UA78778C2 - Process and apparatus for removal of particulate material from gas oil stream produced in a delayed coking unit - Google Patents
Process and apparatus for removal of particulate material from gas oil stream produced in a delayed coking unit Download PDFInfo
- Publication number
- UA78778C2 UA78778C2 UA20041109197A UA20041109197A UA78778C2 UA 78778 C2 UA78778 C2 UA 78778C2 UA 20041109197 A UA20041109197 A UA 20041109197A UA 20041109197 A UA20041109197 A UA 20041109197A UA 78778 C2 UA78778 C2 UA 78778C2
- Authority
- UA
- Ukraine
- Prior art keywords
- separator
- gas oil
- stream
- particles
- micrometers
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 81
- 239000011236 particulate material Substances 0.000 title claims abstract description 33
- 238000004939 coking Methods 0.000 title claims abstract description 19
- 230000003111 delayed effect Effects 0.000 title claims abstract description 10
- 238000000926 separation method Methods 0.000 claims abstract description 17
- 239000002245 particle Substances 0.000 claims description 73
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 claims description 30
- 239000000571 coke Substances 0.000 claims description 28
- 238000005406 washing Methods 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 17
- 239000012530 fluid Substances 0.000 claims description 9
- 238000005201 scrubbing Methods 0.000 claims description 9
- 238000004821 distillation Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 abstract description 9
- 238000004523 catalytic cracking Methods 0.000 abstract description 7
- 230000003197 catalytic effect Effects 0.000 abstract description 3
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 35
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 238000013461 design Methods 0.000 description 4
- 238000001914 filtration Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Substances [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B55/00—Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G55/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process
- C10G55/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only
- C10G55/04—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one thermal cracking step
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G55/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process
- C10G55/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only
- C10G55/06—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one refining process and at least one cracking process plural serial stages only including at least one catalytic cracking step
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of catalytic cracking in the absence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/005—Coking (in order to produce liquid products mainly)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Cyclones (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Separating Particles In Gases By Inertia (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/121,897 US6919017B2 (en) | 2002-04-11 | 2002-04-11 | Separation process and apparatus for removal of particulate material from flash zone gas oil |
| PCT/US2003/011245 WO2003087267A1 (en) | 2002-04-11 | 2003-04-10 | Separation process and apparatus for removal of particulate material from delayed coking gas oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA78778C2 true UA78778C2 (en) | 2007-04-25 |
Family
ID=28790434
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA20041109197A UA78778C2 (en) | 2002-04-11 | 2003-10-04 | Process and apparatus for removal of particulate material from gas oil stream produced in a delayed coking unit |
Country Status (18)
| Country | Link |
|---|---|
| US (2) | US6919017B2 (zh) |
| EP (2) | EP1495089A1 (zh) |
| JP (1) | JP4417726B2 (zh) |
| KR (1) | KR100964418B1 (zh) |
| CN (1) | CN1266253C (zh) |
| AR (1) | AR039407A1 (zh) |
| AU (1) | AU2003234719B2 (zh) |
| BR (3) | BR122012025977B1 (zh) |
| CA (1) | CA2479092C (zh) |
| EA (1) | EA006143B1 (zh) |
| EG (1) | EG23435A (zh) |
| MX (1) | MXPA04009812A (zh) |
| MY (1) | MY132765A (zh) |
| NO (1) | NO342768B1 (zh) |
| TW (1) | TWI256972B (zh) |
| UA (1) | UA78778C2 (zh) |
| WO (1) | WO2003087267A1 (zh) |
| ZA (1) | ZA200407504B (zh) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7720641B2 (en) * | 2006-04-21 | 2010-05-18 | Exxonmobil Research And Engineering Company | Application of abnormal event detection technology to delayed coking unit |
| US7875103B2 (en) * | 2006-04-26 | 2011-01-25 | Mueller Environmental Designs, Inc. | Sub-micron viscous impingement particle collection and hydraulic removal system |
| US20080120060A1 (en) * | 2006-09-29 | 2008-05-22 | Fisher-Rosemount Systems, Inc. | Detection of catalyst losses in a fluid catalytic cracker for use in abnormal situation prevention |
| US9222044B2 (en) | 2010-07-26 | 2015-12-29 | Uop Llc | Methods for producing low oxygen biomass-derived pyrolysis oils |
| US8940067B2 (en) | 2011-09-30 | 2015-01-27 | Mueller Environmental Designs, Inc. | Swirl helical elements for a viscous impingement particle collection and hydraulic removal system |
| US9187696B2 (en) * | 2013-03-14 | 2015-11-17 | Bechtel Hydrocarbon Technology Solutions, Inc. | Delayed coking drum quench overflow systems and methods |
| PL2970046T3 (pl) * | 2013-03-15 | 2019-07-31 | Bechtel Hydrocarbon Technology Solutions, Inc. | Układy i sposoby zewnętrznego przetwarzania oleju gazowego ze strefy zapłonu ze sposobu opóźnionego koksowania |
| WO2015041935A1 (en) * | 2013-09-18 | 2015-03-26 | Shell Oil Company | Methods and systems for supplying hydrogen to a hydrocatalytic reaction |
| EP3083035A1 (en) | 2013-12-20 | 2016-10-26 | Shell Internationale Research Maatschappij B.V. | Methods and systems for processing a reaction product mixture of a cellulosic biomass material |
| BR112018005408B8 (pt) * | 2015-09-21 | 2022-08-02 | Bechtel Hydrocarbon Technology Solutions Inc | Sistema e método para reduzir emissões atmosféricas de vapores de hidrocarboneto |
| CN105233602B (zh) * | 2015-10-12 | 2017-09-22 | 西安交通大学 | 用于粉煤低温干馏中高温焦油气与细粉尘颗粒分离的系统 |
| US10711589B2 (en) | 2018-08-08 | 2020-07-14 | A.S.A.P. Industries Manufacturing, Inc. | Sand separator |
| CN109628135B (zh) * | 2018-12-10 | 2024-01-30 | 西北大学 | 一种生焦装置及使用方法 |
| US11932816B2 (en) | 2019-02-15 | 2024-03-19 | Exxonmobil Chemical Patents Inc. | Coke and tar removal from a furnace effluent |
| US11852258B2 (en) * | 2020-12-31 | 2023-12-26 | Tapcoenpro, Llc | Systems and methods for purging an isolation valve with a liquid purge medium |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2622880C3 (de) * | 1976-05-21 | 1981-05-14 | Amberger Kaolinwerke Gmbh, 8452 Hirschau | Verfahren zum fraktionierten von suspendierten Feststoffen mittels Hydrozyklonen, sowie Anordnung zur Durchführung des Verfahrens |
| US4354920A (en) * | 1976-12-27 | 1982-10-19 | Chevron Research Company | Coal liquefaction process |
| SE403441B (sv) * | 1977-01-05 | 1978-08-21 | Skardal Karl Arvid | Virvelrenare med i dess avsmalnande del axiellt anordnade och i direkt forbindelse med varandra staende kammaravsnitt |
| US4208270A (en) | 1978-03-27 | 1980-06-17 | Krebs Engineers | Hydrocyclone assembly |
| CA1246481A (en) | 1984-03-20 | 1988-12-13 | Frank Souhrada | Coking residuum in the presence of hydrogen donor |
| DE3609988C2 (de) * | 1986-03-25 | 1994-08-04 | Metallgesellschaft Ag | Kombiniertes Verfahren zum Abtrennen und Behandeln von Asphaltenen mit hoher Erweichungstemperatur |
| US4882036A (en) | 1987-09-16 | 1989-11-21 | Exxon Research And Engineering Company | Combination coking and hydroconversion process |
| CA1312033C (en) * | 1987-09-16 | 1992-12-29 | Clarence M. Eidt, Jr. | Combination coking and hydroconversion process |
| US5059301A (en) * | 1988-11-29 | 1991-10-22 | Conoco | Process for the preparation of recarburizer coke |
| FR2716458B1 (fr) | 1994-02-22 | 1996-04-12 | