US20140087034A1 - Biogenic amine oxidizer or unreactive absorber - Google Patents

Biogenic amine oxidizer or unreactive absorber Download PDF

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Publication number
US20140087034A1
US20140087034A1 US13/626,506 US201213626506A US2014087034A1 US 20140087034 A1 US20140087034 A1 US 20140087034A1 US 201213626506 A US201213626506 A US 201213626506A US 2014087034 A1 US2014087034 A1 US 2014087034A1
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United States
Prior art keywords
package
covering
oxidizer
permeable container
food
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
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US13/626,506
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English (en)
Inventor
George E. McKedy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Multisorb Technologies Inc
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Multisorb Technologies Inc
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Priority to US13/626,506 priority Critical patent/US20140087034A1/en
Assigned to MULTISORB TECHNOLOGIES, INC. reassignment MULTISORB TECHNOLOGIES, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MCKEDY, GEORGE E.
Priority to EP13841778.7A priority patent/EP2900569A4/fr
Priority to PCT/US2013/059854 priority patent/WO2014052053A1/fr
Priority to ARP130103437A priority patent/AR092675A1/es
Publication of US20140087034A1 publication Critical patent/US20140087034A1/en
Assigned to HSBC BANK USA reassignment HSBC BANK USA SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MULTISORB TECHNOLOGIES, INC.
Assigned to MULTISORB TECHNOLOGIES, INC. reassignment MULTISORB TECHNOLOGIES, INC. RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: HSBC BANK USA, NATIONAL ASSOCIATION
Abandoned legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
    • B65D81/266—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants
    • B65D81/268—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants the absorber being enclosed in a small pack, e.g. bag, included in the package
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/18—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
    • B65D81/20—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas
    • B65D81/2069—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas in a special atmosphere
    • B65D81/2084—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas in a special atmosphere in a flexible container

Definitions

  • This invention relates to the removal of biogenic amines during food storage and packaging.
  • MAP modified atmosphere packagings
  • JP 59-162832 A2 claims the addition of a polymeric substance, e.g. polyacrylate, to a vegetable package to remove bad odor such as amines from the package.
  • US 2002/010-6466-Hausmann at Al discloses the formation of a polymer film comprising up copolymer of ethylene with carboxylic acid to absorb odiferous compounds when packaging materials such as fish.
  • Mohan et al. in Food Research International 42 (2009) 411-416 discusses biogenic amine formation in seer fish and the use of oxygen absorbers comprising iron and citric acid in combination with chilling to reduce the amines.
  • U.S. Pat. No. 5,654,061-Visioli discloses sulfide scavenging packaging materials.
  • the invention provides a package for protein containing foods comprising a sealable food covering and, in the interior of the covering, a permeable container wherein an oxidizer is in the permeable container oxidizer substantially irreversibly reacts with biogenic amines within the covering to form compounds without objectionable odor or toxicity.
  • the invention provides a package for protein containing foods comprising a sealable food covering and, in the interior of the covering, a permeable container wherein an unreactive absorbent is in the permeable container and the unreactive absorbent absorbs, but does not react with biogenic amines within the covering to largely remove the biogenic amines from the package.
  • FIG. 1 is cross-sectional schematic view of a label or patch with absorbent of the invention.
  • FIG. 2 is a cross-sectional schematic of a sachet containing the biogenic amines absorber of the invention.
  • FIG. 3 is a schematic view of an invention package utilizing the biogenic amines absorber in a label.
  • FIG. 4 is a schematic cross-sectional view of the use of a biogenic amine absorber sachet in package.
  • the invention has numerous advantages over the prior art.
  • the invention provides a method of increasing the shelf life of protein rich foods such as meat and fish at low-cost while generally using present packaging and techniques.
  • Materials of the invention are safe and prevent the formation of toxins in stored meat and fish.
  • the materials of the invention have the advantage that they may be presented in the food packaging art in a way that is familiar to the art and readily carried out in protein packaging.
  • the invention increases the safety of stored foods while preserving their taste.
  • FIG. 1 is a schematic illustration of an absorber patch or label for biogenic amines.
  • the patch would be adhered to the inside of a covering forming a food package.
  • the patch 10 is comprised of a removable base 12 of a strippable material that will not adhere significantly to adhesive layer 14 .
  • the layer 16 is the support for the patch.
  • Layer 18 provides an adhesive layer for heat sealing the cover layer 28 around its edges 22 .
  • Cover layer 28 is permeable to gases but not liquids and attached to layer 18 at its edges 22 .
  • This type of label or patch is generally disclosed in U.S. Pat. No. 6,139,935-Cullen where the formation of oxygen absorbing labels is disclosed.
  • the formation of label or patch of the instant invention is similar except that the absorbent material is suitable for absorbing biogenic amines not for absorbing oxygen.
  • the unreactive or oxidizing absorber for biogenic amines 24 is shown as particles within a fibrous material 26 such as filter paper.
  • the material may be either a solid particle such as activated carbon or molecular sieve for the solid particle or may be an oxidizer such as hydrogen peroxide absorbed onto a carrier such as filter paper. It is noted that although the particles are shown as embedded in a fibrous material the oxidizers such as hydrogen peroxide would be a liquid that is absorbed onto the fibrous material. Solid particles of activated carbon could be placed under cover 22 as loose particles. Generally, it is preferred that solid particles be held in some sort of material to prevent their dispersal if their container is ripped.
  • the invention in another embodiment, includes a biogenic releasable absorbing composition including an absorber that will releasably retain the biogenic amine and an oxidizer that will react with the biogenic amine to irreversibly retain the biogenic amine.
  • the oxidizer will react with the biogenic amine to convert the biogenic amine into another compound that cannot later be released back into the package.
  • the releasable absorber draws the biogenic amine into the composition and the oxidizer absorber reacts with the biogenic amine to form a new compound from which the biogenic amine is not released.
  • the releasable absorber may be any substance that will releasably retain the biogenic amine.
  • the releasable absorber preferably is a porous structure that allows for retention of the biogenic amine in its pores.
  • Releasable absorbers usable in the invention include, but are not limited to, activated carbon and silica gel.
  • the releasable absorber may remove the biogenic amine from a headspace of a container.
  • the releasable absorber can lead to subsequent release of the biogenic amine.
  • preferred embodiments of the invention utilize an oxidizer material that irreversibly reacts with the biogenic amine.
  • FIG. 2 Illustrated schematically in cross-section FIG. 2 is a sachet 30 that could be used in a package as a biogenic amines absorber.
  • the sachet 30 has a cover 32 which is water impermeable and gas permeable.
  • the sachet is sealed at 34 and 36 , and formed from either a tubular sheet member or flat sheet that has been folded over and sealed to form a tube.
  • the tube is filled with the biogenic amine absorber prior to both of the ends being sealed.
  • the absorber shown as particles 38 which may be activated carbon or molecular sieve particles.
  • An oxidizer such as hydrogen peroxide could be absorbed in a fibrous absorbent cellulose member such as the cellulose member 26 utilized in FIG. 1 .
  • FIG. 3 is a package 40 for preparing a protein material such as fish 46 for display or shipping prior to sale.
  • the package comprises a covering 42 that is the outer covering of the package.
  • the covering comprises a bag 42 that is sealed shut at 48 .
  • the package 48 has a patch or label 10 fastened to the surface of the covering bag 42 .
  • the fish is carried in tray 44 . After the fish 46 , tray 44 , and patch 10 have been placed into the covering it is sealed at 48 . While illustrated as having the large space for gas the bag would likely be subjected to vacuum or a modified atmosphere in the bag to lower oxygen content to slow decay and result in closely wrapped fish or other protein material. Conventional packing cannot eliminate oxygen coming from the protein and some decay is caused by enzymes.
  • the biogenic amine unreactive absorber 10 will absorb amines given off by the fish and lengthen the time when the fish is suitable for consumer use as it does not have significant odor. Unreactive absorbers will absorb biogenic amines, but do not react with the biogenic amine. The unreactive absorbers will largely remove biogenic amines from the consumer package. By “largely remove” it is meant that the biogenic amines are not objectionable to the consumer when the package is opened. The level of biogenic amines not objectionable will vary depending on the particular protein being stored and what biogenic amine is being given off.
  • FIG. 4 is a schematic cross-section of a package 50 for fish or other protein with biogenic amines given off from this protein being absorbed by sachet 30 .
  • the FIG. 4 package is similar to the FIG. 3 package.
  • the permeable container of the invention that holds the biogenic amines absorber has been illustrated as either a sachet 30 or a label or patch 10 the invention is not limited to these particular containers for biogenic amine absorbers.
  • the container also could be a permeable tube or a container that has one permeable side. It further could be formed of a polymer strip that had biogenic amines absorber embedded strip.
  • the covering used in the package may be any polymer material that provides good oxygen barrier properties for the food inside. Typical of such materials are polycarbonate, and polyvinyl alcohols, lactic acid polymers, polyesters and polypropylene.
  • a preferred material is polyethylene, particularly low density polyethylene because it is low in cost and has good barrier properties.
  • the covering for the package may be wrapped onto the package and sealed, it may be a bag that is sealed, or may be a tube that is sealed at both ends.
  • the formation of sealed air tight food packages is well known.
  • the water impermeable air permeable covering for at least a portion of the sachet, container or label of the invention may be any material that will pass the amines and inhibits passage of water or other liquids. Typical of such materials are microporous spun bonded materials and microporous materials formed by stretching a voided material. A preferred material is a spun bonded polyolefin material such as the well-known Tyvek trademark material.
  • Biogenic amines such as trimethylamine are synthesized by decaying animal, plant and enzymatic metabolisms, and consequently are found in a wide variety of food products. Biogenic amine formation is initially the result of protein breakdown. Biogenic amines are related to food safety and food quality issues, as some biogenic amines are associated with several acute adverse reactions in consumers. All protein rich foods subjected to the conditions that allow bacterial development and activity are expected to accumulate certain amounts of biogenic amines. Biogenic amines are in fresh meats, fresh meat products, cooked meat products, cured meat products and fermented meat products.
  • Biogenic amines are also found in chesses, tofu, alcoholic beverages, chocolate, sour cream, yogurt, beans, peas, sauerkraut, some fruits, some nuts, and fish.
  • Some of the biogenic amines are trimethylamine, tyramine, tryptamine, phenylamine, histamine, putrescine, phenylethylaminne, agmatine, spermidine, spermine and cadaverine.
  • Fish has been rejected by taste panels in the range of 3.0-9.5 mg/100. grams (3-9.5 ppm) of trimethylamine in fish. Trimethylamine gives fish the pungent fishy odor.
  • the human odor detection threshold of trimethylamine is 0.00026-2.1 mg/m3 (0.00026-2.1 ppm). Because the threshold of detection is so low, this unpleasant odor becomes apparent long before the wholesomeness of the food is compromised. It is desirable therefore to reduce the biogenic amine odor so that the product is not rejected by the consumer prematurely. This is why common culinary practice is to sprinkle lemon juice on a fish fillet, for instance, or to serve a wedge of lemon for the diner's use if they want to reduce the fishy odors.
  • the packages of the invention will reduce the biogenic amine to below the level a human finds unpleasant and off-putting.
  • the absorbers of the invention will reduce the biogenic amines after 7 days of refrigerated storage to a level that is acceptable to consumers.
  • the level is suitably less than 10 ppb biogenic amine.
  • a preferred level of less than 3 ppm is obtainable for a closely wrapped piece of fish after 7 days refrigerated storage. Closely wrapped means not baggy or loose.
  • the gas space is much less that the protein space in a closely wrapped package.
  • biogenic amines given off by foods, other than fish amounts somewhat greater than 5 ppb are not objectionable and greater amounts of these biogenic amines are acceptable to the consumer.
  • the oxidizer may be any material that will oxidize biogenic amines from the atmosphere. Typical of such oxidizers are hydrogen peroxide, sodium chlorite, sodium perchlorate, sodium chlorate, sodium hypochlorite, calcium hypochlorite, sodium chlorate, and potassium permanganate.
  • the preferred oxidizers are hydrogen peroxide and sodium chlorite as they rapidly oxidize vaporous biogenic amines and are safe for use with foods.
  • Any unreactive biogenic amine absorber may be utilized that it is substantially unreactive with biogenic amines.
  • Typical of such materials are activated carbon, silica gel, molecular sieve and clay. Suitable materials are molecular sieve and feldspar.
  • Preferred nonreactive absorbers are activated carbon and silica gel as they absorb biogenic amines in high amounts and are safe for use with foods.
  • Any amount of unreactive absorbent or oxidizer may be used that is effective in a particular package. The amount needed varies with the type of protein packages and the absorber as well as how much protein is packaged.
  • An objective of the invention is to formulate an unreactive absorber or oxidizer for biogenic amine absorbers that will absorb and react with the biogenic amines that are formed, eliminating the off taste and off odor of the food thereby increasing the shelf life and quality of the food product.
  • the oxidizer could be used alone or adsorbed onto an adsorbent such as blotting paper. This would allow the biogenic amine to be irreversibly adsorbed and neither the food product nor consumer would not be in contact with the actual reactant.
  • the hydrogen peroxide could be absorbed in an unreactive absorber particle such as activated carbon or silica gel.
  • an 11 ⁇ 16 inch foil laminated pouch was used to test efficacy of the biogenic amine adsorbers. Inside of the foil pouch was placed a small Tyvek packet with the adsorber material along with a moisture source which was 0.4 grams of water on blotter paper. If the adsorber was a liquid oxidizer such as hydrogen peroxide then the adsorber was put on blotter paper inside of a packet and placed inside of the foil pouch with the moisture source. This foil pouch was then vacuumed, heated sealed and filled with three liters of gas containing 10 ppm of trimethylamine. Blank foil pouches were also filled with the trimethylamine containing gas to be used as a standard.
  • the blanks were determined to contain 12,000 and 13,000 ppb trimethylamine for the 7 day test at room temperature.
  • the blanks were determined to contain 4,500 and 5,200 ppb of trimethylamine at room temperature at the beginning of the test.
  • an outside analytical laboratory measured the trimethylamine content of the foil pouch.
  • the analytical method used was microextraction gas chromatography mass spectroscopy. 5 ppb is the detection limit of the analytical method for trimethylamine.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Food Science & Technology (AREA)
  • Packages (AREA)
  • Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
US13/626,506 2012-09-25 2012-09-25 Biogenic amine oxidizer or unreactive absorber Abandoned US20140087034A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US13/626,506 US20140087034A1 (en) 2012-09-25 2012-09-25 Biogenic amine oxidizer or unreactive absorber
EP13841778.7A EP2900569A4 (fr) 2012-09-25 2013-09-16 Oxydant ou absorbeur non réactif d'amine biogène
PCT/US2013/059854 WO2014052053A1 (fr) 2012-09-25 2013-09-16 Oxydant ou absorbeur non réactif d'amine biogène
ARP130103437A AR092675A1 (es) 2012-09-25 2013-09-25 Oxidante o absorbedor no reactivo de aminas biogenicas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US13/626,506 US20140087034A1 (en) 2012-09-25 2012-09-25 Biogenic amine oxidizer or unreactive absorber

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US20140087034A1 true US20140087034A1 (en) 2014-03-27

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US13/626,506 Abandoned US20140087034A1 (en) 2012-09-25 2012-09-25 Biogenic amine oxidizer or unreactive absorber

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US (1) US20140087034A1 (fr)
EP (1) EP2900569A4 (fr)
AR (1) AR092675A1 (fr)
WO (1) WO2014052053A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20200198870A1 (en) * 2018-12-21 2020-06-25 Altria Client Services Llc Pouch with oxygen scavenger and method of forming pouch with oxygen scavenger
TWI714821B (zh) * 2018-01-24 2021-01-01 國立高雄大學 檢測食材生物胺方法及其裝置
CN112304929A (zh) * 2019-07-24 2021-02-02 高雄大学 检测食材生物胺方法及其装置
US20210322609A1 (en) * 2020-04-20 2021-10-21 Honeywell Federal Manufacturing & Technologies, Llc Methods and devices for sterilizing medical equipment
US20220401919A1 (en) * 2019-11-29 2022-12-22 Saes Getters S.P.A. Food package for amines control or removal

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EP0781242A1 (fr) * 1994-09-14 1997-07-02 Sealed Air (NZ) Limited Conditionnement de la viande et d'autres produits alimentaires
US5977212A (en) * 1997-11-21 1999-11-02 W. R. Grace & Co.-Conn. Oxygen scavenging compositions
US6269945B1 (en) * 1998-10-29 2001-08-07 Tres Fresh Llc Packaging system for preserving perishable items
US20040033269A1 (en) * 2002-08-06 2004-02-19 Ecolab Inc. Critical fluid antimicrobial compositions and their use and generation
EP1435203A1 (fr) * 1998-08-20 2004-07-07 Ecolab Inc. Procédé de traitement d'un produit à base de viande pour diminuer une population microbienne du produit à base de viande
US20120213662A1 (en) * 2011-02-18 2012-08-23 Siemens Industry, Inc. Synergistic methods for odor control

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EP1435203A1 (fr) * 1998-08-20 2004-07-07 Ecolab Inc. Procédé de traitement d'un produit à base de viande pour diminuer une population microbienne du produit à base de viande
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US20120213662A1 (en) * 2011-02-18 2012-08-23 Siemens Industry, Inc. Synergistic methods for odor control

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI714821B (zh) * 2018-01-24 2021-01-01 國立高雄大學 檢測食材生物胺方法及其裝置
US20200198870A1 (en) * 2018-12-21 2020-06-25 Altria Client Services Llc Pouch with oxygen scavenger and method of forming pouch with oxygen scavenger
US11021312B2 (en) * 2018-12-21 2021-06-01 Altria Client Services Llc Pouch with oxygen scavenger and method of forming pouch with oxygen scavenger
CN112304929A (zh) * 2019-07-24 2021-02-02 高雄大学 检测食材生物胺方法及其装置
US20220401919A1 (en) * 2019-11-29 2022-12-22 Saes Getters S.P.A. Food package for amines control or removal
US11772070B2 (en) * 2019-11-29 2023-10-03 Saes Getters S.P.A. Food package for amines control or removal
US20210322609A1 (en) * 2020-04-20 2021-10-21 Honeywell Federal Manufacturing & Technologies, Llc Methods and devices for sterilizing medical equipment
US11672880B2 (en) * 2020-04-20 2023-06-13 Honeywell Federal Manufacturing & Technologies, Llc Methods and devices for sterilizing medical equipment

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EP2900569A4 (fr) 2016-06-01
EP2900569A1 (fr) 2015-08-05
AR092675A1 (es) 2015-04-29
WO2014052053A1 (fr) 2014-04-03

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