about 2.0 and a molecular weight (weight average) of at least about 2,000.
  • the average isocyanate functionality of the urethane prepolymer resin is at least about 2.2, and is more preferably at least about 2.4.
  • the isocyanate functionality is no greater than about 4.0, more preferably no greater than about 3.5 and most preferably no greater than about 3.0.
  • the weight average molecular weight of the urethane prepolymer is at least about 2,500 and is more preferably at least about 3,000; and is preferably no greater than about 40,000, even more preferably no greater than about 20,000, more preferably no greater than about 15,000 and is most preferably no greater than about 10,000.
  • the composition of the present invention contains about 25 to 75 wt. %, preferably about 30 to 70 wt. %, more preferably 35 to 65 wt. % of the urethane prepolymer resin.
  • Aromatic polyisocyanates or a mixture of aromatic and aliphatic polyisocyanates may be used as polyisocyanates in the present invention.
  • the polyisocyanate comprises an aromatic polyisocyanate with a nominal functionality of more than 2.5.
  • polyisocyanates suitable for use in present invention include PAPITM 20 or DesmodurTM N3300.
  • the composition contains no more than 10 wt. %, preferably no more than 7.5 wt. %, more preferably no more than 5 wt. %, and most preferably no more than 3 wt. % of aromatic polyisocyanates.
  • the composition of the present invention typically contain more than 0.1 wt. %, preferably more than 0.25 wt. %, more preferably more than 0.5 wt. %, and most preferably more than 0.75 wt. % of aromatic polyisocyanates.
  • organic amine catalyst examples include JEFFCATTM DMDEE and alkyl substituted morpholino compounds.
  • organo metallic catalyst include dialkyltin dicarboxylate.
  • the composition of the present invention typically contains no more than 2 wt. %, preferably no more than 1.5 wt. %, more preferably no more than 1 wt. %, and most preferably no more than 0.5 wt. % of organic amines. Further, the composition of the present invention typically contain more than 0.01 wt. %, preferably more than 0.1 wt. %, more preferably more than 0.15 wt. %, and most preferably more than 0.20 wt. % of organic amines.
  • organo metallic catalysts e.g. dialkyltin dicarboxylate
  • the organo metallic compounds are present in an amount of about 60 parts per million (ppm) or greater based on the weight of the composition, more preferably 120 parts by million or greater.
  • the organo metallic compounds are present in an amount of about 1.0 wt. % or less based on the weight of the composition, more preferably 0.5 wt. % or less and most preferably 0.2 wt. % or less.
  • Typical fillers used in the present invention include carbon black, clay, calcium carbonate, thermoplastics, flame-retardant additives, and colorants used alone in combination with each other.
  • the composition of the present invent comprises less than 35 wt. %, preferably less than 30, more preferably less than 25 wt. % of one or more fillers.
  • one or more stabilizers may also be added to the composition.
  • stabilizers suitable for present composition include HALS (hindered amine), UV stabilizers, antioxidants, free radical scavengers, heat stabilizers.
  • HALS hindered amine
  • UV stabilizers hindered amine
  • antioxidants hindered amine
  • free radical scavengers heat stabilizers.
  • the amounts of stabilizers used in the composition can vary based on different applications.
  • a moisture scavenger may be used in the composition.
  • Suitable moisture scavengers include methyl orthoformate (Bayer OF), PTSITM, calcium oxide, functional silanes or oxazolidines from The Dow Chemical Company.
  • the amounts of moisture scavenger used in the composition can vary based on different applications.
  • the process typically includes the following steps:
  • the one or more catalysts were added after fillers in the process of making the present composition. No significant difference was noticed due to this change of adding sequence.
  • Viscosities of prepolymers as described herein are determined according to the procedure disclosed in Bhat, U.S. Pat. No. 5,922, 809 at column 12, lines 38 to 49, incorporated herein by reference. Viscosities of adhesives as described herein are determined using press flow. The press flow is the time it takes for 20 grams of adhesive to pass through a 0.157 inch (4.0 mm) orifice under 80 psi (552 kPa) pressure. 3 day-54° C. heat age press flow is measured on the adhesive sample after 3 day 54° C. heat treatment.
  • the sag test is carried out using the following procedure below.
  • a metal panel of 10 cm height and 30 cm long is standing up vertically on the bench with the its length sitting on the bench.
  • a right angle triangle bead of the adhesive composition of 1.8 cm height and 0.6 cm base is dispensed along the top edge of the panel with the base touching the panel and the height perpendicular to the top edge of the panel.
  • the sag at the tip of the adhesive composition is measured and recorded (in millimeter). The sag can be run on either the fresh material or the heat aged material.
  • Quick knife adhesion (QKA) test is run according to the following.
  • An adhesive bead of 6.3 mm (width) ⁇ 6.3 mm (height) ⁇ 100 mm (length) is placed on the tested substrate and the assembly is cured for a specific time at 23° C. and 50 percent RH (relative humidity).
  • RH relative humidity
  • a slit (20-40mm) is made between the adhesive end and the substrate.
  • the cured bead is then cut with a razor blade at a 45° angle while pulling back the end of the bead at 180° angle to the substrate.
  • the degree of adhesion is evaluated as adhesive failure (AF) and/or cohesive failure (CF).
  • AF adhesive failure
  • CF cohesive failure
  • the cured bead can be separated from the substrate and in case of CF, separation occurs only within the adhesive bead as a result of knife cutting.
