US10253263B2 - Method of continuous pyrolysis and carbonization of agricultural and forestry biomass - Google Patents

Method of continuous pyrolysis and carbonization of agricultural and forestry biomass Download PDF

Info

Publication number
US10253263B2
US10253263B2 US15/322,128 US201515322128A US10253263B2 US 10253263 B2 US10253263 B2 US 10253263B2 US 201515322128 A US201515322128 A US 201515322128A US 10253263 B2 US10253263 B2 US 10253263B2
Authority
US
United States
Prior art keywords
pyrolysis
carbonization
gas
biomass
agricultural
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active, expires
Application number
US15/322,128
Other languages
English (en)
Other versions
US20170137715A1 (en
Inventor
Enchen JIANG
Mingfeng WANG
Xinhui GUO
Xiwei XU
Dongdong SHI
Shibo Li
Shijun Zhang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
South China Agricultural University
Original Assignee
South China Agricultural University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by South China Agricultural University filed Critical South China Agricultural University
Assigned to SOUTH CHINA AGRICULTURAL UNIVERSITY reassignment SOUTH CHINA AGRICULTURAL UNIVERSITY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: GUO, Xinhui, JIANG, Enchen, LI, Shibo, SHI, Dongdong, WANG, Mingfeng, XU, Xiwei, ZHANG, SHIJUN
Publication of US20170137715A1 publication Critical patent/US20170137715A1/en
Application granted granted Critical
Publication of US10253263B2 publication Critical patent/US10253263B2/en
Active legal-status Critical Current
Adjusted expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/02Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/18Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with moving charge
    • C10B47/20Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with moving charge according to the moving bed type
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/28Other processes
    • C10B47/32Other processes in ovens with mechanical conveying means
    • C10B47/44Other processes in ovens with mechanical conveying means with conveyor-screws
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/02Multi-step carbonising or coking processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • Y02E50/14
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin

Definitions

  • the invention belongs to the field of biomass energy utilization and in particular relates to a method of continuous pyrolysis and carbonization of agricultural and forestry biomass.
  • biomass can be converted into semicoke, combustible gas, tar and wood vinegar under high temperature and oxygen deprived conditions.
  • This technology is a clean and high efficiency biomass energy conversion technology, wherein the pyrolysis reactor is the key part for realising the conversion.
  • biomass pyrolysis reactors mainly have a plenty of types, such as fixed bed, fluidized bed, rotary kiln and spiral pyrolysis reactor and etc., wherein spiral pyrolysis reactor has the advantages of simple structure, maneuverable reaction conditions and continuous and stable operation.
  • Patent CN 101486921 A discloses a biomass continuous pyrolysis and carbonization apparatus with flexible spiral conveyor, wherein biomass feedstock is transported in the pyrolysis tube with spiral feeder and drying, pre-carbonization, carbonization and calcination reaction are finished therein, and the carbonization process is finished, the resulting biomass charcoal is cooled and collected or further processed after being discharged from the reactor. Since the process of biomass carbonization reaction is slow and time consuming, it needs to be remained in the pyrolysis tube for enough time to fully carbonize the raw material, and the processing capacity of the spiral pyrolysis reactor is greatly limited, and the processing efficiency is hard to be improved.
  • Patent application CN 102226092 A discloses a low-temperature pyrolytic carbonization method of agricultural and forestry waste and a carbonization furnace apparatus thereof, wherein the processing procedures are: pretreated biomass feedstock is fed into a drying apparatus for drying process, then the dried biomass is transported into a biomass pyrolytic carbonization apparatus while N 2 is charged, the biomass low-temperature pyrolytic carbonization process is gradually finished, and pyrolysis gas, biomass tar and biomass charcoal are generated.
  • the procedure is characterized in that the biomass pyrolytic carbonization temperature is relatively low and between 200-300° C.
  • the carbonization process is all finished during the spiral propelling type feeding, the processing efficiency is relatively low, and it needs to charge N 2 to maintain an anaerobic reaction environment during the reaction, which increases the cost of production.
  • Patent CN 102634358 A discloses an efficient selectable pyrolysis system and a using method thereof, wherein the system composition comprises a furnace body, a distiller, combustible gas nozzles and a cooling apparatus, and belongs to fixed bed pyrolysis process. During the process, firstly dried biomass feedstock is fed into the distiller. In the distiller, the material needs to be subjected to a pyrolysis and drying stage, pre-carbonization stage, pyrolytic carbonization stage, and cooling and collecting charcoal stage.
  • the heating time of the pyrolysis and drying stage is 10-20 minutes
  • the heating time of the pre-carbonization stage is 30-45 minutes
  • the heating time of the pyrolytic carbonization stage is 1-2 hours, wherein the time for the completion of feedstock carbonization is long.
  • a plenty of gas nozzles is provided, which improves the temperature homogeneity in the reaction distiller to a certain extent, in the reaction distiller, temperature gradients will appear at both horizontal and longitudinal directions, which affects the homogeneity of pyrolysis charcoal quality. Not only does it consume time in the cooling and collecting char stage, but also the energy is not effectively used.
  • the aim of the present invention is to provide a rapid and efficient method of continuous pyrolysis and carbonization of agricultural and forestry biomass, wherein the biomass is pyrolyzed and carbonized continuously, and the reaction condition is stable and controllable.
  • step (2) and the carbonization of step (3) are performed continuously and subsequently, and after the material comes into the pyrolysis apparatus, the material is transported to the carbonization apparatus for carbonization while being pyrolyzed.
  • the biomass feedstock of step (1) is an organic biomass feedstock, comprising crop straws, cereal chaff, wood dust, leaves and branches with leaves; and the drying temperature is less than 200° C., and the drying time is 10-30 min.
  • the pyrolysis temperature of step (2) is 400-600° C., and the pyrolysis time is 3-8 min.
  • the carbonization temperature of step (3) is 500-800° C., and the carbonization time ⁇ 30 min.
  • the drying medium of step (1) is the flue gas after supplying heat to the pyrolysis apparatus and carbonization apparatus, the flue gas comes into the drying oven for drying the feedstock after supplying heat to the pyrolysis apparatus and carbonization apparatus; and the flue gas is the product after the combustion of pyrolysis gas obtained after the pyrolysis and carbonization of the biomass feedstock.
  • the biomass charcoal of step (3) is transported to a charcoal storage apparatus from the carbonization apparatus, naturally cooled and discharged.
  • the pyrolysis volatiles the semicoke carbonized volatiles of step (4) are discharged into a condenser for condensation from the carbonization apparatus together.
  • the apparatus for realizing the method of continuous pyrolysis and carbonization of agricultural and forestry biomass is a continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass, the apparatus comprises a feeding apparatus, a pyrolysis apparatus, a carbonization apparatus, and a heating apparatus for heating the pyrolysis apparatus and carbonization apparatus;
  • the pyrolysis apparatus comprises a pyrolysis furnace, a pyrolysis tube throughout the pyrolysis furnace and a spiral conveyor provided inside the pyrolysis tube; the outlet end of the pyrolysis tube is connected to the carbonization apparatus; and the carbonization apparatus comprises a housing and a heat exchange tube provided inside the housing.
  • a built-in division plate inside the pyrolysis furnace is to extend the flue gas transferring path and enhance the heat exchange effect.
  • the heating apparatus comprises a combustion furnace, an oil-gas combustor and a distribution valve; the combustion furnace is provided inside the pyrolysis furnace, and the oil-gas combustor is provided outside the combustion furnace; the distribution valve has a heat inlet, two heat outlets and a valve distributing gases; the heat inlet of the distribution valve is connected to a flue gas outlet of the combustion furnace, the two heat outlets of the distribution valve are connected to the pyrolysis furnace in the pyrolysis apparatus and the heat exchange tube in the carbonization apparatus respectively.
  • the continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass further comprises a drying oven, a pyrolysis feeding hopper and a transportation machinery; the material input end of the drying oven is connected to the output end of the feeding apparatus, and the material output end of the drying oven is connected to the input end of the transportation machinery; the output end of the transportation machinery is connected to the input end of the pyrolysis feeding hopper, and the output end of the pyrolysis feeding hopper is connected to the input end of the pyrolysis tube;
  • the drying medium inlet of the drying oven is connected to the pyrolysis furnace by a pipeline.
  • the inlet of the heat exchange tube in the carbonization apparatus is connected to the heat outlet of the distribution valve, and the outlet of the heat exchange tube is connected to the drying medium inlet of the drying oven.
  • the continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass further comprises a condenser and a liquid collecting box; the material inlet of the condenser is connected to the carbonization apparatus, the liquid outlet of the condenser is connected to the inlet of the liquid collecting box, and the gas outlet of the condenser is connected to the gas fuel supply inlet of the oil-gas combustor.
  • the continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass further comprises a gas storage tank and a three-way valve; the gas inlet of the gas storage tank, the gas outlet of the condenser and the gas fuel supply port of the oil-gas combustor are connected by the three-way valve, and the gas outlet of the gas storage tank is connected to the gas fuel supply inlet of the oil-gas combustor.
  • the continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass further comprises an oil storage box; the output end of the oil storage box is connected to the liquid fuel input end of the oil-gas combustor.
  • the feeding apparatus comprises a feeding hopper and a feeding elevator, wherein the output end of the feeding elevator is connected to the material input end of the drying oven, and the input end of the feeding elevator is provided with the feeding hopper.
  • a charcoal storage box is provided at the bottom of the carbonization apparatus, and an inlet seal valve of the charcoal storage box and an outlet seal valve of the charcoal storage box are provided on the charcoal storage box.
  • the gas inlet of the gas storage tank is provided with a gas pump, and the gas outlet of the gas storage tank is provided with a gas control valve.
  • the drying oven is provided with a draft fan for drying, an air blower for drying and a drying oven seal valve; the drying oven seal valve is provided between the drying oven and the transportation machinery.
  • the air blower for drying stops working to prevent air from leaking into the continuous pyrolysis and carbonization apparatus.
  • the feeding elevator inclines upward at an angle of 30-60°; the feeding end of the feeding elevator is provided with a lifting motor.
  • the spiral conveyor is a pitch varied spiral conveyor and the screw pitch of the feeding end is relatively short.
  • the temperature is within the range of 150-250° C.
  • the screw pitch is gradually increased to prevent the material from adhering, and within the range from 250° C. to the final temperature of the reaction, the screw pitch maintains constant.
  • the material in the pyrolysis tube is in a half full state, which is favorable for the discharge of pyrolysis volatiles. (the length of different pitch screws is determined by the temperature range.)
  • the distribution valve controls the high temperature flue gas generated by the combustion of the fuel oil or pyrolysis gas.
  • the distribution valve controls the proportion of the amount of the high temperature flue gas for the pyrolysis apparatus and carbonization apparatus, thereby controls the internal temperature of the pyrolysis apparatus and carbonization apparatus.
  • the high temperature flue gas generated by the combustion of the pyrolysis gas exchanges heat with the pyrolysis tube of the pyrolysis apparatus to heat the pyrolysis tube, and the pyrolysis time is controlled by the transport motor and spiral conveyor according to different material properties.
  • the present invention can realize continuous and stable pyrolysis and carbonization of biomass effectively and rapidly, the biomass pyrolysis stage and the carbonization stage are finished in the same system step-by-step, the primary pyrolysis is finished in the continuous pyrolysis apparatus, and most of volatiles are released out; the carbonization process is performed in the carbonization apparatus, partial volatiles remained in the semicoke are removed and biochar with a homogeneous quality is obtained. Since it does not need to finish carbonization in the continuous pyrolysis tube, the transport efficiency is significantly increased, and the processing efficiency of the pyrolysis system is further significantly increased.
  • the method has a strong adaptability for the size and moisture content of biomass
  • the continuous pyrolysis and carbonization apparatus uses the energy of the feedstock itself to dry biomass, and reduce the moisture of the material fed into the pyrolysis apparatus, enable the system to have a relatively good adaptability for high moisture material, use the adsorption property of biomass feedstock to filter organic volatiles and dusts in the combustion product of the pyrolysis gas, and purify the discharged flue gas.
  • FIG. 1 is process flow diagram of the method of continuous pyrolysis and carbonization of agricultural and forestry biomass of the present invention
  • FIG. 2 is the schematic view of the continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass;
  • a method of continuous pyrolysis and carbonization of agricultural and forestry biomass comprising the following steps: the system is heated by the fuel oil in the oil storage box or the pyrolysis gas in the gas storage tank when being initiated, then begins to feed when the temperature reaches the set temperature.
  • Biomass feedstock is transported into the drying oven from the feeding hopper by the feeding elevator, the flue gas which has supplied heat to the pyrolysis apparatus and carbonization apparatus is used for drying the feedstock, the dried material is transported into the pyrolysis feeding hopper by the transportation machinery, then is transported to the carbonization apparatus by the pyrolysis spiral feeder in the pyrolysis tube; wherein the temperature in the pyrolysis tube generally is 400-600° C., and therefore the biomass feedstock in the pyrolysis tube is transported into the carbonization apparatus by the spiral conveyor while being pyrolyzed, i. e.
  • the primary pyrolysis of the biomass feedstock is finished, and both pyrolysis volatiles and semicoke are transported to the carbonization apparatus, wherein the temperature of the carbonization apparatus generally is 500-800° C., after the semicoke is fully carbonized in the carbonization apparatus (the carbonization time is 10-30 min), biomass charcoal is generated, at this time point, the seal valve between the carbonization apparatus and the charcoal storage box is open, the biomass charcoal falls into the charcoal storage box and is discharged after being cooled (naturally cooled); the volatiles generated in the pyrolysis tube and carbonization apparatus are discharged from the top of the carbonization apparatus for the condensation treatment, then products of tar, wood vinegar and pyrolysis gas are obtained; tar and wood vinegar are collected, and pyrolysis gas is introduced into the combustion furnace for combustion through a pipeline, the generated high temperature flue gas comes into the heat exchange tube in the carbonization apparatus and the pyrolysis furnace in the pyrolysis apparatus for supplying heat through the distribution valve in the heating apparatus at an appropriate proportion, the
  • the pyrolysis gas is pumped into the gas storage tank by the gas pump through the three-way valve for standby application.
  • the pyrolysis gas in the gas storage tank is fed into the oil-gas combustor through the gas control valve, and the pyrolysis gas burns in the combustion furnace by the ignition apparatus of the oil-gas combustor to supply corresponding heat. Its process flow diagram is as shown in FIG. 1 .
  • FIG. 2 The schematic view of the continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass is as shown in FIG. 2 :
  • the continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass comprises a feeding apparatus, a pyrolysis apparatus, a carbonization apparatus ( 8 ), and a heating apparatus for heating the pyrolysis apparatus and carbonization apparatus ( 8 );
  • the pyrolysis apparatus comprises a pyrolysis furnace ( 26 ), a pyrolysis tube ( 23 ) throughout the pyrolysis furnace and a spiral conveyor ( 27 ) built-in the pyrolysis tube ( 23 ); the outlet end of the pyrolysis tube ( 23 ) is connected to the carbonization apparatus ( 8 ).
  • a division plate ( 25 ) is mounted inside the pyrolysis furnace ( 26 ).
  • the carbonization apparatus ( 8 ) comprises a shell and a heat exchange tube ( 9 ) mounted inside the shell.
  • the heating apparatus comprises a combustion furnace ( 22 ), an oil-gas combustor ( 21 ) and a distribution valve ( 24 ); the combustion furnace ( 22 ) is built inside the pyrolysis furnace ( 26 ), and the oil-gas combustor ( 21 ) is installed outside the combustion furnace ( 22 ).
  • the distribution valve ( 24 ) has a heat inlet, two heat outlets and a valve distributing gases; the heat inlet of the distribution valve ( 24 ) is connected to a flue gas outlet of the combustion furnace ( 22 ), the two heat outlets of the distribution valve ( 24 ) are connected to the pyrolysis furnace ( 26 ) in the pyrolysis apparatus and the heat exchange tube ( 9 ) in the carbonization apparatus ( 8 ) respectively.
  • the distribution valve ( 24 ) controls the temperature of the pyrolysis apparatus and carbonization apparatus ( 8 ) by adjusting the proportion of the amount of the high temperature flue gas introduced into the two apparatuses.
  • the continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass further comprises a drying oven ( 3 ), a pyrolysis feeding hopper ( 29 ) and a transportation machinery ( 6 ); the material input end of the drying oven ( 3 ) is connected to the output end of the feeding apparatus, and the material output end of the drying oven ( 3 ) is connected to the input end of the transportation machinery ( 6 ); the output end of the transportation machinery ( 6 ) is connected to the input end of the pyrolysis feeding hopper ( 29 ), and the output end of the pyrolysis feeding hopper ( 29 ) is connected to the input end of the pyrolysis tube ( 23 ).
