US1870407A - Delustering of textile material - Google Patents
Delustering of textile material Download PDFInfo
- Publication number
- US1870407A US1870407A US342666A US34266629A US1870407A US 1870407 A US1870407 A US 1870407A US 342666 A US342666 A US 342666A US 34266629 A US34266629 A US 34266629A US 1870407 A US1870407 A US 1870407A
- Authority
- US
- United States
- Prior art keywords
- latex
- luster
- cellulose
- yarns
- water insoluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title description 35
- 239000004753 textile Substances 0.000 title description 31
- 229920000126 latex Polymers 0.000 description 20
- 239000004816 latex Substances 0.000 description 20
- 239000002932 luster Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000004744 fabric Substances 0.000 description 16
- 239000000243 solution Substances 0.000 description 15
- 229920002678 cellulose Polymers 0.000 description 12
- 239000001913 cellulose Substances 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 12
- 229920002301 cellulose acetate Polymers 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000139306 Platt Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- LKZCRGABYQYUFX-UHFFFAOYSA-L barium(2+);dithiocyanate Chemical compound [Ba+2].[S-]C#N.[S-]C#N LKZCRGABYQYUFX-UHFFFAOYSA-L 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229920001727 cellulose butyrate Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000001761 ethyl methyl cellulose Substances 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- -1 yarns Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
- Y10T442/2869—Coated or impregnated regenerated cellulose fiber fabric
Definitions
- This invention relates to the treatment of textile materials whereby the luster of the same is materially reduced, and relates more particularly to the treatment of textile ma- I terials containing organic derivatives of cellulose for the reduction of the luster thereof.
- An object of our invention is to reduce the luster of textile materials such as yarns, fabrics or garments containing derivatives U of cellulose by treatment of the same with a substance containing finely divided lightcolored materials and in the presence of col loidal rubber or latex.
- Other objects of our invention will appear from the following detailed description.
- textile materials made of any suitable material but particularly those made of or containing organic denvatives of cellulose with a substance containing finely dispersed white or ii ht-colored water insoluble compounds and m the presence of colloidal rubber or latex.
- the textile materials to be treated in accordance with our invention may be in the form of yarns, fabrics or garments.
- the yarns may be treated in the form of hanks or wound onto suitable packages such as bobbins,
- the fabric may be any suitable woven, knitted or netted fabric containing yarns oforganic derivatives of cellulose.
- cellulose ethers examples include ethyl cellulose, methyl cellulose and benzyl cellulose.
- These textile materials need not consist wholly of such organic derivatives of cellulose but may also contain other fibres such as cotton, natural silk, wool, reconstituted cellulose (rayon), etc. If desired the textile material to be treated may be made wholly of such other fibres.
- This yarn may be a composite yarn containing fibres or filaments of cellulose acetate and fibres of the other materials,-or the fabric may consist of yarns of cellulose acetate and yarns of the other materials.
- the textile materials are treated with a bath, paste or other substance containing the finely dispersed white or lightcolored water insoluble compound.
- WVe have found that the higher the degree of dispersion of the compound, the better are the results obtained; and we prefer to employ the same in such dispersion that the same approaches or equals the degree of dispersion occurring in colloidal solutions.
- Any suitable white or light-colored compound may be employed, and the same may be in the form of salts, oxides or hydroxides of metals. Examples of such suitable compounds are zinc oxide, barium sulphate, aluminum hydroxide, zine sulphide, calcium phosphate, etc.
- the presence of the latex or colloidal rubber is of importance, since this causes the com pound to become fixed in the textile material.
- the textile material may be treated with a soluble salt, and an insoluble light colored compound precipitated therein by treatment with a precipitating agent.
- the fabric may be treated with barium thiocyanate and then treated with a solution of a soluble sulphate to precipitate the insoluble barium sulphate.
- assistants such as swelling agents for the derivative of cellulose occurring in the textile material, or salts of strong bases and weak acids may be added to the treating solution.
- swelling agents are aqueous solutions of soluble thiocyanates, of acetone, formic acid, acetic acid, etc
- suitable salts are the thiocyanate of ammonium, potassium or sodium, or bora x. If these substances are employed care should be taken that the nature of the substance and the amounts used should be such as not to coagulate the latex in the bath. For instance the use of strong acid solutions should be avoided, as these tend to coagulate the latex.
- the textile material may be treated in accordance with our invention by'immersing of the same in a bath containing the treated substance, or the treating substance may be padded onto the textile material, or may be applied in the form of a paste or in any other suitable manner.
- the textile material may be washed and finished in any desired manner;
- the treated material may then, if desired, be dyed and/ or printed with appropriate dyestufi's as required. If desired, the textile material may be dyed or printed prior to treatment by our process.
- the textile materials when treated in accordance with our invention have their luster materially reduced, and this deluster effect is not -mat-erially altered even after severe scouring With soap solutions.
- the fabric when delustered in accordance with our invention does not become relustered when ironed or calendered while damp. By dyeing the textile material black, a black of subdued luster may be obtained-a result heretofore unattainable.
- Latex (20%) 20 cc. per liter
- Zinc oxide 10 grams per liter
- the zinc oxide is employed in the form of an impalpable powder and the bath 4 is well stirred in order to maintain the zinc oxide I in suspension.
- a swelling agent such as ammonium thiocyanate in amounts of 5 grams per liter of bath may be added.
- Method of reducing the luster of textile materials containing artificial fibres comprising treating the same with a medium containing latex in dilute solution and a finely divided relatively water insolublebody.
- Method of reducing the luster of textile materials containing organic derivatives of cellulose comprising. treating the same with a medium containing latex in dilute solution gng a finely divided relatively water insoluble 3.
- Method of reducing the luster of textile materials containing cellulose acetate comprising treating the same with a medium containing latex in dilute solution and a finely divided relatively Water insoluble body.
- Method of reducing the luster of fabric containing cellulose acetate yarns comprising treating the same with a medium containing latex in dilute solution and a finely divided relatively water insoluble body.
- Method of reducing the luster of fabric containing organic derivatives of cellulose yarns comprising treating the same with a medium containing latex in dilute solution and a colloidally dispersed relatively water insoluble body.
- Method of reducing the luster of fabric containing cellulose acetate yarns comprising treating the same with a medium containing latex in dilute solution and a colloidally dispersed relatively water insoluble body.
- Method of reducing the luster of fabric containing cellulose acetate yarns comprising treating the same with a medium containing latex in dilute solution and finely divided zinc oxide.
- Method of reducing the luster of hose containing cellulose acetate yarns comprising treating the same with a medium containing latex in dilute solution and a finely divided relatively water insoluble body.
- Textile materials containing artificial fibres having a reduced luster produced by treatment with a finely divided light-colored relatively water insoluble body and latex in dilute solution.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US342666A US1870407A (en) | 1929-02-25 | 1929-02-25 | Delustering of textile material |
GB5117/30A GB346511A (enrdf_load_stackoverflow) | 1929-02-25 | 1930-02-15 | |
FR690406D FR690406A (fr) | 1929-02-25 | 1930-02-21 | Perfectionnements au traitement des matières textiles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US342666A US1870407A (en) | 1929-02-25 | 1929-02-25 | Delustering of textile material |
Publications (1)
Publication Number | Publication Date |
---|---|
US1870407A true US1870407A (en) | 1932-08-09 |
Family
ID=23342763
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US342666A Expired - Lifetime US1870407A (en) | 1929-02-25 | 1929-02-25 | Delustering of textile material |
Country Status (3)
Country | Link |
---|---|
US (1) | US1870407A (enrdf_load_stackoverflow) |
FR (1) | FR690406A (enrdf_load_stackoverflow) |
GB (1) | GB346511A (enrdf_load_stackoverflow) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE472747A (enrdf_load_stackoverflow) * | 1943-11-12 |
-
1929
- 1929-02-25 US US342666A patent/US1870407A/en not_active Expired - Lifetime
-
1930
- 1930-02-15 GB GB5117/30A patent/GB346511A/en not_active Expired
- 1930-02-21 FR FR690406D patent/FR690406A/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR690406A (fr) | 1930-09-19 |
GB346511A (enrdf_load_stackoverflow) | 1931-04-16 |
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