US2121748A - Stable lime soap grease - Google Patents
Stable lime soap grease Download PDFInfo
- Publication number
- US2121748A US2121748A US83452A US8345236A US2121748A US 2121748 A US2121748 A US 2121748A US 83452 A US83452 A US 83452A US 8345236 A US8345236 A US 8345236A US 2121748 A US2121748 A US 2121748A
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- United States
- Prior art keywords
- grease
- lime soap
- soap grease
- mixture
- naphthylamine
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M5/00—Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/063—Peroxides
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/026—Butene
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/14—Synthetic waxes, e.g. polythene waxes
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
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- C—CHEMISTRY; METALLURGY
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/17—Fisher Tropsch reaction products
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- C—CHEMISTRY; METALLURGY
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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- C—CHEMISTRY; METALLURGY
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- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/025—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with condensed rings
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- C10M2207/046—Hydroxy ethers
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- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2207/20—Rosin acids
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- C—CHEMISTRY; METALLURGY
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- C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
- C10M2211/042—Alcohols; Ethers; Aldehydes; Ketones
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10M2211/06—Perfluorinated compounds
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
- C10M2215/065—Phenyl-Naphthyl amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/066—Arylene diamines
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/20—Containing nitrogen-to-oxygen bonds
- C10M2215/202—Containing nitrogen-to-oxygen bonds containing nitro groups
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
Definitions
- fatty acids or vfatty :acid oils may be first saponi- Patented June 21, 1938 UNITED STATES PATENT OFFECE STABLE LIME SOAP GREASE No Drawing. Application June 4, 1936, Serial No. 83,452
- the primary object of the present invention is i the production of a lime soap grease which shall be relatively stable under aging or severe working conditions.
- Another object is to provide a method of manufacturing a grease having the foregoing characteristics.
- a mineral oil of 100-200 Saybolt viscosity at 100 F., and :a fatty acid (or lard oil, tallow, etc.) may be mixed, and the mixture heated to about 220 F. with agitation.
- lime in amount sufficient to neutralize or substantially neutralize and saponify the fatty :acid, which .for example maybe stearic acid.
- the heating and agitation is continued until a smooth homogeneous :soapoil mixture results, after which additional oil is gradually added to substantially. equalize the proportions by weight of oil and soap. After gradually cooling the mixture to a temperature of about 150 F.
- ilhe discovery forming the basis of the invention is that the very small amount of phenylstituents of the grease.
- alpha-naphthylamine employed is efiective in stabilizing the grease, apparently'as a result of some strong stabilizing effect in holding the water in an emulsified dispersion even under severe working conditions.
- Another advantageous prop- 5 erty of the phenyl-alpha-naphthylamine is that by its use no particular care has to be taken to completely saponify the fatty acid, such as is usually necessary in producing this type of grease; since phenyl-alpha--naphthlyamine present in the amount indicated seemingly inhibits any unstabilizing effect of as much as 0.3% to 0.4% unsaponified fatty acid in the grease.
- a grease comprising a semi-solid emulsion of heavy mineral oil, fatty acid-lime soap, 1-2% by weight of water, and 0.1'-%-0:2% phenyl-alpha naphthylamine as a stabilizing agent for the emulsion. adapted to prevent separation of its 6 constituents.
- a method of making grease comprising heating and agitating a mixture of fatty acid-lime soap and heavy mineral oil at a temperature of about-220 F. to produce .a smooth homogeneous base mixture, cooling the mixture to about 150 F. and agitating while gradually admixing therewith about 1-2% by weight of water, 0.1'-%-0.2% of pheny'l-alpha-naphthylamine as a stabilizing agent adapted to prevent separation of the constituents of the grease, and suflicient additional heavy oil to thin the grease to the desired con sistency.
- a grease composition comprising a homogeneous mixture of a lime soap, a mineral oil, and -a relatively small proportion'of phenyl-alpha- I naphthylamine suflic'ient to stabilize the grease and maintain the same homogeneous under storage and use conditions.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
45 fatty acids or vfatty :acid oils may be first saponi- Patented June 21, 1938 UNITED STATES PATENT OFFECE STABLE LIME SOAP GREASE No Drawing. Application June 4, 1936, Serial No. 83,452
4 Claims.
The primary object of the present invention is i the production of a lime soap grease which shall be relatively stable under aging or severe working conditions.
Another object is to provide a method of manufacturing a grease having the foregoing characteristics. I
With the foregoing objects in View, the invention consists in the improved grease and method of manufacture as hereinafter described and more particularly defined by the accompanying claims.
As an example of the method of making a grease of the type forming the subject of the present invention, a mineral oil of 100-200 Saybolt viscosity at 100 F., and :a fatty acid (or lard oil, tallow, etc.) may be mixed, and the mixture heated to about 220 F. with agitation. To the heated mixture there is added lime in amount sufficient to neutralize or substantially neutralize and saponify the fatty :acid, which .for example maybe stearic acid. The heating and agitation is continued until a smooth homogeneous :soapoil mixture results, after which additional oil is gradually added to substantially. equalize the proportions by weight of oil and soap. After gradually cooling the mixture to a temperature of about 150 F. while continuing the agitation, a small amount of water -(1'%2 iis added togeth- -.er with additional mineral oil containingin solution from 0.1%-0.2% by weight of the finished grease .of p'henyl-a'lpha naphthylamine. The total volume of oil :added to the soap is proportioned in accordance with the "desired consistency of the finished grease. If more convenient, the
fled with lime to produce soap before any of the -.oil is added.
ilhe discovery forming the basis of the invention is that the very small amount of phenylstituents of the grease.
alpha-naphthylamine employed is efiective in stabilizing the grease, apparently'as a result of some strong stabilizing effect in holding the water in an emulsified dispersion even under severe working conditions. Another advantageous prop- 5 erty of the phenyl-alpha-naphthylamine is that by its use no particular care has to be taken to completely saponify the fatty acid, such as is usually necessary in producing this type of grease; since phenyl-alpha--naphthlyamine present in the amount indicated seemingly inhibits any unstabilizing effect of as much as 0.3% to 0.4% unsaponified fatty acid in the grease.
The invention having been thus described,' w'hat .is claimed as new is:
1. A grease comprising a semi-solid emulsion of heavy mineral oil, fatty acid-lime soap, 1-2% by weight of water, and 0.1'-%-0:2% phenyl-alpha naphthylamine as a stabilizing agent for the emulsion. adapted to prevent separation of its 6 constituents.
2. A method of making grease comprising heating and agitating a mixture of fatty acid-lime soap and heavy mineral oil at a temperature of about-220 F. to produce .a smooth homogeneous base mixture, cooling the mixture to about 150 F. and agitating while gradually admixing therewith about 1-2% by weight of water, 0.1'-%-0.2% of pheny'l-alpha-naphthylamine as a stabilizing agent adapted to prevent separation of the constituents of the grease, and suflicient additional heavy oil to thin the grease to the desired con sistency.
3. A grease composition comprising a homogeneous mixture of a lime soap,a mineral oil, and -a relatively small proportion'of phenyl-alpha- I naphthylamine suflic'ient to stabilize the grease and maintain the same homogeneous under storage and use conditions.
4. The process of stabilizing greases containing m a lime soap and mineral oil against separation of their constituents under storage and use conditions, which comprises intimately incorporating in the grease a relatively small proportion of phenyl-alpha-naphthylamine as a stabilizing agent adapted to prevent separation at the con-
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US83452A US2121748A (en) | 1936-06-04 | 1936-06-04 | Stable lime soap grease |
US129380A US2198567A (en) | 1936-06-04 | 1937-03-06 | Driving journal lubricant |
US257206A US2289748A (en) | 1936-06-04 | 1939-02-18 | Grease composition for lubrication |
FR867261D FR867261A (en) | 1936-06-04 | 1940-02-02 | Lurifying fat |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US83452A US2121748A (en) | 1936-06-04 | 1936-06-04 | Stable lime soap grease |
US129380A US2198567A (en) | 1936-06-04 | 1937-03-06 | Driving journal lubricant |
US257206A US2289748A (en) | 1936-06-04 | 1939-02-18 | Grease composition for lubrication |
Publications (1)
Publication Number | Publication Date |
---|---|
US2121748A true US2121748A (en) | 1938-06-21 |
Family
ID=22178426
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US83452A Expired - Lifetime US2121748A (en) | 1936-06-04 | 1936-06-04 | Stable lime soap grease |
US129380A Expired - Lifetime US2198567A (en) | 1936-06-04 | 1937-03-06 | Driving journal lubricant |
US257206A Expired - Lifetime US2289748A (en) | 1936-06-04 | 1939-02-18 | Grease composition for lubrication |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US129380A Expired - Lifetime US2198567A (en) | 1936-06-04 | 1937-03-06 | Driving journal lubricant |
US257206A Expired - Lifetime US2289748A (en) | 1936-06-04 | 1939-02-18 | Grease composition for lubrication |
Country Status (2)
Country | Link |
---|---|
US (3) | US2121748A (en) |
FR (1) | FR867261A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2443026A (en) * | 1946-01-23 | 1948-06-08 | Texas Co | Stabilized grease compositions |
US3320165A (en) * | 1965-05-11 | 1967-05-16 | Mobil Oil Corp | Lubricants and fuels stabilized with antioxidants for high and low temperature conditions |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2428123A (en) * | 1945-05-23 | 1947-09-30 | Cities Service Oil Co | Soda base grease |
US2585182A (en) * | 1947-03-18 | 1952-02-12 | Union Carbide & Carbon Corp | Grease lubricant |
US2468099A (en) * | 1947-10-01 | 1949-04-26 | Standard Oil Dev Co | High-temperature grease |
US2503969A (en) * | 1948-03-30 | 1950-04-11 | Standard Oil Dev Co | High-temperature lubricating grease |
US2515133A (en) * | 1948-06-30 | 1950-07-11 | Standard Oil Dev Co | Lubricating grease |
US2545114A (en) * | 1948-07-30 | 1951-03-13 | Gulf Oil Corp | Lubricating grease composition |
US2652362A (en) * | 1950-08-15 | 1953-09-15 | Shell Dev | Grease composition |
-
1936
- 1936-06-04 US US83452A patent/US2121748A/en not_active Expired - Lifetime
-
1937
- 1937-03-06 US US129380A patent/US2198567A/en not_active Expired - Lifetime
-
1939
- 1939-02-18 US US257206A patent/US2289748A/en not_active Expired - Lifetime
-
1940
- 1940-02-02 FR FR867261D patent/FR867261A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2443026A (en) * | 1946-01-23 | 1948-06-08 | Texas Co | Stabilized grease compositions |
US3320165A (en) * | 1965-05-11 | 1967-05-16 | Mobil Oil Corp | Lubricants and fuels stabilized with antioxidants for high and low temperature conditions |
Also Published As
Publication number | Publication date |
---|---|
US2289748A (en) | 1942-07-14 |
FR867261A (en) | 1941-10-10 |
US2198567A (en) | 1940-04-23 |
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