US1661881A - Treatment of cellulosic fabrics - Google Patents

Treatment of cellulosic fabrics Download PDF

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Publication number
US1661881A
US1661881A US153720A US15372026A US1661881A US 1661881 A US1661881 A US 1661881A US 153720 A US153720 A US 153720A US 15372026 A US15372026 A US 15372026A US 1661881 A US1661881 A US 1661881A
Authority
US
United States
Prior art keywords
caustic
fabric
solution
cuprammonium
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US153720A
Other languages
English (en)
Inventor
Goncz Denis De
Albert S Jones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ARNOLD PRINT WORKS
Original Assignee
ARNOLD PRINT WORKS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL22722D priority Critical patent/NL22722C/xx
Priority to BE344897D priority patent/BE344897A/xx
Priority to NL22723D priority patent/NL22723C/xx
Priority to NL22724D priority patent/NL22724C/xx
Priority to US739201A priority patent/US1661879A/en
Priority to US153720A priority patent/US1661881A/en
Application filed by ARNOLD PRINT WORKS filed Critical ARNOLD PRINT WORKS
Priority to GB1792/27A priority patent/GB276877A/en
Priority to FR630279D priority patent/FR630279A/fr
Priority to DEA50382D priority patent/DE497408C/de
Priority to GB23147/27A priority patent/GB282002A/en
Priority to DEP56221D priority patent/DE528492C/de
Application granted granted Critical
Publication of US1661881A publication Critical patent/US1661881A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/05Cellulose or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D06M11/42Oxides or hydroxides of copper, silver or gold
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
    • D06M11/62Complexes of metal oxides or complexes of metal salts with ammonia or with organic amines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
    • D06M17/02Producing multi-layer textile fabrics by applying cellulose derivatives as adhesives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06QDECORATING TEXTILES
    • D06Q1/00Decorating textiles

Definitions

  • This invention relates to methods of treating cellulosic materials such as, for example, cotton fabrics and the like.
  • One of the objects of the invention is to alter the physical character of woven cellulosic fabrics so as to enhance its appearance andgive to fabrics other than linen an appearance and quality closely resembling linen.
  • Another object of the invention is to produce certain novel effects in cellulosic fabrics by a printing or analogous operation in which the appearance and quality of the fabric are physically altered in accordance with a predetermined design or figure.
  • 16 still further object of the invention is to produce an improved laminated fabric in which the adhesion of a plurality of plies 0f cellulosic fabric is obtained to such a high degree as-to successfully withstand all ordl- 20 nary handling and treatments, such as laundering, without the plies becoming separated.
  • One of the features of the present invention is in the nature of an improvement upon the process therein setforth and it difiers from the aforesaid treatment in that the cellulosic material impregnated with caustic alkali (caustic soda or caustic potash) is allowed to dry before the subsequent treatment with the cuprammonium solution.
  • caustic alkali caustic soda or caustic potash
  • This drying of the impregnated fabric has the effect of further intensifying the action 7 of the cuprammonium solution so that the alteration of the fabric is intensified.
  • caustic of at least 3035 Tw. should be used in this case, as the dried cloth will take up much larger quantities of the copper-ammonia solution, more caustic being required in consequence to activate it.
  • the printing method according to the present application embraces the preliminary impregnation of the cellulosic fabric with caustic alkali and the subsequent treatment with cuprammonium solution, with or without previous drying of the caustic-filled fabric.
  • the printing method also includes the further feature of the use of a thickened paste of cuprammonium solution, so as to facilitate the application of the cuprammonium to the caustic-prepared fabric in the printing operation.
  • the cellulosic material for example cotton fabric, is first impregnated with caustic alkali solution (especially caustic soda or caustic potash) either by padding or by printing, and preferably it is then dried.
  • caustic alkali solution especially caustic soda or caustic potash
  • the strength of caustic may vary from about 15 'lw. up to mercerizing strength and over, according to the effect desired.
  • a satisfactory composition of the printing paste is as follows:
  • the cellulosic fabric may, for example, first be lmpregnated with caustic alkali solution such as caustic soda 30-35 Tw.) and then ried. Thereafter the material containing the dried caustic is padded with cuprammomum solution made up of 400 pounds copper sulphate, 150 gallons water, 80 gallons commercial ammonia.
  • caustic alkali solution such as caustic soda 30-35 Tw.
  • cuprammonium solution upon the fabric contaming the dried caustic is very rapid and a few seconds immersion of the fabric in the cuprammonium solution is sufficient to develop the adhesive qualities, when the plies should be immediately brought together and united by pressure rolls or the like. Thereafter the webs or plies which have been joined together may be passed through the usual tentering machine and thence to the souring and washing operations for the removal of the excess of reagents and the precipitated copper compound produced in the cuprammonium treatment.
  • the cloth is soured in d1- lute sulphuric acid of, for example, 6 Tw., washed in copious water and laundered, dried, ironed or calendered, as may be desired.
  • the duration of treatment in the cuprammonium bath in any of the processes described may amount to, for example, three to five seconds at ordinary tem eratures.
  • T e e ressions natural fibrous material of the. c aracter described and natural cellulosic fabrics of the character described are employed to indicate the well known vegetable fibres such as cotton, jute, linen, ramie and wood, but to exclude esters of cellulose such as the well known'artificial silks and the like.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US153720A 1924-09-22 1926-12-09 Treatment of cellulosic fabrics Expired - Lifetime US1661881A (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
NL22722D NL22722C (enrdf_load_stackoverflow) 1926-12-09
BE344897D BE344897A (enrdf_load_stackoverflow) 1926-12-09
NL22723D NL22723C (enrdf_load_stackoverflow) 1926-12-09
NL22724D NL22724C (enrdf_load_stackoverflow) 1926-12-09
US739201A US1661879A (en) 1924-09-22 1924-09-22 Treatment of cellulosic materials
US153720A US1661881A (en) 1926-12-09 1926-12-09 Treatment of cellulosic fabrics
GB1792/27A GB276877A (en) 1926-12-09 1927-01-21 Improvements in the treatment of cellulosic materials
FR630279D FR630279A (fr) 1926-12-09 1927-03-04 Traitement de matières cellulosiques
DEA50382D DE497408C (de) 1926-12-09 1927-03-20 Verfahren zur Erzeugung leinenartiger Effekte auf cellulosehaltigem Textilgut
GB23147/27A GB282002A (en) 1926-12-09 1927-09-03 Improvements in treatment of cellulosic fabrics
DEP56221D DE528492C (de) 1926-12-09 1927-10-05 Verfahren zur Erzeugung besonderer Effekte auf Baumwollgeweben

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US153720A US1661881A (en) 1926-12-09 1926-12-09 Treatment of cellulosic fabrics

Publications (1)

Publication Number Publication Date
US1661881A true US1661881A (en) 1928-03-06

Family

ID=22548441

Family Applications (1)

Application Number Title Priority Date Filing Date
US153720A Expired - Lifetime US1661881A (en) 1924-09-22 1926-12-09 Treatment of cellulosic fabrics

Country Status (6)

Country Link
US (1) US1661881A (enrdf_load_stackoverflow)
BE (1) BE344897A (enrdf_load_stackoverflow)
DE (1) DE528492C (enrdf_load_stackoverflow)
FR (1) FR630279A (enrdf_load_stackoverflow)
GB (2) GB276877A (enrdf_load_stackoverflow)
NL (3) NL22722C (enrdf_load_stackoverflow)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2749256A (en) * 1954-02-16 1956-06-05 Nat Cylinder Gas Co Process of impregnating cellulosic materials with copper in chemically bound relation with the cellulose

Also Published As

Publication number Publication date
FR630279A (fr) 1927-11-30
BE344897A (enrdf_load_stackoverflow)
NL22722C (enrdf_load_stackoverflow)
GB276877A (en) 1927-09-08
NL22724C (enrdf_load_stackoverflow)
GB282002A (en) 1928-06-07
NL22723C (enrdf_load_stackoverflow)
DE528492C (de) 1931-06-27

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