  • E′ modulus is measured by dynamic mechanical analyzer (“DMA”). Sample dimension is 4 to 5 mm thickness, 60 mm in length and 12 mm in width. Tested sample is placed on the dual cantilever clamp with 35 mm between the two clamps. The frequency is 1 Hz and amplitude is 150 micrometer. Temperature is scanned from ⁇ 40° C. to 100° C. Both storage modulus (E′) and loss modulus (E′′) are reported.
  • DMA dynamic mechanical analyzer
  • G modulus at 10% strain is obtained from lap shear samples.
  • the lap shear sample is prepared according to the following. First, two steel coupons of 25 mm by 100 mm were primed with BetasealTM 43533ATU. A bead of adhesive composition is applied along the width and at the primed end of the first steel coupon. The primed end of a second steel coupon is immediately pressed on the adhesive bead so that the adhesive bead has a final dimension of 6 mm height, 10 mm width and 25 mm height. The sample is allowed to cure under conditions of 23° C. and 50 percent relative humidity (RH) for about 10 days. The lap shear sample is then pulled at a rate of 4 inch/minute (100 mm/min) with an Instron Tester.
  • Prepolymer 1 is prepared by chemically reacting components in their amounts as listed below.
  • the urethane prepolymer resin prepared with the above procedure (“Prepolymer 1”) has a viscosity measured at 25° C. of about 11160 cps and a NCO of about 1.49%.
  • the comparative sample (Sample A) is prepared by adding the stated amount of Prepolymer 1, DMDEE, DABCO DC21, Desmodur N-3300 hexamethylene diisocyanate trimer if any, and PAPI 20 if any into a 2 gallon mixer.
  • the mixture is degassed under vacuum and mixed for 15 minutes.
  • the vacuum is broken and both carbon black and clay, previously oven dried and cooled to room temperature, are added.
  • the vacuum is applied slowly. When half of the vacuum is achieved, mixing is started to wet out the fillers for 2 minutes.
  • the vacuum valve is then fully opened and mixing is continued under full vacuum for 15 minutes. Thereafter, the vacuum is broken again and the mixture is scraped down.
  • the full vacuum is applied again and the mixture is mixed under vacuum for another 5 minutes. Then, the vacuum is removed with nitrogen and the adhesive composition is packaged into sealed tubes and stored in aluminum bags.
  • Samples 1 to 10 are examples of embodiments of the present invention.
  • Samples 1 to 3 containing polyisocyanate Desmodur N3300, are similarly prepared with various components as listed below.
  • Sample 1 Sample 2 Sample 3 Sample ID Wt % Wt % Wt % Prepolymer I 57.58% 56.58% 55.58% DMDEE 0.28% 0.28% 0.28% DABCO DC-21 0.14% 0.14% 0.14% Desmodur N3300 1.00% 2.00% 3.00% PAPI20 Carbon Black 15.00% 15.00% 15.00% Clay 26.00% 26.00% 26.00% SUM 100.00% 100.00% 100.00%
  • Samples 4 to 7, in accordance with the present invention and containing polyisocyanate PAPI 20, are similarly prepared with various components as listed below.
  • Sample 4 Sample 5 Sample 6 Sample 7 Wt % Wt % Wt % Wt % Wt % Prepolymer I 57.58% 56.58% 55.58% 53.68% DMDEE 0.28% 0.28% 0.28% 0.18% DABCO DC-21 0.14% 0.14% 0.14% 0.14% Desmodur N3300 PAPI20 1.00% 2.00% 3.00% 5.00% Carbon black 15.00% 15.00% 15.00% 15.00% Clay 26.00% 26.00% 26.00% 26.00% 26.00% 26.00% SUM 100.00% 100.00% 100.00% 100.00% 100.00% 100.00%
  • Samples 8 to 10 containing IPDI are similarly prepared with various components as listed below.
  • Sample 8 Sample 9 Sample 10 Wt % Wt % Wt % Prepolymer I 57.58% 56.58% 55.58% DMDEE 0.28% 0.28% 0.28% DABCO DC-21 0.14% 0.14% 0.14% IPDI 1.00% 2.00% 3.00% PAPI 20 Carbon black 15.00% 15.00% 15.00% Clay 26.00% 26.00% 26.00% SUM 100.00% 100.00% 100.00%
  • E′ Storage modulus
  • Table 1 provides the E′ modulus results for comparative Sample A and comparative Samples 1 through 3. Samples 1 to 3 have higher modulus than that of Sample A. As the content of N3300 in samples increases, E′ values of the samples also increase.
  • Table 2 lists the storage modulus (E′) results for Samples 4 to 7. Samples 4 to 7 have higher modulus than that of Sample A. As the content of PAPI 20 in the samples increases, the storage modulus has also increased. Comparing Samples 1 to 3 with Samples 4 to 7, it is found surprisingly that samples containing PAPI 20 at the equal weight percentage amounts have much higher modulus than those containing N3300. This higher value of modulus is also true for higher temperatures.
  • Table 3 lists the storage modulus for comparative Samples 8 to 10. These samples show similar increase in storage modulus to comparative Samples 1 to 3 but not as dramatic increase as those of samples 4 to 7 of this invention.
  • Tables 7, 8 and 9 show the Young's Modulus of the samples. All samples have much higher Young's Modulus than that of the comparative Sample A. Samples containing aromatic polyisocyanate show the most significant increase for the Young's modulus.
  • Tables 10, 11 and 12 show the viscosities of these samples. Their viscosities are low enough at room temperature so that compositions are pump transferable.
  • the samples of the present invention have about the same viscosities of the comparative sample. Results from sag test on heat aged samples show that samples with aromatic polyisocyanate have the best sag resistant performance.
  • Table 13 shows the adhesion performance of the urethane adhesive compositions of the present invention. All samples of Samples 4 to 7 have shown the direct adhesion capability towards painted metal substrates with 100% cohesive failure (100% CF).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Adhesives Or Adhesive Processes (AREA)
US14/391,180 2012-05-22 2013-04-23 High modulus urethane adhesive compositions, manufacture and use thereof Abandoned US20150080529A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US14/391,180 US20150080529A1 (en) 2012-05-22 2013-04-23 High modulus urethane adhesive compositions, manufacture and use thereof

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261650189P 2012-05-22 2012-05-22
US14/391,180 US20150080529A1 (en) 2012-05-22 2013-04-23 High modulus urethane adhesive compositions, manufacture and use thereof
PCT/US2013/037684 WO2013176815A1 (fr) 2012-05-22 2013-04-23 Compositions adhésives d'uréthane à module élevé, leur fabrication et leur utilisation

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/037684 A-371-Of-International WO2013176815A1 (fr) 2012-05-22 2013-04-23 Compositions adhésives d'uréthane à module élevé, leur fabrication et leur utilisation

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US16/590,824 Continuation US11104831B2 (en) 2012-05-22 2019-10-02 High modulus urethane adhesive compositions, manufacture and use thereof

Publications (1)

Publication Number Publication Date
US20150080529A1 true US20150080529A1 (en) 2015-03-19

Family

ID=48289661

Family Applications (2)

Application Number Title Priority Date Filing Date
US14/391,180 Abandoned US20150080529A1 (en) 2012-05-22 2013-04-23 High modulus urethane adhesive compositions, manufacture and use thereof
US16/590,824 Active US11104831B2 (en) 2012-05-22 2019-10-02 High modulus urethane adhesive compositions, manufacture and use thereof

Family Applications After (1)

Application Number Title Priority Date Filing Date
US16/590,824 Active US11104831B2 (en) 2012-05-22 2019-10-02 High modulus urethane adhesive compositions, manufacture and use thereof

Country Status (6)

Country Link
US (2) US20150080529A1 (fr)
EP (1) EP2852626B1 (fr)
JP (1) JP6196297B2 (fr)
KR (1) KR20150013856A (fr)
CN (2) CN104334598A (fr)
WO (1) WO2013176815A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113614590A (zh) * 2019-04-30 2021-11-05 3M创新有限公司 光学叠堆

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4355838A1 (fr) * 2021-06-16 2024-04-24 DDP Specialty Electronic Materials US, LLC Adhésif de polyuréthane à un composant

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4758648A (en) 1986-10-20 1988-07-19 Essex Specialty Products, Inc. High speed cure sealant
DE4210277C5 (de) 1992-03-28 2009-02-26 Henkel Ag & Co. Kgaa Kleb- und Dichtstoff und dessen Verwendung
EP0764670A1 (fr) * 1995-09-25 1997-03-26 Minnesota Mining And Manufacturing Company Composition thermofusible réactive d'adhésif et/ou d'étanchéité
US5922809A (en) 1996-01-11 1999-07-13 The Dow Chemical Company One-part moisture curable polyurethane adhesive
US5852137A (en) 1997-01-29 1998-12-22 Essex Specialty Products Polyurethane sealant compositions
JP2005239753A (ja) * 2004-02-24 2005-09-08 Yokohama Rubber Co Ltd:The 一液湿気硬化型ウレタン組成物
WO2006042305A1 (fr) * 2004-10-08 2006-04-20 Dow Global Technologies Inc. Monomere d'isocyanate faiblement volatil contenant un prepolymere de polyurethanne et systeme adhesif
US7361292B2 (en) * 2004-11-08 2008-04-22 Dow Global Technologies Inc. High modulus, nonconductive adhesive useful for installing vehicle windows
JP4539298B2 (ja) * 2004-11-08 2010-09-08 横浜ゴム株式会社 一液湿気硬化型ウレタン組成物
EP1811006B1 (fr) * 2006-01-23 2009-03-04 Purbond AG Système adhésif
CN101595146B (zh) 2006-12-21 2012-11-14 陶氏环球技术公司 用作安装交通工具窗户的粘合剂的组合物
US8207252B2 (en) 2007-03-07 2012-06-26 Momentive Performance Materials Inc. Moisture-curable silylated polymer resin composition
EP2183294B1 (fr) 2007-07-23 2019-01-09 Dow Global Technologies LLC Composition vulcanisable de polyuréthane à deux parties ayant un module g sensiblement constant sur la plage de températures d'utilisation
US20090068479A1 (en) * 2007-09-11 2009-03-12 Sika Technology Ag Moisture-reactive adhesive compositions with very low temperature dependency of the shear modulus
EP2189485B1 (fr) * 2008-10-31 2011-02-16 Sika Technology AG Composition de polyuréthane contenant alpha-silane présentant des propriétés de matériaux anisotropes
WO2011137047A1 (fr) * 2010-04-30 2011-11-03 Dow Global Technologies Llc Adhésif amélioré pour verre de véhicule et procédé d'adhésion dudit verre

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113614590A (zh) * 2019-04-30 2021-11-05 3M创新有限公司 光学叠堆
US12117635B2 (en) 2019-04-30 2024-10-15 3M Innovative Properties Company Optical stack

Also Published As

Publication number Publication date
JP2015520262A (ja) 2015-07-16
EP2852626A1 (fr) 2015-04-01
WO2013176815A1 (fr) 2013-11-28
JP6196297B2 (ja) 2017-09-13
EP2852626B1 (fr) 2019-06-19
US20200032118A1 (en) 2020-01-30
US11104831B2 (en) 2021-08-31
KR20150013856A (ko) 2015-02-05
CN109265652A (zh) 2019-01-25
CN104334598A (zh) 2015-02-04

Similar Documents

Publication Publication Date Title
US10400145B2 (en) Latent two-part polyurethane adhesives cured with infrared radiation
JP5530355B2 (ja) 使用温度範囲を通して実質的に不変の弾性率ｇを有する２部分型ポリウレタンの硬化性組成物
JP4176840B2 (ja) ポリウレタンシーラント組成物
KR101568069B1 (ko) 경화 상태에서 개선된 내구성을 갖는 이소시아네이트 작용성 성분을 함유하는 경화성 조성물
US20060079661A1 (en) Low volatile isocyanate monomer containing polyurethane prepolymer and adhesive system
US9085716B2 (en) Alkoxysilane containing polyurethane adhesive compositions containing calcium carbonate
US9102854B2 (en) Polyurethane sealant compositions having high filler levels
EP3688061B1 (fr) Adhésif à fonction isocyanate se liant sans couche d'apprêt à un revêtement à base de polyol acrylique silané
US11104831B2 (en) High modulus urethane adhesive compositions, manufacture and use thereof
EP2718345B1 (fr) Polymères de polyuréthane
US20170275509A1 (en) Storage-stable, moisture-curing polyurethane adhesive with rapid adhesive formation on glass
JP5760691B2 (ja) ウレタン樹脂接着剤組成物
WO2018102333A1 (fr) Amidines bloquées par isocyanate en tant que catalyseurs de polyuréthane latents
WO2022081251A1 (fr) Adhésif de polyuréthane mono-composant
US20230017467A1 (en) A polyurethane composition having low total voc content capable of rapid curing with no need of primer
JP2024532204A (ja) 一液型ポリウレタン接着剤組成物
WO2014024262A1 (fr) Composition adhésive de résine d'uréthane
JPH03167286A (ja) 湿気硬化性シーリング材組成物

Legal Events

Date Code Title Description
AS Assignment

Owner name: DOW GLOBAL TECHNOLOGIES LLC, MICHIGAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:ZHU, HUIDE D.;KNEISEL, ANDREW R.;SOPHIEA, DANIEL P.;SIGNING DATES FROM 20120606 TO 20120614;REEL/FRAME:039129/0183

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE AFTER FINAL ACTION FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: ADVISORY ACTION MAILED

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION