US1906484A - Soap preparation - Google Patents

Soap preparation Download PDF

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Publication number
US1906484A
US1906484A US525603A US52560331A US1906484A US 1906484 A US1906484 A US 1906484A US 525603 A US525603 A US 525603A US 52560331 A US52560331 A US 52560331A US 1906484 A US1906484 A US 1906484A
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US
United States
Prior art keywords
soap
acid
parts
per cent
radicle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US525603A
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English (en)
Inventor
Nuesslein Joseph
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Application granted granted Critical
Publication of US1906484A publication Critical patent/US1906484A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/126—Acylisethionates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/03—Organic sulfoxy compound containing
    • Y10S516/04—Protein or carboxylic compound containing

Definitions

  • JOSEPH N'UESSLEIN OF LUDWiGSHAFEN-ON-THE-RHINE, GERMANY, ASSIGNOR TO I. G. FARBENINDUSTRIE AKTIENGESELLSCHAFT, OF FRANKFORT-ON-THE-MAIN, GER- MANY SOAP PREPARATION No Drawing. Application filed March 26; 1931, Serial No. 525,603, and in Germany April 7, 1930.
  • the present invention relates to new and basic oxygen-containing mineral acids, as
  • non-aromatic i. e. aliphatic or cycloaliphatic alcohols or oleiines or olefinic alcohols having more than 8 carbon atoms, or of the true sulphonic acids, or their salts, of any non-armomat-ic, i. e.
  • esters or amides aliphatic or hydroaromatic compounds containing at least 8 carbon atoms, preferably from 10 to 16 carbon atoms, as for example of acids of fats or oils of vegetable or animal origin, fatty acid esters, amides, or alcohols, ethers or hydrocarbons, in which esters or amides or other derivatives the sulphonic group may be contained in the component of low molecular weight.
  • Such products are obtainable, for example, by the condensation of hydroxylated or halogenated derivatives of ethane, mono or di-sulphonic acid or of ethionic acid, carbyl sulphate or aminosulphonic acids with higher fatty acids, such as the fatty acids of vegetal origin or their synthetic equivalents, or their derivatives or salts of these compounds.
  • esters and amides correspond to the general formula RCOXR SO Me,
  • R denotes an aliphatic radicle
  • er/an amino-alkylene radicle and Me denotes an alkali radicle.
  • h ulp ric esters emp y according to the present invention may be obtained by treatin the alcohols or olefines with sulphonatmg agents, such as concentrated sulphuric acid, at a temperature up to about 35 C. sulphonic acids being obtained on working at about 100 C. or in the presence of agents removing Water such as anhydrides of strong inorganic polybasic acids or with the aid of sulphuric anhydride.
  • sulphonatmg agents such as concentrated sulphuric acid
  • the conversion of the said alcohols with the oxygen-containing polybasic mineral acids may be carried out for the production of the sulphuric esters by treating the alcohols with sulphuric acid, or chlorsulphonic acid in the presence of organic inert diluents, and for the production of the phosphoric esters by acting with phosphorus pentoxide on the alcohols in the presence of organic inert diluents.
  • Small portions of the initial materials which have not been converted with the mineral acids, as for example fatty acids, neutral fats, parafiins and the like may be present in the finished product before it is incorporated with the soaps.
  • esters employed is at least 5 per cent by weight of the soaps but in most cases considerably above 5 per cent will be used, especially as the sensitivity of the preparations to hard water is thus diminished; the esters may be employed, for example, in quantities of from 10, 20, 30, or 80 per cent of the soap but for the aforesaid reasons quantities of from 100 to about 1000 per cent are preferred in order to render the preparations particularly valuable for any purpose and in water of a high degree of hardness.
