US1767076A - Lubricant and method of producing the same - Google Patents
Lubricant and method of producing the same Download PDFInfo
- Publication number
- US1767076A US1767076A US166593A US16659327A US1767076A US 1767076 A US1767076 A US 1767076A US 166593 A US166593 A US 166593A US 16659327 A US16659327 A US 16659327A US 1767076 A US1767076 A US 1767076A
- Authority
- US
- United States
- Prior art keywords
- degras
- soap
- zinc
- petroleum
- lubricant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000314 lubricant Substances 0.000 title description 6
- 238000000034 method Methods 0.000 title description 3
- 239000003208 petroleum Substances 0.000 description 12
- 239000000344 soap Substances 0.000 description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 10
- 239000011701 zinc Substances 0.000 description 10
- 229910052725 zinc Inorganic materials 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- 239000012188 paraffin wax Substances 0.000 description 9
- 239000010687 lubricating oil Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
Definitions
- the invention relates to an improved lubricant and the method of producing the same. 4
- the object of the invention is to so treat 5 petroleum lubricating oils having paraffin bases as to reduce-the cold test thereof so that heavier oils, which contain a better body and are better lubricants, can be used in cold Weather without becoming too stifi and solid for practical purposes.
- my invention am able to take petroleum lubricatin oils having parflin bases, such as are usable for lubricating automobiles or other machinery and reduce the cold test thereof, for example, Mid-continent or Pennsylvania petroleum oil and similar paraffin oils, having a viscosity test of two hundred seconds at one hundred degrees F. Saybolt Universal Viscosimeter and a cold test of thirty-five degrees F. and reduce the cold test to zero F. without affecting the lubricating or other qualities of the oil.
- my invention I take degras of any suitable kind, including American degras, and make a zinc degras soap therefrom.
- Degras contains a mixture of fats made from various fatty acids, and I may make this soap directly by boiling zinc oxide (ZnO) and the degras together until completely saponified, or I may make it indirectly.
- ZnO zinc oxide
- the zinc replaces the sodium with the result that I get a zinc soap and sodium sulphate (NfigSO the-latter being soluble and easily washed out, leaving the resultant waterinsoluble zinc degras soap.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
Patented June 24, 1930 UNITED STATES PATENT OFFICE RUSH NICHOLAS J'ARMAN, OF MILWAUKEE, WISCONSIN, ASSIGNOR TO LINDSAY- MCMILLAN COMPANY, A CORPORATION OF WISCONSIN LUBRICANT AND METHOD OF PRODUCING THE SAME No Drawing.
The invention relates to an improved lubricant and the method of producing the same. 4
The object of the invention is to so treat 5 petroleum lubricating oils having paraffin bases as to reduce-the cold test thereof so that heavier oils, which contain a better body and are better lubricants, can be used in cold Weather without becoming too stifi and solid for practical purposes.
By my invention I am able to take petroleum lubricatin oils having parflin bases, such as are usable for lubricating automobiles or other machinery and reduce the cold test thereof, for example, Mid-continent or Pennsylvania petroleum oil and similar paraffin oils, having a viscosity test of two hundred seconds at one hundred degrees F. Saybolt Universal Viscosimeter and a cold test of thirty-five degrees F. and reduce the cold test to zero F. without affecting the lubricating or other qualities of the oil. In carrying out my invention I take degras of any suitable kind, including American degras, and make a zinc degras soap therefrom. Degras, as is well known, contains a mixture of fats made from various fatty acids, and I may make this soap directly by boiling zinc oxide (ZnO) and the degras together until completely saponified, or I may make it indirectly. In the latter case I take degras and make a sodium soap therefrom with sodium hydroxide (Nz OH) and this soap is then dissolved in water, zinc sulphate (ZnSO in solution added thereto and the mixture may then be heated to hasten the action, although heating is not necessary. The zinc replaces the sodium with the result that I get a zinc soap and sodium sulphate (NfigSO the-latter being soluble and easily washed out, leaving the resultant waterinsoluble zinc degras soap.
In either case I obtain a product of zinc degras soap which when added to the petroleum lubricating oil having a paraffin base I desire to treat reduces the cold testthereof.
For practical commercial purposes I dissolve the soap so made in a small amount of lubricating oil, generally a ten per cent solution, which I call my base. If now I de- Applieation filed February 7, 1927. Serial No. 166,593.
sire to reduce the cold test of a particular petroleum lubricating oil having a paraffin base, such as one of the examples given above, I mix it with some of this base, for example, ten per cent base and ninety per 5 cent of the lubricating oil, such as I have indicated, which gives a one per cent zinc degras soap solution. This one per cent of zinc degras soap will reduce the cold test in the case of a Mid-continent or Pennsylvania petroleum oil having a paraffin base of twohundred viscosity test at one hundred degrees Fahrenheit from thirty-five degrees F. down to zero F.
While I have described In invention in connection with two known ubricating petroleum oils having paraffin bases, having a cold test of thirty-five degrees F., it will be understood that the zinc degras soap may be used with other lubricating petroleum oils having paraffin bases or greases made from petroleum oils having paraffin bases to reduce the cold test thereof and hence I desire it to be understood that this invention is not to be limited to any specific oil or proportion of parts except as such limita tions are specified in the claims.
What I claim as my invention is:
1. As a new lubricant, a petroleum oil having a parafiin base and having a small so amount of zinc degras 'soap added thereto to reduce the cold test of said oil.
2. As a new base for treating petroleum lubricants having paraffin bases to reduce the cold test thereof, a petroleum lubricating oil having zinc degras soap added-thereto in an amount not to exceed'ten per cent of the mixture. i
In testimony whereof, I affix my signature.
RUSH NICHOLAS JARMAN.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US166593A US1767076A (en) | 1927-02-07 | 1927-02-07 | Lubricant and method of producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US166593A US1767076A (en) | 1927-02-07 | 1927-02-07 | Lubricant and method of producing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1767076A true US1767076A (en) | 1930-06-24 |
Family
ID=22603951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US166593A Expired - Lifetime US1767076A (en) | 1927-02-07 | 1927-02-07 | Lubricant and method of producing the same |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1767076A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2439820A (en) * | 1941-10-14 | 1948-04-20 | Standard Oil Co | Compound lubricants |
| US3367869A (en) * | 1965-06-18 | 1968-02-06 | British Petroleum Co | Alkaline lubricating oil |
| US4478731A (en) * | 1978-09-08 | 1984-10-23 | Centre Stephanois De Recherches Mecaniques Hydromecanique Et Frottement Zone Industrielle | Aqueous lubricating composition and process of manufacturing same |
| EP3845622A1 (en) | 2020-01-03 | 2021-07-07 | Indian Oil Corporation Limited | High temperature zinc complex grease |
-
1927
- 1927-02-07 US US166593A patent/US1767076A/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2439820A (en) * | 1941-10-14 | 1948-04-20 | Standard Oil Co | Compound lubricants |
| US3367869A (en) * | 1965-06-18 | 1968-02-06 | British Petroleum Co | Alkaline lubricating oil |
| US4478731A (en) * | 1978-09-08 | 1984-10-23 | Centre Stephanois De Recherches Mecaniques Hydromecanique Et Frottement Zone Industrielle | Aqueous lubricating composition and process of manufacturing same |
| EP3845622A1 (en) | 2020-01-03 | 2021-07-07 | Indian Oil Corporation Limited | High temperature zinc complex grease |
| US11236285B2 (en) | 2020-01-03 | 2022-02-01 | Indian Oil Corporation Limited | High temperature zinc complex grease |
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