US1795491A - Sulfonic lubricating material and process of making the same - Google Patents
Sulfonic lubricating material and process of making the same Download PDFInfo
- Publication number
- US1795491A US1795491A US736634A US73663424A US1795491A US 1795491 A US1795491 A US 1795491A US 736634 A US736634 A US 736634A US 73663424 A US73663424 A US 73663424A US 1795491 A US1795491 A US 1795491A
- Authority
- US
- United States
- Prior art keywords
- lubricant
- sulfonic
- water
- tallow
- making
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
- C10M135/10—Sulfonic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
- Y10S516/04—Protein or carboxylic compound containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/924—Significant dispersive or manipulative operation or step in making or stabilizing colloid system
- Y10S516/928—Mixing combined with non-mixing operation or step, successively or simultaneously, e.g. heating, cooling, ph change, ageing, milling
Definitions
- Patented 10, 1931 UNITED STATES PATENT- OFFICE HERBERT I. JOHNSON, OF BROOKLYN, NEW YORK: ASSIGNOR TO STANDARD OIL DEVELOPMENT COMPANY, A CORPORATION OF DELAWARE '7 SUI-FONIC LUBRICATIITG NIATERIAL AND PROCESS OF MAKING THE SAME No Drawing.
- This invention relates to improvements in lubricants of the type comprising sulfonic compounds derived from mineral oils and the like.
- the lubricant contains a mineral oil sulfonic compound, an animal or vegetable oil or fat, and water. While the lubricant has many uses, it is especially advantageous in the drawing and polishing of steel, copper, brass, and nickel tubing or wire and in general to any operations in which metal is cold drawn to shape with the aid of a lubricant.
- the sulfonic compound I may use the green sulfonic acid which is the principal organic acid occurring in the sludge formed in the treatment of petroleum lubricating oil with strong sulfuric acid.
- the sulfonic acid maybe urified in any suitable way, if desired.
- I refer to use sulfonic acid salts, which may be readily repared by neutralizing the acid by a suita le base, for example sodium hydroxide.
- the sulfonic compound is incorporated with an oleaginous material having lubricating properties, such 2 as animal or vegetable oils, fats, or fatty acids, especially tallow, palm oil, cocoanut oil, cottonseedoil, and oleic acid.
- an oleaginous material having lubricating properties such 2 as animal or vegetable oils, fats, or fatty acids, especially tallow, palm oil, cocoanut oil, cottonseedoil, and oleic acid.
- Various other materials of this type, as well as mixtures of the same, may be used.
- suflicient water there is added suflicient water to make a total of 100 parts. For many purposes 20 parts sodium sulfonate, 5 parts tallow and 75 parts 40 of water ap ear tobe most satisfactory.
- This mixture may beprepared for use by heating, with or without agitation.
- sodium sulfonate is preferably first dissolved 3.
- Process according to claim 1 in-which the mixture is heated simultaneously producing some boiling, whereby distribution of the ingredients is effected.
- a lubricant comprising a metallic salt of a sulfonic compound obtained from the sludge formed by treating petroleum lubrieating oil with strong sulphuric acid and a non-mineral, substantially unsaponified' oleaginous material.
- a lubricant comprisin a metallic salt of the green sulfonic acid 0 taind from the sludge formed by treating petroleum lubricating oil with strong sulphuric acid a normally solid, non-mineral, substantially unsaponified oleaginous material.
- a lubricant comprising a sodium salt of the green sulfonic acid obtained from the sludge formed by treating petroleum lubrieating oil with strong sulphuric acid and unsap'onified tallow.
- a lubricant comprising a sodium salt of the green sulfonic acid obtained from the sludge formed by treating petroleum lubricating oil with strong sulphuric acid -30 parts,'and tallow 1-15 parts.
- a lubricant comprising a, sodium salt of the green sulfonic aci obtained from the 15 sludge formed by treating petroleum lubricating oil with strong sulphuric acid parts, and tallow 5 parts.
- a lubricant comprising a salt of the green sulfonic acid obtained from the sludge 20 formed by treating petroleum lubricating oil with strong sulphuric acid, a normally solid, substantially unsaponified lubricant material, and water.
- a lubricant comprising a salt of the 5 green sulfonic acid obtained from the sludge formed by treating petroleum lubricating oil with strong sulphuric acid, unsaponified tallow, and water.
- a lubricant comprising a salt of the green sulfonic acid obtained from the sludge formed by treating petroleum lubricating oil wlth strong sulphuric acid 15-30%, tallow 1-15%, and water to make up to 100%.
- a lubricant comprising a sodium salt of the green sulfonic acid obtained from the sludge formed bytreating petroleum lubrieating oil with' strong sulphuric acid 20%, t'allow 5%, and water 75%.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
Patented 10, 1931 UNITED STATES PATENT- OFFICE HERBERT I. JOHNSON, OF BROOKLYN, NEW YORK: ASSIGNOR TO STANDARD OIL DEVELOPMENT COMPANY, A CORPORATION OF DELAWARE '7 SUI-FONIC LUBRICATIITG NIATERIAL AND PROCESS OF MAKING THE SAME No Drawing.
This invention relates to improvements in lubricants of the type comprising sulfonic compounds derived from mineral oils and the like. In a referred embodiment of the invention the lubricant contains a mineral oil sulfonic compound, an animal or vegetable oil or fat, and water. While the lubricant has many uses, it is especially advantageous in the drawing and polishing of steel, copper, brass, and nickel tubing or wire and in general to any operations in which metal is cold drawn to shape with the aid of a lubricant. As the sulfonic compound, I may use the green sulfonic acid which is the principal organic acid occurring in the sludge formed in the treatment of petroleum lubricating oil with strong sulfuric acid. The sulfonic acid maybe urified in any suitable way, if desired. rdinarily I refer to use sulfonic acid salts, which may be readily repared by neutralizing the acid by a suita le base, for example sodium hydroxide. The sulfonic compound is incorporated with an oleaginous material having lubricating properties, such 2 as animal or vegetable oils, fats, or fatty acids, especially tallow, palm oil, cocoanut oil, cottonseedoil, and oleic acid. Various other materials of this type, as well as mixtures of the same, may be used.
The following example is illustrative of the invention: For the preparation of a lubricant especially adapted for use in die-drawing meta-ls, 15 to arts of a water soluble sodium sulfonate, erived from petroleum '35 hydrocarbons, are mixed with 1 to 15 arts Application filed September 8, 1924. Serial No. 736,634.
in water, which may be heated by steam coils or other suitable means. @lhe tallow is then added and liquefies in the hot solution. The steam pipes may' advantageously b'e sufficiently hot to produce some boiling in the solution. In this way proper admixture of the tallow is secured. The pipes or the like to be drawn are immersed in the hot mixture and are preferably allowedto dry after removal before being drawn. The lubricant described is an excellent dr awing compound, as it gives a tough coating which is not easily displaced and has adequate lubricating properties to prevent abrasion or stickingof the rubbing surfaces.
Heating themixture to an average temerature of 180 F. with steam coils has been ound to be satisfactory, but other temperatures and means of heat-ing may'of course be employed, depending upon the particu-' lar character of the ingredients used and the results sought. Various modifications of the compositions and procedures described may also be made within the scope of the appended claims.
I claim:
1. Process of making a lubricant, comprising heatin together a salt of a substantially water-solu le green sulfonic acid obtained from the sludge formed by treating petroleum lubricating oil with strong sulphuric acid, water, and a fatty ole'aginous material, under conditions to effect the distribution of the latter in'the water. J
2. Process according to claim 1 in which of tallow and to the mixture so pro need .the mixture is heated to. about 180 F.
there is added suflicient water to make a total of 100 parts. For many purposes 20 parts sodium sulfonate, 5 parts tallow and 75 parts 40 of water ap ear tobe most satisfactory.
' However, I 0 not wish to be limited to any of the proportions stated, as these will vary with the urpose for 'WlllCh the lubricant is to be used Water may be incorporated also in any desired amount. A suitable composition for die-drawing purposes is sodium sulfonate 20%, tallow 5%, water 75%.
This mixture may beprepared for use by heating, with or without agitation. The
sodium sulfonate is preferably first dissolved 3. Process according to claim 1 in-which the mixture is heated simultaneously producing some boiling, whereby distribution of the ingredients is effected.
4. A lubricant comprising a metallic salt of a sulfonic compound obtained from the sludge formed by treating petroleum lubrieating oil with strong sulphuric acid and a non-mineral, substantially unsaponified' oleaginous material.
5. A lubricant comprisin a metallic salt of the green sulfonic acid 0 taind from the sludge formed by treating petroleum lubricating oil with strong sulphuric acid a normally solid, non-mineral, substantially unsaponified oleaginous material.
6. A lubricant comprising a sodium salt of the green sulfonic acid obtained from the sludge formed by treating petroleum lubrieating oil with strong sulphuric acid and unsap'onified tallow.
7. A lubricant comprising a sodium salt of the green sulfonic acid obtained from the sludge formed by treating petroleum lubricating oil with strong sulphuric acid -30 parts,'and tallow 1-15 parts.
8. A lubricant comprising a, sodium salt of the green sulfonic aci obtained from the 15 sludge formed by treating petroleum lubricating oil with strong sulphuric acid parts, and tallow 5 parts. 9. A lubricant comprising a salt of the green sulfonic acid obtained from the sludge 20 formed by treating petroleum lubricating oil with strong sulphuric acid, a normally solid, substantially unsaponified lubricant material, and water.
10. A lubricant comprising a salt of the 5 green sulfonic acid obtained from the sludge formed by treating petroleum lubricating oil with strong sulphuric acid, unsaponified tallow, and water.
11. A lubricant comprising a salt of the green sulfonic acid obtained from the sludge formed by treating petroleum lubricating oil wlth strong sulphuric acid 15-30%, tallow 1-15%, and water to make up to 100%.
12. A lubricant comprising a sodium salt of the green sulfonic acid obtained from the sludge formed bytreating petroleum lubrieating oil with' strong sulphuric acid 20%, t'allow 5%, and water 75%.
HERBERT L. JOHNSON.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US736634A US1795491A (en) | 1924-09-08 | 1924-09-08 | Sulfonic lubricating material and process of making the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US736634A US1795491A (en) | 1924-09-08 | 1924-09-08 | Sulfonic lubricating material and process of making the same |
Publications (1)
Publication Number | Publication Date |
---|---|
US1795491A true US1795491A (en) | 1931-03-10 |
Family
ID=24960645
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US736634A Expired - Lifetime US1795491A (en) | 1924-09-08 | 1924-09-08 | Sulfonic lubricating material and process of making the same |
Country Status (1)
Country | Link |
---|---|
US (1) | US1795491A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2578689A (en) * | 1946-08-27 | 1951-12-18 | Michael W Freeman | Lubricant containing a reaction product of water-soluble sulfonic acids and phosphorus sulfide |
DE747422C (en) * | 1941-01-12 | 1952-10-13 | Dr Fritz Singer | Process for the non-cutting deformation of iron and steel |
US2914975A (en) * | 1953-05-18 | 1959-12-01 | Pennzoil Co | Processes for cold metal reduction |
US3364143A (en) * | 1962-03-07 | 1968-01-16 | Swift & Co | Method for improving the working properties of metals |
-
1924
- 1924-09-08 US US736634A patent/US1795491A/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE747422C (en) * | 1941-01-12 | 1952-10-13 | Dr Fritz Singer | Process for the non-cutting deformation of iron and steel |
US2578689A (en) * | 1946-08-27 | 1951-12-18 | Michael W Freeman | Lubricant containing a reaction product of water-soluble sulfonic acids and phosphorus sulfide |
US2914975A (en) * | 1953-05-18 | 1959-12-01 | Pennzoil Co | Processes for cold metal reduction |
US3364143A (en) * | 1962-03-07 | 1968-01-16 | Swift & Co | Method for improving the working properties of metals |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2332202A (en) | Lubricating grease manufacture and apparatus therefor | |
GB537615A (en) | Improved grease composition and method for making the same | |
US1795491A (en) | Sulfonic lubricating material and process of making the same | |
US2450254A (en) | Lithium base grease and method of preparing the same | |
US1463092A (en) | Lubricant and process of preparing same | |
US2121748A (en) | Stable lime soap grease | |
US2352811A (en) | Lubricant | |
USRE22299E (en) | Lubricating composition | |
US2353830A (en) | Air pump lubricant | |
US2151788A (en) | Acid addition compounds of higher fatty acid amides | |
US1971750A (en) | Grease and its manufacture | |
US1767076A (en) | Lubricant and method of producing the same | |
US2659695A (en) | Lubricating greases | |
US2383904A (en) | Lubricant manufacture | |
US1920202A (en) | Lubricating composition | |
US2626898A (en) | Process for preparing alkali metal greases | |
US1871864A (en) | Lubricating grease | |
US2672976A (en) | Drawing lubricant compositions | |
US1939995A (en) | Lubricating oil | |
US2442828A (en) | Lubricating greases | |
US1806933A (en) | Of san francisco | |
US2629721A (en) | Sulfurized fatty and waxy materials | |
US2255278A (en) | Short fiber grease | |
US1749251A (en) | Process for making lubricating grease | |
US2070014A (en) | Solid lubricants and method of manufacturing the same |