US20080241086A1 - Line of cosmetic compositions - Google Patents

Line of cosmetic compositions Download PDF

Info

Publication number
US20080241086A1
US20080241086A1 US11/984,193 US98419307A US2008241086A1 US 20080241086 A1 US20080241086 A1 US 20080241086A1 US 98419307 A US98419307 A US 98419307A US 2008241086 A1 US2008241086 A1 US 2008241086A1
Authority
US
United States
Prior art keywords
composition
composition according
pigment
multilayer interference
color
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/984,193
Other languages
English (en)
Inventor
Ludovic Thevenet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR0654977A external-priority patent/FR2908633A1/fr
Priority claimed from FR0654975A external-priority patent/FR2908656A1/fr
Priority claimed from FR0654979A external-priority patent/FR2908635A1/fr
Priority claimed from FR0654982A external-priority patent/FR2908638A1/fr
Priority claimed from FR0654981A external-priority patent/FR2908637A1/fr
Priority claimed from FR0654980A external-priority patent/FR2908636A1/fr
Priority claimed from FR0655458A external-priority patent/FR2908642A1/fr
Priority claimed from FR0655454A external-priority patent/FR2908639A1/fr
Priority claimed from FR0655459A external-priority patent/FR2908643A1/fr
Priority claimed from FR0655452A external-priority patent/FR2908632B1/fr
Priority claimed from FR0655457A external-priority patent/FR2908641B1/fr
Priority claimed from FR0655460A external-priority patent/FR2908644B1/fr
Priority to US11/984,193 priority Critical patent/US20080241086A1/en
Application filed by LOreal SA filed Critical LOreal SA
Assigned to L'OREAL reassignment L'OREAL ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: THEVENET, LUDOVIC
Publication of US20080241086A1 publication Critical patent/US20080241086A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/436—Interference pigments, e.g. Iridescent, Pearlescent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/437—Diffractive phenomena; Photonic arrays
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/438—Thermochromatic; Photochromic; Phototropic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/08—Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00—Manicure or pedicure preparations
    • A61Q3/02—Nail coatings

Definitions

  • the present invention relates to cosmetic compositions, and more particularly to compositions for making up the skin, the lips, hair, or the nails.
  • coloring agents having a color that is sensitive to an external stimulus
  • the coloring agents also being referred to as “Xchrome” coloring agents, with X designating the external factor.
  • the coloring agents can be photochromic, thermochromic, solvatochromic, or tribochromic coloring agents.
  • the coloring agent that is sensitive to at least one external stimulus may be suitable in one state for taking on a bulk color of dominant wavelength that differs from the dominant wavelength of the composition by an amount ⁇ of less than 30 nm.
  • a characteristic makes it possible for the Xchrome coloring agent and the multilayer interference pigment to be substantially the same color, for example.
  • the bulk color of the Xchrome coloring agent in the composition may be colorless, which can be preferable, particularly when said composition is white.
  • the invention also provides a loose- or compacted-powder composition including, in a cosmetically-acceptable medium:
  • the invention provides a solid cosmetic composition, in particular in stick form, comprising in a cosmetically-acceptable medium at least one multilayer interference pigment suitable for conferring a white color to the composition in its bulk, and for giving rise, after application of the composition, to a color variation ⁇ E of at least 5.
  • the composition may be anhydrous or aqueous.
  • the coverage of the composition may lie in the range 30 to 70, in particular it may be greater than any integer lying in said range, for example it may be greater than or equal to 40.
  • the second composition need have no solid bodies, so as to avoid diffusing light reflected by the first composition.
  • the second composition may include at least one effect pigment, in particular a metallic reflecting pigment, interference pigments, compounds having properties chosen from photochromic, thermochromic, solvatochromic, piezochromic, tribochromic, or mechanoluminescent properties.
  • the first composition may include two multilayer interference pigments having layers made of the same material, at least one layer of one pigment having a thickness that is different from a corresponding layer of the other pigments so as to produce different colors.
  • the second composition as a top coat may comprise a liquid fatty body or a film-forming agent.
  • the top coat composition is preferably liquid and transparent, advantageously including a fatty phase.
  • the first composition can be packaged in a device that includes means that are representative of the color that is revealed on application, e.g. a deposit of a layer of a composition or of an ink or a varnish that includes the same coloring agent as the first composition.
  • the amount of multilayer interference pigment in at least one of the compositions may lie in the range 7% to 20%, by weight, better 8% to 15%.
  • the color of at least one of the compositions in its bulk may be white. All of the blocks may be white, i.e. achromatic in the CIE meaning, with a whiteness index greater than or equal to 40, for example.
  • At least one of the blocks may present a melting point or thermal transition temperature (e.g. a softening point) greater than 25° C., in particular lying in the range 250° C. to 85° C. or 30° C. to 60° C., and in particular in the range 30° C. to 45° C.
  • a melting point or thermal transition temperature e.g. a softening point
  • the hardness of at least one of the blocks of composition may, for example, lie in the range 0.001 megapascals (MPa) to 0.5 MPa, in particular in the range 0.005 MPa to 0.4 MPa.
  • the hardness of the block may be determined by measuring compression force at 20° C. with the help of a texture meter sold under the name TA-XT2i® by the supplier RHEO, fitted with a stainless steel cylinder having a diameter of 2 millimeters (mm) that moves at a measuring speed of 0.01 millimeters per second (mm/s), and penetrating into the composition of the block to a penetration depth of 0.3 mm.
  • hardness can also be measured by the so-called “cheese-wire” method which consists in cutting a stick of lipstick having a diameter of 8.1 mm and in measuring hardness at 20° C. by means of a DFGHS 2 dynamometer from the supplier Indelco-Chatillon moving at a speed of 100 millimeters per minute (mm/min).
  • the measured hardness is expressed as the shear force (expressed in grams force) needed to cut the stick under such conditions.
  • the hardness of a solid cosmetic of the invention may lie for example in the range 50 grams (g) to 300 g, e.g. in the range 100 g to 250 g, and for example in the range 120 g to 230 g.
  • compositions for example, compositions for application to the lips, in particular liquid lipsticks, liquid lip glosses, and liquid lip balms; nail varnishes; eyeshadows; liquid foundations; mascara; and other liquid makeup that is not for application to the lips.
  • liquid compositions for example, compositions for application to the lips, in particular liquid lipsticks, liquid lip glosses, and liquid lip balms; nail varnishes; eyeshadows; liquid foundations; mascara; and other liquid makeup that is not for application to the lips.
  • the measurements are performed on the compositions spread in this way.
  • compositions are compositions cast in stick form, or they are powders in loose or compacted form.
  • Reflection spectra are acquired by means of a MINOLTA 3700-d spectrocolorimeter (measurement shape diffuse/8° and observation D65/10°, specular component mode excluded, small opening (CREISS)) on black and white backgrounds, contrast cards optionally being covered in BLENDERM® as indicated above.
  • MINOLTA 3700-d spectrocolorimeter measurement shape diffuse/8° and observation D65/10°, specular component mode excluded, small opening (CREISS)
  • the spectra are expressed in calorimetric co-ordinates in the CIELab76 space in the meaning of the CIE in accordance with recommendation 15:2004.
  • the coverage or contrast ratio is calculated by taking the arithmetic mean of Y on a black background, divided by the mean value of Y on a white background, multiplied by 100.
  • the bulk color is measured after filling a container that presents a depth that is sufficiently deep to enable the thickness of composition to be considered as being infinite for measurement purposes, e.g. a depth of 3 mm or more.
  • the L*, a*, and b* co-ordinates are measured with a spectrocolorimeter, e.g. of trade name MINOLTA CM-2002 (D65/10°, specular component mode excluded).
  • a spectrocolorimeter e.g. of trade name MINOLTA CM-2002 (D65/10°, specular component mode excluded).
  • the composition may include a single multilayer interference pigment or a plurality of multilayer interference pigments having different dominant wavelengths.
  • the multilayer interference pigment may comprise a substrate (also known as a core) that is covered, on at least one face, by one or more layers made of materials and thicknesses that are selected such that a color is produced by interference.
  • the interference pigment may include more than four layers of different refractive indices.
  • the proportion of multilayer interference pigment is greater than 7%, for example, and lies in the range 7% to 20%, for example, for a non-powder, liquid, or cast composition, e.g. a composition in stick form, and in the range 40% to 95%, for example, for a loose- or compacted-powder composition.
  • Suitable goniochromatic pigments are some nacres; pigments having effects on synthetic substrates, in particular alumina, silica, borosilicate, iron oxide, or aluminum type substrates; or interference flakes coming from a polyterephthalate film.
  • They may be photochromic coloring agents.
  • R′ 1 represents a group selected from:
  • thermochromic agent may comprise capsules of a polymer containing a solvent, that solvent, depending on whether it is in the molten state or otherwise, allowing compounds to come into contact and modify the light absorption properties.
  • the color change may be reversible.
  • Mechanoluminescent materials that may be mentioned are as follows:
  • transition metal ions are copper or manganese.
  • Preferred rare earth ions are europium or cerium. Of these materials, ZnS:Mn is preferred.
  • the materials listed under b) and c) may be synthesized by a solid phase reaction involving dry mixing followed by heat treatment and high temperature sintering, or by a sol-gel process followed by drying, heating and sintering.
  • the sintering temperature is more than 1000° C.
  • the materials listed under b) are preferred. Of these, SrAl 2 O 4 and SrMgAl 10 O 17 doped with rare metals are preferred.
  • the reflecting pigment with metallic reflection is not a multilayer interference pigment in the meaning of the invention.
  • the reflecting particles with metallic reflection may be in flakes or they may be globular, in particular spherical, optionally elongate, with a large form factor, where appropriate. When in the form of flakes, that can enable reflection to be more directional. In contrast, a substantially spherical shape can serve to provide reflection that is more diffuse.
  • the reflecting particles with metallic reflection include at least one electrically conductive layer on the surface, formed by at least one optionally doped metal or metal oxide.
  • particles comprising a borosilicate substrate coated in silver As examples of reflecting particles with metallic reflection comprising an inorganic substrate coated in a layer of metal, mention can be made of particles comprising a borosilicate substrate coated in silver. Particles having a glass substrate coated in silver and in the form of flakes are sold under the name MICROGLASS METASHINE REFSX 2025 PS by the supplier TOYAL. Particles with a glass substrate coated in an alloy of nickel-chromium-molybdenum are sold under the name CRYSTAL STAR GF 550, GF 2525 by the same supplier.
  • the reflecting particles with metallic reflection may be present in the composition in an amount lying in the range 0.1% to 60% relative to the total weight of the first composition, and in particular in the range 1% to 30% by weight, e.g. in the range 3% to 10% by weight.
  • the reflecting pigment with metallic reflection may contribute to obtaining the looked-for coverage.
  • the spatial frequency of the matrix and the motif depth will be selected as a function of the desired degree of separation of the various orders.
  • the frequency may lie in the range 500 to 3000 lines per mm.
  • the diffracting pigment may have a multi-layered structure comprising a layer of reflective material, covered on at least one side by a layer of a dielectric material. This layer may provide the diffracting pigment with better rigidity and durability.
  • the dielectric material may thus, for example, be selected from the following materials: MgF 2 , SiO 2 , Al 2 O 3 , AlF 3 , CeF 3 , LaF 3 , NdF 3 , SmF 2 , BaF 2 , CaF 2 , LiF, and combinations thereof.
  • the oils may be present at a content lying in the range 0.01% to 90% relative to the total composition weight.
  • Suitable film-forming polymers include synthetic polymers, of the radical or polycondensate type, natural polymers, and mixtures thereof.
  • copolymers examples include the following copolymers: vinyl acetate and allyl stearate; vinyl acetate and vinyl laurate; vinyl acetate and vinyl stearate; vinyl acetate and octadecene; vinyl acetate and octadecyl vinyl ether; vinyl propionate and allyl laurate; vinyl propionate and vinyl laurate; vinyl stearate and 1-octadecene; vinyl acetate and 1-dodecene; vinyl stearate and ethyl vinyl ether; vinyl propionate and cetyl vinyl ether; vinyl stearate and allyl acetate; vinyl dimethyl-2,2 octanoate and vinyl laurate; allyl dimethyl-2,2 pentanoate and vinyl laurate; vinyl dimethyl propionate and vinyl stearate; allyl dimethyl propionate and vinyl stearate; vinyl propionate and vinyl stearate;
  • the composition can include one or more diffusing pigments, generating a color by an absorption phenomenon, in a proportion that makes it possible to preserve the interference phenomenon that is responsible for the color of the composition once applied to keratinous materials.
  • composition may not comprise other coloring agents than the multilayer interference pigment(s), for example not comprise pigments comprising iron oxides or other pigments producing colors by a phenomenon of absorbing light.
  • Particular organic lakes include those with the following denominations: D&C Red No. 2 Aluminum lake, D&C Red No. 3 Aluminum lake, D&C Red No. 4 Aluminum lake, D&C Red No. 6 Aluminum lake, D&C Red No. 6 Barium lake, D&C Red No. 6 Barium/Strontium lake, D&C Red No. 6 Strontium lake, D&C Red No. 6 Potassium lake, D&C Red No. 7 Aluminum lake, D&C Red No. 7 Barium lake, D&C Red No. 7 Calcium lake, D&C Red No. 7 Calcium/Strontium lake, D&C Red No. 7 Zirconium lake, D&C Red No. 8 Sodium lake, D&C Red No. 9 Aluminum lake, D&C Red No.
  • the diffusing pigment can be a composite pigment, comprising a core that is coated at least in part by a husk.
  • a composite pigment may be composed of particles comprising an inorganic core and at least one at least partial coating of at least one organic coloring substance.
  • At least one binder may advantageously contribute to fixing the organic coloring substance onto the inorganic core.
  • suitable natural hydrosoluble coloring agents that may be mentioned in particular for use in the invention are: caramel; beetroot juice; carmine; betanine (beetroot); copper chlorophyllin; methylene blue; anthocyanin (enocianin, black carrot, hibiscus, elder); and riboflavin.
  • suitable natural liposoluble coloring agents that may be mentioned in particular for use in the invention are: Sudan red; ⁇ -carotene; carotenoids; lycopene; palm oil; Sudan brown; quinoline yellow; xanthophylls (capsanthin, capsorubin, lutein); and curcumin.
  • Suitable natural colorants that may be mentioned more particularly are: anthcyanin flowers or fruit or derivatives thereof; flavonoids and tannin extracts of native or fermented plants; juglone; lawsone; extracts of fermented soya, algae, mushrooms, micro-organisms; Flavylium salts non-substituted in position 3 as described in patent EP 1 172 091; extracts of Gesneria Fulgens, Blechum Procerum, Saxifraga ; and pigments that can be extracted with an organic or hydro-organic solvent from a culture medium of a microfungus of the monascus Monascus type.
  • Suitable cosmetically, dermatologically, hygienically, or pharmaceutically active ingredients for use in the compositions of the invention are moisturizing agents (polyols such as glycerine), vitamins (C, A, E, F, B, or PP), essential fatty acids, essential oils, ceramides, sphingolipids, liposoluble or nanoparticle sun screens, and specific skin treatment active ingredients (protective agents, antibacterials, anti-wrinkle agents, etc).
  • Said active ingredients may be used in concentrations in the range 0.001% to 15%, for example, relative to the total weight of the composition.
  • composition may also include constituents which are conventionally used in the fields under consideration, and which are present in quantities appropriate to the desired dosage or “galenical” form.
  • anhydrous composition means a composition having less than 5% by weight of water, better less than 3%, or even less than 1%.
  • An anhydrous composition need not include water that has been intentionally added during the preparation of the composition.
  • composition may be packaged in any receptacle or on any support provided for this purpose.
  • Application can also be performed using a finger or by placing the composition directly on the substrate that is to be made up, for example by rubbing a stick or by spraying with the help of a piezoelectric device, or by transferring a layer of composition that has previously been deposited on an intermediate substrate.
  • the packaging device is a receptacle having a body that is transparent, at least in part, and/or includes a stopper member that is transparent, at least in part.
  • the composition can be packaged in a device that makes it possible to see both the bulk color of the composition and the color of the composition after application to keratinous materials.
  • the composition can also be packaged in a device that includes means that are representative of the color that is revealed on application, e.g. a deposit of a layer of the composition or of an ink or a varnish that includes the same coloring agents as the composition.
  • Packaging the composition can be arranged in such a manner as to make it possible to expose the coloring agent(s) that is/are sensitive to an external stimulus to said stimulus, so as to be able to observe a change in color in the composition within its bulk or after application, while being exposed to the stimulus.
  • the cosmetic composition in its packaging, can present a zone that can optionally be exposed to light.
  • the first and second regions belong to different samples.
  • the first and second regions correspond to the same region, and the diffused and directional lighting are applied in alternation.
  • the display stand can be arranged so as to make it possible to expose the coloring agent(s) that is/are sensitive to an external stimulus to said stimulus, so as to reveal the corresponding variation in color.
  • Octyl-2 dodecanol 10 Ditertiobutyl 4-hydroxytoluene 0.07 Polybutene (monoolefins/isoparaffins 95/5) 37 (MW: 2060) A mixture of isopropyl, isobutyl, and n-butyl 0.6 p-hydroxybenzoates (40/30/30) Pentaerythrityl tetraisostearate 11.33 Tridecyl trimellitate 11 2-decyl tetradecanoic acid triglyceride 15 (GUERBET C24) Multilayer interference pigment* 12 Xchrome coloring agent** 3 *TIMIRON SILK RED by MERCK. **REVERSACOL by JAMES ROBINSON.
  • Triethanolamine 1 Disodium ethylene diamino tetraacetic acid salt, 0.2 2H 2 0 Cross-linked carboxyvinyl homopolymer 0.5 Polyvinylpyrrolidone 0.6 Glycerol 5.75 Demineralized water 77.45 1,3-butylene glycol 2 Silica microsphere (3 ⁇ m) 1.5 Multilayer interference pigment* 8 Xchrome coloring agent** 3 *TIMIRON SILK RED by MERCK. **Photogenica ® by CATALYST & CHEMICALS.
  • the effect produced by this nail varnish is a result of the association of a plurality of phenomena.
  • the first relates to the color rendering on application, which is intense and covering. To that is added the Xchromic effect that induces a change in color depending on the type of light and how it is exposed.
  • This nail varnish presents a bulk color that is white.
  • the effect produced by this eyeshadow is a result of the association of a plurality of phenomena.
  • the first relates to the color rendering on application, which is intense and covering. To that is added the Xchromic effect that induces a change in color depending on the type of light and how it is exposed.
  • This eyeshadow presents a bulk color that is white.
  • the examples 8 to 14 relate to compositions comprising at least one multilayer interference pigment and at least one reflecting pigment with metallic reflection.
  • This lip gloss presents a bulk color that is white.
  • This lipstick presents a bulk color that is white.
  • Triethanolamine 1 Disodium ethylene diamino tetraacetic acid salt, 0.2 2H 2 0 Cross-linked carboxyvinyl homopolymer 0.5 Polyvinylpyrrolidone 0.6 Glycerol 5.75 Demineralized water 77.45 1,3-butylene glycol 1,3 2 Silica microsphere (3 ⁇ m) 1.5 Multilayer interference pigment* 8 Metallic reflection pigment** 3 *TIMIRON SILK RED by MERCK. **METASHINE ME 2040 PS by NIPPON SHEET GLASS.
  • the background is preferably spread out well in order to reveal the color effect.
  • a flocked endpiece can be used for this purpose.
  • the examples 15 to 20 relate to compositions having at least one multilayer interference pigment and at least one diffracting pigment.
  • the effect produced by this lipstick is a result of the association of a plurality of phenomena.
  • the first relates to the color rendering on application, which is intense and covering. To that is added the “rainbow effect” provided by the diffracting pigment.
  • This lipstick presents a bulk color that is white.
  • the effect produced by this nail varnish is a result of the association of a plurality of phenomena.
  • the first relates to the color rendering on application, which is intense and covering. To that is added the “rainbow effect” provided by the diffracting pigment.
  • This nail varnish presents a bulk color that is white.
  • Second composition Octyl-2 dodecanol 10 DITERTIOBUTYL 4-hydroxytoluene 0.07 Polybutene (monoolefins/isoparaffins 95/5) 50 (PM: 2060) A mixture of isopropyl, isobutyl, and n-butyl 0.4 p-hydroxybenzoates (40/30/30) Pentaerythrityl tetraisostearate 11.33 Tridecyl trimellitate 12 2-decyl tetradecanoic acid triglyceride 11 (GUERBET C24) Effect pigment** 3 **METASHINE ME 2040 PS by NIPPON SHEET GLASS.
  • Tridecyl trimellitate 12 Liquid lanolin 11 Isostearyl malate 14 Acetylated lanolin 11 Lauric/palmitic/cetylic/stearic acid 6 triglycerides (50/20/10/10) Microcrystalline wax (C20-C60) 3 Protected isopropyl lanolate 10 Octyl-2-decanol 16 Phenyl trimethylsiloxytrisiloxane 4 (VISCOSITY: 20 CST-PM: 372) Polyethylene wax (PM: 500) 8 Black iron oxide (Fe 3 O 4 ) pigment* 5 *TIMIRON SILK RED by MERCK.
  • Composition containing multilayer interference pigment Octyl-2 dodecanol 10 DITERTIOBUTYL 4-hydroxytoluene 0.07 Polybutene (monoolefins/isoparaffins 95/5) 45.2 (PM: 2060)
  • Pentaerythrityl tetraisostearate 11.33
  • Tridecyl trimellitate 12 2-decyl tetradecanoic acid triglyceride 11 (GUERBET C24)
  • compositions of the cosmetic are melted and mixed together, and then the coverage is measured as described above for a single composition.
  • the medium may include a pasty compound selected for example from:
  • the pasty compound is preferably a polymer, in particular a hydrocarbon.
  • silicone and fluorinated pasty compound is polymethyl trifluoropropyl methylaklyl dimethylsiloxane manufactured under the name X22-1088 by the supplier SHIN-ETSU.
  • esters the following are particularly preferred:
  • the hydroxy aliphatic carboxylic acid ester is advantageously derived from a hydroxylated aliphatic carboxylic acid having 2 to 40 carbon atoms, preferably 10 to 34 carbon atoms, and better 12 to 28 carbon atoms, and 1 to 20 hydroxyl groups, preferably 1 to 10 hydroxyl groups and better 1 to 6 hydroxyl groups.
  • the hydroxy aliphatic carboxylic acid ester is selected from:
  • the pasty compounds preferably represent 1% to 99%, preferably 1% to 60%, better 2% to 30%, and better still 5% to 15% by weight of each composition of the solid cosmetic.
  • the pasty compound is an ester as defined above suitable for being associated in the cosmetic composition in a ratio by weight between the pasty compound and the ester lying in the range 0.25 to 0.75, in particular 0.3 to 0.6.
  • the cosmetic composition of the invention may present a continuous fatty phase, possibly containing less than 5% water, and in particular less than 1% water relative to its total weight.
  • Each composition in particular when the cosmetic is for application to the lips, may include at least one fatty phase and in particular at least one fat that is liquid at ambient temperature (25° C.) and at atmospheric pressure and/or one fat that is solid at ambient temperature and at atmospheric pressure such as waxes, gums, and mixtures thereof.
  • the fatty phase may also contain agents for gelling and structuring oils of organic nature and/or lipophilic organic solvents.
  • volatile oil is used in the invention to mean any oil liable to evaporate on being in contact with the skin for less than 1 hour, at ambient temperature, and at atmospheric pressure.
  • Volatile oils of the invention are cosmetic volatile oils, that are liquid at ambient temperature, having non-zero vapor pressure at ambient temperature and atmospheric pressure, in particular lying in the range 1.01 millimeters of mercury (mmHg) to 300 mmHg (i.e. 1.33 pascals (Pa) to 40,000 Pa), and preferably being greater than 0.3 mmHg (30 Pa).
  • volatile or non-volatile oils may be hydrocarbon oils in particular of vegetable origin, silicone oils, or mixtures thereof.
  • hydrocarbon oil is used to mean an oil containing mainly atoms of hydrogen and of carbon, possibly together with atoms of oxygen, nitrogen, sulfur, and/or phosphorus.
  • volatile oils such as for example volatile linear or cyclic silicone oils, in particular those having viscosity ⁇ 8 centistokes (8 ⁇ 10 ⁇ 6 m 2 /s), and having in particular 2 to 7 silicon atoms, these silicones optionally including alkyl or alkoxy groups having 1 to 10 carbon atoms.
  • a volatile silicone oil suitable for use in the invention mention can be made in particular of octamethyl cyclotetrasiloxane, decamethyl cyclotetrasiloxane, dodecamethyl cyclohexasiloxane, heptamethyl hexyltrisiloxane, heptamethyloctyl trisiloxane, hexamethyl disiloxane, octamethyl trisiloxane, decamethyl tetrasiloxane, dodecamethyl pentasiloxane, and mixtures thereof.
  • the volatile oil may be present in the composition of the invention at a concentration lying in the range 0.1% to 98% by weight, in particular 1% to 65% by weight, and more particularly 2% to 50% by weight relative to the total weight of the composition.
  • the non-volatile oils may be selected in particular from hydrocarbon oils that are fluorinated, where appropriate, and/or non-volatile silicone oils.
  • non-volatile hydrocarbon oils mention can be made in particular of the following:
  • the non-volatile silicone oils usable in a composition of a cosmetic of the invention may be non-volatile polydimethylsiloxanes (PDSM), polydimethylsiloxanes including alkyl or alcoxy groupings that are pendant and/or at the ends of the silicone chain, groupings each having 2 to 24 carbon atoms, phenyl silicones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, and 2-phenylethyl trimethylsiloxysilicates, and mixtures thereof.
  • PDSM non-volatile polydimethylsiloxanes
  • phenyl silicones such as phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, di
  • the non-volatile oils may be present in a composition of a cosmetic of the invention at a concentration lying in the range 0.01% to 90% by weight, in particular 0.1% to 85% by weight, and more particularly 1% to 70% by weight, relative to the total weight of the composition.
  • the oils may represent 0% to 99% of the total weight of each composition, preferably 0.05% to 60%, better 1% to 35%.
  • each composition has an oily phase comprising at least 70% by weight of an oil having molar weight lying in the range 650 g/mol to 10,000 g/mol, preferably in the range 750 g/mol to 7500 g/mol.
  • the oily phase has more than 80%, preferably more than 85% by weight of an oil of molecular weight lying in the range 650 g/mol to 10,000 g/mol, preferably 750 g/mol to 7500 g/mol.
  • the oil of high molecular weight may be selected from lipophilic polymers:
  • Each composition may also include a fatty body that is solid at ambient temperature and at atmospheric pressure, e.g. selected from waxes, gums, and mixtures thereof.
  • the solid fatty body may represent 0.01% to 50% and in particular 0.1% to 40%, and more particularly 0.2% to 30% by weight relative to the total weight of the fatty phase.
  • wax is used to mean a lipophilic fatty compound that is solid at ambient temperature (25° C.), with a reversible solid/liquid change of state, presenting a melting temperature greater than 30° C. and possibly as high as 200° C., of hardness greater than 0.5 MPa, and presenting in the solid state an anisotropic crystal organization.
  • Waxes suitable for structuring the composition in particular in the form of a stick are compounds that are solid at ambient temperature; they may be hydrocarbon, fluorinated, and/or silicone waxes, and they may be of vegetable, mineral, animal, and/or synthetic origin. In particular, they present a melting temperature higher than 40° C., better higher than 45° C.
  • silicone waxes such as alkyl- or alkoxydimethicones with an alkyl or an alkoxy chain having 10 to 45 carbon atoms
  • the gums usable in the invention are generally presented in oil-solubilized form, the polymers are solid at ambient temperature and the resins may be liquid or solid at ambient temperature.
  • the wax may be present in the form of a wax-in-water emulsion.
  • the wax may be present in each composition in an amount lying in the range 0.01% to 50% by weight, in particular 0.1% to 30% by weight, and more specifically 0.2% to 20% by weight, relative to the total weight of the composition.
  • the cosmetic may be extruded, compacted, or cast to form a stick or into a cup.
  • the compositions of the cosmetic may be coextruded.
  • the cosmetic may constitute a cosmetic for application to the lips, e.g. a lip gloss, a lipstick, a lip balm, a blusher, a foundation, an eyeliner, an eyeshadow, a makeup base, a cosmetic for making up the body or the hair.
  • a cosmetic for application to the lips e.g. a lip gloss, a lipstick, a lip balm, a blusher, a foundation, an eyeliner, an eyeshadow, a makeup base, a cosmetic for making up the body or the hair.
  • FIG. 1 shows a stick S having two blocks A and B extending over the entire length of the stick.
  • Each block A or B occupies, for example, half of the stick, and the two blocks meet on a diameter of the stick, for example.
  • the packaging and dispenser device may be of any type adapted to packaging a stick and a drive mechanism M and for example it includes, at its bottom end, a knob that can be turned.
  • the two blocks A and B may optionally be equal proportions within the stick.
  • Each of the blocks A and B may present a color difference ⁇ E between color within the stick and color after application on keratinous materials.
  • the two blocks A and B may optionally be of substantially the same color within the stick, e.g. white in color.
  • the stick may be made by coextrusion, casting, or compacting compositions that are to form the various blocks.
  • the cosmetic comprises two blocks A and B that have been cast or compacted in a cup.
  • the blocks of composition are contained in a sheath so as to form a crayon.
  • Each block A or B may be of cross-section that is constant along the entire width of the cosmetic.
  • one of the blocks at least may present a cross-section that varies along the length of the cosmetic.
  • each of the compositions may be taken by means of an applicator or a finger, for example.
  • Tridecyl trimellitate 11 Liquid lanolin 10
  • Isostearyl malate 12 Acetylated lanolin 10
  • 2-Octyl decanol 15 Phenyl trimethylsiloxy trisiloxane (viscosity: 4 20 cSt-MW: 372)
  • Polyethylene wax (MW: 500) 8
  • Tridecyl trimellitate 11 Liquid lanolin 10
  • Isostearyl malate 12 Acetylated lanolin 10
  • 2-Octyl decanol 15 Phenyl trimethylsiloxy trisiloxane (viscosity: 4 20 cSt-MW: 372)
  • Polyethylene wax (MW: 500) 8

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
US11/984,193 2006-11-17 2007-11-14 Line of cosmetic compositions Abandoned US20080241086A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/984,193 US20080241086A1 (en) 2006-11-17 2007-11-14 Line of cosmetic compositions

Applications Claiming Priority (31)

Application Number Priority Date Filing Date Title
FR0654982A FR2908638A1 (fr) 2006-11-17 2006-11-17 Composition cosmetique comportant au moins un agent de coloration sensible a un stimulus exterieur
FR0654975A FR2908656A1 (fr) 2006-11-17 2006-11-17 Produit solide cosmetique comportant deux blocs de deux compositions cosmetiques revelant des couleurs differentes a l'application
FR0654979 2006-11-17
FR0654980A FR2908636A1 (fr) 2006-11-17 2006-11-17 Composition cosmetique comportant au moins un pigment interferentiel multicouche et au moins un pigment diffractant
FR0654981A FR2908637A1 (fr) 2006-11-17 2006-11-17 Ensemble comportant deux compositions cosmetiques et procede de maquillage
FR0654977 2006-11-17
FR0654979A FR2908635A1 (fr) 2006-11-17 2006-11-17 Composition cosmetique comportant au moins un pigment interferentiel multicouche et au moins un pigment reflechissant a reflet metallique
FR0654981 2006-11-17
FR0654977A FR2908633A1 (fr) 2006-11-17 2006-11-17 Composition cosmetique couvrante, blanche dans la masse, et revelant une couleur a l'application
FR0654975 2006-11-17
FR0654980 2006-11-17
FR0654982 2006-11-17
FR0655458A FR2908642A1 (fr) 2006-11-17 2006-12-12 Composition cosmetique comportant au moins un pigment interferentiel multicouche et au moins un pigment diffractant
FR0655459 2006-12-12
FR0655454A FR2908639A1 (fr) 2006-11-17 2006-12-12 Composition cosmetique comportant au moins un pigment interferentiel multicouche et au moins un pigment reflechissant a reflet metallique
FR0655457 2006-12-12
FR0655452 2006-12-12
FR0655459A FR2908643A1 (fr) 2006-11-17 2006-12-12 Composition cosmetique comportant au moins un agent de coloration sensible a un stimulus exterieur
FR0655460 2006-12-12
FR0655452A FR2908632B1 (fr) 2006-11-17 2006-12-12 Produit solide cosmetique comportant deux blocs de deux compositions cosmetiques revelant des couleurs differentes a l'application
FR0655454 2006-12-12
FR0655458 2006-12-12
FR0655457A FR2908641B1 (fr) 2006-11-17 2006-12-12 Composition cosmetique comportant au moins un pigment interferentiel multicouche et au moins un pigment reflechissant a reflet metallique
FR0655460A FR2908644B1 (fr) 2006-11-17 2006-12-12 Ensemble comportant deux compositions cosmetiques et procede de maquillage
US87555406P 2006-12-19 2006-12-19
US87555506P 2006-12-19 2006-12-19
US87554906P 2006-12-19 2006-12-19
US87616206P 2006-12-21 2006-12-21
US87616006P 2006-12-21 2006-12-21
US87616106P 2006-12-21 2006-12-21
US11/984,193 US20080241086A1 (en) 2006-11-17 2007-11-14 Line of cosmetic compositions

Publications (1)

Publication Number Publication Date
US20080241086A1 true US20080241086A1 (en) 2008-10-02

Family

ID=39232918

Family Applications (1)

Application Number Title Priority Date Filing Date
US11/984,193 Abandoned US20080241086A1 (en) 2006-11-17 2007-11-14 Line of cosmetic compositions

Country Status (3)

Country Link
US (1) US20080241086A1 (de)
EP (1) EP1923040A2 (de)
JP (1) JP2008127390A (de)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110155162A1 (en) * 2008-08-01 2011-06-30 L'oreal Method for treating human keratinous fibers
US20150016857A1 (en) * 2012-03-01 2015-01-15 Mitsubishi Pencil Company, Limited Liquid cosmetic
WO2019092494A1 (fr) * 2017-11-08 2019-05-16 Elegant Best Investment Limited Film a effet metallique colore pour application maquillage
US11497687B2 (en) 2017-06-22 2022-11-15 TheUnseen Limited Chromic compositions

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2942406B1 (fr) * 2009-02-23 2011-04-22 Oreal Procede de demaquillage et composition cosmetique demaquillante
JP2013216590A (ja) * 2012-04-05 2013-10-24 Hitachi Chemical Co Ltd 化粧料用粒子及び化粧料
JP7242257B2 (ja) * 2018-11-06 2023-03-20 ロレアル ゴニオクロマチック顔料及び白色顔料を含むメークアップ用の液状組成物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020064509A1 (en) * 2000-10-03 2002-05-30 Sabine Grimm Method for producing a goniochromatic effect comprising applying to skin a cosmetic composition comprising at least one continuous lipophilic phase and at least one goniochromatic pigment
US6428773B1 (en) * 2000-01-13 2002-08-06 Color Access, Inc. Shadow-effect cosmetic composition
US20040105827A1 (en) * 2000-10-03 2004-06-03 Sabine Grimm Use for make-up in particular of a cosmetic composition having a continuous hydrophilic comprising a multilayer goniochromatic pigment
US20060013838A1 (en) * 2004-07-13 2006-01-19 Qinyun Peng Cosmetic powder compositions having large particle size color travel effect pigments

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9309992D0 (en) 1993-05-14 1993-06-30 Heller Harry G Tribochromic compounds and their applications
AU704152B2 (en) 1995-01-06 1999-04-15 Ciba Specialty Chemicals Holding Inc. Triboluminescent lanthanide III complexes
US6117574A (en) 1997-10-20 2000-09-12 Agency Of Industrial Science And Technology Triboluminescent inorganic material and a method for preparation thereof
JP3511083B2 (ja) 1999-08-06 2004-03-29 独立行政法人産業技術総合研究所 高輝度応力発光材料、その製造方法及びそれを用いた発光方法
FR2811558B1 (fr) 2000-07-12 2002-09-13 Oreal Compositions comprenant des composes du type sel de flavylium non substitues en position 3 pour la coloration de la peau et utilisations
US20020015965A1 (en) 2000-07-27 2002-02-07 Sweeting Linda Marie Efficient synthesis of triboluminescent lanthanide complexes
JP2002194349A (ja) 2000-12-27 2002-07-10 National Institute Of Advanced Industrial & Technology 応力発光材料およびその製造方法
US6692830B2 (en) 2001-07-31 2004-02-17 Flex Products, Inc. Diffractive pigment flakes and compositions
GB0119726D0 (en) 2001-08-14 2001-10-03 Qinetiq Ltd Triboluminescent materials and devices
JP3837488B2 (ja) 2001-11-30 2006-10-25 独立行政法人産業技術総合研究所 メカノルミネッセンス材料
JP4159025B2 (ja) 2002-07-12 2008-10-01 独立行政法人科学技術振興機構 高輝度メカノルミネッセンス材料及びその製造方法
JP3918051B2 (ja) 2002-07-29 2007-05-23 独立行政法人産業技術総合研究所 メカノルミネッセンス材料及びその製造方法
US20040228818A1 (en) 2002-10-18 2004-11-18 L'oreal Cosmetic composition combining at least two dyes including at least one photochromic dye

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6428773B1 (en) * 2000-01-13 2002-08-06 Color Access, Inc. Shadow-effect cosmetic composition
US20020064509A1 (en) * 2000-10-03 2002-05-30 Sabine Grimm Method for producing a goniochromatic effect comprising applying to skin a cosmetic composition comprising at least one continuous lipophilic phase and at least one goniochromatic pigment
US20040105827A1 (en) * 2000-10-03 2004-06-03 Sabine Grimm Use for make-up in particular of a cosmetic composition having a continuous hydrophilic comprising a multilayer goniochromatic pigment
US20060013838A1 (en) * 2004-07-13 2006-01-19 Qinyun Peng Cosmetic powder compositions having large particle size color travel effect pigments

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110155162A1 (en) * 2008-08-01 2011-06-30 L'oreal Method for treating human keratinous fibers
US20150016857A1 (en) * 2012-03-01 2015-01-15 Mitsubishi Pencil Company, Limited Liquid cosmetic
US10028564B2 (en) * 2012-03-01 2018-07-24 Mitsubishi Pencil Company, Limited Liquid cosmetic
US11497687B2 (en) 2017-06-22 2022-11-15 TheUnseen Limited Chromic compositions
WO2019092494A1 (fr) * 2017-11-08 2019-05-16 Elegant Best Investment Limited Film a effet metallique colore pour application maquillage

Also Published As

Publication number Publication date
JP2008127390A (ja) 2008-06-05
EP1923040A2 (de) 2008-05-21

Similar Documents

Publication Publication Date Title
JP5048911B2 (ja) 化粧組成物
JP5089849B2 (ja) 化粧組成物
ES2405997T3 (es) Dispositivo de acondicionamiento y de distribución de por lo menos dos composiciones diferentes
US20080226574A1 (en) Line of cosmetic compositions
US20060088484A1 (en) Method of applying makeup to a surface and a kit for implementing such a method
US20060088483A1 (en) Kit and method of applying makeup
US9549892B2 (en) Compositions based on polyester in an oily phase and uses thereof
US20080241086A1 (en) Line of cosmetic compositions
US20050008595A1 (en) Cosmetic compositions with optical variability
US20080268003A1 (en) Covering cosmetic composition
US20040228817A1 (en) Makeup combining at least one photochromic dye and at least one goniochromatic agent
US20110002863A1 (en) Cosmetic product, uses thereof and make-up kit containing said product
FR2925302A1 (fr) Produit cosmetique comprenant au moins deux compositions cosmetiques.
FR2908644A1 (fr) Ensemble comportant deux compositions cosmetiques et procede de maquillage
US20080095723A1 (en) Cosmetic composition
FR2908639A1 (fr) Composition cosmetique comportant au moins un pigment interferentiel multicouche et au moins un pigment reflechissant a reflet metallique
FR2908643A1 (fr) Composition cosmetique comportant au moins un agent de coloration sensible a un stimulus exterieur
FR2908641A1 (fr) Composition cosmetique comportant au moins un pigment interferentiel multicouche et au moins un pigment reflechissant a reflet metallique
FR2908638A1 (fr) Composition cosmetique comportant au moins un agent de coloration sensible a un stimulus exterieur
FR2908637A1 (fr) Ensemble comportant deux compositions cosmetiques et procede de maquillage
FR2908656A1 (fr) Produit solide cosmetique comportant deux blocs de deux compositions cosmetiques revelant des couleurs differentes a l'application
FR2925322A1 (fr) Produit cosmetique, ses utilisations et kit de maquillage contenant ce produit.
FR2908642A1 (fr) Composition cosmetique comportant au moins un pigment interferentiel multicouche et au moins un pigment diffractant
FR2908633A1 (fr) Composition cosmetique couvrante, blanche dans la masse, et revelant une couleur a l'application
FR2908636A1 (fr) Composition cosmetique comportant au moins un pigment interferentiel multicouche et au moins un pigment diffractant

Legal Events

Date Code Title Description
AS Assignment

Owner name: L'OREAL, FRANCE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:THEVENET, LUDOVIC;REEL/FRAME:021082/0935

Effective date: 20071212

STCB Information on status: application discontinuation

Free format text: EXPRESSLY ABANDONED -- DURING EXAMINATION