  • soap substitutes may be added as well as salts of all kinds and the soap preparations may be adulterated with protective colloids, as for example albumious substances, vegetable gums, starch and the like.
  • protective colloids as for example albumious substances, vegetable gums, starch and the like.
  • organic solvents for many purposes, especiallyfor the dissolution and removalvof fat, oil or like stains, an addition of organic solvents to the soap preparations is advantageous.
  • the known and, approved substances The parts are by weight.
  • Ema/mple 1 80 parts of the sodium salt of the acid sulphuric ester of cetyl alcohol are intimately worked up with 10 parts of potassium and/or sodium stearate and 10 parts of glycerine' and pressed into moulds.
  • the product is eminently suitable as a bath soap.
  • Example 2 parts of the disodium salt of the sulphonic acid of stearic acid are ground with 10 parts of Glaubers salt, 10 parts of sodium palmitate and 10 parts of trisodium phosphate.
  • a soap powder is obtained which has an excellent cleansing action.
  • Example 3 80 parts of the neutral sodium salt of the condensation product of oleic acid chloride and ethionic acid are intimately mixed with 15 parts of sodium palmitate and 5 parts of sodium perborate. The product obtained has an excellent cleansing and bleaching action even in hard water.
  • E wample 4 30 parts of the neutral ammonium salt of the acid sulphuric ester of stearyl alcohol together with 30 parts of ammonium oleate and 40 parts of water are kneaded into a homogeneous paste.
  • the preparation possesses a good cleansing action which may be increased by the addition of 5 parts of cyclohexanol.
  • Example 5 100 parts of a normal grain soap paste containing about 65 per cent of fatty acid is kneaded with a concentrated solution of 10 parts of the neutral sodium salt of the sulphuric ester of laur 1 alcohol. The mixture is worked up in t e usual manner into shreds or flakes which are distinguished by their high solubility. 1 per cent by weight of the mass of purified lemon grass oil may be added in order to give a. fresh smell to the soap.
  • Soap preparations comprising an alkali metal soap and from 100 to about 1000 per cent, by weight of the soap, of neutralized sulphonic acid corresponding to the formula R.COO.C H .SO H in which RCOO is the radicle of a fatty acid of vegetal origin.
  • Soap preparations comprising an alkali metal soap and from 100 to about 1000 per cent, by. weight of the soap, of an alkali metal salt of a sul honic acid corresponding to the formula R. OO.G H.,.SO H in which H.600 is the radicle of a fatty acid of vegetal origin.
  • Soap preparations comprising an alkali metal soap and from 100 to about 1000 per cent, by weight of the soap, of an alkali metal salt of a sul honic acid corresponding to the formula R. OO.C H .SO H in which RG00 is the radicle of oleic acid.
  • Soap preparations comprising a soap derived from a water-soluble base and at least 5 per cent, by weight of the soap, of a true sulphonic acid substance containing at least 8 carbon atoms and corresponding to the formula RCOX- -R SO -OMe in which R denotes an aliphatic radicle, XR denotes an oxalkylene (O-R or an amino-alkylene radicle and Me denotes an alkali radicle.
  • Soap preparations comprising a soap derived from a water-soluble base and from 100 to about 1000 per cent, by weight of the soap, of a true sulphonic acid substance containing at least 8 carbon atoms and corresponding to the formula.
  • R denotes an aliphatic radicle
  • XR denotes an oxalkylene (OR or an aminolene radicle
  • Me denotes an alkali radio e.
  • Soap preparations comprising an alkali metal soap and from 100 to about 1000 per 5 cent, by weight of the soap, of a true sulmy hand. 5 JOSEPH NUESSLEIN.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
US525603A 1930-04-08 1931-03-26 Soap preparation Expired - Lifetime US1906484A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE638302T 1930-04-08

Publications (1)

Publication Number Publication Date
US1906484A true US1906484A (en) 1933-05-02

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ID=34812936

Family Applications (1)

Application Number Title Priority Date Filing Date
US525603A Expired - Lifetime US1906484A (en) 1930-04-08 1931-03-26 Soap preparation

Country Status (5)

Country Link
US (1) US1906484A (en(2012))
BE (1) BE378069A (en(2012))
DE (1) DE638302C (en(2012))
FR (1) FR712913A (en(2012))
NL (1) NL55394C (en(2012))

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2494580A (en) * 1947-05-24 1950-01-17 Procter & Gamble Detergent composition
US2508578A (en) * 1944-05-05 1950-05-23 Colgate Palmolive Peet Co Combined soap and synthetic detergent bar
US2567645A (en) * 1947-05-16 1951-09-11 Shell Dev Process of producing a detergent composition
US2603606A (en) * 1952-07-15 Alkyl sulfates
US2739130A (en) * 1956-03-20 Cleaning composition
US2749315A (en) * 1951-04-28 1956-06-05 Colgate Palmolive Co Toilet detergent bar and process of preparing same
US2765279A (en) * 1949-03-11 1956-10-02 Metallgesellschaft Ag Shaped mixture of soap and phosphonate
US2781320A (en) * 1957-02-12 All purpose
US2781321A (en) * 1953-05-12 1957-02-12 Gen Aniline & Film Corp All purpose detergent bar
US2865811A (en) * 1952-05-02 1958-12-23 Irval Cosmetics Inc Hair straightener containing a kerating reducing agent, anionic wetting agent and water-soluble soap and method of using same
US2886585A (en) * 1956-08-15 1959-05-12 Drew & Co Inc E F Method of making a synthetic detergent in cake form
US2894912A (en) * 1954-09-21 1959-07-14 Lever Brothers Ltd Isethionate detergent bar
US2988511A (en) * 1955-03-31 1961-06-13 Mills Victor Nonsmearing detergent bar
US2991253A (en) * 1952-08-20 1961-07-04 Armour & Co Solid soap composition
US3043778A (en) * 1958-02-20 1962-07-10 Lever Brothers Ltd Soap bar compositions
US3057805A (en) * 1962-10-09 Synthetic detergent cake and process
US3070547A (en) * 1953-07-13 1962-12-25 Procter & Gamble Soap-synthetic bar
US3224976A (en) * 1960-05-20 1965-12-21 Colgate Palmolive Co Detergent bar
US4260507A (en) * 1970-08-18 1981-04-07 Lever Brothers Company Soap-synthetic detergent tablets
US4476055A (en) * 1982-07-06 1984-10-09 Westvaco Corporation C21-Dicarboxylic acid isethionates as primary anionic surfactants
US4514335A (en) * 1982-07-06 1985-04-30 Westvaco Corporation C21 -Dicarboxylic acid isethionates as primary anionic surfactants
US4571309A (en) * 1983-07-20 1986-02-18 Westvaco Corporation C22 -Cycloaliphatic tricarboxylic acid derived isethionate esters and method of preparation

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE895289C (de) * 1934-07-03 1953-11-02 Bataafsche Petroleum Verfahren zum Herstellen von Salzen saurer Alkylester
DE750286C (de) * 1935-05-02 1945-01-03 Kalle & Co Ag Seifenfreie Waschmittel
DE895815C (de) * 1940-01-06 1953-11-05 Basf Ag Waschmittel
BE577250A (en(2012)) * 1958-04-14
DE1111761B (de) * 1959-09-25 1961-07-27 Shell Int Research Toilettenseife
BE611781A (en(2012)) * 1960-12-23

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3057805A (en) * 1962-10-09 Synthetic detergent cake and process
US2603606A (en) * 1952-07-15 Alkyl sulfates
US2739130A (en) * 1956-03-20 Cleaning composition
US2781320A (en) * 1957-02-12 All purpose
US2508578A (en) * 1944-05-05 1950-05-23 Colgate Palmolive Peet Co Combined soap and synthetic detergent bar
US2567645A (en) * 1947-05-16 1951-09-11 Shell Dev Process of producing a detergent composition
US2494580A (en) * 1947-05-24 1950-01-17 Procter & Gamble Detergent composition
US2765279A (en) * 1949-03-11 1956-10-02 Metallgesellschaft Ag Shaped mixture of soap and phosphonate
US2749315A (en) * 1951-04-28 1956-06-05 Colgate Palmolive Co Toilet detergent bar and process of preparing same
US2865811A (en) * 1952-05-02 1958-12-23 Irval Cosmetics Inc Hair straightener containing a kerating reducing agent, anionic wetting agent and water-soluble soap and method of using same
US2991253A (en) * 1952-08-20 1961-07-04 Armour & Co Solid soap composition
US2781321A (en) * 1953-05-12 1957-02-12 Gen Aniline & Film Corp All purpose detergent bar
US3070547A (en) * 1953-07-13 1962-12-25 Procter & Gamble Soap-synthetic bar
US2894912A (en) * 1954-09-21 1959-07-14 Lever Brothers Ltd Isethionate detergent bar
US2988511A (en) * 1955-03-31 1961-06-13 Mills Victor Nonsmearing detergent bar
US2886585A (en) * 1956-08-15 1959-05-12 Drew & Co Inc E F Method of making a synthetic detergent in cake form
US3043778A (en) * 1958-02-20 1962-07-10 Lever Brothers Ltd Soap bar compositions
US3224976A (en) * 1960-05-20 1965-12-21 Colgate Palmolive Co Detergent bar
US4260507A (en) * 1970-08-18 1981-04-07 Lever Brothers Company Soap-synthetic detergent tablets
US4476055A (en) * 1982-07-06 1984-10-09 Westvaco Corporation C21-Dicarboxylic acid isethionates as primary anionic surfactants
US4514335A (en) * 1982-07-06 1985-04-30 Westvaco Corporation C21 -Dicarboxylic acid isethionates as primary anionic surfactants
US4571309A (en) * 1983-07-20 1986-02-18 Westvaco Corporation C22 -Cycloaliphatic tricarboxylic acid derived isethionate esters and method of preparation

Also Published As

Publication number Publication date
DE638302C (de) 1936-11-13
NL55394C (en(2012))
BE378069A (en(2012))
FR712913A (fr) 1931-10-15

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