  • the input end of the transportation machinery ( 6 ) is connected to the material output end of the drying oven ( 3 ) by the drying oven seal valve ( 5 ).
  • the drying medium inlet of the drying oven ( 3 ) is connected to the pyrolysis furnace ( 26 ) by a pipeline, and the drying medium inlet of the drying oven ( 3 ) is provided at one side of the drying oven ( 3 ) and near the bottom.
  • the inlet of the heat exchange tube ( 9 ) in the carbonization apparatus ( 8 ) is connected to the energy outlet of the distribution valve ( 24 ), and outlet of the heat exchange tube ( 9 ) is connected to the drying medium inlet of the drying oven ( 3 ), and the drying medium inlet of the drying oven ( 3 ) is provided at one side of the drying oven ( 3 ) and near the bottom.
  • the continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass further comprises a condenser ( 11 ) and a liquid collecting box ( 17 ); the material inlet of the condenser ( 11 ) is connected to the carbonization apparatus ( 8 ), the liquid outlet of the condenser ( 11 ) is connected to the inlet of the liquid collecting box ( 17 ), the gas outlet of the condenser ( 11 ) is connected to the gas fuel supply inlet of the oil-gas combustor ( 21 ), and the liquid collecting box ( 17 ) is provided with a draining valve ( 16 ).
  • the continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass further comprises a gas storage tank ( 13 ) and a three-way valve ( 15 ).
  • the gas inlet of the gas storage tank ( 13 ), the gas outlet of the condenser ( 11 ) and the gas fuel supply inlet of the oil-gas combustor ( 21 ) are connected by the three-way valve ( 15 ), and the gas outlet of the gas storage tank ( 13 ) is connected to the gas fuel supply inlet of the oil-gas combustor ( 21 ).
  • the valve of the three-way valve ( 15 ) connecting the gas outlet of the condenser ( 11 ) and the gas fuel supply inlet of the oil-gas combustor ( 21 ) is closed, another valve of the three-way valve ( 15 ) connecting the gas outlet of the condenser ( 11 ) and the gas inlet of the gas storage tank ( 13 ) is open, and the pyrolysis gas is introduced into the gas storage tank ( 13 ) for storage by the gas pump ( 14 );
  • the valve of the three-way valve ( 15 ) connecting the gas outlet of the condenser ( 11 ) and the gas fuel supply inlet of the oil-gas combustor ( 21 ) is open, and another valve of the three-way valve ( 15 ) connecting the gas outlet of the condenser ( 11 ) and the gas inlet of the gas storage tank ( 13 ) is
  • the continuous pyrolysis and carbonization apparatus of agricultural and forestry biomass further comprises an oil storage box ( 20 ); the output end of the oil storage box ( 20 ) is connected to the liquid fuel input end of the oil-gas combustor ( 21 ).
  • the oil-gas combustor is an combustion apparatus of diesel oil and the pyrolysis gas, it is equipped with components for ignition and air distribution itself; wherein the flame generated by the combustion of the pyrolysis gas is inside the combustion furnace, i. e. the combustion furnace provides a space for the combustion of oil-gas and transports high temperature flue gas to the pyrolysis apparatus and carbonization apparatus.
  • the oil-gas combustor is a dual-use oil-gas combustor which can burn diesel oil and pyrolysis gas, when the combustion of the pyrolysis gas cannot provide enough heat, diesel oil is burned for auxiliary heating.
  • the feeding apparatus comprises a feeding hopper ( 1 ) and a feeding elevator ( 2 ), wherein the output end of the feed elevator ( 2 ) is connected to the material input end of the drying oven ( 3 ) (i.e. the top of the drying oven), and the input end of the feeding elevator ( 2 ) is provided with the feeding hopper ( 1 ) (i.e. the bottom of the feeding hopper is connected to the input end of the feeding elevator).
  • a charcoal storage box ( 19 ) is provided at the bottom of the carbonization apparatus ( 8 ), and an inlet seal valve ( 10 ) of the charcoal storage box and an outlet seal valve ( 18 ) of the charcoal storage box are provided on the charcoal storage box ( 19 ).
  • the gas inlet of the gas storage tank ( 13 ) is provided with a gas pump ( 14 ), and the gas outlet of the gas storage tank ( 13 ) is provided with a gas control valve ( 12 ).
  • the drying oven is provided with a draft fan for drying ( 4 ), an air blower for drying ( 7 ) and a drying oven seal valve ( 5 );
  • the draft fan for drying ( 4 ) is provided at one side of the drying oven ( 3 ) and near the top, and the air blower for drying ( 7 ) is provided on the pipeline connecting to the drying medium inlet;
  • the drying oven seal valve ( 5 ) is provided between the drying oven ( 3 ) and the transportation machinery ( 6 ).
  • the air blower for drying ( 7 ) stops to prevent air from leaking into the continuous pyrolysis and carbonization apparatus.
  • the feeding elevator ( 2 ) inclines upward at an angle of 30-60°; the feeding end of the feed elevator is provided with a lifting motor ( 30 ).
  • the feeding end of the pyrolysis tube ( 23 ) is provided with a transport motor ( 28 ).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Coke Industry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
US15/322,128 2014-06-24 2015-04-02 Method of continuous pyrolysis and carbonization of agricultural and forestry biomass Active 2035-09-05 US10253263B2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CN201410290296.5 2014-06-24
CN201410290296 2014-06-24
CN201410290296.5A CN104017590B (zh) 2014-06-24 2014-06-24 一种农林生物质连续热解炭化方法
PCT/CN2015/075784 WO2015196841A1 (zh) 2014-06-24 2015-04-02 一种农林生物质连续热解炭化方法

Publications (2)

Publication Number Publication Date
US20170137715A1 US20170137715A1 (en) 2017-05-18
US10253263B2 true US10253263B2 (en) 2019-04-09

Family

ID=51434602

Family Applications (1)

Application Number Title Priority Date Filing Date
US15/322,128 Active 2035-09-05 US10253263B2 (en) 2014-06-24 2015-04-02 Method of continuous pyrolysis and carbonization of agricultural and forestry biomass

Country Status (3)

Country Link
US (1) US10253263B2 (de)
CN (1) CN104017590B (de)
WO (1) WO2015196841A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025210117A1 (en) 2024-04-05 2025-10-09 Envigas Technology Ab Manufacture of carbon

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104017590B (zh) * 2014-06-24 2016-04-27 华南农业大学 一种农林生物质连续热解炭化方法
CN104538644B (zh) * 2014-12-18 2017-03-29 广东省生态环境与土壤研究所 一种污泥碳板电极的制备方法及应用
CN104861993B (zh) * 2015-03-31 2017-05-24 张家港天源生物能源科技有限公司 塔式生物质连续碳化炉
CN104807014B (zh) * 2015-04-20 2017-06-23 华南农业大学 一种畜禽热解焚化无害化处理装置
CN104860778B (zh) * 2015-04-30 2017-09-08 上海交通大学 控制和去除生物炭制备过程中多环芳烃产生的方法
CN104910936A (zh) * 2015-05-25 2015-09-16 华南农业大学 一种基于强化传热的生物质连续热解装置与方法
TWI586798B (zh) * 2016-01-05 2017-06-11 China Steel Corp Material Heating System for Continuous Carbonization Process
CN105723904B (zh) * 2016-01-20 2018-09-07 浙江大学 一种利用生物质炭对缺钾少钙稻田改良提效的方法
CN106479536B (zh) * 2016-04-01 2019-06-07 首都师范大学 水稻秸秆生物炭生产设备及用于生产生物炭的工艺
CN107057729A (zh) * 2016-08-26 2017-08-18 江苏禾能生物科技有限公司 一种分料式裂解反应系统
CN106433712A (zh) * 2016-10-09 2017-02-22 农业部规划设计研究院 一种回转式生物质连续热解炭气联产工艺
CN107098560A (zh) * 2017-06-19 2017-08-29 重庆航天机电设计院 污泥、油污复合热解系统
CN107267174A (zh) * 2017-06-22 2017-10-20 张晓敏 生物质热解制油工艺
CN107828433A (zh) * 2017-11-06 2018-03-23 湖北师范大学 一种综合废弃物再生能源多联产工艺系统
CN107942876A (zh) * 2017-12-15 2018-04-20 广州中天联合高新技术发展有限公司 一种基于生物纤维炭化的智能控制系统
CN108102673B (zh) * 2017-12-20 2019-10-25 华中科技大学 一种生物质热解液化多联产系统
CN108034443A (zh) * 2017-12-31 2018-05-15 广西贺州匠心科技有限责任公司 一种生物质源干馏系统
CN108676573B (zh) * 2018-05-22 2024-06-18 吉林鼎运新能源股份有限公司 环保氢炭无人全自动智能生产设备
CN108929170A (zh) * 2018-09-04 2018-12-04 蔡信弟 集约型竹炭生物质有机肥生产设备及方法
EP3636729B1 (de) * 2018-10-10 2021-11-24 BDI Holding GmbH Verfahren zur herstellung von coker-kohle
CN109628121B (zh) * 2019-01-22 2020-07-14 华中科技大学 一种稻壳分级联产能源化学品及硅炭材料的系统及方法
CN109929576A (zh) * 2019-03-13 2019-06-25 珠海晨骏环保科技有限公司 一种用农林废弃物快速生产机制炭的工艺方法及生产线
WO2020212198A1 (en) 2019-04-15 2020-10-22 Carbonzero Sagl Continuous reactor device and process for treatment of biomass
CN110240919A (zh) * 2019-07-16 2019-09-17 洛阳佳易新能源技术有限公司 一种秸秆分级加热提取木醋液装置及生产工艺
CN110387250A (zh) * 2019-08-20 2019-10-29 赫普能源环境科技有限公司 一种利用电站锅炉烟气生产生物质炭的系统及方法
CN110437860A (zh) * 2019-08-22 2019-11-12 浙江大学 一种双层或多层卧式回转筒式连续生物质炭化系统
CN111117674A (zh) * 2019-12-13 2020-05-08 深圳先进技术研究院 生物质废物热催化重组方法以及系统
CN111704920A (zh) * 2020-07-17 2020-09-25 国际竹藤中心 一种连续生物质炭化装置及方法
CN111978972B (zh) * 2020-08-05 2021-10-08 上海工程技术大学 一种秸秆废弃物耦合油页岩综合利用系统及工艺
CN112923371A (zh) * 2021-01-21 2021-06-08 东南大学 一种污泥耦合生物质热解气化装置与方法
CN113184825A (zh) * 2021-01-21 2021-07-30 云南农业大学 一种食用菌废料处理协同改性磷石膏的装置及方法
CN113528167B (zh) * 2021-08-26 2025-02-11 安徽长思机械设备科技有限公司 一种疫木炭化装备
CN116064061B (zh) * 2021-10-30 2025-08-05 中国石油化工股份有限公司 一种生物质组合工艺生产氢气的方法和系统
CN114196425B (zh) * 2021-12-17 2024-10-01 上海秦鄠工程技术有限公司 一种生物质热解制炭的工艺方法及装置
CN115109606B (zh) * 2022-07-06 2023-09-08 山东省红森林新材料科技有限公司 一种生物质废弃物制取纯氢及多联产耦合系统
FI20225937A1 (en) * 2022-10-14 2024-04-15 Upm Kymmene Corp A conveyor for pretreated biomass
CN115849986A (zh) * 2022-11-21 2023-03-28 鄂尔多斯市环保投资有限公司 基于热处理半焦和木醋液的土壤修复剂及其制备、使用方法
CN116751598A (zh) * 2023-06-15 2023-09-15 江南大学 一种可移动式小型连续生产天然烟熏风味液体的装置
CN117778036B (zh) * 2024-01-11 2024-07-09 国际竹藤中心 一种移动型竹材烘干炭化一体式装备
CN119371974A (zh) * 2024-12-30 2025-01-28 陕西新能生物质科技开发有限公司 一种环形生物质炭汽联产装置及其方法
CN120607902A (zh) * 2025-05-12 2025-09-09 国能龙源环保有限公司 一种生物质炭化的系统与方法

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050247553A1 (en) * 2004-03-23 2005-11-10 Central Research Institute Of Electric Power Industry Carbonization and gasification of biomass and power generation system
CN1935941A (zh) 2006-09-14 2007-03-28 武汉凯迪科技发展研究院有限公司 生物质分级控温慢速热解工艺及其系统
CN101691495A (zh) 2009-10-28 2010-04-07 中国科学院广州能源研究所 生物质分级热解制备生物油和化学品的方法及装置
CN101693845A (zh) 2009-10-28 2010-04-14 中国科学院广州能源研究所 生物质选择性热解制备高品质生物油的方法及装置
WO2010130988A1 (en) 2009-05-11 2010-11-18 Aston University Staged biomass pyrolysis process and apparatus
CN102226092A (zh) * 2011-05-30 2011-10-26 南京师范大学 连续式生物质低温热解炭化方法及其炭化炉
WO2012058218A2 (en) 2010-10-29 2012-05-03 Conocophillips Company Process for producing high quality pyrolysis oil from biomass
CN102703098A (zh) * 2012-05-29 2012-10-03 东南大学 生物质制取生物油的装置及其方法
CN104017590A (zh) 2014-06-24 2014-09-03 华南农业大学 一种农林生物质连续热解炭化方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101140677B1 (ko) * 2010-04-13 2012-04-25 한국생산기술연구원 2단 탄화 시스템
JP5584647B2 (ja) * 2011-04-08 2014-09-03 株式会社日立製作所 バイオマスの半炭化燃料の製造装置と製造方法、及び半炭化燃料を用いた発電システム

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050247553A1 (en) * 2004-03-23 2005-11-10 Central Research Institute Of Electric Power Industry Carbonization and gasification of biomass and power generation system
CN1935941A (zh) 2006-09-14 2007-03-28 武汉凯迪科技发展研究院有限公司 生物质分级控温慢速热解工艺及其系统
WO2010130988A1 (en) 2009-05-11 2010-11-18 Aston University Staged biomass pyrolysis process and apparatus
CN101691495A (zh) 2009-10-28 2010-04-07 中国科学院广州能源研究所 生物质分级热解制备生物油和化学品的方法及装置
CN101693845A (zh) 2009-10-28 2010-04-14 中国科学院广州能源研究所 生物质选择性热解制备高品质生物油的方法及装置
WO2012058218A2 (en) 2010-10-29 2012-05-03 Conocophillips Company Process for producing high quality pyrolysis oil from biomass
CN102226092A (zh) * 2011-05-30 2011-10-26 南京师范大学 连续式生物质低温热解炭化方法及其炭化炉
CN102703098A (zh) * 2012-05-29 2012-10-03 东南大学 生物质制取生物油的装置及其方法
CN104017590A (zh) 2014-06-24 2014-09-03 华南农业大学 一种农林生物质连续热解炭化方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Derwent abstract of CN 102226092, 1 page (2011). *
Derwent abstract of CN 102703098, 1 page (2013). *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025210117A1 (en) 2024-04-05 2025-10-09 Envigas Technology Ab Manufacture of carbon

Also Published As

Publication number Publication date
CN104017590A (zh) 2014-09-03
CN104017590B (zh) 2016-04-27
US20170137715A1 (en) 2017-05-18
WO2015196841A1 (zh) 2015-12-30

Similar Documents

Publication Publication Date Title
US10253263B2 (en) Method of continuous pyrolysis and carbonization of agricultural and forestry biomass
CN104017591B (zh) 一种农林生物质连续热解炭化装置
CN202530040U (zh) 一种连续式生物质干馏炭化设备
CN204265698U (zh) 一种生物质炭化装置
CN102732274A (zh) 以燃煤热风炉作为供热的褐煤干馏方法
CN102226092A (zh) 连续式生物质低温热解炭化方法及其炭化炉
CN109485043A (zh) 生物质两段式制备活性炭的系统和方法
CN106190416B (zh) 一种生物质炭燃料
CN104342178A (zh) 一种生物质炭化方法及其装置
CN110437860A (zh) 一种双层或多层卧式回转筒式连续生物质炭化系统
CN106939170A (zh) 一种太阳能协同两步法生物质螺旋烘焙预处理方法及装置
CN105062521A (zh) 一种回转式连续热解秸秆炭化炉
US20230134219A1 (en) Biomass pyrolysis device and method with optimized matching of thermal energy and microwave energy
CN105505475A (zh) 一种生物质气化-干馏耦合炭气油联产工艺
CN204824726U (zh) 一种煤炭低温干馏系统
CN204939394U (zh) 回转式连续热解秸秆炭化炉
CN205328941U (zh) 热解设备
CN111334319A (zh) 生物质高温热解气化方法和系统
CN103131493A (zh) 一种褐煤成型提质方法
CN203128486U (zh) 一种高效高温环保炭化炉
CN107245344B (zh) 农业废弃物低能耗的循环流化床炭化装置和方法
CN203999498U (zh) 一种农林生物质连续热解炭化装置
CN108359486A (zh) 一种生物质多部位连续热裂解集成装置
CN204529732U (zh) 一种滚筒式棉杆连续炭化装置
CN219194885U (zh) 一种沼渣制备单环芳香烃并联产含氮热解炭的系统

Legal Events

Date Code Title Description
AS Assignment

Owner name: SOUTH CHINA AGRICULTURAL UNIVERSITY, CHINA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:JIANG, ENCHEN;WANG, MINGFENG;GUO, XINHUI;AND OTHERS;REEL/FRAME:041198/0865

Effective date: 20161219

STCF Information on status: patent grant

Free format text: PATENTED CASE

MAFP Maintenance fee payment

Free format text: PAYMENT OF MAINTENANCE FEE, 4TH YR, SMALL ENTITY (ORIGINAL EVENT CODE: M2551); ENTITY STATUS OF PATENT OWNER: SMALL ENTITY

Year of fee payment: 4