US1661881A - Treatment of cellulosic fabrics - Google Patents
Treatment of cellulosic fabrics Download PDFInfo
- Publication number
- US1661881A US1661881A US153720A US15372026A US1661881A US 1661881 A US1661881 A US 1661881A US 153720 A US153720 A US 153720A US 15372026 A US15372026 A US 15372026A US 1661881 A US1661881 A US 1661881A
- Authority
- US
- United States
- Prior art keywords
- caustic
- fabric
- solution
- cuprammonium
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 title description 41
- 238000011282 treatment Methods 0.000 title description 14
- 239000003518 caustics Substances 0.000 description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000000463 material Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000003513 alkali Substances 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 6
- 230000009471 action Effects 0.000 description 5
- 235000011121 sodium hydroxide Nutrition 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 244000144992 flock Species 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 235000011118 potassium hydroxide Nutrition 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229920002955 Art silk Polymers 0.000 description 1
- 240000008564 Boehmeria nivea Species 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
- D06M11/42—Oxides or hydroxides of copper, silver or gold
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
- D06M11/62—Complexes of metal oxides or complexes of metal salts with ammonia or with organic amines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M17/00—Producing multi-layer textile fabrics
- D06M17/02—Producing multi-layer textile fabrics by applying cellulose derivatives as adhesives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
Definitions
- This invention relates to methods of treating cellulosic materials such as, for example, cotton fabrics and the like.
- One of the objects of the invention is to alter the physical character of woven cellulosic fabrics so as to enhance its appearance andgive to fabrics other than linen an appearance and quality closely resembling linen.
- Another object of the invention is to produce certain novel effects in cellulosic fabrics by a printing or analogous operation in which the appearance and quality of the fabric are physically altered in accordance with a predetermined design or figure.
- 16 still further object of the invention is to produce an improved laminated fabric in which the adhesion of a plurality of plies 0f cellulosic fabric is obtained to such a high degree as-to successfully withstand all ordl- 20 nary handling and treatments, such as laundering, without the plies becoming separated.
- One of the features of the present invention is in the nature of an improvement upon the process therein setforth and it difiers from the aforesaid treatment in that the cellulosic material impregnated with caustic alkali (caustic soda or caustic potash) is allowed to dry before the subsequent treatment with the cuprammonium solution.
- caustic alkali caustic soda or caustic potash
- This drying of the impregnated fabric has the effect of further intensifying the action 7 of the cuprammonium solution so that the alteration of the fabric is intensified.
- caustic of at least 3035 Tw. should be used in this case, as the dried cloth will take up much larger quantities of the copper-ammonia solution, more caustic being required in consequence to activate it.
- the printing method according to the present application embraces the preliminary impregnation of the cellulosic fabric with caustic alkali and the subsequent treatment with cuprammonium solution, with or without previous drying of the caustic-filled fabric.
- the printing method also includes the further feature of the use of a thickened paste of cuprammonium solution, so as to facilitate the application of the cuprammonium to the caustic-prepared fabric in the printing operation.
- the cellulosic material for example cotton fabric, is first impregnated with caustic alkali solution (especially caustic soda or caustic potash) either by padding or by printing, and preferably it is then dried.
- caustic alkali solution especially caustic soda or caustic potash
- the strength of caustic may vary from about 15 'lw. up to mercerizing strength and over, according to the effect desired.
- a satisfactory composition of the printing paste is as follows:
- the cellulosic fabric may, for example, first be lmpregnated with caustic alkali solution such as caustic soda 30-35 Tw.) and then ried. Thereafter the material containing the dried caustic is padded with cuprammomum solution made up of 400 pounds copper sulphate, 150 gallons water, 80 gallons commercial ammonia.
- caustic alkali solution such as caustic soda 30-35 Tw.
- cuprammonium solution upon the fabric contaming the dried caustic is very rapid and a few seconds immersion of the fabric in the cuprammonium solution is sufficient to develop the adhesive qualities, when the plies should be immediately brought together and united by pressure rolls or the like. Thereafter the webs or plies which have been joined together may be passed through the usual tentering machine and thence to the souring and washing operations for the removal of the excess of reagents and the precipitated copper compound produced in the cuprammonium treatment.
- the cloth is soured in d1- lute sulphuric acid of, for example, 6 Tw., washed in copious water and laundered, dried, ironed or calendered, as may be desired.
- the duration of treatment in the cuprammonium bath in any of the processes described may amount to, for example, three to five seconds at ordinary tem eratures.
- T e e ressions natural fibrous material of the. c aracter described and natural cellulosic fabrics of the character described are employed to indicate the well known vegetable fibres such as cotton, jute, linen, ramie and wood, but to exclude esters of cellulose such as the well known'artificial silks and the like.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL22722D NL22722C (enrdf_load_stackoverflow) | 1926-12-09 | ||
BE344897D BE344897A (enrdf_load_stackoverflow) | 1926-12-09 | ||
NL22723D NL22723C (enrdf_load_stackoverflow) | 1926-12-09 | ||
NL22724D NL22724C (enrdf_load_stackoverflow) | 1926-12-09 | ||
US739201A US1661879A (en) | 1924-09-22 | 1924-09-22 | Treatment of cellulosic materials |
US153720A US1661881A (en) | 1926-12-09 | 1926-12-09 | Treatment of cellulosic fabrics |
GB1792/27A GB276877A (en) | 1926-12-09 | 1927-01-21 | Improvements in the treatment of cellulosic materials |
FR630279D FR630279A (fr) | 1926-12-09 | 1927-03-04 | Traitement de matières cellulosiques |
DEA50382D DE497408C (de) | 1926-12-09 | 1927-03-20 | Verfahren zur Erzeugung leinenartiger Effekte auf cellulosehaltigem Textilgut |
GB23147/27A GB282002A (en) | 1926-12-09 | 1927-09-03 | Improvements in treatment of cellulosic fabrics |
DEP56221D DE528492C (de) | 1926-12-09 | 1927-10-05 | Verfahren zur Erzeugung besonderer Effekte auf Baumwollgeweben |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US153720A US1661881A (en) | 1926-12-09 | 1926-12-09 | Treatment of cellulosic fabrics |
Publications (1)
Publication Number | Publication Date |
---|---|
US1661881A true US1661881A (en) | 1928-03-06 |
Family
ID=22548441
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US153720A Expired - Lifetime US1661881A (en) | 1924-09-22 | 1926-12-09 | Treatment of cellulosic fabrics |
Country Status (6)
Country | Link |
---|---|
US (1) | US1661881A (enrdf_load_stackoverflow) |
BE (1) | BE344897A (enrdf_load_stackoverflow) |
DE (1) | DE528492C (enrdf_load_stackoverflow) |
FR (1) | FR630279A (enrdf_load_stackoverflow) |
GB (2) | GB276877A (enrdf_load_stackoverflow) |
NL (3) | NL22722C (enrdf_load_stackoverflow) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2749256A (en) * | 1954-02-16 | 1956-06-05 | Nat Cylinder Gas Co | Process of impregnating cellulosic materials with copper in chemically bound relation with the cellulose |
-
0
- NL NL22724D patent/NL22724C/xx active
- NL NL22723D patent/NL22723C/xx active
- BE BE344897D patent/BE344897A/xx unknown
- NL NL22722D patent/NL22722C/xx active
-
1926
- 1926-12-09 US US153720A patent/US1661881A/en not_active Expired - Lifetime
-
1927
- 1927-01-21 GB GB1792/27A patent/GB276877A/en not_active Expired
- 1927-03-04 FR FR630279D patent/FR630279A/fr not_active Expired
- 1927-09-03 GB GB23147/27A patent/GB282002A/en not_active Expired
- 1927-10-05 DE DEP56221D patent/DE528492C/de not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR630279A (fr) | 1927-11-30 |
BE344897A (enrdf_load_stackoverflow) | |
NL22722C (enrdf_load_stackoverflow) | |
GB276877A (en) | 1927-09-08 |
NL22724C (enrdf_load_stackoverflow) | |
GB282002A (en) | 1928-06-07 |
NL22723C (enrdf_load_stackoverflow) | |
DE528492C (de) | 1931-06-27 |
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