US20020001931A1 - Method for forming conductive contact of semiconductor device - Google Patents
Method for forming conductive contact of semiconductor device Download PDFInfo
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- US20020001931A1 US20020001931A1 US09/839,855 US83985501A US2002001931A1 US 20020001931 A1 US20020001931 A1 US 20020001931A1 US 83985501 A US83985501 A US 83985501A US 2002001931 A1 US2002001931 A1 US 2002001931A1
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 42
- 238000005530 etching Methods 0.000 claims abstract description 67
- 239000000758 substrate Substances 0.000 claims abstract description 37
- 238000011049 filling Methods 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 70
- 239000000463 material Substances 0.000 claims description 44
- 239000000377 silicon dioxide Substances 0.000 claims description 35
- 125000006850 spacer group Chemical group 0.000 claims description 27
- 238000001312 dry etching Methods 0.000 claims description 19
- 229920002120 photoresistant polymer Polymers 0.000 claims description 19
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 18
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 18
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76897—Formation of self-aligned vias or contact plugs, i.e. involving a lithographically uncritical step
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
Definitions
- the present invention relates to a method for manufacturing a semiconductor device, and more particularly, to a method for forming an interdielectric layer having openings by using a difference in an etch-rate and for forming a conductive contact for filling the openings.
- the interdielectric layer does not have a very high etching selectivity with respect to silicon nitride (Si 3 N 4 ), which is used to form a spacer.
- Si 3 N 4 silicon nitride
- the method is capable of preventing an electrical short-circuit and preventing a contact hole from not opening, while realizing a high etch selectivity with respect to a spacer when forming the contact hole, thereby reducing the required thickness of the spacer and allowing the spacerto be formed of a material having a low dielectric constant.
- a dummy dielectric layer comprised of insulating materials having a relatively high etch-rate and an interdielectric layer pattern having a lower etch-rate than that of the dummy dielectric layer are formed on a semiconductor substrate.
- the dummy dielectric layer is selectively removed by using a high etching selectivity between the dummy dielectric layer and the interdielectric layer pattern, and thereby forming a contact opening exposing a portion in which a contact will be formed.
- the dummy dielectric layer is formed of an organic material
- the interdielectric layer pattern is formed of a silicon dioxide (SiO 2 ) layer which is in one preferred embodiment, selectively deposited from a liquid phase precursor.
- the dummy dielectric layer is selectively etched, to form a dummy opening which exposes a portion in which the contact body is not formed:
- the interdielectric layer is then formed to fill the dummy opening.
- the dummy dialectric material remaining in the contact area is then selectively etched to form the contact opening.
- the contact opening is filled with conductive materials and divided into the contact body by using surface etching or polishing.
- the defects that occur when forming the contact opening can be minimized.
- FIGS. 1A and 1B through FIGS. 6A and 6B are plan views and sectional views illustrating a method for manufacturing a conductive contact of a semiconductor device according to a preferred embodiment of the present invention.
- FIG. 1A is a plan view schematically illustrating the step of forming a gate line 300 on a semiconductor substrate 100
- FIG. 1 B is a sectional view taken along line X 1 -X 1 ′-Y 1 -Y 1 ′-Z 1 -Z 1 ′ of FIG. 1A.
- the gate line 300 is formed of a line-type on the semiconductor substrate 100 using a conventional process of manufacturing a transistor. For example, after forming an isolation region 200 on the semiconductor substrate 100 using a shallow trench isolation (STI) process, gates 330 and 350 are formed of a line-type conductive pattern so as to intersect an active region 120 defined by the isolation region 200 .
- STI shallow trench isolation
- the gates 330 and 350 are formed by interposing a gate oxide layer 310 between the gates 330 and 350 and the substrate 100 .
- the gates 330 and 350 are formed of various conductive materials.
- the gates 330 and 350 may be formed by sequentially forming a polycrystalline silicon layer 330 and a silicide layer 350 on the gate oxide layer 310 and patterning them.
- the silicide layer 350 can be formed of metal silicide such as tungsten silicide (WSi).
- the gates can be only formed of metal materials such as tungsten (W).
- a hard mask 370 may be formed by depositing insulating materials, for example, silicon nitride (Si 3 N 4 ) or silicon dioxide (SiO 2 ) on the silicide layer 350 .
- the hard mask 370 may also be formed of silicon oxynitride (SiON) or silicon carbide (SiC).
- the hard mask 370 is patterned together when patterning the gates 330 and 350 and shields the top of the gates 330 and 350 to be protected.
- a spacer 390 for covering the sidewalls of the gates 330 and 350 is formed using a conventional spacer process.
- the spacer 390 can be formed of an insulating material such as silicon nitride (Si 3 N 4 ) or silicon dioxide (SiO 2 ).
- the spacer 390 can be formed of silicon oxynitride (SiON) or silicon carbide (SiC).
- the spacer 390 is formed of silicon nitride (Si 3 N 4 ) so as to provide a high selectivity in the following etching process.
- the spacer 390 and the hard mask 370 comprise shielding dielectric layers 370 and 390 for protecting the gates 330 and 350 .
- a stopper layer used as the end point of etching in an etching process or a polishing process can be further formed on the shielding dielectric layers 370 and 390 , but the stopper layer can be omitted in the preferred embodiment of the present invention.
- the problems of the SAC process due to the integration of semiconductor devices as described previously usually occur in a cell region 110 .
- the following description of a preferred embodiment of the present invention is focused on the cell region 110 .
- the gate line 300 will be described as the example of a conductive line, but the present invention can be also applied to the conductive line for use in conventional interconnections.
- the conductive line includes a conductive pattern formed of polycrystalline silicon, titanium (Ti), titanium nitride (TiN), aluminum (Al), copper (Cu), tungsten (W), tungsten silicide (WSi), platinum (Pt), or another metal having high conductivity, and an upper layer of a metallic conductive oxide, or silicide.
- the spacer 390 is formed on the sidewalls of the conductive pattern, and the hard mask 370 is formed on the top of the conductive pattern.
- FIG. 2A is a plan view schematically illustrating the step of forming a dummy dielectric layer 400 and forming a photoresist pattern 550 on the dummy dielectric layer 400
- FIG. 2B is a sectional view taken along lines X 2 -X 2 ′, Y 2 -Y 2 ′, and Z 2 -Z 2 ′ of FIG. 2A.
- the dummy dielectric layer 400 for filling a gap between gate lines 300 is formed on a semiconductor substrate 100 .
- the dummy dielectric layer 400 is formed of an insulating material having a flowability that is high enough so that it can fill the gap between the gate lines 300 .
- the dummy dielectric layer 400 has a high dry or wet etch-rate compared to a hard mask 370 or the spacer 390 , specifically, the dummy dielectric layer 400 is formed of an insulating material having a high etching selectivity to the hard mask 370 or the spacer 390 .
- the dummy dielectric layer 400 is formed of an insulating material having a very high wet or dry etch-rate compared to an insulating material comprising an interdielectric layer to be formed later.
- the dummy dielectric layer 400 can be formed of an organic material such as polymer.
- the dummy dielectric layer 400 can be formed of a resist material used in a photolithographic process of semiconductor processes.
- the dummy dielectric layer 400 can be formed of a material used in forming an organic antireflective layer in the semiconductor processes, that is, an organic antireflective layer material.
- the dummy dielectric layer 400 can be formed of an insulating material having a high dry etch-rate such as an organic insulator, such as, FLARE (manufactured by AlliedSignal Advanced Microelectronic Materials).
- a photoresist layer 550 is formed on the dummy dielectric layer 400 , and the photoresist layer is exposed and developed, thereby forming a photoresist pattern 550 exposing a portion 600 .
- Portion 600 comprises a portion of the cell region 110 in which a contact will not be formed.
- the dummy dielectric layer 400 is formed of the resist material or the organic antireflective layer material, it may be difficult to provide an adequate etching selectivity between the resist material or the organic antireflective layer of the dummy dielectric layer 400 and the photoresist pattern 550 used in the following process of patterning the dummy dielectric layer 400 .
- an etching mask layer 510 can be formed on the dummy dielectric layer 400 .
- the etching mask layer 510 is preferably formed of a material having a higher etching resistance than the resist material or organic antireflective layer material. Suitable materials include, silicon dioxide (SiO 2 ), silicon nitride (Si 3 N 4 ), silicon carbide (SiC), or silicon oxynitride (SiON).
- the dummy dielectric layer 400 is formed of the organic material such as the FLARE, it is possible to provide an etching selectivity between the organic insulator of FLARE and the photoresist pattern 550 by selecting an appropriate etching gas used in dry etching.
- the etching mask layer 510 can be omitted.
- the portion 600 of the dummy dielectric layer 400 can correspond to an isolation region 200 between active regions 120 . Since the active regions 120 can be formed in the shape of ( ⁇ )-type or t-type arrangement, the portion 600 to be exposed by the photoresist pattern 550 can be set in a long oval type or ( ⁇ )-type for exposing a region between active regions 120 . Thus, the photoresist pattern 550 is shielded by covering the portion on which the contact will be formed.
- FIG. 3A is a plan view schematically illustrating the step of forming a dummy dielectric layer pattern 401 having a dummy opening 450 , for patterning the dummy dielectric layer 400
- FIG. 3B is a sectional view taken along line X 3 -X 3 ′, Y 3 -Y 3 ′, and Z 3 -Z 3 ′ of FIG. 3A.
- the dummy dielectric layer 400 is selectively etched using the photoresist pattern 550 as an etching mask, and a dummy dielectric layer pattern 401 having a dummy opening 450 exposing gap regions between gate lines 300 is formed.
- an etching process of forming the dummy opening 450 can be performed by a selective dry etching, and the dummy opening 450 exposes substrates 100 of gap regions between the gate lines 300 on which a contact will be not formed.
- the etching process can be performed by dry etching in which an oxygen source is used. Since the resist material or the organic antireflective layer material forming the dummy dielectric layer 400 is comprised of organic materials such as polymer, the resist material or the organic antireflective material can be removed by the dry etching.
- the photoresist pattern 550 can be together removed in the dry etching, but the etching mask layer 510 acts as a hard mask, and the dummy dielectric layer 400 is selectively patterned to form the dummy dielectric layer pattern 401 .
- the etching process can be supplemented by additionally performing a wet etching process such a strip process in which phosphoric acid is used, and by removing residual materials after dry etching.
- the etching mask layer 510 is removed.
- the etching process can be performed by dry etching in which etching gas containing nitrogen (N) gas or hydrogen (H) gas is used. Since the gas used in the dry etching process has an etching selectivity between the photoresist pattern 550 and the organic insulator of the dummy dielectric layer 400 , the dummy dielectric layer 400 of the organic insulator can be selectively patterned with respect to the photoresist pattern 550 . Thus, the etching mask layer 510 can be omitted.
- the spacer 390 and the hard mask 370 can be introduced in thinner thickness than that of in a conventional SAC process, and the spacer 390 and the hard mask 370 can be formed of insulating materials having a low dielectric constant, for example, silicon carbide (SiC).
- SiC silicon carbide
- FIG. 4A is a plan view schematically illustrating the step of forming an interdielectric layer pattern 700 for filling the dummy opening 450
- FIG. 4B is a sectional view taken along line X 4 -X 4 ′, Y 4 -Y 4 ′, and Z 4 -Z 4 ′ of FIG. 4A.
- an interdielectric layer 700 for filling the dummy opening 450 is formed.
- the interdielectric layer 700 can be formed of insulating materials such as silicon dioxide (SiO 2 ), silicon nitride (Si 3 N 4 ), silicon oxynitride (SiON), or silicon carbide (SiC).
- a process for forming the interdielectric layer pattern 700 can be performed at a low temperature, for example, at 400 ⁇ C and below.
- the process of forming the interdielectric layer pattern 700 can be performed by low temperature CVD or coating.
- the interdielectric layer pattern 700 is formed by liquid phase deposition.
- Silicon dioxide (SiO 2 ) can be selectively deposited by liquid phase deposition as disclosed in U.S. Pat. No. 5,547,900 (assigned to Jengping Lin et al., on 20 August 1996 , entitled “Method of fabricating a self-aligned contact using a liquid-phase oxide-deposition process”) and a paper (entitled “A Selective SiO 2 Film-Formation Technology Using Liquid Phase Deposition for Fully Planarized Multilevel Interconnections, by Tetsuya Homma et al., J. Electrochm. Soc., Vol. 140, No. 8, pp2410-2414, in 1993), the text of which are both hereby incorporated by reference into this specification.
- the interdielectric layer pattern 700 of silicon dioxide (SiO 2 ) is deposited only in the dummy opening 450 of the dummy layer 401 and grows.
- the interdielectric layer pattern 700 can be selectively formed in the dummy opening 450 of the dummy dielectric layer pattern 401 comprising organic materials without the following process.
- the interdielectric layer pattern 700 by the liquid phase deposition has very high filling characteristics that are characteristic of a liquid phase deposition process.
- the interdielectric layer pattern 700 can be formed without a seam or a void between the gate lines 300 .
- the interdielectric layer pattern 700 is formed using a low temperature CVD method, due to the high aspect ratio between the gate lines 300 , a seam or a void may occur in the interdielectric layer pattern 700 .
- the void or the seam is closed and isolated by insulating materials forming the interdielectric layer pattern 700 . That is, the interdielectric layer pattern 700 grows from the inside and bottom of the dummy opening 450 due to the deposition characteristics of CVD, and so the void or the seam occurs in the center of the interdielectric layer pattern 700 between the gate lines 300 .
- the void or the seam does not extend to the outside of the interdielectric layer pattern 700 in either lateral direction.
- a conductive material is filled in the void or the seam in the following process of depositing the conductive material, it is possible to prevent the residual conductive material from acting as a defect that causes an electrical short-circuit such as a bridge.
- the portion of the interdielectric layer pattern 700 covering the dummy dielectric layer pattern 401 is chemical mechanical polished (CMP) or dry-etched back to the dummy opening 450 .
- CMP chemical mechanical polished
- a wet etch back process can also be used. The polishing or etch back process is performed so that the surface of the dummy dielectric layer pattern 401 may be exposed.
- FIG. 5A is a plan view schematically illustrating the step of selectively removing a dummy dielectric layer pattern 401
- FIG. 5B is a sectional view taken along line X 5 -X 5 ′, Y 5 -Y 5 ′, and Z 5 -Z 5 ′ of FIG. 5A.
- a contact opening 750 is formed by selectively removing a dummy dielectric layer pattern 401 using an interdielectric layer pattern 700 as an etching mask.
- the contact opening 750 is located in a portion in which the dummy dielectric layer pattern 401 is located.
- the selective removal of the dummy dielectric layer pattern 401 is performed by a dry etching process.
- the etching process can be performed using ashing. That is, the etching process can be performed by dry etching in which an oxygen source is used. Since the resist material or the organic antireflective layer material forming the dummy dielectric layer pattern 401 is formed of organic materials such as polymer, the resist material or the organic antireflective layer material can be removed by the ashing.
- the interdielectric layer pattern 700 is formed of inorganic materials such as silicon dioxide (SiO 2 )
- the interdielectric layer pattern 700 is not etched by a dry etching process such as the ashing.
- a dry etching process such as the ashing.
- a very high etching selectivity can be realized in the dry etching, and the dummy dielectric layer pattern 401 can be selectively removed.
- the etching process can be supplemented by additionally performing a wet etching process such as a strip in which phosphoric acid is used, and by removing residual materials after ashing.
- the etching process can be performed by dry etching in which etching gas containing nitrogen (N) gas or hydrogen (H) gas is used. Since inorganic materials such as silicon dioxide (SiO 2 ) forming the interdielectric layer pattern 700 is not etched by the dry etching in which the etching gas is used, the dummy dielectric layer pattern 401 can be selectively removed.
- etching gas containing nitrogen (N) gas or hydrogen (H) gas is used. Since inorganic materials such as silicon dioxide (SiO 2 ) forming the interdielectric layer pattern 700 is not etched by the dry etching in which the etching gas is used, the dummy dielectric layer pattern 401 can be selectively removed.
- a very high etch selectivity can be provided with respect to a lower spacer 390 and a hard mask 370 .
- damage to the spacer 390 and the hard mask 370 by etching away the dummy dielectric layer pattern 401 can be minimized.
- a contact opening 750 for exposing the lower semiconductor substrate 100 adjacent to the spacer 390 of the gate 330 and 350 is formed by selectively removing the dummy dielectric layer pattern 401 . Since the semiconductor substrate 100 exposed by the contact opening 750 includes active regions 120 , the semiconductor substrate 100 includes a portion to which a contact to be later formed is electrically connected.
- the contact opening 750 is formed to expose a plurality of gate lines 300 and the semiconductor substrate 100 adjacent to the gate lines 300 other than a contact hole formed in the conventional SAC process, while selectively exposing only a specific portion of the semiconductor substrate between gate lines.
- FIG. 6A is a plan view schematically illustrating the step of forming a conductive contact body 800 electrically connected to a semiconductor substrate 100 exposed by the contact opening 750
- FIG. 6B is a sectional view taken along line X 6 -X 6 ′-Y 6 -Y 6 ′-Z 6 -Z 6 ′ of FIG. 6A.
- the surface of the conductive layer is removed CMP or dry and wet etched back, so that the conductive material remaining is separated into gaps between gate lines 30 .
- the conductive contact body 800 is formed.
- the surface of an interdielectric layer pattern 700 lower of the conductive layer is also etched.
- a hard mask 370 for protecting the top of the gates 330 and 350 is used as an etching stop.
- two opposite sidewalls of the conductive contact body 800 are separated by a spacer 390 of gate 330 and 350 , and the other two opposite sidewalls are separated by the interdielectric layer pattern 700 .
- the conductive layer can be formed of conventional conductors such as polycrystalline silicon, tungsten (W), titanium (Ti), titanium nitride (TiN), tungsten silicide (WSi), platinum (Pt), aluminum (Al), or copper (Cu).
- W tungsten
- Ti titanium
- TiN titanium nitride
- WSi tungsten silicide
- Pt platinum
- Al aluminum
- Cu copper
- the conductive contact body 800 used as a buried contact (BC) was described, but, the present invention can be also applied to form a storage nod pad or a direct contact (DC).
- the present invention can provide a conductive contact body surrounded by the interdielectric layer pattern and the spacer by etching the surface of the conductive layer that is deposited for filling the contact opening.
- the damage to the lower layer can be minimized by forming a dummy dielectric layer pattern for the contact opening of an organic material and by forming the interdielectric layer pattern of silicon dioxide (SiO 2 ) and by using a high etching selectivity between the dummy dielectric layer pattern and the interdielectric layer pattern.
- the contact opening can be formed by selectively removing the dummy dielectric layer pattern using the interdielectric layer pattern filled in the dummy opening as an etching mask. Even if an exposed portion of the spacer or the hard mask is damaged by the dummy opening process, the exposed portion is shielded by the following interdielectric layer pattern, thereby preventing an electrical short-circuit.
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Abstract
Description
- This application claims priority on Korean application number 2000-37397, filed Jun. 30, 2000 in the name of Samsung Electronics Co., Ltd. and is herein incorporated by reference for all purposes.
- 1. Field of the Invention
- The present invention relates to a method for manufacturing a semiconductor device, and more particularly, to a method for forming an interdielectric layer having openings by using a difference in an etch-rate and for forming a conductive contact for filling the openings.
- 2. Description of the Related Art
- As the integration density of semiconductor devices increases, the misalignment margins in a photolithographic process becomes narrower. As a result, it is not easy to achieve the necessary misalignment margin when manufacturing the semiconductor devices. Thus, an electrical short-circuit can occur between a gate line and a contact pad adjacent to the gate line, or between a bit line and a buried contact (BC) adjacent to the bit line, or between the gate line and the BC or a direct contact (DC).
- In order to overcome this problem, a self aligned contact (SAC) etching process has been implemented. However, the SAC etching process has limitations in views of non-opening and a selectivity.
- In detail, since the bonding energy of silicon dioxide (SiO2), which used as an interdielectric layer, is large, the interdielectric layer does not have a very high etching selectivity with respect to silicon nitride (Si3N4), which is used to form a spacer. As a result, it is necessary to increase the thickness of the spacer, and due to the increased thickness of the spacer, the interval between the gate lines becomes narrower and the aspect ratio increases.
- Due to the increase in the aspect ratio when forming the contact hole, it is more difficult to obtain the bottom critical dimension of the contact hole. As a result, a defect occurs in which the hole does not open properly. Also, the increase in the aspect ratio of the contact hole causes filling failures such as voids or seams in the interdielectric layer when filling the contact hole.
