US20080083448A1 - Interconnect for thin film photovoltaic modules - Google Patents
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- US20080083448A1 US20080083448A1 US11/537,285 US53728506A US2008083448A1 US 20080083448 A1 US20080083448 A1 US 20080083448A1 US 53728506 A US53728506 A US 53728506A US 2008083448 A1 US2008083448 A1 US 2008083448A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
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- H01L31/044—PV modules or arrays of single PV cells including bypass diodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/0445—PV modules or arrays of single PV cells including thin film solar cells, e.g. single thin film a-Si, CIS or CdTe solar cells
- H01L31/046—PV modules composed of a plurality of thin film solar cells deposited on the same substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/0475—PV cell arrays made by cells in a planar, e.g. repetitive, configuration on a single semiconductor substrate; PV cell microarrays
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Definitions
- the present invention relates to methods for making interconnections used in thin film photovoltaic (TF PV) modules, and more particularly to improved interconnect techniques that allow for TF PV modules to be divided into sub-modules, which can be further interconnected together and/or connected to separate outputs.
- TF PV thin film photovoltaic
- TF PV modules offer a potential cost advantage over other types of photovoltaic modules, such as modules based on silicon wafers.
- modules suffer from a number of drawbacks, including lower efficiency, lower reliability, and incompatibility with the balance of the system design.
- TF PV modules enjoy only about a 10% share of the market as compared to about a 90% share for silicon modules.
- a conventional method for forming and configuring a TF PV module is described as follows. Thin film material layers are deposited on the surface of a large substrate, typically glass. During this process, a set of scribes are made at regular spacing, most commonly using lasers, but occasionally using mechanical scribing. The combination of the scribes and successive depositions form long series-connected photovoltaic regions.
- the large glass substrate which may be several square meters in area, is then cut into sections, which may be on the order of 1000 ⁇ 1300 mm, to form modules 100 .
- the film is also removed from the surface of the substrate around the periphery to isolate the cells 102 from the edge. Each cell may be 10 mm wide and run the full length of the module.
- terminals 104 are bonded to the end cells 102 -L and 102 -R.
- each cell 102 is a diode 110 with a current generator 112 .
- this model neglects resistance elements.
- the cells are connected in series during the formation process.
- the photocurrent generated in the n th cell is I Ln . If all cells generate exactly the same photocurrent, then the module delivers this current at the output terminals. However, if one of the cells in the series string generates less current, it will limit the current in that cell. Because of the series connection, the output current of the entire module will be limited by a similar amount.
- the present invention relates to configuring and wiring together cells in TF PV modules.
- cells within the module are adjusted in size to compensate for known process non-uniformity.
- the module is divided into a number of smaller series-connected sub-modules that are then wired in parallel.
- the module and/or sub-module may have a non-rectangular shape.
- lithography and etch processes are preferably used to form interconnects.
- contact pads are formed using photolithographic processes, which may be used to mount protect diodes to minimize the risk of damage due to shading or non-uniformity.
- protect diodes are included as part of the patterning.
- FIGS. 1A and 1B are diagrams illustrating conventional configurations of TF PV modules
- FIG. 2 is a diagram illustrating a TF PV module configured in accordance with one embodiment of the invention
- FIGS. 3A and 3B illustrate a TF PV module configured in accordance with another embodiment of the invention
- FIG. 4 is a diagram illustrating techniques for processing a TF PV module to accomplish the novel configurations according to certain aspects of the invention
- FIG. 5 illustrate example techniques for configuring a TF PV module with protect diodes in accordance with certain aspects of the invention
- FIG. 6 illustrates example techniques for wiring a TF PV module in accordance with certain aspects of the invention
- FIGS. 7A and 7B illustrate example techniques for configuring a TF PV module with integrated protect diodes in accordance with certain aspects of the invention.
- FIGS. 8A and 8B illustrate non-rectangular module examples made possible in accordance with the principles of the invention.
- the present invention recognizes that many advantages in TF PV module efficiency, flexibility, cost and reliability can be achieved by configuring and/or interconnecting such modules in new and useful ways. For example, the present invention recognizes that smaller modules are typically more efficient due to their higher process uniformity. As another example, the present invention recognizes that there is typically less Voc than Isc variation due to non-uniformities.
- the present invention recognizes that using photolithographic processes to process a TF PV module provides unique abilities to configure and interconnect cells in such modules. Because lithography exposes an entire region through a mask, it is possible to make any density of interconnects, and any shape of interconnects, without added cost. There is very little edge damage, and the cut regions can be made small (a few microns vs. tens or hundreds of microns), so the cells can be relatively narrow. Furthermore, etching of lithographically-defined areas allows exposure of under-layers, for example, to make contacts or interconnects.
- 11/395,080, 11/394,721 and 11/394,723 provide example implementations of using such photolithographic processes to form and interconnect cells in a TF PV module, the contents of each application being incorporated herein by reference.
- the present invention can exploit these types of processes in new and useful ways.
- a module 200 is divided into photovoltaic regions, or cells 202 , that are connected in series as done in the prior art. Unlike the prior art, however, where all cells have the same area, the areas of these cells are adjusted to compensate for known process variation.
- the effect on cell current at the maximum power point, I max may be determined by fabricating and testing a module. Alternately, small cells could be formed by, for example, placing small substrates on a larger carrier. These small cells can be tested to map the performance with respect to location in the deposition system. Once I max is mapped for a particular fabrication process, it is possible to adjust the area of the cells within the module to compensate for this non-uniformity.
- I max is degraded 10% within 2 cm of the module edge, 5% within 4 cm of the edge, and is uniform to within 1% inside this 6 cm total edge region.
- the width of a nominal cell 202 - c in the central “uniform” region is 1 cm (only three are shown in FIG. 2 for ease of illustration, but there can be many more).
- the two outermost cells 202 - a on each edge are made 1.1 cm wide, so that their I max equals that of a cell in the uniform region.
- the next two inner cells 202 - b on each edge are made 1.05 cm wide (only one on each edge are shown in FIG. 2 for ease of illustration), to compensate for their 5% degradation. Therefore, the currents at the maximum power point of all cells are matched, and the module suffers minimal degradation due to the edge non-uniformity.
- any number of conventional methods of dividing and interconnecting cells in a TF PV module can be used in this embodiment, including laser scribing or etch and deposition processes. Those skilled in the art will appreciate how such conventional methods can be modified to obtain different cell sizes rather than equal cell sizes after being taught by the present invention on how to determine the different sizes.
- the module is divided into a number of sub-modules which are connected together in new and useful ways.
- the cells within each sub-module are series connected, and the sub-modules are parallel connected. This results in improved performance because regions are easier to match in voltage than current.
- FIG. 3A One example implementation of this embodiment is shown in FIG. 3A .
- the module 300 is divided into 16 sub-modules 302 .
- the 16 sub-modules 302 are arranged in four sets 306 of four sub-modules each.
- Those skilled in the art will appreciate that various divisions into various numbers of sub-modules are possible, that it is not necessary for each set to have the same number of sub-modules, and that the number of sets and the number of sub-modules per set can be different.
- the areas and cells of each sub-module formed by the above process are equal. In other embodiments, the areas of the sub-modules and/or cells therein are varied to account for process variation or other factors.
- FIG. 3B An equivalent circuit of one set 306 is shown in FIG. 3B .
- the cells in each sub-module 302 are series connected, and the series connected sub-modules 302 within each set are connected in parallel.
- each sub-module 302 is thus connected between a first (e.g. output) common node 310 and a second (e.g. ground) common node 312 .
- first (e.g. output) common node 310 e.g. output) common node 310
- second (e.g. ground) common node 312 e.g. ground
- the four sets 306 are connected together in parallel. In this example, this is accomplished by connecting the first common node 310 of each set to a common output bus 320 .
- the number of sub-modules could be any number of two or more. However, a larger number (>10) is preferable because it reduces sensitivity to non-uniformity or shading of part of the module, as might be seen in building integrated photovoltaic (BIPV) applications, or in dense fields of modules, especially at the start and end of the day when shadows are longer.
- BIPV building integrated photovoltaic
- the total current of module 300 will likely be higher than an undivided module having the same total cell area. Being smaller in area (e.g. 1/16) than the total area of the whole module, each sub-module 302 will likely be more uniform than what is typically possible over the full module area. Accordingly, it is less likely that the current of individual cells in each sub-module 302 will be substantially different from other cells, thus reducing the likelihood of current limiting within a sub-module. Moreover, sub-modules 302 that have process defects or that exhibit substantial process non-uniformity will be more likely to be localized such that current in other sub-modules is not affected.
- the four columns 306 of cells are wired in parallel, and these four outputs are connected in parallel via common bus 320 .
- This obtains the advantage of parallel wiring of cells, which is a preferred configuration to minimize losses due to shading, non-uniformity, or local degradation.
- the module output voltage can be maintained the same as an undivided module by making the width of the cells within each sub-module four times smaller (i.e. by increasing the number of cells in each sub-module by a factor of four).
- the divided module 300 is fabricated with each cell having a width of 0.33 cm.
- this is achieved using the lithographic techniques of the incorporated co-pending applications, which makes possible narrow line-width for the interconnect regions on the order of 20-30 ⁇ m.
- another possible embodiment uses laser scribing for some or all of the interconnects.
- the concepts of the invention can include forming cell regions of non-rectangular shapes. This may be desirable in certain applications such as building integrated photovoltaics (BIPV), where, for example, a triangular module may be desirable as an architectural element.
- BIPV building integrated photovoltaics
- a triangular module is difficult to make with conventional patterning, as the cell stripes are not of constant length and, therefore, not current matched.
- these concepts enable fabrication of stripes varying in both length and width.
- the high spatial resolution of lithography allows the longest stripe to be very narrow, so that the shorter stripe can be of limited width, thereby reducing power loss incurred as the current flows through the relatively high resistivity transparent conductor on the cell surface.
- the widths of the stripes 802 can increase linearly, so that each stripe is of constant area. This provides current matching.
- multiple non-rectangular shapes 804 are provided in order to make a larger non-rectangular figure.
- Using smaller sub-modules 804 enables construction of a large non-rectangular shape while limiting the width of the stripes to a practical value (on the order of 1 cm, depending on the cell technology).
- the sub-areas 804 can be wired together using methods similar to those employed for the module as shown and described in connection with FIG, 3 A.
- FIG. 4 An example method of configuring a module using photolithographic techniques such as that described in co-pending application Ser. No. 11/394,723 is illustrated in more detail in FIG. 4 .
- a stack 402 of photovoltaic material is deposited on a substrate 404 which is, for example, a 3 mm thick sheet of glass.
- the stack can include a 0.1 ⁇ m bottom layer corresponding to the opaque metal electrode—typically molybdenum—in contact with the glass substrate 404 , and a 2 ⁇ m layer of CIGS material capped with a 0.07 ⁇ m buffer layer of CdS (the CIGS layer or CIGS+CdS layers can be referred to as a semiconducting layer) on top of the Mo layer.
- the initial stack can further include a top transparent conductor layer, such as aluminum-doped ZnO, or it can be added later.
- the stack is coated with a photoresist layer (not shown) using, for example a spray, dip or roll-on process.
- the thickness can be 1-10 ⁇ m and the material can be Shipley 3612.
- mask 412 is suspended about 10 um above, or in contact with stack 402 .
- Mask 412 includes vertical (with respect to the orientation of the drawing) lines 420 (e.g. 30 ⁇ m wide, and about 0.33 to 1 cm apart, depending on the design) through which the photoresist can be exposed. As explained in more detail below, and in the co-pending applications, these lines 410 isolate the individual cells of the module.
- mask 412 further includes four horizontal lines 422 (with respect to the orientation of the drawing) and four wide vertical lines 424 that are used to define the sub-modules.
- the lines 422 can be about 100 ⁇ m wide and the lines 424 can be about 100 ⁇ m wide.
- the resist is exposed through the mask 412 , the mask is removed and the exposed resist is developed to complete the pattern. Lines 422 and 424 in some cases are made wider than the cell isolation lines to leave room for metal interconnects.
- the number of lines 420 defining individual cells can be many more than illustrated in FIG. 4 , and that the number of lines 422 and 424 will depend on the number of sub-modules to be created. Many variations from the numbers provided in the illustrations are possible.
- a staged etch process is used to cut through the stack 402 down to the substrate 404 through the exposed lines, thereby isolating the cells and dividing the module into sub-modules.
- a HCl or CH 3 COOH solution can be used to etch through the top ZnO layer of stack 402 .
- an etch mixture such as a H 2 SO 4 +H 2 O 2 mixture or H 2 SO 4 +HNO 3 mixture diluted with water, is used to etch the CIGS material in the stack 402 through the patterned photoresist down to the underlying metal layer.
- an etch such as PAN (phosphoric acid, acetic acid and nitric acid H 3 PO 4 +CH 3 COOH+HNO 3 ) can be used. In some cases, it may be necessary to precede this etch with a short etch to remove a thin MoSe 2 layer at the CIGS-Mo interface, using an etch such as NH 4 OH+H 2 O 2 .
- These successive etches form isolation grooves through the stack 402 , which can partially or fully run the vertical length of the module (e.g. 1 m), corresponding to lines 420 of mask 412 .
- These etches also form isolation grooves through stack 402 corresponding to horizontal lines 422 and wide vertical lines 424 which divide the module into sub-modules.
- aligned pad regions e.g. having area of about 0.1 to 1 cm 2
- pad regions 504 are also formed by etching a small area down to the metal layer in corresponding cells.
- external protect diodes for individual strings it is preferred to connect external protect diodes for individual strings, so that power losses due to effects such as shading are minimized.
- exposed pad regions 504 make it possible for protect diodes 506 to be connected between pad regions and wired in polarity so that they turn on if the region between the pads is reverse-biased.
- FIG. 5 shows protect diode 506 connected between several cells, this is not necessary.
- One or any number of adjacent cells can be configured with protect diodes.
- the invention contemplates many methods for wiring the protect diodes into the module. In the example embodiment shown above in FIG. 5 , they can be placed as discrete components, much as is done with surface mount printed circuit boards.
- the protect diodes can be fabricated as part of the lithographic process used to form the connections between adjacent cells. For example, as shown in FIG. 7A , during an etch step used to isolate adjacent cells in sub-module 700 , a cut 704 can also be made to isolate regions adjacent to the cells 702 for forming protect diodes 706 . In subsequent steps, contact ledges are formed for the protect diode at the same time and similar manner as the contact ledges are formed for the isolated cells as taught in co-pending application No. 11 / 394 , 721 . When conductors are formed to wire adjacent cells together, the protect diodes are also wired to adjacent cells. In this manner, the protect diodes are formed as integrated elements without extra process steps, thereby forming a reliable connection at negligible additional cost.
- FIG. 7B is a side cutaway view taken along the line 7 B in FIG. 7A to illustrate how wiring can be performed to accomplish the reverse polarity of the diodes 706 versus the cells 702 .
- the bottom layer 716 adjacent to substrate 718 is metal—typically molybdenum for cells 702 in which the semiconducting layer 714 is CIGS.
- the top layer 712 is a transparent conductor.
- the top layer 712 of a protect diode 702 is wired via interconnect 708 to bottom layer 716 of cell 702
- the bottom layer 716 of diode 702 is wired via interconnect 710 to top layer 712 of cell 702 .
- the protect diodes 706 can be wired in reverse polarity without use of extra process steps.
- protect diodes 706 are not necessarily series-connected together like cells 702 . It should be further noted that although FIG. 7A shows the one protect diode 706 per cell 702 , this arrangement is not necessary and various configurations are possible.
- processing can be performed to create the parallel connections between sub-modules 302 .
- busses run vertically with respect to the orientation in FIG. 3A to provide the parallel connection between sub-modules 302 in a given set 306 .
- busses 602 are fabricated on the front of the module, on the same side of the substrate 610 as the active cells 612 , and in areas corresponding to lines 424 in FIG. 4 that vertically divide the sub-modules into sets.
- busses 602 are comprised of plated nickel—in order to provide a thick conductor with minimum resistance—and are connected to cells by being deposited and patterned so that they terminate at the proper location, which may be a contact pad.
- a bus 604 is also fabricated on the front of the module, and can be connected to busses 602 , thereby providing a common output bus such as bus 320 shown in FIG. 3A .
- Bus 604 can be formed in areas corresponding to one of horizontal lines 422 in FIG. 4 .
- Techniques such as those described more fully in co-pending application Ser. No. ______ (AMAT-10921) can be used to implement alternative embodiments of forming busses and interconnecting cells and/or areas.
- sub-modules can be further wired to ground independently, or can share a common ground.
- sub-module connections need not reside within the module itself. Whereas a prior-art module has a single output, it is possible to make modules with multiple outputs, for example, having two separate terminals from each sub-module accessible to external circuitry. This provides a number of benefits. For example, there is greater flexibility in how an array is wired. In one example, three outputs are provided: a common output, one positive with respect to common, and one negative with respect to common. This enables use of a simpler DC to AC converter, since switching is done over only half of the AC cycle. Regions with more likelihood of shading may be electrically separated from regions with less likelihood, such as the bottom versus the top of the array.
- arrays may be made much larger, thereby saving packaging costs at the module level; for example, instead of cutting a Gen 8 substrate into 5 modules, each 1 m 2 in area, the single substrate could be packaged as a module with five outputs, each representing a sub-module area of 1 m 2 .
- a switching system is built into or externally from the module that controls switches that selectively connect sub-modules together, rather than having fixed connections.
- This system can dynamically measure part or all of the current-voltage characteristic of each sub-module and use electronic switches to dynamically re-wire the sub-modules together to optimize output. In this manner, degradation due to defects, shading, or other non-uniform effects is dynamically minimized.
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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US11/537,285 US20080083448A1 (en) | 2006-09-29 | 2006-09-29 | Interconnect for thin film photovoltaic modules |
JP2009530590A JP2010505282A (ja) | 2006-09-29 | 2007-09-27 | 薄膜太陽光電池モジュールのための改良された相互接続部 |
DE112007002316T DE112007002316T5 (de) | 2006-09-29 | 2007-09-27 | Verbesserte Schaltung für Dünnfilm-Photovoltaische Module |
PCT/US2007/079636 WO2008042682A2 (en) | 2006-09-29 | 2007-09-27 | Improved interconnect for thin film photovoltaic modules |
TW096136390A TW200828608A (en) | 2006-09-29 | 2007-09-28 | Improved interconnect for thin film photovoltaic modules |
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US11/537,285 US20080083448A1 (en) | 2006-09-29 | 2006-09-29 | Interconnect for thin film photovoltaic modules |
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US11/537,285 Abandoned US20080083448A1 (en) | 2006-09-29 | 2006-09-29 | Interconnect for thin film photovoltaic modules |
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US (1) | US20080083448A1 (zh) |
JP (1) | JP2010505282A (zh) |
DE (1) | DE112007002316T5 (zh) |
TW (1) | TW200828608A (zh) |
WO (1) | WO2008042682A2 (zh) |
Cited By (13)
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US20090186191A1 (en) * | 2008-01-19 | 2009-07-23 | Peter Lechner | Method of making a transparent metal oxide coated glass panel for photovoltaic module |
US20110061706A1 (en) * | 2009-09-16 | 2011-03-17 | Jusung Engineering Co., Ltd. | Thin film type solar cell and method for manufacturing the same, and thin film type solar cell module and power generation system using the same |
US20110073153A1 (en) * | 2009-09-28 | 2011-03-31 | Sanyo Electric Co., Ltd. | Photovoltaic device and manufacturing method thereof |
EP2309540A1 (de) * | 2009-10-12 | 2011-04-13 | Inventux Technologies AG | Photovoltaik-Modul |
US20110265846A1 (en) * | 2009-01-09 | 2011-11-03 | Yoshiyuki Nasuno | Thin-film solar cell module and thin-film solar cell array |
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US20160087137A1 (en) * | 2014-09-19 | 2016-03-24 | Kabushiki Kaisha Toshiba | Multi-junction solar cell |
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WO2016169595A1 (en) * | 2015-04-22 | 2016-10-27 | Fundación Tekniker | Method for manufacturing a photovoltaic panel comprising a plurality of thin film photovoltaic cells connected in series |
EP3185308A1 (en) * | 2015-12-21 | 2017-06-28 | Gama Sonic USA, Inc. | Array of unequally shaped solar panels |
US11189432B2 (en) | 2016-10-24 | 2021-11-30 | Indian Institute Of Technology, Guwahati | Microfluidic electrical energy harvester |
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EP3327170B1 (en) | 2007-09-12 | 2020-11-04 | Flisom AG | Apparatus for manufacturing a compound film |
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DE202010013136U1 (de) | 2010-12-16 | 2011-02-17 | Malibu Gmbh & Co. Kg | Dünnschicht-Photovoltaikmodul |
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Cited By (19)
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US8707643B1 (en) | 2007-11-08 | 2014-04-29 | Certainteed Corporation | Roofing element and roof covering comprised thereof |
US20090186191A1 (en) * | 2008-01-19 | 2009-07-23 | Peter Lechner | Method of making a transparent metal oxide coated glass panel for photovoltaic module |
EP2378561A4 (en) * | 2009-01-09 | 2016-08-24 | Sharp Kk | THIN-FILM SOLAR CELL MODULE AND THIN-FILM SOLAR CELL MATRIX |
US20110265846A1 (en) * | 2009-01-09 | 2011-11-03 | Yoshiyuki Nasuno | Thin-film solar cell module and thin-film solar cell array |
US20110061706A1 (en) * | 2009-09-16 | 2011-03-17 | Jusung Engineering Co., Ltd. | Thin film type solar cell and method for manufacturing the same, and thin film type solar cell module and power generation system using the same |
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US10573771B2 (en) * | 2014-09-19 | 2020-02-25 | Kabushiki Kaisha Toshiba | Multi-junction solar cell |
US11205732B2 (en) | 2014-09-19 | 2021-12-21 | Kabushiki Kaisha Toshiba | Multi-junction solar cell |
WO2016169595A1 (en) * | 2015-04-22 | 2016-10-27 | Fundación Tekniker | Method for manufacturing a photovoltaic panel comprising a plurality of thin film photovoltaic cells connected in series |
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EP3185308A1 (en) * | 2015-12-21 | 2017-06-28 | Gama Sonic USA, Inc. | Array of unequally shaped solar panels |
US11189432B2 (en) | 2016-10-24 | 2021-11-30 | Indian Institute Of Technology, Guwahati | Microfluidic electrical energy harvester |
Also Published As
Publication number | Publication date |
---|---|
WO2008042682A3 (en) | 2008-10-16 |
WO2008042682B1 (en) | 2008-11-20 |
JP2010505282A (ja) | 2010-02-18 |
DE112007002316T5 (de) | 2009-11-26 |
TW200828608A (en) | 2008-07-01 |
WO2008042682A2 (en) | 2008-04-10 |
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