US20020107147A1 - Plant-activating agent - Google Patents

Plant-activating agent Download PDF

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US20020107147A1
US20020107147A1 US10/061,226 US6122602A US2002107147A1 US 20020107147 A1 US20020107147 A1 US 20020107147A1 US 6122602 A US6122602 A US 6122602A US 2002107147 A1 US2002107147 A1 US 2002107147A1
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Prior art keywords
alcohol
surfactant
poe
plant
acid
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US10/061,226
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Masaharu Hayashi
Tadayuki Suzuki
Masatoshi Kamei
Toshio Hayashi
Kazuhiko Kurita
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Kao Corp
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Kao Corp
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/04Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02Acyclic compounds

Definitions

  • the present invention relates to a plant-activating agent and/or a plant-activating composition. Also, as use thereof, the present invention provides a method of activating a plant by applying thereof in the state of solution or solid to a root, stem, phylloplane or fruit of plant, such as spraying onto phylloplanes and irrigating into soil.
  • plant includes plants, vegetables, fruits, crops, seeds, flowers, herbs, floras, and so on.
  • Various nutrient elements are necessary for growth of plants. It is known that lack of some of the elements causes the hindrance of the growth of the plants.
  • the big three fertilizer components function as follows. Nitrogen is a component element of proteins, and phosphorus is a formation element of nucleic acid or phosphorus lipid and further plays an important part in energy metabolism and synthetic or decomposing reaction of a substance. Potassium has a physiological action of substance metabolism or substance migration. If these main components lacks, the growth of plants generally becomes poor. Calcium is an important component constituting the plant-realities and cells, and further plays an important part in maintenance of the balance of the metabolic system. The lacking state of calcium causes physiological troubles. Besides, various nutrients as follows are necessary for plants: Mg, Fe, S, B, Mn, Cu, Zn, Mo, Cl, Si, Na and the like.
  • Nutritious components such as nitrogen, phosphorus and potassium are applied as basal fertilizer or additional fertilizer. Alternatively, they are applied by diluting liquid fertilizer and irrigating the diluted fertilizer into soil or by spraying the diluted fertilizer onto phylloplanes. These fertilizers are necessary and/or essential for the growth of plants. However, even if they are applied at larger concentrations than some values, the growth of plants and the yield of the plants cannot be further improved.
  • JP-A 9-322647 JP-A 9-322647
  • a liquid fertilizer comprising a sugar, a mineral, an amino acid, an extract from seaweeds, or a fermentation extract of microorganisms is sprayed onto phylloplanes or is applied in the form of the liquid.
  • JP-A 9-322647 JP-A 9-322647
  • a liquid fertilizer comprising a sugar, a mineral, an amino acid, an extract from seaweeds, or a fermentation extract of microorganisms
  • the present invention relates to plant-activating agent comprising a mono-alcohol having 12-24 carbon atoms and relates to a plant-activating composition comprising the mono-alcohol, and a surfactant, a fertilizer component or a chelating agent.
  • the present invention provides a plant-activating agent comprising a mono-alcohol having 12-24 carbon atoms, and provides a plant-activating composition comprising the mono-alcohol and at least one compound selected from a surfactant and a chelating agent.
  • the invention provides a method of activating a plant, which comprises treating the plant with a mono-alcohol having 12 to 24 carbon atoms as a plant-activating agent; and use of the mono-alcohol as a plant-activating agent.
  • the plant is treated further with at least one compound selected from a surfactant, a fertilizer component and a chelating agent, in use or method of the above-mentioned.
  • the surfactant maybe selected from an ester group-containing nonionic surfactant, an ether group-containing nonionic surfactant having no nitrogen atom, an amphoteric surfactant, a carboxylic anionic surfactant and a phosphoric anionic surfactant, in use or method of the above-mentioned.
  • the invention provides a plant-activating composition
  • a plant-activating composition comprising a mono-alcohol having 12 to 24 carbon atoms and one group selected from (i) a chelating agent, (ii) a surfactant and a chelating agent, (iii) a fertilizer component and a chelating agent, and (iv) a surfactant, a fertilizer component and a chelating agent.
  • compositions may preferably comprise a mono-alcohol having 12 to 24 carbon atoms and at least one surfactant selected from an ester group-containing nonionic surfactant, a ether group-containing nonionic surfactant having no nitrogen atom, an amphoteric surfactant, a carboxylic anionic surfactant and a phosphoric anionic surfactant.
  • surfactant selected from an ester group-containing nonionic surfactant, a ether group-containing nonionic surfactant having no nitrogen atom, an amphoteric surfactant, a carboxylic anionic surfactant and a phosphoric anionic surfactant.
  • a plant-activating composition of the invention comprises a mono-alcohol having 12 to 24 carbon atoms and at least one surfactant selected from an ester group-containing nonionic surfactant, an ether group-containing nonionic surfactant having no nitrogen atom, an amphoteric surfactant, a carboxylic anionic surfactant and a phosphoric anionic surfactant, optionally further comprising a fertilizer component.
  • a plant-activating composition of the invention comprises a mono-alcohol having 12 to 24 carbon atoms and one group selected from (iii) a fertilizer component and a chelating agent, (iv) a surfactant, a fertilizer component and a chelating agent and (v) a surfactant and a fertilizer component.
  • a mono-alcohol having 12-24 carbon atoms, preferably 14-22 carbon atoms, particularly preferably 16-20 carbon atoms is used since the alcohol can effectively give plant vital power activation without causing chemical injury.
  • the hydrocarbon group of the mono-alcohol may be saturated or unsaturated, and may be in the form of a straight chain, a branched chain or a cyclic chain.
  • the hydrocarbon group is preferably an alkyl group being a straight or branched chain, particularly preferably an alkyl group being a straight chain.
  • Specific examples of the mono-alcohol include lauryl alcohol, cetyl alcohol, stearyl alcohol, eicosanol, behenyl alcohol, phytol, oleyl alcohol, and alcohols originated from natural fats and/or oils.
  • the form of the plant-activating agent comprising the mono-alcohol according to the present invention may be any form, such as a liquid, a flowable, a paste, a wettable powder, a granule, a dust formulation or a tablet.
  • the plant-activating agent is generally sprayed in the form of an aqueous solution, an aqueous dispersion, or an aqueous emulsion which has a mono-alcohol concentration of from 1 to 500 ppm onto phylloplanes or roots of a plant.
  • various methods may be used,.
  • the methods include a method of applying a dust formation or a granule as fertilizer directly, a method of spraying a diluted aqueous solution directly onto phylloplanes, stems or fruits of a plant, a method of injecting a diluted aqueous solution into soil, and a method of supplying to dilute and to mix into a liquid for a hydroponics and a supplying water which are contacted with roots and which are such as a hydroponics and a rock wool.
  • Plants which can be treated with the plant-activating agent of the present invention, may be a fruit vegetable such as a cucumber, a pumpkin, a watermelon-plant, a melon, a tomato, an eggplant, a green pepper, a strawberry, an okra, kidney beans in a pod, a broad bean, a pea, green soybeans in a pod and a corn; a leaf vegetables such as a Chinese cabbage, greens for pickling, a Brassica campestris (a Chinese spinach-like green vegetable), a cabbage, a cauliflower, a broccoli, a Brussels sprout, an onion, a Welsh onion, a garlic, a scallion, a leek, an asparagus, a lettuce, a green for salad (which is called Saladana in Japan), a celery, a spinach, a crown daisy, a parsley, a trefoil (which is called Mitsuba in Japan and is useful as herb), a dropwort, an udo (
  • the following surfactant is preferably used together with the above-mentioned mono-alcohol to promote emulsification, dispersion, solubilization and permeation of the mono-alcohol.
  • nonionic surfactants include sorbitan fatty acid esters, polyoxyalkylene sorbitan fatty acid esters, polyoxyalkylene fatty acid esters, glycerol fatty acid esters, polyoxyalkylene glycerol fatty acid esters, polyglycerol fatty acid esters, polyoxyalkylene polyglycerol fatty acid esters, sucrose fatty acid esters, resin acid esters, polyoxyalkylene resin acid esters, polyoxyalkylene alkyl ethers, polyoxyalkylene alkylphenyl ethers, alkyl(poly)glycosides and polyoxyalkylenealkyl(poly)glycosides.
  • an ether group-containing nonionic surfactant having no nitrogen atom and ester group-containing nonionic surfactant may be cited.
  • anionic surfactants include carboxylic, sulfonic, sulfuric ester group-containing and phosphoric ester group-containing surfactants, and a carboxylic and phosphoric ester group-containing surfactants are preferred.
  • carboxylic surfactants include fatty acids having 6-30 carbon atoms or salts thereof, polyhydric carboxylic acid salts, polyoxyalkylene alkyl ether carboxylic acid salts, polyoxyalkylene alkylamide ether carboxylic acid salts, rhodinic acid salts, dimmer acid salts, polymer acid salts and tall oil fatty acid salts.
  • sulfonic surfactants include alkylbenezenesulfonic acid salts, alkylsulfonic acid salts, alkylnaphthalenesulfonic acid salts, naphthalenesulfonic acid salts, diphenyl ether sulfonic acid salts, condensates of alkylnaphthalenesulfonic acid, and condensate of naphthalenesulfonic acid.
  • sulfuric ester group-containing surfactants examples include alkylsulfuric ester salts (alkylsulfuric acid salts), polyoxyalkylene alkylsulfuric ester salts (polyoxyalkylene alkylsulfuric acid salts), polyoxyalkylene alkyl phenyl ether sulfuric acid salts, tristyrenated phenol sulfuric acid ester salts, polyoxyalkylene distyrenated phenol sulfuric acid ester salts and alkylpolyglycoside sulfuric acid salts.
  • Examples of phosphoric acid ester group-containing surfactants include alkyl phosphoric acid ester salts, alkylphenylphosphoric acid ester salts, polyoxyalkylene alkylphosphoric acid ester salts and polyoxyalkylene alkylpheneylphosphoric acid ester salts.
  • salts examples include metallic salts (such as salts of Na, K, Ca, Mg and Zn), ammonium salts, alkanol amine salts and aliphatic amine salts.
  • amphoteric surfactants include amino acid group-containing, betaine group-containing, imidazoline group-containing and amine oxide group-containing surfactants.
  • amino acid group-containing surfactants examples include acylamino acid salts, acylsarcosine acid salts, acyloylmethylaminopropionic acid salts, alkylaminopropionic acid salts and acylamide ethylhydroxyethylmethylcarboxylic acid salts.
  • betaine group-containing surfactants examples include alkyldimethylbetaine, alkylhydroxyethylbetaine, acylamide propylhydroxypropylammonia sulfobetaine, acylamide propylhydroxypropylammonia sulfobetaine and ricinoleic acid amide propyl dimethylcarboxy methylammonia betaine.
  • imidazoline group-containing surfactants examples include alkylcarboxy methylhydroxy ethylimidazolinium betaine and alkylethoxy carboxy methylimidazolinium betaine.
  • amine oxide group-containing surfactants examples include alkyldimethylamine oxide, alkyldiethanolamine oxide and alkylamidepropylamine oxide.
  • One kind of the above-mentioned surfactants may be used, and a mixture of two or more kinds of the above-mentioned surfactants may be used.
  • one of these surfactants comprises a polyoxyalkylene group
  • the polyoxyalkylene group is preferably a polyoxyethylene group and the average mole number of added polyoxyethylene groups is preferably from 1 to 50.
  • the surfactant at least one compound selected from ester group-containing nonionic surfactants, ether group-containing nonionic surfactants having no nitrogen atom, amphoteric surfactants, carboxylic anionic surfactants and phosphoric anionic surfactant is preferable.
  • ester group-containing nonionic surfactants and ether group-containing nonionic surfactants having no nitrogen atom.
  • the following fertilizer components may be used together with the above-mentioned mono-alcohol.
  • Specific examples thereof may be inorganic or organic compounds which can supply elements such as N, P, K, Ca, Mg, S, B, Fe, Mn, Cu, Zn, Mo, Cl, Si and Na, in particular N, P, X, Ca and Mg.
  • inorganic compounds include ammonium nitrate, potassium nitrate, ammonium sulfate, ammonium chloride, ammonium phosphate, sodium nitrate, urea, ammonium carbonate, potassium phosphate, calcium superphosphate, fused phosphate fertilizer (3Mgo.Cao.P 2 O 5 .3CaSiO 2 ) , potassium sulfate, potassium chloride, nitrate of lime, slaked lime, carbonate of lime, magnesium sulfate, magnesium hydroxide and magnesium carbonate.
  • organic compounds examples include fowl droppings, cow dung, Bark compost, amino acid, peptone, amino acid solution (which is called Mieki in Japan), fermentation extracts, calcium salts of organic acids (such as citric acid, gluconic acid and succinic acid) , and calcium salts of fatty acids (such as formic acid, acetic acid, propionic acid, caprylic acid, capric acid and caproic acid).
  • organic acids such as citric acid, gluconic acid and succinic acid
  • calcium salts of fatty acids such as formic acid, acetic acid, propionic acid, caprylic acid, capric acid and caproic acid.
  • the fertilizer component is preferably mixed.
  • the plant-activating composition of the present invention is mixed with the following organic acid having chelating ability or a salt thereof, the growth and absorption efficiency of fertilizer improved further.
  • organic acid having chelating ability or a salt thereof include oxycarboxylic acids such as citric acid, gluconic acid, malic acid, heptonic acid, oxalic acid, malonic acid, lactic acid, tartaric acid, succinic acid, fumaric acid, maleic acid, adipic acid and glutaric acid; polyhydric carboxylic acids; and salts thereof such as potassium salt, sodium salt, alkanolamine salt and aliphatic amine salt.
  • Mixing a chelating agent besides the organic acids also causes the growth and absorption efficiency of fertilizer to be improved.
  • the mixed chelating agents include aminocarboxylic group-containing chelating agents such as EDTA, NTA and CDTA.
  • the plant-activating composition or the fertilizer composition of the present invention it is preferable to use respectively; per 100 parts by weight of the mono-alcohol; 10-20000 parts, in particular 100-2000 parts, by weight of the surfactant; 0-50000 parts, in particular 10-5000 parts, by weight of the fertilizer component; 0-1000 parts, in particular 10-500 parts, by weight of the chelating agent; and 0-5000 parts, in particular 10-500 parts, by weight of other nutritious sources (such as sugars, amino acids and vitamins).
  • other nutritious sources such as sugars, amino acids and vitamins.
  • the plant-activating composition is applied in the form of a dust formulation or granule as fertilizer to soil
  • the used dust formulation or granule comprise the above-mentioned components except water at the same ratios as above, in general.
  • This dust formulation or granule may comprise a vehicle to prevent caking.
  • the plant-activating agent of the present invention makes it possible to improve the activity of plant effectively without causing any chemical injury on plants if the plants are treated with an appropriate concentration of the plant-activating agent. For this reason, it can be used for various plants. According to the present invention, promotion of taking root of a plant, increase of chlorophyll value (SPAD value), increase of absorption efficiency of fertilizer and so on are seen as improvement at growth of plant.
  • Vessel for cultivation a cell tray having 50 holes for germination, and a pot (diameter: 14 cm) for cultivation
  • the growth state [height and weight (,hereinafter, “weight” means raw-weight,] of the respective plants and the SPAD value (SPAD 502 made by Minolta Co., Ltd.) representing a green degree were measured.
  • the measured values obtained from the 3 repetitions were averaged.
  • the averaged value was relatively compared as the value that was obtained from the no-treated area (Comparative product 1-4) and made to be 100.
  • the results are shown in Table 1. TABLE 1 Results of the test Concentration SPAD No.
  • Blended raw materials (ppm) Height Weight value Invention product 1-1 Stearyl alcohol 100 148 142 122 POE(20) sorbitan monooleate 500 1-2 Eicosanol 200 145 140 119 POE(20) hardened castor oil 1000 1-3 Decyldodecanol 100 134 124 110 POE(15) glycerol beef tallow fatty acid ester 500 1-4 Lauryl alcohol 50 132 122 112 Na salt of POE(3) lauryl sulfuric ester 100 POE(20) sorbitan monolaurate 200 1-5 Oleyl alcohol 300 138 130 118 POE(20) sorbitan monolaurate 600 Sorbitan monolaurate 400 1-6 Stearyl alcohol 200 144 138 122 Cetyl alcohol 100 POE(20) sorbitan monolaurate 500 Tetraglycerol monooleate 500 1-7 Branched C 12 /C 13 alcohol* 100 118 110 112 POE(10) oleic acid ester 500 Alky
  • Vessel for cultivation a cell tray having 50 holes
  • Used soil Takii soil for seeding (which was the same as in Example 1)
  • Vessel for cultivation a cell tray having 50 holes
  • Chlorella cells which are green cells of a higher plant, were cultured with vibration in an inorganic-salt medium. Raw materials shown in Table 4 were added thereto, and then reproductive ability of chlorella cells (ability for increasing the number of the cells) was evaluated by comparison with the result obtained from a medium which was no-treated (i.e., only original nutrients of the inorganic salt medium). For the respective compositions, the test was repeated 3 times. The concentration of the cells was set to 1.00 ⁇ 105 cells (per ml) at the start of the test.
  • the numbers of the chlorella cells after 10 days from the addition of the various raw materials followed by culture of the cells are shown as the relative values compared with the value that was obtained from the medium which was no-treated (Comparative product 4-9) and made to be 100.
  • the results are shown in Table 4.
  • As the inorganic salt medium a Linsmaier-Skoog (LS) medium was used. TABLE 4 Result of the test Test Concentration proliferating ability No.
  • Blended raw materials (ppm) of cells Invention product 4-1 Lauryl alcohol 10 115 4-2 Myristyl alcohol 10 128 4-3 Myristyl alcohol 5 138 Stearyl alcohol 5 4-4 Cetyl alcohol 10 148 4-5 Cetyl alcohol 5 160 Stearyl alcohol 5 4-6 Stearyl alcohol 10 168 4-7 Oleyl alcohol 10 154 4-8 Eicosanol 10 152 4-9 Docosanol 10 130 4-10 Tetracosanol 10 122 4-11 Lauryl alcohol 10 119 Malonic acid 4 4-12 Cetyl alcohol 10 152 Ascorbic acid Na salt 4 4-13 Stearyl alcohol 10 172 EDTA.4Na 4 4-14 Eicosanol 10 160 EDTA.4Na 4 4-15 Cetyl alcohol 30 142 4-16 Stearyl alcohol 30 156 4-17 Eicosanol 30 146 4-18 Cetyl alcohol 30 146 Ascorbic acid Na salt 15 4-19 Stearyl alcohol 30 159 EDTA.4Na 15 4-20 Eicosano
  • the each value as relative value shows an absorption amount of nitrate nitrogen at each treatment in the case of making NPK culturing solution to be control.
  • SPAD value (SPAD 502 made by Minolta Co., Ltd.) representing green degree of a leaf were measured.
  • control Comparative product 5-4 made up to be 100
  • the relative value is compared.
  • fertilizer composition of OKF2 (Otsuka Chemical Co., Ltd.) was as follows: N:P:K:Ca:Mg 14:8:16:6:2. TABLE 5 Result of the test Concentration Efficency of Test No.
  • Used soil Kureha Engei Baido (horticultural soil made by Kureha Chemical Industry Co., Ltd.)
  • Blended raw materials (ppm) Weight SPAD value Invention product 6-1 Stearyl alcohol 50 125 115 POE(20) sorbitan monooleic acid ester (RHEODOL TW-O120) 150 6-2 Stearyl alcohol 50 121 115 POE(6) sorbitan monooleic acid ester (RHEODOL TW-O106) 150 6-3 Stearyl alcohol 50 125 112 POE(20) sorbitan monostearic acid ester (RHEODOL TW-S120) 150 6-4 Stearyl alcohol 50 122 110 POE(20) sorbitan tristearic acid ester (RHEODOL TW-S320) 150 6-5 Stearyl alcohol 50 123 114 POE(20) sorbitan coconut oil fatty acid ester (RHEODOL TW-L120) 150 6-6 Stearyl alcohol 50 122 112 Sorbitan monostearic acid ester (RHEODOL SP-S10) 150 6-7 Stearyl alcohol 50 123 113 Sorbitan
  • Unhulled rice seeds (species of Koshihikari) were sown into a box (60 ⁇ 30 cm) for raising seedling. At the period transferring from the hardening period to the greening period after germination, treatment was started in an treating amount of 500 ml/the box for raising seedling.
  • Raw materials shown in Table 8 were used to irrigate the soil 3 times into soil. After the 3 treatments, that is, after 15 days from the sowing, the heights and the weights of the seedlings and the SPAD value were examined. When the no-treated area (Comparative product 7-6) made up to be 100, the relative value is compared. The results are shown in Table 8.
  • N component was applied in an amount of 0.5 g per the box for raising seedling. During the test period, fertilizer components were not applied as additional fertilizer and rice-plant seedlings absorbed only nutrients contained in the soil. TABLE 8 Concentration Result of the test Test No.
  • Blended raw materials (ppm) Height Weight SPAD value Invention product 7-1 Stearyl alcohol 100 106 115 113 POE(20) sorbitan monooleate 300 7-2 Myristyl alcohol 100 107 107 108 POE(20) sorbitan monooleate 300 tartaric acid Na solt 50 7-3 Tetracosanol 100 102 107 106 POE(20) sorbitan monooleate 300 7-4 Myristyl alcohol 100 106 108 110 POE(20) sorbitan monooleate 300 Oxamide 50 7-5 Lauryl alcohol 100 102 102 105 POE(20) sorbitan monolaurate 300 7-6 Eicosanol 100 104 110 109 POE(20) sorbitan monooleate 300 7-7 Oleyl alcohol 100 108 119 116 POE(20) sorbitan monooleate 300 EDTA ⁇ 4Na 50 7-8 Stearyl alcohol 50 108 118 116 Cetyl alcohol 50 POE(20

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
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  • Cultivation Of Plants (AREA)

Abstract

The present invention provides a plant-activating agent which effects no chemical injury on plant and which makes an activity of plant improve efficiently. That is to say, the present invention provides a method of activating a plant, which comprises treating the plant with a mono-alcohol having 12 to 24 carbon atoms as a plant-activating agent; use of the mono-alcohol as a plant-activating agent; and a plant-activating agent or composition comprising the mono-alcohol; optionally with a surfactant, a fertilizer component and/or a chelating agent.

Description

    TECHNICAL FIELD
  • The present invention relates to a plant-activating agent and/or a plant-activating composition. Also, as use thereof, the present invention provides a method of activating a plant by applying thereof in the state of solution or solid to a root, stem, phylloplane or fruit of plant, such as spraying onto phylloplanes and irrigating into soil. Now, hereinafter, the term of “plant” includes plants, vegetables, fruits, crops, seeds, flowers, herbs, floras, and so on. [0001]
  • BACKGROUND ART
  • Various nutrient elements are necessary for growth of plants. It is known that lack of some of the elements causes the hindrance of the growth of the plants. For example, the big three fertilizer components function as follows. Nitrogen is a component element of proteins, and phosphorus is a formation element of nucleic acid or phosphorus lipid and further plays an important part in energy metabolism and synthetic or decomposing reaction of a substance. Potassium has a physiological action of substance metabolism or substance migration. If these main components lacks, the growth of plants generally becomes poor. Calcium is an important component constituting the plant-realities and cells, and further plays an important part in maintenance of the balance of the metabolic system. The lacking state of calcium causes physiological troubles. Besides, various nutrients as follows are necessary for plants: Mg, Fe, S, B, Mn, Cu, Zn, Mo, Cl, Si, Na and the like. [0002]
  • Nutritious components such as nitrogen, phosphorus and potassium are applied as basal fertilizer or additional fertilizer. Alternatively, they are applied by diluting liquid fertilizer and irrigating the diluted fertilizer into soil or by spraying the diluted fertilizer onto phylloplanes. These fertilizers are necessary and/or essential for the growth of plants. However, even if they are applied at larger concentrations than some values, the growth of plants and the yield of the plants cannot be further improved. [0003]
  • However, it is an important theme in agricultural production to promote the growth of agricultural plants and increase the yield per unit area to strive for an increase in income. Various plant growth regulators being necessary for this have been developed and used. The plant growth regulators, the typical examples of which include gibberellin and auxin, are used to regulate growth reaction or form-producing reaction such as germination, rooting, expansion, flowering and bearing. The actions of these substances are many-sided or complicated. The uses thereof are restrictive. [0004]
  • In order to solve such problems, there are known a phylloplane spraying agent using an oligosaccharide (JP-A 9-322647), and techniques in which a liquid fertilizer comprising a sugar, a mineral, an amino acid, an extract from seaweeds, or a fermentation extract of microorganisms is sprayed onto phylloplanes or is applied in the form of the liquid. In the present situation, however, their effects are insufficient for practical use. [0005]
  • For an increased yield, when a large amount of fertilizer is applied into the soil, various components may become excessive in the soil so that the balance of absorption thereof may become bad or the growth of plants may be delayed. As a result, there arise, for example, problems that the increased yield, as an aim, cannot be attained or the quality such as sugar concentration (Brix. value) or freshness (green degree) does not rise. And then, since there are a limit of absorption from roots which aim absorption of nutrients, direct absorption of necessary fertilizer elements from phylloplanes or fruits is attempted by spraying an aqueous solution or aqueous suspension of the elements. However, even if the aqueous solution of the necessary elements is merely sprayed onto phylloplanes, a problem arises from the viewpoint of absorption efficiency. Spraying excessive amounts of fertilizer elements impose stress on plants, resulting in chemical injury. [0006]
  • Handbook of Agricultural Chemicals (edited in 1994), on page 475, discloses decyl alcohol as a restrainer of an axillary bud of a tobacco plant. JP-a 55-40674 discloses an alcohol having 30 carbon atoms as a plant growth promoter. [0007]
  • It is known to dilute a foam concentrated product with water, generate foams at a static pressure of 15 psi or more in a foam generator connected to a tap water pipe, and treat plants or soil with the resultant foams (U.S. Pat. No. 3922977). However, this patent never discloses nor suggests use as a plant-activating agent or method for activating plants. [0008]
  • DISCLOSURE OF THE INVENTION
  • The present invention relates to plant-activating agent comprising a mono-alcohol having 12-24 carbon atoms and relates to a plant-activating composition comprising the mono-alcohol, and a surfactant, a fertilizer component or a chelating agent. [0009]
  • Namely, the present invention provides a plant-activating agent comprising a mono-alcohol having 12-24 carbon atoms, and provides a plant-activating composition comprising the mono-alcohol and at least one compound selected from a surfactant and a chelating agent. [0010]
  • The invention provides a method of activating a plant, which comprises treating the plant with a mono-alcohol having 12 to 24 carbon atoms as a plant-activating agent; and use of the mono-alcohol as a plant-activating agent. [0011]
  • It is preferred that the plant is treated further with at least one compound selected from a surfactant, a fertilizer component and a chelating agent, in use or method of the above-mentioned. [0012]
  • The surfactant maybe selected from an ester group-containing nonionic surfactant, an ether group-containing nonionic surfactant having no nitrogen atom, an amphoteric surfactant, a carboxylic anionic surfactant and a phosphoric anionic surfactant, in use or method of the above-mentioned. [0013]
  • The invention provides a plant-activating composition comprising a mono-alcohol having 12 to 24 carbon atoms and one group selected from (i) a chelating agent, (ii) a surfactant and a chelating agent, (iii) a fertilizer component and a chelating agent, and (iv) a surfactant, a fertilizer component and a chelating agent. [0014]
  • Another composition may preferably comprise a mono-alcohol having 12 to 24 carbon atoms and at least one surfactant selected from an ester group-containing nonionic surfactant, a ether group-containing nonionic surfactant having no nitrogen atom, an amphoteric surfactant, a carboxylic anionic surfactant and a phosphoric anionic surfactant. [0015]
  • A plant-activating composition of the invention comprises a mono-alcohol having 12 to 24 carbon atoms and at least one surfactant selected from an ester group-containing nonionic surfactant, an ether group-containing nonionic surfactant having no nitrogen atom, an amphoteric surfactant, a carboxylic anionic surfactant and a phosphoric anionic surfactant, optionally further comprising a fertilizer component. [0016]
  • A plant-activating composition of the invention comprises a mono-alcohol having 12 to 24 carbon atoms and one group selected from (iii) a fertilizer component and a chelating agent, (iv) a surfactant, a fertilizer component and a chelating agent and (v) a surfactant and a fertilizer component. [0017]
  • MODES FOR CARRYING OUT THE INVENTION
  • In the present invention, a mono-alcohol having 12-24 carbon atoms, preferably 14-22 carbon atoms, particularly preferably 16-20 carbon atoms, is used since the alcohol can effectively give plant vital power activation without causing chemical injury. The hydrocarbon group of the mono-alcohol may be saturated or unsaturated, and may be in the form of a straight chain, a branched chain or a cyclic chain. The hydrocarbon group is preferably an alkyl group being a straight or branched chain, particularly preferably an alkyl group being a straight chain. Specific examples of the mono-alcohol include lauryl alcohol, cetyl alcohol, stearyl alcohol, eicosanol, behenyl alcohol, phytol, oleyl alcohol, and alcohols originated from natural fats and/or oils. [0018]
  • The form of the plant-activating agent comprising the mono-alcohol according to the present invention may be any form, such as a liquid, a flowable, a paste, a wettable powder, a granule, a dust formulation or a tablet. At the time of use, the plant-activating agent is generally sprayed in the form of an aqueous solution, an aqueous dispersion, or an aqueous emulsion which has a mono-alcohol concentration of from 1 to 500 ppm onto phylloplanes or roots of a plant. [0019]
  • In order to supply the plant-activating agent of the present invention to a plant, various methods may be used,. Examples of the methods include a method of applying a dust formation or a granule as fertilizer directly, a method of spraying a diluted aqueous solution directly onto phylloplanes, stems or fruits of a plant, a method of injecting a diluted aqueous solution into soil, and a method of supplying to dilute and to mix into a liquid for a hydroponics and a supplying water which are contacted with roots and which are such as a hydroponics and a rock wool. [0020]
  • Plants, which can be treated with the plant-activating agent of the present invention, may be a fruit vegetable such as a cucumber, a pumpkin, a watermelon-plant, a melon, a tomato, an eggplant, a green pepper, a strawberry, an okra, kidney beans in a pod, a broad bean, a pea, green soybeans in a pod and a corn; a leaf vegetables such as a Chinese cabbage, greens for pickling, a [0021] Brassica campestris (a Chinese spinach-like green vegetable), a cabbage, a cauliflower, a broccoli, a Brussels sprout, an onion, a Welsh onion, a garlic, a scallion, a leek, an asparagus, a lettuce, a green for salad (which is called Saladana in Japan), a celery, a spinach, a crown daisy, a parsley, a trefoil (which is called Mitsuba in Japan and is useful as herb), a dropwort, an udo (which is an Aralia cordata), a Japanese ginger, a Japanese butterbur and a labiate; and a root vegetable such as a radish, a turnip, a burdock, a carrot, a potato, a taro, a sweet potato, a yam, a ginger-plant (which is called Shoga in Japan) and a lotus root. Besides, the plant-activating agent may be used for a rice-plant; a barley, a wheat or a group thereof; petalous-plants and the like.
  • In the present invention, the following surfactant is preferably used together with the above-mentioned mono-alcohol to promote emulsification, dispersion, solubilization and permeation of the mono-alcohol. [0022]
  • Examples of nonionic surfactants include sorbitan fatty acid esters, polyoxyalkylene sorbitan fatty acid esters, polyoxyalkylene fatty acid esters, glycerol fatty acid esters, polyoxyalkylene glycerol fatty acid esters, polyglycerol fatty acid esters, polyoxyalkylene polyglycerol fatty acid esters, sucrose fatty acid esters, resin acid esters, polyoxyalkylene resin acid esters, polyoxyalkylene alkyl ethers, polyoxyalkylene alkylphenyl ethers, alkyl(poly)glycosides and polyoxyalkylenealkyl(poly)glycosides. Preferably, an ether group-containing nonionic surfactant having no nitrogen atom and ester group-containing nonionic surfactant may be cited. [0023]
  • Examples of anionic surfactants include carboxylic, sulfonic, sulfuric ester group-containing and phosphoric ester group-containing surfactants, and a carboxylic and phosphoric ester group-containing surfactants are preferred. [0024]
  • Examples of the carboxylic surfactants include fatty acids having 6-30 carbon atoms or salts thereof, polyhydric carboxylic acid salts, polyoxyalkylene alkyl ether carboxylic acid salts, polyoxyalkylene alkylamide ether carboxylic acid salts, rhodinic acid salts, dimmer acid salts, polymer acid salts and tall oil fatty acid salts. [0025]
  • Examples of the sulfonic surfactants include alkylbenezenesulfonic acid salts, alkylsulfonic acid salts, alkylnaphthalenesulfonic acid salts, naphthalenesulfonic acid salts, diphenyl ether sulfonic acid salts, condensates of alkylnaphthalenesulfonic acid, and condensate of naphthalenesulfonic acid. [0026]
  • Examples of the sulfuric ester group-containing surfactants include alkylsulfuric ester salts (alkylsulfuric acid salts), polyoxyalkylene alkylsulfuric ester salts (polyoxyalkylene alkylsulfuric acid salts), polyoxyalkylene alkyl phenyl ether sulfuric acid salts, tristyrenated phenol sulfuric acid ester salts, polyoxyalkylene distyrenated phenol sulfuric acid ester salts and alkylpolyglycoside sulfuric acid salts. [0027]
  • Examples of phosphoric acid ester group-containing surfactants include alkyl phosphoric acid ester salts, alkylphenylphosphoric acid ester salts, polyoxyalkylene alkylphosphoric acid ester salts and polyoxyalkylene alkylpheneylphosphoric acid ester salts. [0028]
  • Examples of the salts include metallic salts (such as salts of Na, K, Ca, Mg and Zn), ammonium salts, alkanol amine salts and aliphatic amine salts. [0029]
  • Examples of amphoteric surfactants include amino acid group-containing, betaine group-containing, imidazoline group-containing and amine oxide group-containing surfactants. [0030]
  • Examples of the amino acid group-containing surfactants include acylamino acid salts, acylsarcosine acid salts, acyloylmethylaminopropionic acid salts, alkylaminopropionic acid salts and acylamide ethylhydroxyethylmethylcarboxylic acid salts. [0031]
  • Examples of the betaine group-containing surfactants include alkyldimethylbetaine, alkylhydroxyethylbetaine, acylamide propylhydroxypropylammonia sulfobetaine, acylamide propylhydroxypropylammonia sulfobetaine and ricinoleic acid amide propyl dimethylcarboxy methylammonia betaine. [0032]
  • Examples of the imidazoline group-containing surfactants include alkylcarboxy methylhydroxy ethylimidazolinium betaine and alkylethoxy carboxy methylimidazolinium betaine. [0033]
  • Examples of the amine oxide group-containing surfactants include alkyldimethylamine oxide, alkyldiethanolamine oxide and alkylamidepropylamine oxide. [0034]
  • One kind of the above-mentioned surfactants may be used, and a mixture of two or more kinds of the above-mentioned surfactants may be used. In the case that one of these surfactants comprises a polyoxyalkylene group, the polyoxyalkylene group is preferably a polyoxyethylene group and the average mole number of added polyoxyethylene groups is preferably from 1 to 50. [0035]
  • As the surfactant, at least one compound selected from ester group-containing nonionic surfactants, ether group-containing nonionic surfactants having no nitrogen atom, amphoteric surfactants, carboxylic anionic surfactants and phosphoric anionic surfactant is preferable. [0036]
  • In particular, it is preferable to be at least one compound selected from ester group-containing nonionic surfactants and ether group-containing nonionic surfactants having no nitrogen atom. [0037]
  • The following fertilizer components may be used together with the above-mentioned mono-alcohol. Specific examples thereof may be inorganic or organic compounds which can supply elements such as N, P, K, Ca, Mg, S, B, Fe, Mn, Cu, Zn, Mo, Cl, Si and Na, in particular N, P, X, Ca and Mg. Examples of such inorganic compounds include ammonium nitrate, potassium nitrate, ammonium sulfate, ammonium chloride, ammonium phosphate, sodium nitrate, urea, ammonium carbonate, potassium phosphate, calcium superphosphate, fused phosphate fertilizer (3Mgo.Cao.P[0038] 2O5.3CaSiO2) , potassium sulfate, potassium chloride, nitrate of lime, slaked lime, carbonate of lime, magnesium sulfate, magnesium hydroxide and magnesium carbonate. Examples of the organic compounds include fowl droppings, cow dung, Bark compost, amino acid, peptone, amino acid solution (which is called Mieki in Japan), fermentation extracts, calcium salts of organic acids (such as citric acid, gluconic acid and succinic acid) , and calcium salts of fatty acids (such as formic acid, acetic acid, propionic acid, caprylic acid, capric acid and caproic acid). These fertilizer components may be used together with the surfactant. In the case that fertilizer components are sufficiently applied as basal fertilizer to soil as seen in outdoor cultivation of a rice-plant or vegetables, it is unnecessary to mix the fertilizer components. Further, when a cultivation form is such as a fertigation (a hydroponic soil culture) or a hydroponics, when it avoids applying excessively basal fertilizer and when it is a type of providing a fertilizer component as well as irrigation-water, the fertilizer component is preferably mixed.
  • When the plant-activating composition of the present invention is mixed with the following organic acid having chelating ability or a salt thereof, the growth and absorption efficiency of fertilizer improved further. Specific examples thereof include oxycarboxylic acids such as citric acid, gluconic acid, malic acid, heptonic acid, oxalic acid, malonic acid, lactic acid, tartaric acid, succinic acid, fumaric acid, maleic acid, adipic acid and glutaric acid; polyhydric carboxylic acids; and salts thereof such as potassium salt, sodium salt, alkanolamine salt and aliphatic amine salt. [0039]
  • Mixing a chelating agent besides the organic acids also causes the growth and absorption efficiency of fertilizer to be improved. Examples of the mixed chelating agents include aminocarboxylic group-containing chelating agents such as EDTA, NTA and CDTA. [0040]
  • The form, spraying method and the like of plant-activating composition of the present invention are the same as described above. If necessary, water and/or a solvent may be added to the composition. [0041]
  • In the plant-activating composition or the fertilizer composition of the present invention, it is preferable to use respectively; per 100 parts by weight of the mono-alcohol; 10-20000 parts, in particular 100-2000 parts, by weight of the surfactant; 0-50000 parts, in particular 10-5000 parts, by weight of the fertilizer component; 0-1000 parts, in particular 10-500 parts, by weight of the chelating agent; and 0-5000 parts, in particular 10-500 parts, by weight of other nutritious sources (such as sugars, amino acids and vitamins). [0042]
  • In the case that the plant-activating composition is applied in the form of a dust formulation or granule as fertilizer to soil, it is preferable that the used dust formulation or granule comprise the above-mentioned components except water at the same ratios as above, in general. This dust formulation or granule may comprise a vehicle to prevent caking. [0043]
  • The plant-activating agent of the present invention makes it possible to improve the activity of plant effectively without causing any chemical injury on plants if the plants are treated with an appropriate concentration of the plant-activating agent. For this reason, it can be used for various plants. According to the present invention, promotion of taking root of a plant, increase of chlorophyll value (SPAD value), increase of absorption efficiency of fertilizer and so on are seen as improvement at growth of plant.[0044]
  • EXAMPLES Example 1 Test of Soil-treatment for Tomato Seedlings
  • Species: “Home Momotaro” (Takii & Company LTD) [0045]
  • Vessel for cultivation: a cell tray having 50 holes for germination, and a pot (diameter: 14 cm) for cultivation [0046]
  • Used soil: Takii soil for seeding [N: P[0047] 2O5: K2O=480: 750: 345 (mg/L), pH 6.4, and EC: 0.96]
  • Under the above-mentioned conditions, seeds were sown in the cell tray having 50 holes. When 2 weeks went by after germination, the plants were transplanted to the pot. At intervals of 1 week after 3 days from the transplantation, the soil was treated 4 times with fertilizer compositions being blended raw materials shown in Table 1 and 1000 ppm of a fertilizer component “Otsuka OKF2” (made by Otsuka Chemical Co., Ltd.). The concentrations of the blended raw materials are shown in Table 1 and their balance was water. The amount for each of the treatments was about 50 ml per pot. The fertilizer compositions were caused to penetrate into the soils. For the respective compositions, the test was repeated 3 times. On the 7th day after the fourth treatment, the growth state [height and weight (,hereinafter, “weight” means raw-weight,] of the respective plants and the SPAD value (SPAD 502 made by Minolta Co., Ltd.) representing a green degree were measured. The measured values obtained from the 3 repetitions were averaged. The averaged value was relatively compared as the value that was obtained from the no-treated area (Comparative product 1-4) and made to be 100. The results are shown in Table 1. [0048]
    TABLE 1
    Results of the test
    Concentration SPAD
    No. Blended raw materials (ppm) Height Weight value
    Invention product 1-1 Stearyl alcohol 100 148 142 122
    POE(20) sorbitan monooleate 500
    1-2 Eicosanol 200 145 140 119
    POE(20) hardened castor oil 1000
    1-3 Decyldodecanol 100 134 124 110
    POE(15) glycerol beef tallow fatty acid ester 500
    1-4 Lauryl alcohol 50 132 122 112
    Na salt of POE(3) lauryl sulfuric ester 100
    POE(20) sorbitan monolaurate 200
    1-5 Oleyl alcohol 300 138 130 118
    POE(20) sorbitan monolaurate 600
    Sorbitan monolaurate 400
    1-6 Stearyl alcohol 200 144 138 122
    Cetyl alcohol 100
    POE(20) sorbitan monolaurate 500
    Tetraglycerol monooleate 500
    1-7 Branched C12/C13 alcohol* 100 118 110 112
    POE(10) oleic acid ester 500
    Alkylglucoside** 200
    1-8 C16/C18 alcohol (weight ratio = 3/7. This is true hereinafter.) 200 158 144 120
    POE(20) sorbitan monoolaate 200
    Sucrose stearic acid ester 300
    1-9 Stearyl alcohol 50 156 147 129
    POE(20) sorbitan monooleate 200
    EDTA · 4Na 20
    1-10 Coconut alcohol (C14/C16/C18 = 10/70/20) 100 122 124 118
    Oleic acid monodiglyceride 200
    POE(20) sorbitan monooleate 500
    Comparative product 1-1 Ethanol 200 95 98 99
    POE(20) sorbitan monooleate 200
    1-2 Isopropanol 100 86 98 88
    Na salt of POE(3) lauryl sulfuric ester 100
    POE(20) sorbitan monolaurate 200
    1-3 Octyl alcohol 100 75 88 86
    POE(20) sorbitan monolaurate 200
    1-4 Water (no-treated area) 100 100 100
  • (Notes) In Table 1, polyoxyethylene is abbreviated to POE, the respective numbers inside parentheses are the average mole numbers of added ethylene oxide (,the hereinafter is the same as this). Also, for example, notes of C[0049] 16 and C18 mean the number of carbon atoms being 16 and 18, respectively (,the hereinafter is the same as this).
  • From the results shown in Table 1, it is noted that the plant-activating composition of the present invention made the growth of the plants promote remarkably and the green degree raise obviously, compared with comparative products. [0050]
  • Example 2 Test of Soil-treatment for Brassica Campestris Seedlings
  • [0051] Brassica campestris seeds: Takii & Company LTD
  • Vessel for cultivation: a cell tray having 50 holes [0052]
  • Used soil: Takii soil for seeding (which was the same as in Example 1) [0053]
  • Under the above-mentioned conditions, seeds were sown in the cell tray having 50 holes. At intervals of 1 week after 2 weeks from germination, the soil was treated 4 times with fertilizer compositions being blended raw materials shown in Table 2 and 1000 ppm of a fertilizer component “Otsuka OKF2”. The concentrations of the blended raw materials are shown in Table 2 and their balance was water. The amount for each of the treatments was about 60 ml for respective 10 holes. The fertilizer compositions were caused to penetrate into the soils. For the respective compositions, the test for 10 holes was performed3 times, i.e. 3 repetitions. On the 7th day after the fourth treatment, the growth state (height and weight) of the respective plants and the SPAD value (SPAD 502 made by Minolta Co., Ltd.) representing a green degree were measured. The measured values obtained from the 3 repetitions were averaged. The averaged value was relatively compared as the value that was obtained from the no-treated area (Comparative product 2-4) and was made to be 100. The results are shown in Table 2. [0054]
    TABLE 2
    Concentration Results of the test
    No. Blended raw materials (ppm) Height Weight SPAD value
    Invention product 2-1 Lauryl alcohol 100 142 138 110
    POE(20) sorbitan monooleate 200
    2-2 Myristyl alcohol 100 148 140 114
    POE(20) sorbitan monooleate 200
    2-3 Cetyl alcohol 100 158 144 114
    POE(20) sorbitan monooleate 200
    2-4 Stearyl alcohol 100 160 152 140
    POE(20) sorbitan monooleate 200
    2-5 Oleyl alcohol 100 152 160 138
    POE(20) sorbitan monooleate 200
    2-6 Eicosanol 100 140 138 120
    POE(20) sorbitan monooleate 200
    2-7 Behenyl alcohol 100 132 142 118
    POE(20) sorbitan monooleate 200
    2-8 Phytol 100 142 146 110
    POE(20) sorbitan monooleate 200
    2-9 C16/C18 alcohol (C16/C18 = 3/7) 100 156 162 136
    POE(20) sorbitan monooleate 200
    2-10 C16/C18 alcohol (C16/C18 = 3/7) 100 168 176 136
    POE(20) sorbitan monooleate 200
    Heptononic acid Na salt 20
    2-11 C16/C18 alcohol (C16/C18 = 3/7) 100 166 176 132
    POE(20) sorbitan monooleate 200
    Malonic acid 20
    2-12 C16/C18 alcohol (C16/C18 = 3/7) 100 172 172 130
    POE(20) sorbitan monooleate 200
    Maleic acid 20
    2-13 Branched C12/C13 alcohol 100 136 148 112
    POE(20) sorbitan monooleate 200
    EDTA · 4Na 20
    2-14 coconut alcohol (C14/C16/C18 = 10/70/20) 100 146 156 118
    POE(20) sorbitan monooleate 200
    EDTA · 4Na 20
    Comparative product 2-1 Ethanol 100 96 86 90
    POE(20) sorbitan monooleate 200
    2-2 Octyl alcohol 100 74 68 88
    POE(20) sorbitan monooleate 200
    2-3 Decyl alcohol 100 82 76 88
    POE(20) sorbitan monooleate 200
    2-4 Water (no-treated area) 100 100 100
  • Example 3 Test of Phylloplane-treatment for Rice-plant Seedlings
  • Species: Kinuhikari [0055]
  • Vessel for cultivation: a cell tray having 50 holes [0056]
  • Used soil: Ryujou Iseki Baido (seedling soil for rice-plant) (N:P:X=1:1:1) (made by Iseki & Company, LTD) [0057]
  • Under the above-mentioned conditions, seeds were sown in the cell tray having 50 holes. After the plants geminated, the plants fell in the dark age followed by the virescent age. At a period when the height of the plants became about 3 cm (after 3 days), the phylloplanes were treated 1 time with fertilizer compositions being blended raw materials shown in Table 3 and 1000 ppm of a fertilizer component “Otsuka OKF2”. The concentrations of the blended raw materials are shown in Table 3 and their balance was water. The amount for each of the treatments was about 1 L per 50 holes. At the 3.2 leaf age, which was final during the raising seedling period, the growth state (height, weight, weight of the portion on the ground and weight of the portion under the ground) of the respective plants and the SPAD value (SPAD 502 made by Minolta Co., Ltd.) representing a green degree of a leaf were measured. The measured value was relatively compared as the value that was obtained from the no-treated area (Comparative product 3-4) and made to be 100. The results are shown in Table 3. [0058]
    TABLE 3
    Results of the test
    weight of the weight of the
    portion on the portion under the
    Concentration Height ground ground SPAD value
    No. Blended raw materials (ppm) n = 20 n = 20 n = 20 n = 20
    Invention product 3-1 Cetyl alcohol 10 140 106 112 110
    POE(20) sorbitan monooleate 50
    3-2 Cetyl alcohol 50 144 108 116 114
    POE(20) sorbitan monooleate 250
    3-3 Cetyl alcohol 100 152 114 120 120
    POE(20) sorbitan monooleate 500
    3-4 Cetyl alcohol 500 156 116 130 128
    POE(20) sorbitan monooleate 1000
    3-5 Stearyl alcohol 10 138 108 120 116
    POE(20) sorbitan monooleate 50
    3-6 Stearyl alcohol 50 142 110 124 120
    POE(20) sorbitan monooleate 250
    3-7 Stearyl alcohol 100 156 118 130 122
    POE(20) sorbitan monooleate 500
    3-8 Stearyl alcohol 500 162 120 133 136
    POE(20) sorbitan monooleate 1000
    3-9 C16/C18 alcohol (C16/C18 = 3/7) 10 136 106 118 136
    POE(20) sorbitan monooleate 50
    3-10 C16/C18 alcohol (C16/C18 = 3/7) 50 136 110 122 136
    POE(20) sorbitan monooleate 250
    3-11 C16/C18 alcohol (C16/C18 = 3/7) 100 142 112 128 132
    POE(20) sorbitan monooleate 500
    3-12 C16/C18 alcohol (C16/C18 = 3/7) 500 148 116 130 130
    POE(20) sorbitan monooleate 1000
    Comparative product 3-1 Octyl alcohol 10 90 92 96 86
    POE(20) sorbitan monooleate 50
    3-2 Octyl alcohol 50 88 80 74 76
    POE(20) sorbitan monooleate 250
    3-3 Octyl alcohol 100 68 72 62 66
    POE(20) sorbitan monooleate 500
    3-4 Water (no-treated area) 100 100 100 100
  • Example 4 Test of Reproductive Ability Using Chlorella Cells
  • Chlorella cells, which are green cells of a higher plant, were cultured with vibration in an inorganic-salt medium. Raw materials shown in Table 4 were added thereto, and then reproductive ability of chlorella cells (ability for increasing the number of the cells) was evaluated by comparison with the result obtained from a medium which was no-treated (i.e., only original nutrients of the inorganic salt medium). For the respective compositions, the test was repeated 3 times. The concentration of the cells was set to 1.00×105 cells (per ml) at the start of the test. The numbers of the chlorella cells after 10 days from the addition of the various raw materials followed by culture of the cells are shown as the relative values compared with the value that was obtained from the medium which was no-treated (Comparative product 4-9) and made to be 100. The results are shown in Table 4. As the inorganic salt medium, a Linsmaier-Skoog (LS) medium was used. [0059]
    TABLE 4
    Result of the test
    Test Concentration proliferating ability
    No. Blended raw materials (ppm) of cells
    Invention product
    4-1 Lauryl alcohol 10 115
    4-2 Myristyl alcohol 10 128
    4-3 Myristyl alcohol 5 138
    Stearyl alcohol 5
    4-4 Cetyl alcohol 10 148
    4-5 Cetyl alcohol 5 160
    Stearyl alcohol 5
    4-6 Stearyl alcohol 10 168
    4-7 Oleyl alcohol 10 154
    4-8 Eicosanol 10 152
    4-9 Docosanol 10 130
    4-10 Tetracosanol 10 122
    4-11 Lauryl alcohol 10 119
    Malonic acid 4
    4-12 Cetyl alcohol 10 152
    Ascorbic acid Na salt 4
    4-13 Stearyl alcohol 10 172
    EDTA.4Na 4
    4-14 Eicosanol 10 160
    EDTA.4Na 4
    4-15 Cetyl alcohol 30 142
    4-16 Stearyl alcohol 30 156
    4-17 Eicosanol 30 146
    4-18 Cetyl alcohol 30 146
    Ascorbic acid Na salt 15
    4-19 Stearyl alcohol 30 159
    EDTA.4Na 15
    4-20 Eicosanol 30 150
    EDTA.4Na 15
    4-21 Tetracosanol 10 128
    Fumaric acid 4
    Comparative product
    4-1 Propanol 10 96
    4-2 Hexanol 10 93
    4-3 Propanol 5 92
    Octanol 5
    4-4 Decyl alcohol 10 91
    4-5 Decyl alcohol 10 94
    Fumaric acid 4
    4-6 Hexanol 5 96
    Ethanol 5
    4-7 Octanol 30 95
    4-8 Propanol 10 98
    EDTA.4Na 4
    4-9 Inorganic salt medium 100
    (no-treated area)
  • Example 5 Evaluation of Water Culture of Tomato Seedlings
  • Seeds of tomato “Momotaro” were sown in a box, and seedlings having 3 true leaves at the expansion period were used. For the respective compositions, the test was repeated 3 times. OKF2 (made by Otsuka Chemical Co., Ltd.) was diluted (as N:P:K=260:149:247 (ppm/OKF2 to be 538 times) as a NPK base and then resultant was added to a culturing solution. The present test was performed under conditions shown in Table 5. After 6 days from the start of the test, the culturing solution was sampled, and it was examined by means of RQ Flex (made by Merk) to obtain absorption efficiency of nitrate nitrogen. The each value as relative value shows an absorption amount of nitrate nitrogen at each treatment in the case of making NPK culturing solution to be control. Also, at 6 days after starting of test, SPAD value (SPAD 502 made by Minolta Co., Ltd.) representing green degree of a leaf were measured. When the control (Comparative product 5-4) made up to be 100, the relative value is compared. The results are shown in Table 5. Then, fertilizer composition of OKF2 (Otsuka Chemical Co., Ltd.) was as follows: N:P:K:Ca:Mg 14:8:16:6:2. [0060]
    TABLE 5
    Result of the test
    Concentration Efficency of
    Test No. Blended raw materials (ppm) absorbing nitrogen SPAD value
    Invention product 5-1 Stearyl alcohol 50 207 109
    POE(20) sorbitan monooleate 150
    EDTA · 4Na 20
    5-2 Stearyl alcohol 50 182 107
    POE(20) sorbitan monooleate 150
    5-3 Stearyl alcohol 50 175 106
    POE(20) sorbitan monooleate 150
    Lauryl sulfuric acid sodium salt 150
    EDTA · 4Na 20
    5-4 Stearyl alcohol 50 170 105
    POE(20) sorbitan monooleate 150
    Lauryl sulfuric acid sodium salt 150
    5-5 Stearyl alcohol 50 125 103
    Lauryl sulfuric acid sodium salt 150
    EDTA · 4Na 20
    5-6 Lauryl alcohol 50 134 104
    POE(20) sorbitan monooleate 150
    5-7 Cetyl alcohol 100 158 105
    POE(20) sorbitan monooleate 150
    5-8 Eicosanol 50 162 104
    POE(20) sorbitan monooleate 150
    5-9 Tetracosanol 50 146 103
    POE(20) sorbitan monooleate 150
    5-10 Lauryl alcohol 50 128 102
    POE(20) sorbitan monooleate 150
    Lauryl sulfuric acid sodium salt 150
    5-11 Cetyl alcohol 50 149 104
    POE(20) sorbitan monooleate 150
    Lauryl sulfuric acid sodium salt 150
    5-12 Eicosanol 50 145 103
    POE(20) sorbitan monooleate 150
    Lauryl sulfuric acid sodium salt 150
    5-13 Tetracosanol 50 135 101
    POE(20) sorbitan monooleate 150
    Lauryl sulfuric acid sodium salt 150
    Comparative product 5-1 Ethanol 50 100 95
    POE(20) sorbitan monooleate 150
    5-2 Hexanol 50 97 97
    POE(20) sorbitan monooleate 150
    5-3 Decyl alcohol 50 95 96
    POE(20) sorbitan monooleate 150
    5-4 NPK culturing solution (control) 100 100
  • Example 6 Test of Soil-irrigating Treatment for Spinach: Leaf Vegetable
  • Species: “Esper”[0061]
  • Form of cultivation: a pot (diameter: 18 cm) for cultivation [0062]
  • Used soil: Kureha Engei Baido (horticultural soil made by Kureha Chemical Industry Co., Ltd.) [0063]
  • (Fertilizer components; N:P:K=0.4:1.9:0.6 (g) per 1 kg of the soil) [0064]
  • Seeds of spinach “Esper” were directly sown on the soil. As the culturing soil, the horticultural soil (made by Kureha Chemical Industry Co., Ltd.) was used in an amount of 1.3 L (1.5 kg) per 1 pot (diameter of 18 cm). The number of repetition was made up to 18 pots. After 12 days from the sowing, treatment was started. At the intervals of 7 days, raw materials shown in Tables 6 and 7 were used to irrigate the soil 5 times in a treating amount of 150 ml/18 cm pot. After 6 days from the 5th irrigating treatment, weights of the plant and the SPAD value were examined. When the no-treated area (Comparative product 6-5) made up to be 100, the relative value is compared. The results are shown in Tables 6 and 7. During the test period, fertilizer components such as nitrogen, phosphorous and potassium were not applied as additional fertilizer and the plant absorbed only nutrients contained in the soil. Then, composition ratio of NPK fertilizer as the additional fertilizer was follows: N:P:K:Mg=17:9.5:18:3.5. [0065]
    TABLE 6
    Concentration Result of the test
    Test No. Blended raw materials (ppm) Weight SPAD value
    Invention product 6-1 Stearyl alcohol 50 125 115
    POE(20) sorbitan monooleic acid ester (RHEODOL TW-O120) 150
    6-2 Stearyl alcohol 50 121 115
    POE(6) sorbitan monooleic acid ester (RHEODOL TW-O106) 150
    6-3 Stearyl alcohol 50 125 112
    POE(20) sorbitan monostearic acid ester (RHEODOL TW-S120) 150
    6-4 Stearyl alcohol 50 122 110
    POE(20) sorbitan tristearic acid ester (RHEODOL TW-S320) 150
    6-5 Stearyl alcohol 50 123 114
    POE(20) sorbitan coconut oil fatty acid ester (RHEODOL TW-L120) 150
    6-6 Stearyl alcohol 50 122 112
    Sorbitan monostearic acid ester (RHEODOL SP-S10) 150
    6-7 Stearyl alcohol 50 123 113
    Sorbitan monooleic acid ester (RHEODOL SP-O10) 150
    6-8 Stearyl alcohol 50 122 112
    Sorbitan tristearic acid ester (RHEODOL SP-S30) 150
    6-9 Stearyl alcohol 50 121 110
    Sorbitan monopalmitic acid ester (RHEODOL SP-P10) 150
    6-10 Stearyl alcohol 50 122 112
    Sorbitan coconut oil fatty acid ester (RHEODOL SP-L10) 150
    6-11 Stearyl alcohol 50 121 112
    POE(30) sorbit tetraoleic acid ester (RHEODOL 430) 150
    6-12 Stearyl alcohol 50 123 114
    POE(40) sorbit tetraoleic acid ester (RHEODOL 440) 150
    6-13 Stearyl alcohol 50 122 113
    POE(60) sorbit tetraoleic acid ester (RHEODOLI 460) 150
    6-14 Stearyl alcohol 50 122 114
    POE(140) monostearic acid polyethylene glycol (EMANON 3199) 150
    6-15 Stearyl alcohol 50 121 111
    POE(140) distearic acid polyethylene glycol (EMANON 3299) 150
    6-16 Stearyl alcohol 50 122 113
    POE(40) hardened caster oil (EMANON CH-40) 150
    6-17 Stearyl alcohol 50 121 113
    POE(80) hardened caster oil (EMANON CH-80) 150
  • [0066]
    TABLE 7
    Concentration Result of the test
    Test No. Blended raw materials (ppm) Weight SPAD value
    Invention product 6-18 C16/C18 alcohol (C16/C18 = 15/85) 50 120 112
    Oleic acid potassium salt (OS-SOAP) 150
    6-19 C16/C18 alcohol (C16/C18 = 15/85) 50 119 110
    Semi-hardened beef tallow fatty acid sodium salt (NS-SOAP) 150
    6-20 C16/C18 alcohol (C16/C18 = 15/85) 50 118 110
    Stearic acid sodium salt (SS-40N) 150
    6-21 C16/C18 alcohol (C16/C18 = 15/85) 50 117 111
    POE(4.5) lauryl ether acetic acid sodium salt (AKYPO RLM45NV) 150
    6-22 C16/C18 alcohol (C16/C18 = 15/85) 50 116 111
    POE(10) myristyl ether acetic acid sodium salt (AKYPO RLM100NV) 150
    6-23 C16/C18 alcohol (C16/C18 = 15/85) 50 115 112
    Lauryl phosphoric acid monoester sodium salt 150
    6-24 C16/C18 alcohol (C16/C18 = 15/85) 50 117 110
    Lauryl phosphoric acid diester sodium salt 150
    6-25 C16/C18 alcohol (C16/C18 = 15/85) 50 118 110
    POE(3) lauryl phosphoric acid monoester sodium salt 150
    6-26 C16/C18 alcohol (C16/C18 = 15/85) 50 117 111
    POE(4) lauryl ether (EMULGEN 104P) 75
    6-27 C16/C18 alcohol (C16/C18 = 15/85) 50 115 111
    POE(13) cetyl ether (EMULGEN 220) 75
    6-28 C16/C18 alcohol (C16/C18 = 15/85) 50 115 113
    POE(12) stearyl ether (EMULGEN 320P) 75
    6-29 C16/C18 alcohol (C16/C18 = 15/85) 50 116 112
    POE(9) octyl phenyl ether (EMULGEN 810) 75
    6-30 C16/C18 alcohol (C16/C18 = 15/85) 50 114 110
    POE(9) nonyl phenyl ether (EMULGEN 909) 75
    6-31 C16/C18 alcohol (C16/C18 = 15/85) 50 112 109
    POE(50) nonyl phenyl ether (EMULGEN 950) 75
    6-32 C16/C18 alcohol (C16/C18 = 15/85) 50 113 110
    Alkyl glucoside (C10/C12/C14) (MYDOL 12) 150
    6-33 C16/C18 alcohol (C16/C18 = 15/85) 50 112 107
    Alkyl glucoide (C9/C10/C11) (MYDOL 10) 150
    6-34 C16/C18 alcohol (C16/C18 = 15/85) 50 111 105
    Lauryl diethyl amine oxide (AMPHITOL 20N) 150
    6-35 C16/C18 alcohol (C16/C18 = 15/85) 50 111 110
    2-alkyl-N-carboxy methyl-N-hydorxy ethyl imidazolium betaine 150
    6-36 C16/C18 alcohol (C16/C18 = 15/85) 50 110 110
    Lauryl amido propyl betaine (AMPHITOL 20AB) 150
    6-37 C16/C18 alcohol (C16/C18 = 15/85) 50 109 107
    Lauryl dimethyl amino acetic acid betaine (AMPHITOL 24B) 150
    Comparative product 6-1 Decyl alcohol 50 75 80
    Lauryl sulfuric acid sodium salt (EMAL 0) 150
    6-2 Hexacosanol 50 90 92
    Lauryl sulfuric acid sodium salt (EMAL 0) 150
    6-3 Decyl alcohol 50 68 72
    POE(9) nonyl phenyl ether (EMULGEN 909) 150
    6-4 Hexacosanol 50 85 87
    POE(9) nonyl phenyl ether (EMULGEN 909) 150
    6-5 Water (no-treated area) 100 100
  • Example 7 Test of Soil-treating for Rice-plant Seedlings: Treatment at the Raising Seedling Period
  • Unhulled rice seeds (species of Koshihikari) were sown into a box (60×30 cm) for raising seedling. At the period transferring from the hardening period to the greening period after germination, treatment was started in an treating amount of 500 ml/the box for raising seedling. Raw materials shown in Table 8 were used to irrigate the soil 3 times into soil. After the 3 treatments, that is, after 15 days from the sowing, the heights and the weights of the seedlings and the SPAD value were examined. When the no-treated area (Comparative product 7-6) made up to be 100, the relative value is compared. The results are shown in Table 8. As basal fertilizer, N component was applied in an amount of 0.5 g per the box for raising seedling. During the test period, fertilizer components were not applied as additional fertilizer and rice-plant seedlings absorbed only nutrients contained in the soil. [0067]
    TABLE 8
    Concentration Result of the test
    Test No. Blended raw materials (ppm) Height Weight SPAD value
    Invention product 7-1 Stearyl alcohol 100 106 115 113
    POE(20) sorbitan monooleate 300
    7-2 Myristyl alcohol 100 107 107 108
    POE(20) sorbitan monooleate 300
    tartaric acid Na solt 50
    7-3 Tetracosanol 100 102 107 106
    POE(20) sorbitan monooleate 300
    7-4 Myristyl alcohol 100 106 108 110
    POE(20) sorbitan monooleate 300
    Oxamide 50
    7-5 Lauryl alcohol 100 102 102 105
    POE(20) sorbitan monolaurate 300
    7-6 Eicosanol 100 104 110 109
    POE(20) sorbitan monooleate 300
    7-7 Oleyl alcohol 100 108 119 116
    POE(20) sorbitan monooleate 300
    EDTA · 4Na 50
    7-8 Stearyl alcohol 50 108 118 116
    Cetyl alcohol 50
    POE(20) sorbitan monooleate 300
    succucinic acid 50
    7-9 Docosanol 100 103 108 108
    POE(20) sorbitan monooleate 300
    7-10 Myristyl alcohol 100 102 104 108
    POE(20) sorbitan monooleate 300
    7-11 Docasanol 100 106 116 110
    POE(20) sorbitan monooleate 300
    EDTA · 4Na 50
    7-12 Cetyl alcohol 100 104 106 110
    POE(20) sorbitan monooleate 300
    7-13 Stearyl alcohol 100 109 119 115
    POE(20) sorbitan monooleate 300
    Malonic acid 50
    7-14 Cetyl alcohol 100 108 112 112
    POE(20) sorbitan monooleate 300
    EDTA · 4Na 50
    7-15 Stearyl alcohol 100 110 121 118
    POE(20) sorbitan monooleate 300
    EDTA · 4Na 50
    7-16 Oleyl alcohol 100 104 113 110
    POE(20) sorbitan monooleate 300
    7-17 Stearyl alcohol 50 104 109 112
    Cetyl alcohol 50
    POE(20) sorbitan monooleate 300
    7-18 Tetracosanol 100 104 110 109
    POE(20) sorbitan monooleate 300
    gluconic acid 50
    7-19 Eicosanol 100 108 118 114
    POE(20) sorbitan monooleate 300
    Ascorbic acid Na salt 50
    7-20 Lauryl alcohol 100 104 104 106
    POE(20) sorbitan monolaurate 300
    Fumaric acid 50
    Comparative product 7-1 Ethanol 100 96 92 91
    POE(20) sorbitan monooletae 300
    7-2 Ethanol 100 97 96 95
    POE(20) sorbitan monooleate 300
    Heptonic acid Na salt 50
    7-3 Hexanol 100 93 96 89
    POE(20) sorbitan monooleate 300
    Malonic acid 50
    7-4 Hexanol 100 90 93 87
    POE(20) sorbitan monooleate 300
    7-5 Octyl alcohol 100 78 82 83
    POE(20) sorbitan monooleate 300
    7-6 Water (non-treated area) 100 100 100

Claims (15)

What is claimed:
1. A method of promoting plant growth, which comprises treating a plant with a mono-alcohol having 12 to 24 carbon atoms as a plant growth agent.
2. The method as claimed in claim 1, in which the plant is treated further with at least one compound selected from the group consisting of a surfactant, a fertilizer and a chelating agent.
3. The method as claimed in claim 2, in which the surfactant is selected from the group consisting of an ester group-containing nonionic surfactant, an ether group-containing nonionic surfactant having no nitrogen atom, an amphoteric surfactant, a carboxylic anionic surfactant and a phosphoric anionic surfactant.
4. A composition for promoting plant growth comprising a mono-alcohol having 12 to 24 carbon atoms and one member selected from the group consisting of (i) a chelating agent, (ii) a surfactant and a chelating agent, (iii) a fertilizer and a chelating agent and (iv) a surfactant, a fertilizer and a chelating agent.
5. The composition as claimed in claim 4, which comprises said mono-alcohol having 12 to 24 carbon atoms and at least one surfactant selected from an ester group-containing nonionic surfactant, a ether group-containing nonionic surfactant having no nitrogen atom, an amphoteric surfactant, a carboxylic anionic surfactant and a phosphoric anionic surfactant.
6. A composition for promoting plant growth comprising a mono-alcohol having 12 to 24 carbon atoms and at least one surfactant selected from an ester group-containing nonionic surfactant, an ether group-containing nonionic surfactant having no nitrogen atom, an amphoteric surfactant, a carboxylic anionic surfactant and a phosphoric anionic surfactant.
7. The composition as claimed in claim 6, which further comprises a fertilizer.
8. A method of treating a plant, which comprises treating a plant directly with a mono-alcohol having 12 to 24 carbon atoms.
9. The method as claimed in claim 8, in which the plant is treated further with at least one compound selected from the group consisting of a surfactant, a fertilizer and a chelating agent.
10. The method as claimed in claim 9, in which the surfactant is selected from the group consisting of an ester group-containing nonionic surfactant, an ether group-containing nonionic surfactant having no nitrogen atom, an amphoteric surfactant, a carboxylic anionic surfactant and a phosphoric anionic surfactant.
11. The method of claim 8, wherein the mono-alcohol having 12 to 24 carbon atoms is a plant growth agent.
12. The method as claimed in claim 2, wherein the plant is treated further with at least one compound selected from the group consisting of an ester group-containing non-ionic surfactant and an ether group-containing non-ionic surfactant having no nitrogen atom.
13. The method as claimed in claim 8, wherein the plant is treated further with at least one compound selected from the group consisting of an ester group-containing non-ionic surfactant and an ether group-containing non-ionic surfactant having no nitrogen atom.
14. The composition as claim ed in claim 5, which comprises said mono-alcohol having 12 to 24 carbon atoms and at least one surfactant selected from an ester group-containing non-ionic surfactant and an ether group-containing non-ionic surfactant having no nitrogen atom.
15. The composition as claimed in claim 6, which comprises said mono-alcohol having 12 to 24 carbon atoms and at least one surfactant selected from an ester group-containing non-ionic surfactant and an ether group-containing non-ionic surfactant having no nitrogen atom.
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US9376546B2 (en) 2011-12-12 2016-06-28 Dai-Ichi Kogyo Seiyaku Co., Ltd. Polylactic acid resin composition and resin molded article thereof
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US9518168B2 (en) 2011-12-12 2016-12-13 Dai-Ichi Kogyo Seiyaku Co., Ltd. Polylactic acid resin composition and resin molded article thereof
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