- To solve the above problems, it is a feature of the present invention to provide a method for forming a conductive contact. The method is capable of preventing an electrical short-circuit and preventing a contact hole from not opening, while realizing a high etch selectivity with respect to a spacer when forming the contact hole, thereby reducing the required thickness of the spacer and allowing the spacerto be formed of a material having a low dielectric constant.
- Accordingly, to achieve the above feature, according to one aspect of the present invention, a dummy dielectric layer comprised of insulating materials having a relatively high etch-rate and an interdielectric layer pattern having a lower etch-rate than that of the dummy dielectric layer are formed on a semiconductor substrate. The dummy dielectric layer is selectively removed by using a high etching selectivity between the dummy dielectric layer and the interdielectric layer pattern, and thereby forming a contact opening exposing a portion in which a contact will be formed.
- Here, the dummy dielectric layer is formed of an organic material, and the interdielectric layer pattern is formed of a silicon dioxide (SiO2) layer which is in one preferred embodiment, selectively deposited from a liquid phase precursor.
- Meanwhile, in order to form the contact opening, the dummy dielectric layer is selectively etched, to form a dummy opening which exposes a portion in which the contact body is not formed: The interdielectric layer is then formed to fill the dummy opening. The dummy dialectric material remaining in the contact area is then selectively etched to form the contact opening. The contact opening is filled with conductive materials and divided into the contact body by using surface etching or polishing.
- According to the present invention, by introducing the dummy dielectric layer pattern formed of the organic material, the defects that occur when forming the contact opening can be minimized.
- The above feature and advantages of the present invention will become more apparent by describing in detail a preferred embodiment thereof with reference to the attached drawings in which:
- FIGS. 1A and 1B through FIGS. 6A and 6B are plan views and sectional views illustrating a method for manufacturing a conductive contact of a semiconductor device according to a preferred embodiment of the present invention.
- The present invention will be described more fully hereinafter with reference to the accompanying drawings in which preferred embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. In the drawings, the forms of elements are exaggerated for clarity. Like reference numerals refer to like elements throughout the drawings. It will be understood that when a layer is referred to as being on another layer or “on” a semiconductor substrate, it can be directly on the other layer or on the semiconductor substrate, or intervening layers may also be present.
- FIG. 1A is a plan view schematically illustrating the step of forming a
gate line 300 on asemiconductor substrate 100, and FIG. 1 B is a sectional view taken along line X1-X1′-Y1-Y1′-Z1-Z1′ of FIG. 1A. - In detail, the
gate line 300 is formed of a line-type on thesemiconductor substrate 100 using a conventional process of manufacturing a transistor. For example, after forming anisolation region 200 on thesemiconductor substrate 100 using a shallow trench isolation (STI) process,gates active region 120 defined by theisolation region 200. - The
gates gate oxide layer 310 between thegates substrate 100. Thegates gates polycrystalline silicon layer 330 and asilicide layer 350 on thegate oxide layer 310 and patterning them. Here, thesilicide layer 350 can be formed of metal silicide such as tungsten silicide (WSi). Also, the gates can be only formed of metal materials such as tungsten (W). - Before patterning the
gates hard mask 370 may be formed by depositing insulating materials, for example, silicon nitride (Si3N4) or silicon dioxide (SiO2) on thesilicide layer 350. Thehard mask 370 may also be formed of silicon oxynitride (SiON) or silicon carbide (SiC). - This is to implement a high etching selectivity of the
hard mask 370 in a process of forming the following contact. As a result, it can be prevented that thehard mask 370 is damaged to occur the exposure of thegates hard mask 370 is patterned together when patterning thegates gates - After the
gates spacer 390 for covering the sidewalls of thegates spacer 390 can be formed of an insulating material such as silicon nitride (Si3N4) or silicon dioxide (SiO2). Also, thespacer 390 can be formed of silicon oxynitride (SiON) or silicon carbide (SiC). Preferably, thespacer 390 is formed of silicon nitride (Si3N4) so as to provide a high selectivity in the following etching process. - As described above, the
spacer 390 and thehard mask 370 comprise shieldingdielectric layers gates dielectric layers - Meanwhile, the problems of the SAC process due to the integration of semiconductor devices as described previously usually occur in a
cell region 110. The following description of a preferred embodiment of the present invention is focused on thecell region 110. In the preferred embodiment of the present invention, thegate line 300 will be described as the example of a conductive line, but the present invention can be also applied to the conductive line for use in conventional interconnections. - In a case where the conductive line is used as interconnections, the conductive line includes a conductive pattern formed of polycrystalline silicon, titanium (Ti), titanium nitride (TiN), aluminum (Al), copper (Cu), tungsten (W), tungsten silicide (WSi), platinum (Pt), or another metal having high conductivity, and an upper layer of a metallic conductive oxide, or silicide. The
spacer 390 is formed on the sidewalls of the conductive pattern, and thehard mask 370 is formed on the top of the conductive pattern. - FIG. 2A is a plan view schematically illustrating the step of forming a
dummy dielectric layer 400 and forming aphotoresist pattern 550 on thedummy dielectric layer 400, and FIG. 2B is a sectional view taken along lines X2-X2′, Y2-Y2′, and Z2-Z2′ of FIG. 2A. - Specifically, the
dummy dielectric layer 400 for filling a gap betweengate lines 300 is formed on asemiconductor substrate 100. Thedummy dielectric layer 400 is formed of an insulating material having a flowability that is high enough so that it can fill the gap between the gate lines 300. Also, since thedummy dielectric layer 400 has a high dry or wet etch-rate compared to ahard mask 370 or thespacer 390, specifically, thedummy dielectric layer 400 is formed of an insulating material having a high etching selectivity to thehard mask 370 or thespacer 390. - This is to prevent the
spacer 390 or thehard mask 370 from being damaged by the following process of patterning or removing thedummy dielectric layer 400. As a result, thegates dummy dielectric layer 400 is formed of an insulating material having a very high wet or dry etch-rate compared to an insulating material comprising an interdielectric layer to be formed later. - The
dummy dielectric layer 400 can be formed of an organic material such as polymer. For example, thedummy dielectric layer 400 can be formed of a resist material used in a photolithographic process of semiconductor processes. Also, thedummy dielectric layer 400 can be formed of a material used in forming an organic antireflective layer in the semiconductor processes, that is, an organic antireflective layer material. Or, thedummy dielectric layer 400 can be formed of an insulating material having a high dry etch-rate such as an organic insulator, such as, FLARE (manufactured by AlliedSignal Advanced Microelectronic Materials). - As described above, a
photoresist layer 550 is formed on thedummy dielectric layer 400, and the photoresist layer is exposed and developed, thereby forming aphotoresist pattern 550 exposing aportion 600.Portion 600 comprises a portion of thecell region 110 in which a contact will not be formed. - In a case where the
dummy dielectric layer 400 is formed of the resist material or the organic antireflective layer material, it may be difficult to provide an adequate etching selectivity between the resist material or the organic antireflective layer of thedummy dielectric layer 400 and thephotoresist pattern 550 used in the following process of patterning thedummy dielectric layer 400. Thus, in this case, anetching mask layer 510 can be formed on thedummy dielectric layer 400. Preferably, theetching mask layer 510 is preferably formed of a material having a higher etching resistance than the resist material or organic antireflective layer material. Suitable materials include, silicon dioxide (SiO2), silicon nitride (Si3N4), silicon carbide (SiC), or silicon oxynitride (SiON). - However, in a case where the
dummy dielectric layer 400 is formed of the organic material such as the FLARE, it is possible to provide an etching selectivity between the organic insulator of FLARE and thephotoresist pattern 550 by selecting an appropriate etching gas used in dry etching. Thus, in a case where thedummy dielectric layer 400 is formed of the organic insulator, theetching mask layer 510 can be omitted. - Meanwhile, the
portion 600 of thedummy dielectric layer 400 can correspond to anisolation region 200 betweenactive regions 120. Since theactive regions 120 can be formed in the shape of (−)-type or t-type arrangement, theportion 600 to be exposed by thephotoresist pattern 550 can be set in a long oval type or (−)-type for exposing a region betweenactive regions 120. Thus, thephotoresist pattern 550 is shielded by covering the portion on which the contact will be formed. - FIG. 3A is a plan view schematically illustrating the step of forming a dummy
dielectric layer pattern 401 having adummy opening 450, for patterning thedummy dielectric layer 400, and FIG. 3B is a sectional view taken along line X3-X3′, Y3-Y3′, and Z3-Z3′ of FIG. 3A. - In detail, the
dummy dielectric layer 400 is selectively etched using thephotoresist pattern 550 as an etching mask, and a dummydielectric layer pattern 401 having adummy opening 450 exposing gap regions betweengate lines 300 is formed. Here, an etching process of forming thedummy opening 450 can be performed by a selective dry etching, and thedummy opening 450 exposessubstrates 100 of gap regions between the gate lines 300 on which a contact will be not formed. - For example, in a case where the
dummy dielectric layer 400 is formed of a resist material or an organic antireflective layer material, the etching process can be performed by dry etching in which an oxygen source is used. Since the resist material or the organic antireflective layer material forming thedummy dielectric layer 400 is comprised of organic materials such as polymer, the resist material or the organic antireflective material can be removed by the dry etching. - Here, the
photoresist pattern 550 can be together removed in the dry etching, but theetching mask layer 510 acts as a hard mask, and thedummy dielectric layer 400 is selectively patterned to form the dummydielectric layer pattern 401. After the dry etching, the etching process can be supplemented by additionally performing a wet etching process such a strip process in which phosphoric acid is used, and by removing residual materials after dry etching. After the dummydielectric layer pattern 401 is formed, theetching mask layer 510 is removed. - Meanwhile, in a case where the
dummy dielectric layer 400 is formed of an organic insulator, the etching process can be performed by dry etching in which etching gas containing nitrogen (N) gas or hydrogen (H) gas is used. Since the gas used in the dry etching process has an etching selectivity between thephotoresist pattern 550 and the organic insulator of thedummy dielectric layer 400, thedummy dielectric layer 400 of the organic insulator can be selectively patterned with respect to thephotoresist pattern 550. Thus, theetching mask layer 510 can be omitted. - Meanwhile, in the etching process of forming the dummy
dielectric layer pattern 401, a very high selectivity can be provided with respect to alower spacer 390 and ahard mask 370. Thus, damage to thespacer 390 and thehard mask 370 by the etching process when forming the dummydielectric layer pattern 401 can be minimized. Thus, thespacer 390 and thehard mask 370 can be introduced in thinner thickness than that of in a conventional SAC process, and thespacer 390 and thehard mask 370 can be formed of insulating materials having a low dielectric constant, for example, silicon carbide (SiC). As a result, the desired effect of reducing the loading capacitance of a semiconductor device can be additionally realized. - FIG. 4A is a plan view schematically illustrating the step of forming an
interdielectric layer pattern 700 for filling thedummy opening 450, and FIG. 4B is a sectional view taken along line X4-X4′, Y4-Y4′, and Z4-Z4′ of FIG. 4A. - Specifically, an
interdielectric layer 700 for filling thedummy opening 450 is formed. Theinterdielectric layer 700 can be formed of insulating materials such as silicon dioxide (SiO2), silicon nitride (Si3N4), silicon oxynitride (SiON), or silicon carbide (SiC). Here, since an organic material forming the dummydielectric layer pattern 401 is not resistant to higher processing temperature, preferably, a process for forming theinterdielectric layer pattern 700 can be performed at a low temperature, for example, at 400 □C and below. Thus, the process of forming theinterdielectric layer pattern 700 can be performed by low temperature CVD or coating. - However, preferably, the
interdielectric layer pattern 700 is formed by liquid phase deposition. Silicon dioxide (SiO2) can be selectively deposited by liquid phase deposition as disclosed in U.S. Pat. No. 5,547,900 (assigned to Jengping Lin et al., on 20 August 1996, entitled “Method of fabricating a self-aligned contact using a liquid-phase oxide-deposition process”) and a paper (entitled “A Selective SiO2 Film-Formation Technology Using Liquid Phase Deposition for Fully Planarized Multilevel Interconnections, by Tetsuya Homma et al., J. Electrochm. Soc., Vol. 140, No. 8, pp2410-2414, in 1993), the text of which are both hereby incorporated by reference into this specification. - When deposited by liquid phase deposition, silicon dioxide (SiO2) is not deposited on the organic material. Thus, the
interdielectric layer pattern 700 of silicon dioxide (SiO2) is deposited only in the dummy opening 450 of thedummy layer 401 and grows. When the liquid phase deposition is precisely controlled, theinterdielectric layer pattern 700 can be selectively formed in the dummy opening 450 of the dummydielectric layer pattern 401 comprising organic materials without the following process. Theinterdielectric layer pattern 700 by the liquid phase deposition has very high filling characteristics that are characteristic of a liquid phase deposition process. Thus, theinterdielectric layer pattern 700 can be formed without a seam or a void between the gate lines 300. - Meanwhile, in a case where the
interdielectric layer pattern 700 is formed using a low temperature CVD method, due to the high aspect ratio between thegate lines 300, a seam or a void may occur in theinterdielectric layer pattern 700. However, the void or the seam is closed and isolated by insulating materials forming theinterdielectric layer pattern 700. That is, theinterdielectric layer pattern 700 grows from the inside and bottom of thedummy opening 450 due to the deposition characteristics of CVD, and so the void or the seam occurs in the center of theinterdielectric layer pattern 700 between the gate lines 300. - Thus, the void or the seam does not extend to the outside of the
interdielectric layer pattern 700 in either lateral direction. As a result, although a conductive material is filled in the void or the seam in the following process of depositing the conductive material, it is possible to prevent the residual conductive material from acting as a defect that causes an electrical short-circuit such as a bridge. - In addition, in a case where the
interdielectric layer pattern 700 is extended to cover the surface of the dummydielectric layer pattern 401, the portion of theinterdielectric layer pattern 700 covering the dummydielectric layer pattern 401 is chemical mechanical polished (CMP) or dry-etched back to thedummy opening 450. Here, a wet etch back process can also be used. The polishing or etch back process is performed so that the surface of the dummydielectric layer pattern 401 may be exposed. - FIG. 5A is a plan view schematically illustrating the step of selectively removing a dummy
dielectric layer pattern 401, and FIG. 5B is a sectional view taken along line X5-X5′, Y5-Y5′, and Z5-Z5′ of FIG. 5A. - In detail, a
contact opening 750 is formed by selectively removing a dummydielectric layer pattern 401 using aninterdielectric layer pattern 700 as an etching mask. Thus, thecontact opening 750 is located in a portion in which the dummydielectric layer pattern 401 is located. - The selective removal of the dummy
dielectric layer pattern 401 is performed by a dry etching process. For example, in a case where the dummydielectric layer pattern 401 is formed of a resist material or an organic antireflective layer material, the etching process can be performed using ashing. That is, the etching process can be performed by dry etching in which an oxygen source is used. Since the resist material or the organic antireflective layer material forming the dummydielectric layer pattern 401 is formed of organic materials such as polymer, the resist material or the organic antireflective layer material can be removed by the ashing. - Where the
interdielectric layer pattern 700 is formed of inorganic materials such as silicon dioxide (SiO2), theinterdielectric layer pattern 700 is not etched by a dry etching process such as the ashing. A very high etching selectivity can be realized in the dry etching, and the dummydielectric layer pattern 401 can be selectively removed. After the ashing, the etching process can be supplemented by additionally performing a wet etching process such as a strip in which phosphoric acid is used, and by removing residual materials after ashing. - Meanwhile, in a case where the dummy
dielectric layer pattern 401 is formed of an organic insulator, the etching process can be performed by dry etching in which etching gas containing nitrogen (N) gas or hydrogen (H) gas is used. Since inorganic materials such as silicon dioxide (SiO2) forming theinterdielectric layer pattern 700 is not etched by the dry etching in which the etching gas is used, the dummydielectric layer pattern 401 can be selectively removed. - Meanwhile, in the etching process of removing the dummy
dielectric layer pattern 401, a very high etch selectivity can be provided with respect to alower spacer 390 and ahard mask 370. Thus, damage to thespacer 390 and thehard mask 370 by etching away the dummydielectric layer pattern 401 can be minimized. - As described above, a
contact opening 750 for exposing thelower semiconductor substrate 100 adjacent to thespacer 390 of thegate dielectric layer pattern 401. Since thesemiconductor substrate 100 exposed by thecontact opening 750 includesactive regions 120, thesemiconductor substrate 100 includes a portion to which a contact to be later formed is electrically connected. - In a preferred embodiment, the
contact opening 750 is formed to expose a plurality ofgate lines 300 and thesemiconductor substrate 100 adjacent to thegate lines 300 other than a contact hole formed in the conventional SAC process, while selectively exposing only a specific portion of the semiconductor substrate between gate lines. - FIG. 6A is a plan view schematically illustrating the step of forming a
conductive contact body 800 electrically connected to asemiconductor substrate 100 exposed by thecontact opening 750, and FIG. 6B is a sectional view taken along line X6-X6′-Y6-Y6′-Z6-Z6′ of FIG. 6A. - Specifically, after depositing a conductive layer which fills the formed
contact opening 750 and is electrically connected to the exposedsemiconductor substrate 100, the surface of the conductive layer is removed CMP or dry and wet etched back, so that the conductive material remaining is separated into gaps between gate lines 30. Thus, theconductive contact body 800 is formed. In order to completely separate the conductive layer into theconductive contact body 800, the surface of aninterdielectric layer pattern 700 lower of the conductive layer is also etched. Here, preferably, in the etching, ahard mask 370 for protecting the top of thegates conductive contact body 800 are separated by aspacer 390 ofgate interdielectric layer pattern 700. - The conductive layer can be formed of conventional conductors such as polycrystalline silicon, tungsten (W), titanium (Ti), titanium nitride (TiN), tungsten silicide (WSi), platinum (Pt), aluminum (Al), or copper (Cu).
- In the preferred embodiment of the present invention, the
conductive contact body 800 used as a buried contact (BC) was described, but, the present invention can be also applied to form a storage nod pad or a direct contact (DC). - The present invention can provide a conductive contact body surrounded by the interdielectric layer pattern and the spacer by etching the surface of the conductive layer that is deposited for filling the contact opening. Here, the damage to the lower layer can be minimized by forming a dummy dielectric layer pattern for the contact opening of an organic material and by forming the interdielectric layer pattern of silicon dioxide (SiO2) and by using a high etching selectivity between the dummy dielectric layer pattern and the interdielectric layer pattern.
- That is, by using the high etching selectivity, damage to the spacer and the hard mask for protecting the conductive pattern, such as the lower gate, can be minimized. The contact opening can be formed by selectively removing the dummy dielectric layer pattern using the interdielectric layer pattern filled in the dummy opening as an etching mask. Even if an exposed portion of the spacer or the hard mask is damaged by the dummy opening process, the exposed portion is shielded by the following interdielectric layer pattern, thereby preventing an electrical short-circuit.
- While this invention has been particularly shown and described with reference to preferred embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (24)
Applications Claiming Priority (2)
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KR10-2000-0037397A KR100366622B1 (en) | 2000-06-30 | 2000-06-30 | Method for manufacturing conductive contact of semiconductor device |
KR2000-37397 | 2000-06-30 |
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US20020001931A1 true US20020001931A1 (en) | 2002-01-03 |
US6429107B2 US6429107B2 (en) | 2002-08-06 |
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US09/839,855 Expired - Lifetime US6429107B2 (en) | 2000-06-30 | 2001-04-20 | Method for forming conductive contact of semiconductor device |
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US (1) | US6429107B2 (en) |
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KR100366621B1 (en) * | 2000-06-28 | 2003-01-09 | 삼성전자 주식회사 | Method for manufacturing conductive contact body of semiconductor device |
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-
2000
- 2000-06-30 KR KR10-2000-0037397A patent/KR100366622B1/en not_active IP Right Cessation
-
2001
- 2001-04-20 US US09/839,855 patent/US6429107B2/en not_active Expired - Lifetime
- 2001-05-24 TW TW090112542A patent/TW508740B/en not_active IP Right Cessation
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Also Published As
Publication number | Publication date |
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KR20020003013A (en) | 2002-01-10 |
US6429107B2 (en) | 2002-08-06 |
KR100366622B1 (en) | 2003-01-09 |
TW508740B (en) | 2002-11-01 |
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