US20040082742A1 - N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith - Google Patents

N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith Download PDF

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Publication number
US20040082742A1
US20040082742A1 US10/450,229 US45022903A US2004082742A1 US 20040082742 A1 US20040082742 A1 US 20040082742A1 US 45022903 A US45022903 A US 45022903A US 2004082742 A1 US2004082742 A1 US 2004082742A1
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US
United States
Prior art keywords
diethyl
aza
dioxa
spiro
phenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/450,229
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English (en)
Inventor
Peter Nesvadba
Marie-Odile Zink
Wiebke Wunderlich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Performance Products LLC
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Ciba Specialty Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Specialty Chemicals Corp filed Critical Ciba Specialty Chemicals Corp
Assigned to CIBA SPECIALTY CHEMICALS CORP. reassignment CIBA SPECIALTY CHEMICALS CORP. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: NESVADBA, PETER, ZINK, MARIE-ODILE, WUNDERLICH, WIEBKE
Publication of US20040082742A1 publication Critical patent/US20040082742A1/en
Priority to US11/364,537 priority Critical patent/US7288613B2/en
Priority to US11/903,093 priority patent/US7572869B2/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94Oxygen atom, e.g. piperidine N-oxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D491/00Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/10Spiro-condensed systems
    • C07D491/113Spiro-condensed systems with two or more oxygen atoms as ring hetero atoms in the oxygen-containing ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D491/00Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/22Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains four or more hetero rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D519/00Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups C07D453/00 or C07D455/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/46Polymerisation initiated by wave energy or particle radiation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Hydrogenated Pyridines (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
US10/450,229 2000-12-14 2001-11-12 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith Abandoned US20040082742A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US11/364,537 US7288613B2 (en) 2000-12-14 2006-02-28 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith
US11/903,093 US7572869B2 (en) 2000-12-14 2007-09-20 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP00811190 2000-12-14
EP008111908 2000-12-14
PCT/EP2001/013072 WO2002048205A1 (fr) 2000-12-14 2001-11-12 Composes n-alcoxy-4,4-dioxy-polyalkyl-piperidine, leurs n-oxydes correspondants et polymerisation radicalaire regulee avec

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/364,537 Continuation US7288613B2 (en) 2000-12-14 2006-02-28 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith

Publications (1)

Publication Number Publication Date
US20040082742A1 true US20040082742A1 (en) 2004-04-29

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Family Applications (3)

Application Number Title Priority Date Filing Date
US10/450,229 Abandoned US20040082742A1 (en) 2000-12-14 2001-11-12 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
US11/364,537 Expired - Fee Related US7288613B2 (en) 2000-12-14 2006-02-28 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith
US11/903,093 Expired - Fee Related US7572869B2 (en) 2000-12-14 2007-09-20 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith

Family Applications After (2)

Application Number Title Priority Date Filing Date
US11/364,537 Expired - Fee Related US7288613B2 (en) 2000-12-14 2006-02-28 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith
US11/903,093 Expired - Fee Related US7572869B2 (en) 2000-12-14 2007-09-20 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith

Country Status (9)

Country Link
US (3) US20040082742A1 (fr)
EP (1) EP1343827A1 (fr)
JP (2) JP4602638B2 (fr)
KR (1) KR100838217B1 (fr)
CN (1) CN1198851C (fr)
AU (1) AU2002224841A1 (fr)
CA (1) CA2431393A1 (fr)
TW (1) TW557305B (fr)
WO (1) WO2002048205A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100249386A1 (en) * 2009-03-26 2010-09-30 Universite De Provence Dinitroxide-type biradical compounds optimized for dynamic nuclear polarization (dnp)
US8900779B2 (en) 2006-07-11 2014-12-02 Ciba Corporation Color filter composition

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
US7253232B2 (en) 2002-09-26 2007-08-07 Ciba Specialty Chemicals Corp. Thermoplastic compositions with enhanced melt flow and compatibility
WO2005118651A1 (fr) * 2004-05-27 2005-12-15 Ciba Specialty Chemicals Holding Inc. Alcoxyamines contenant un groupe polymerisable par voie radicalaire
EP1786860B1 (fr) * 2004-09-03 2008-03-26 Ciba Specialty Chemicals Holding Inc. Stabilisants en recipient
KR101712683B1 (ko) * 2009-03-23 2017-03-06 바스프 에스이 포토레지스트 조성물
EP2588520B1 (fr) 2010-06-29 2014-06-25 Basf Se Procédé d'amélioration des propriétés d'écoulement du polymère en fusion et utilisation de copolymères block ou block en peigne
US20140298591A1 (en) 2011-10-25 2014-10-09 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
WO2014154508A1 (fr) 2013-03-27 2014-10-02 Basf Se Copolymères blocs comme agents de libération de la saleté dans des procédés de blanchisserie
FR3004450B1 (fr) * 2013-04-15 2015-12-18 Univ Aix Marseille Composes biradicalaires du type dinitroxyde rigides utilises comme agents de polarisation perfectionnes pour les techniques de polarisation dynamique nucleaire (pdn)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4105626A (en) * 1975-05-28 1978-08-08 Ciba-Geigy Corporation Derivatives of 4-oxopiperidines and their use as polymer stabilizers
US4581429A (en) * 1983-07-11 1986-04-08 Commonwealth Scientific And Industrial Research Organization Polymerization process and polymers produced thereby
US6353107B1 (en) * 1998-03-09 2002-03-05 Ciba Specialty Chemicals Corporation 1-alkoxy-polyallkyl-piperidine derivatives and their use as polymerization regulators
US6479603B1 (en) * 1998-12-16 2002-11-12 Basf Aktiengesellschaft Method for living free-radical polymerization
US20030065184A1 (en) * 2000-03-22 2003-04-03 Peter Nesvadba 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
US20030216494A1 (en) * 2000-05-19 2003-11-20 Michael Roth Hydroxylamine esters as polymerization initiators

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3852742T3 (de) 1987-09-21 2005-02-10 Ciba Speciality Chemicals Holding Inc. N-substituierte sterisch gehinderte Amin-Stabilisatoren.
US5096950A (en) * 1988-10-19 1992-03-17 Ciba-Geigy Corporation Polyolefin compositions stabilized with NOR-substituted hindered amines
EP0467851A1 (fr) * 1990-07-20 1992-01-22 Ciba-Geigy Ag Compositions monomères stabilisées
DE4219471A1 (de) 1992-06-13 1993-12-16 Huels Chemische Werke Ag N-Oxyl-Derivate des 2,2,6,6-Tetramethylpiperidins und deren Herstellung
US6379494B1 (en) * 1999-03-19 2002-04-30 Weyerhaeuser Company Method of making carboxylated cellulose fibers and products of the method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4105626A (en) * 1975-05-28 1978-08-08 Ciba-Geigy Corporation Derivatives of 4-oxopiperidines and their use as polymer stabilizers
US4581429A (en) * 1983-07-11 1986-04-08 Commonwealth Scientific And Industrial Research Organization Polymerization process and polymers produced thereby
US6353107B1 (en) * 1998-03-09 2002-03-05 Ciba Specialty Chemicals Corporation 1-alkoxy-polyallkyl-piperidine derivatives and their use as polymerization regulators
US6479603B1 (en) * 1998-12-16 2002-11-12 Basf Aktiengesellschaft Method for living free-radical polymerization
US20030065184A1 (en) * 2000-03-22 2003-04-03 Peter Nesvadba 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
US20030216494A1 (en) * 2000-05-19 2003-11-20 Michael Roth Hydroxylamine esters as polymerization initiators

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8900779B2 (en) 2006-07-11 2014-12-02 Ciba Corporation Color filter composition
US20100249386A1 (en) * 2009-03-26 2010-09-30 Universite De Provence Dinitroxide-type biradical compounds optimized for dynamic nuclear polarization (dnp)
US8648193B2 (en) 2009-03-26 2014-02-11 Universite D'aix Marseille Dinitroxide-type biradical compounds optimized for dynamic nuclear polarization (DNP)
US9035054B2 (en) 2009-03-26 2015-05-19 Universite D'aix-Marseille Dinitroxide-type biradical compounds optimized for dynamic nuclear polarization (DNP)

Also Published As

Publication number Publication date
AU2002224841A1 (en) 2002-06-24
TW557305B (en) 2003-10-11
CN1198851C (zh) 2005-04-27
US7572869B2 (en) 2009-08-11
JP2010065058A (ja) 2010-03-25
US20060149011A1 (en) 2006-07-06
CN1481393A (zh) 2004-03-10
CA2431393A1 (fr) 2002-06-20
JP2004526683A (ja) 2004-09-02
KR20040010572A (ko) 2004-01-31
KR100838217B1 (ko) 2008-06-13
US7288613B2 (en) 2007-10-30
US20080015276A1 (en) 2008-01-17
JP4602638B2 (ja) 2010-12-22
EP1343827A1 (fr) 2003-09-17
WO2002048205A1 (fr) 2002-06-20

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AS Assignment

Owner name: CIBA SPECIALTY CHEMICALS CORP., NEW YORK

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:NESVADBA, PETER;ZINK, MARIE-ODILE;WUNDERLICH, WIEBKE;REEL/FRAME:014626/0568;SIGNING DATES FROM 20030505 TO 20030513

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION