US2121748A - Stable lime soap grease - Google Patents

Stable lime soap grease Download PDF

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Publication number
US2121748A
US2121748A US83452A US8345236A US2121748A US 2121748 A US2121748 A US 2121748A US 83452 A US83452 A US 83452A US 8345236 A US8345236 A US 8345236A US 2121748 A US2121748 A US 2121748A
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Prior art keywords
grease
lime soap
soap grease
mixture
naphthylamine
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Expired - Lifetime
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US83452A
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George A Suit
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Cities Service Oil Co
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Cities Service Oil Co
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Priority to US83452A priority Critical patent/US2121748A/en
Priority to US129380A priority patent/US2198567A/en
Application granted granted Critical
Publication of US2121748A publication Critical patent/US2121748A/en
Priority to US257206A priority patent/US2289748A/en
Priority to FR867261D priority patent/FR867261A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C10M5/00Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
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    • C10M2201/02Water
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    • C10M2207/02Hydroxy compounds
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2215/065Phenyl-Naphthyl amines
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    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
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    • C10N2010/02Groups 1 or 11
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    • C10N2040/02Bearings
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01Wetting, emulsifying, dispersing, or stabilizing agents

Definitions

  • fatty acids or vfatty :acid oils may be first saponi- Patented June 21, 1938 UNITED STATES PATENT OFFECE STABLE LIME SOAP GREASE No Drawing. Application June 4, 1936, Serial No. 83,452
  • the primary object of the present invention is i the production of a lime soap grease which shall be relatively stable under aging or severe working conditions.
  • Another object is to provide a method of manufacturing a grease having the foregoing characteristics.
  • a mineral oil of 100-200 Saybolt viscosity at 100 F., and :a fatty acid (or lard oil, tallow, etc.) may be mixed, and the mixture heated to about 220 F. with agitation.
  • lime in amount sufficient to neutralize or substantially neutralize and saponify the fatty :acid, which .for example maybe stearic acid.
  • the heating and agitation is continued until a smooth homogeneous :soapoil mixture results, after which additional oil is gradually added to substantially. equalize the proportions by weight of oil and soap. After gradually cooling the mixture to a temperature of about 150 F.
  • ilhe discovery forming the basis of the invention is that the very small amount of phenylstituents of the grease.
  • alpha-naphthylamine employed is efiective in stabilizing the grease, apparently'as a result of some strong stabilizing effect in holding the water in an emulsified dispersion even under severe working conditions.
  • Another advantageous prop- 5 erty of the phenyl-alpha-naphthylamine is that by its use no particular care has to be taken to completely saponify the fatty acid, such as is usually necessary in producing this type of grease; since phenyl-alpha--naphthlyamine present in the amount indicated seemingly inhibits any unstabilizing effect of as much as 0.3% to 0.4% unsaponified fatty acid in the grease.
  • a grease comprising a semi-solid emulsion of heavy mineral oil, fatty acid-lime soap, 1-2% by weight of water, and 0.1'-%-0:2% phenyl-alpha naphthylamine as a stabilizing agent for the emulsion. adapted to prevent separation of its 6 constituents.
  • a method of making grease comprising heating and agitating a mixture of fatty acid-lime soap and heavy mineral oil at a temperature of about-220 F. to produce .a smooth homogeneous base mixture, cooling the mixture to about 150 F. and agitating while gradually admixing therewith about 1-2% by weight of water, 0.1'-%-0.2% of pheny'l-alpha-naphthylamine as a stabilizing agent adapted to prevent separation of the constituents of the grease, and suflicient additional heavy oil to thin the grease to the desired con sistency.
  • a grease composition comprising a homogeneous mixture of a lime soap, a mineral oil, and -a relatively small proportion'of phenyl-alpha- I naphthylamine suflic'ient to stabilize the grease and maintain the same homogeneous under storage and use conditions.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

45 fatty acids or vfatty :acid oils may be first saponi- Patented June 21, 1938 UNITED STATES PATENT OFFECE STABLE LIME SOAP GREASE No Drawing. Application June 4, 1936, Serial No. 83,452
4 Claims.
The primary object of the present invention is i the production of a lime soap grease which shall be relatively stable under aging or severe working conditions.
Another object is to provide a method of manufacturing a grease having the foregoing characteristics. I
With the foregoing objects in View, the invention consists in the improved grease and method of manufacture as hereinafter described and more particularly defined by the accompanying claims.
As an example of the method of making a grease of the type forming the subject of the present invention, a mineral oil of 100-200 Saybolt viscosity at 100 F., and :a fatty acid (or lard oil, tallow, etc.) may be mixed, and the mixture heated to about 220 F. with agitation. To the heated mixture there is added lime in amount sufficient to neutralize or substantially neutralize and saponify the fatty :acid, which .for example maybe stearic acid. The heating and agitation is continued until a smooth homogeneous :soapoil mixture results, after which additional oil is gradually added to substantially. equalize the proportions by weight of oil and soap. After gradually cooling the mixture to a temperature of about 150 F. while continuing the agitation, a small amount of water -(1'%2 iis added togeth- -.er with additional mineral oil containingin solution from 0.1%-0.2% by weight of the finished grease .of p'henyl-a'lpha naphthylamine. The total volume of oil :added to the soap is proportioned in accordance with the "desired consistency of the finished grease. If more convenient, the
fled with lime to produce soap before any of the -.oil is added.
ilhe discovery forming the basis of the invention is that the very small amount of phenylstituents of the grease.
alpha-naphthylamine employed is efiective in stabilizing the grease, apparently'as a result of some strong stabilizing effect in holding the water in an emulsified dispersion even under severe working conditions. Another advantageous prop- 5 erty of the phenyl-alpha-naphthylamine is that by its use no particular care has to be taken to completely saponify the fatty acid, such as is usually necessary in producing this type of grease; since phenyl-alpha--naphthlyamine present in the amount indicated seemingly inhibits any unstabilizing effect of as much as 0.3% to 0.4% unsaponified fatty acid in the grease.
The invention having been thus described,' w'hat .is claimed as new is:
1. A grease comprising a semi-solid emulsion of heavy mineral oil, fatty acid-lime soap, 1-2% by weight of water, and 0.1'-%-0:2% phenyl-alpha naphthylamine as a stabilizing agent for the emulsion. adapted to prevent separation of its 6 constituents.
2. A method of making grease comprising heating and agitating a mixture of fatty acid-lime soap and heavy mineral oil at a temperature of about-220 F. to produce .a smooth homogeneous base mixture, cooling the mixture to about 150 F. and agitating while gradually admixing therewith about 1-2% by weight of water, 0.1'-%-0.2% of pheny'l-alpha-naphthylamine as a stabilizing agent adapted to prevent separation of the constituents of the grease, and suflicient additional heavy oil to thin the grease to the desired con sistency.
3. A grease composition comprising a homogeneous mixture of a lime soap,a mineral oil, and -a relatively small proportion'of phenyl-alpha- I naphthylamine suflic'ient to stabilize the grease and maintain the same homogeneous under storage and use conditions.
4. The process of stabilizing greases containing m a lime soap and mineral oil against separation of their constituents under storage and use conditions, which comprises intimately incorporating in the grease a relatively small proportion of phenyl-alpha-naphthylamine as a stabilizing agent adapted to prevent separation at the con-
US83452A 1936-06-04 1936-06-04 Stable lime soap grease Expired - Lifetime US2121748A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US83452A US2121748A (en) 1936-06-04 1936-06-04 Stable lime soap grease
US129380A US2198567A (en) 1936-06-04 1937-03-06 Driving journal lubricant
US257206A US2289748A (en) 1936-06-04 1939-02-18 Grease composition for lubrication
FR867261D FR867261A (en) 1936-06-04 1940-02-02 Lurifying fat

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US83452A US2121748A (en) 1936-06-04 1936-06-04 Stable lime soap grease
US129380A US2198567A (en) 1936-06-04 1937-03-06 Driving journal lubricant
US257206A US2289748A (en) 1936-06-04 1939-02-18 Grease composition for lubrication

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US2121748A true US2121748A (en) 1938-06-21

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US83452A Expired - Lifetime US2121748A (en) 1936-06-04 1936-06-04 Stable lime soap grease
US129380A Expired - Lifetime US2198567A (en) 1936-06-04 1937-03-06 Driving journal lubricant
US257206A Expired - Lifetime US2289748A (en) 1936-06-04 1939-02-18 Grease composition for lubrication

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US129380A Expired - Lifetime US2198567A (en) 1936-06-04 1937-03-06 Driving journal lubricant
US257206A Expired - Lifetime US2289748A (en) 1936-06-04 1939-02-18 Grease composition for lubrication

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FR (1) FR867261A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2443026A (en) * 1946-01-23 1948-06-08 Texas Co Stabilized grease compositions
US3320165A (en) * 1965-05-11 1967-05-16 Mobil Oil Corp Lubricants and fuels stabilized with antioxidants for high and low temperature conditions

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2428123A (en) * 1945-05-23 1947-09-30 Cities Service Oil Co Soda base grease
US2585182A (en) * 1947-03-18 1952-02-12 Union Carbide & Carbon Corp Grease lubricant
US2468099A (en) * 1947-10-01 1949-04-26 Standard Oil Dev Co High-temperature grease
US2503969A (en) * 1948-03-30 1950-04-11 Standard Oil Dev Co High-temperature lubricating grease
US2515133A (en) * 1948-06-30 1950-07-11 Standard Oil Dev Co Lubricating grease
US2545114A (en) * 1948-07-30 1951-03-13 Gulf Oil Corp Lubricating grease composition
US2652362A (en) * 1950-08-15 1953-09-15 Shell Dev Grease composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2443026A (en) * 1946-01-23 1948-06-08 Texas Co Stabilized grease compositions
US3320165A (en) * 1965-05-11 1967-05-16 Mobil Oil Corp Lubricants and fuels stabilized with antioxidants for high and low temperature conditions

Also Published As

Publication number Publication date
US2289748A (en) 1942-07-14
FR867261A (en) 1941-10-10
US2198567A (en) 1940-04-23

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