US20030126796A1 - Fuel gas for a fuel cell - Google Patents

Fuel gas for a fuel cell Download PDF

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Publication number
US20030126796A1
US20030126796A1 US10/323,976 US32397602A US2003126796A1 US 20030126796 A1 US20030126796 A1 US 20030126796A1 US 32397602 A US32397602 A US 32397602A US 2003126796 A1 US2003126796 A1 US 2003126796A1
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US
United States
Prior art keywords
fuel cell
gas
fuel
odor
odorant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/323,976
Inventor
Kouetsu Hibino
Tsuyoshi Takahashi
Yuichi Yagami
Mikio Wada
Tsutomu Ochi
Katsuhiro Kajio
Toshiyuki Inagaki
Yasuyuki Asai
Yixin Zeng
Toshiyuki Suzuki
Haruhisa Niimi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Motor Corp
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Assigned to TOYOTA JIDOSHI KABUSHIKI KAISHA reassignment TOYOTA JIDOSHI KABUSHIKI KAISHA ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ASAI, YASUYUKI, HIBINO, KOUETSU, INAGAKI, TOSHIYUKI, KAJIO, KATSUHIRO, NIIMI, HARUHISA, OCHI, TSUTOMU, SUZUKI, TOSHIYUKI, TAKAHASHI, TSUYOSHI, WADA, MIKIO, YAGAMI, YUICHI, ZENG, YIXIN
Publication of US20030126796A1 publication Critical patent/US20030126796A1/en
Priority to US11/176,202 priority Critical patent/US20050241233A1/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • C10L1/1881Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/003Additives for gaseous fuels
    • C10L3/006Additives for gaseous fuels detectable by the senses

Definitions

  • the invention relates to a fuel gas for a fuel cell, and more particularly to a fuel gas for a fuel cell having an odor by which a gas leakage can be immediately detected.
  • a fuel gas for a fuel cell supplied to an anode side of a fuel cell a reformed gas rich in hydrogen obtained by reforming light hydrocarbons such as a hydrogen, a natural gas or a naphtha has been used.
  • an odorant is added to such a fuel gas for a fuel cell so that a gas leakage can be easily detected when it occurs.
  • Japanese Patent Laid-Open Publication No. 2000-233901 discloses an example of the fuel gas to which a sulfur based odorant is added.
  • the invention was made in view of the conventional problems. It is an object of the invention to provide a fuel gas for a fuel cell that does not poison an electrode catalyst and an electrolyte in a fuel cell, and by which a leakage can be easily detected when it occurs.
  • a fuel gas for a fuel cell according to the invention is comprising a reaction gas which produces an electricity by a chemical reaction, and an odorant which does not poison an electrode catalyst and an electrolyte, and dissolves in water so that an odor thereof disappears.
  • an odorant is added to a fuel gas supplied to a fuel cell in order to easily detect a gas leakage, which makes it possible to detect the gas leakage by the odor when the gas leakage occurs.
  • an odorant that does not poison an electrode catalyst or an electrolyte.
  • a fatty acid into a reformed hydrogen gas, in a case where a reformer is used as means of producing the fuel gas for a fuel cell mounted on a vehicle.
  • some fatty acids having a relatively low carbon number have pungent odors, and are water-solvable. Therefore, although the fuel gas for a fuel cell to which the fatty acid is added has an odor, the fatty acid dissolves in water produced by an electrochemical reaction occurred in the fuel cell, which prevents the odor from remaining in the exhaust gas emitted from the fuel cell. This precludes a possibility that the exhaust gas from the fuel cell is confused with a leaked gas because of its odor. Therefore, it becomes possible to detect the gas leakage, when the fuel gas leaks from the fuel cell.
  • the acetic acid or the butyric acid can be exemplified as fatty acids used as the odorants. Both the acetic acid and the butyric acid have strong odors, and also do no poison the electrode catalyst or the electrolyte. Further, the fatty acids dissolve in water produced by the electrochemical reaction of hydrogen and oxygen in the fuel cell, which prevents the exhaust gas from exuding the odor.
  • an odor can be added to a fuel gas without poisoning an electrode catalyst and an electrolyte in a fuel cell by employing fatty a acid having an odor such as an acetic acid or a butyric acid as an odorant added to a fuel gas for a fuel cell.
  • the odorant dissolves in water produced by an electrochemical reaction, which makes it possible to provide the fuel gas for a fuel cell whose odor does not remain in an exhaust gas emitted from the fuel cell.

Abstract

A fatty acid such as an acetic acid or a butyric acid is added to a fuel gas for a fuel cell as an odorant. This makes it possible to add an odor to the fuel gas without poisoning an electrode catalyst and an electrolyte, and to prevent the odor from remaining in an exhaust gas emitted from the fuel cell.

Description

    INCORPORATION BY REFERENCE
  • The disclosure of Japanese Patent Application No. 2002-003215 filed on Jan. 10, 2002 including the specification, drawings and abstract are incorporated herein by reference in its entirety. [0001]
  • BACKGROUND OF THE INVENTION
  • 1. Field of Invention [0002]
  • The invention relates to a fuel gas for a fuel cell, and more particularly to a fuel gas for a fuel cell having an odor by which a gas leakage can be immediately detected. [0003]
  • 2. Description of Related Art [0004]
  • As a fuel gas for a fuel cell supplied to an anode side of a fuel cell, a reformed gas rich in hydrogen obtained by reforming light hydrocarbons such as a hydrogen, a natural gas or a naphtha has been used. Generally, an odorant is added to such a fuel gas for a fuel cell so that a gas leakage can be easily detected when it occurs. [0005]
  • For example, Japanese Patent Laid-Open Publication No. 2000-233901 discloses an example of the fuel gas to which a sulfur based odorant is added. [0006]
  • Conventional odorants added to fuel gases for fuel cell are sulfur based substances such as a mercaptan, as mentioned above. However, it is known that these substances may poison an electrode catalyst or an electrolyte in a fuel cell, which results in degradation in performance of the fuel cell. Therefore, a desulfurizer may be provided in order to remove sulfur components contained in the odorants. However, desulfurization may not be adequately executed, and the above-mentioned problem of poisoning the catalyst cannot be entirely solved. [0007]
  • In addition, there exists a problem that since the fuel cell does not utilize a combustion reaction unlike an internal combustion engine, the odorant remains in an exhaust gas emitted from the fuel cell, which causes confusion with the gas leakage. [0008]
  • SUMMARY OF THE INVENTION
  • The invention was made in view of the conventional problems. It is an object of the invention to provide a fuel gas for a fuel cell that does not poison an electrode catalyst and an electrolyte in a fuel cell, and by which a leakage can be easily detected when it occurs. [0009]
  • In order to attain the above-mentioned object, a fuel gas for a fuel cell according to the invention is comprising a reaction gas which produces an electricity by a chemical reaction, and an odorant which does not poison an electrode catalyst and an electrolyte, and dissolves in water so that an odor thereof disappears. [0010]
  • According to the above-mentioned structures, it is possible to prevent the odorant from poisoning the electrode catalyst or the electrolyte in the fuel cell, and to easily detect the gas leakage when it occurs. In addition, the odorant dissolves in water so that the odor disappears, which makes it possible to prevent confusion with the gas leakage due to a remaining odor in an exhaust gas.[0011]
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • Hereinafter, an embodiment according to the invention (hereinafter referred to as embodiments) will be explained. [0012]
  • As mentioned above, an odorant is added to a fuel gas supplied to a fuel cell in order to easily detect a gas leakage, which makes it possible to detect the gas leakage by the odor when the gas leakage occurs. As mentioned above, it is necessary to employ an odorant that does not poison an electrode catalyst or an electrolyte. [0013]
  • Also, even after the fuel gas for a fuel cell is supplied to the fuel cell and undergoes a reaction, the odorant does not undergo a reaction and remains unchanged. Therefore, the same odor as that of the fuel gas is imparted to the exhaust gas emitted from the fuel cell, which may cause confusion with the gas leakage. Thus, it is necessary to employ an odorant that does not impart the odor to the exhaust gas emitted from the fuel cell. [0014]
  • In addition, it is preferable to add a fatty acid into a reformed hydrogen gas, in a case where a reformer is used as means of producing the fuel gas for a fuel cell mounted on a vehicle. [0015]
  • As a result of a thorough study conducted by the inventors from the above-mentioned each viewpoint, it was found that the fatty acid having an odor is suitable as the odorant. [0016]
  • When the fatty acid is used as the odorant, degradation in performance can be prevented since the electrode catalyst or the electrolyte in the fuel cell are not poisoned. [0017]
  • Also, some fatty acids having a relatively low carbon number have pungent odors, and are water-solvable. Therefore, although the fuel gas for a fuel cell to which the fatty acid is added has an odor, the fatty acid dissolves in water produced by an electrochemical reaction occurred in the fuel cell, which prevents the odor from remaining in the exhaust gas emitted from the fuel cell. This precludes a possibility that the exhaust gas from the fuel cell is confused with a leaked gas because of its odor. Therefore, it becomes possible to detect the gas leakage, when the fuel gas leaks from the fuel cell. [0018]
  • The acetic acid or the butyric acid can be exemplified as fatty acids used as the odorants. Both the acetic acid and the butyric acid have strong odors, and also do no poison the electrode catalyst or the electrolyte. Further, the fatty acids dissolve in water produced by the electrochemical reaction of hydrogen and oxygen in the fuel cell, which prevents the exhaust gas from exuding the odor. [0019]
  • For example, in the case of the butyric acid, adding approximately 2 to 10 ppm of butyric acid to the fuel gas for a fuel cell allows the fuel gas for a fuel cell to exude the odor that can be sufficiently detected by human nose. Also, since the butyric acid dissolves in reaction product water, no odor remains in the exhaust gas emitted from the fuel cell. [0020]
  • However, in a case where water is recovered from the exhaust gas from the fuel cell, dissolved fatty acid components need to be removed. Therefore, it is preferable to provide a removal process. [0021]
  • As explained above, according to the invention, an odor can be added to a fuel gas without poisoning an electrode catalyst and an electrolyte in a fuel cell by employing fatty a acid having an odor such as an acetic acid or a butyric acid as an odorant added to a fuel gas for a fuel cell. Thus, the odorant dissolves in water produced by an electrochemical reaction, which makes it possible to provide the fuel gas for a fuel cell whose odor does not remain in an exhaust gas emitted from the fuel cell. [0022]

Claims (3)

What is claimed is:
1. A fuel gas for a fuel cell comprising:
a reaction gas that is supplied to a fuel cell and produces electricity by a chemical reaction; and
an odorant which is added to the reaction gas, is non-poisonous to an electrode catalyst and an electrolyte in the fuel cell, and dissolves in water so that an odor thereof disappears.
2. The fuel gas for a fuel cell according to claim 1 wherein:
the odorant is a fatty acid having an odor.
3. The fuel gas for a fuel cell according to claim 2 wherein:
the fatty acid is one of an acetic acid and a butyric acid.
US10/323,976 2002-01-10 2002-12-20 Fuel gas for a fuel cell Abandoned US20030126796A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/176,202 US20050241233A1 (en) 2002-01-10 2005-07-08 Fuel gas for a fuel cell

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2002003215A JP2003201487A (en) 2002-01-10 2002-01-10 Fuel gas for fuel cell
JP2002-003215 2002-01-10

Related Child Applications (1)

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US11/176,202 Division US20050241233A1 (en) 2002-01-10 2005-07-08 Fuel gas for a fuel cell

Publications (1)

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US10/323,976 Abandoned US20030126796A1 (en) 2002-01-10 2002-12-20 Fuel gas for a fuel cell
US11/176,202 Abandoned US20050241233A1 (en) 2002-01-10 2005-07-08 Fuel gas for a fuel cell

Family Applications After (1)

Application Number Title Priority Date Filing Date
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Country Status (3)

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US (2) US20030126796A1 (en)
JP (1) JP2003201487A (en)
DE (1) DE10300556B4 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040072050A1 (en) * 2002-10-11 2004-04-15 Toyota Jidosha Kabushiki Kaisha Fuel cell system
US20100035130A1 (en) * 2003-09-30 2010-02-11 Honeywell International Inc. Electrolyte with indicator
US20100092835A1 (en) * 2007-04-12 2010-04-15 Toyota Jidosha Kabushiki Kaisha Fuel cell system
US7794888B2 (en) 2006-08-04 2010-09-14 Toyota Jidosha Kabushiki Kaisha Fuel cell system
US20110121237A1 (en) * 2002-08-13 2011-05-26 Enersol, Inc. N.A., L.P. Hydrogen odorants and odorant selection method
US8871392B2 (en) 2006-08-09 2014-10-28 Toyota Jidosha Kabushiki Kaisha Fuel cell system

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040197919A1 (en) * 2003-04-01 2004-10-07 Herman Gregory S. Fuel cell leak detection
US7851097B2 (en) * 2006-08-09 2010-12-14 Toyota Jidosha Kabushiki Kaisha Fuel cell system
JP5082759B2 (en) * 2007-10-23 2012-11-28 トヨタ自動車株式会社 Fuel cell system

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3970745A (en) * 1974-05-09 1976-07-20 Director-General Of The Agency Of Industrial Science And Technology Method for producing hydrogen from water
US4480017A (en) * 1982-01-29 1984-10-30 Hitachi, Ltd. Fuel cell
US5830423A (en) * 1995-11-22 1998-11-03 International Fuel Cells Corp. Waste gas treatment system
US6033794A (en) * 1997-12-10 2000-03-07 The United States Of America As Represented By The United States Department Of Energy Multi-stage fuel cell system method and apparatus
US6156084A (en) * 1998-06-24 2000-12-05 International Fuel Cells, Llc System for desulfurizing a fuel for use in a fuel cell power plant

Family Cites Families (5)

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JPS5556190A (en) * 1978-10-23 1980-04-24 Soda Koryo Kk Odorant for fuel gas
JP3378673B2 (en) * 1994-08-24 2003-02-17 東京瓦斯株式会社 Odorant for fuel gas
DE19837066A1 (en) * 1998-08-17 2000-02-24 Haarmann & Reimer Gmbh Odorizing a gas, e.g. city gas comprises adding an acrylic acid, nitrogen compound and antioxidant to the gas
EP1234167A4 (en) * 1999-11-18 2005-06-29 Mst Technology Gmbh Optical hydrogen detector
US6820464B2 (en) * 2002-12-16 2004-11-23 Air Products And Chemicals, Inc. Odorized seals for the detection of gas leak

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3970745A (en) * 1974-05-09 1976-07-20 Director-General Of The Agency Of Industrial Science And Technology Method for producing hydrogen from water
US4480017A (en) * 1982-01-29 1984-10-30 Hitachi, Ltd. Fuel cell
US5830423A (en) * 1995-11-22 1998-11-03 International Fuel Cells Corp. Waste gas treatment system
US6033794A (en) * 1997-12-10 2000-03-07 The United States Of America As Represented By The United States Department Of Energy Multi-stage fuel cell system method and apparatus
US6156084A (en) * 1998-06-24 2000-12-05 International Fuel Cells, Llc System for desulfurizing a fuel for use in a fuel cell power plant

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110121237A1 (en) * 2002-08-13 2011-05-26 Enersol, Inc. N.A., L.P. Hydrogen odorants and odorant selection method
US8394553B2 (en) * 2002-08-13 2013-03-12 Enersol Inc., N.A.L.P. Hydrogen odorants and odorant selection method
US20040072050A1 (en) * 2002-10-11 2004-04-15 Toyota Jidosha Kabushiki Kaisha Fuel cell system
US7267901B2 (en) * 2002-10-11 2007-09-11 Toyota Jidosha Kabushiki Kaisha Fuel cell system
US20100035130A1 (en) * 2003-09-30 2010-02-11 Honeywell International Inc. Electrolyte with indicator
US7794888B2 (en) 2006-08-04 2010-09-14 Toyota Jidosha Kabushiki Kaisha Fuel cell system
US8871392B2 (en) 2006-08-09 2014-10-28 Toyota Jidosha Kabushiki Kaisha Fuel cell system
US20100092835A1 (en) * 2007-04-12 2010-04-15 Toyota Jidosha Kabushiki Kaisha Fuel cell system
US8227133B2 (en) 2007-04-12 2012-07-24 Toyota Jidosha Kabushiki Kaisha Fuel cell system

Also Published As

Publication number Publication date
DE10300556A1 (en) 2003-07-31
DE10300556B4 (en) 2004-09-09
JP2003201487A (en) 2003-07-18
US20050241233A1 (en) 2005-11-03

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AS Assignment

Owner name: TOYOTA JIDOSHI KABUSHIKI KAISHA, JAPAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:HIBINO, KOUETSU;TAKAHASHI, TSUYOSHI;YAGAMI, YUICHI;AND OTHERS;REEL/FRAME:013618/0288

Effective date: 20021125

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION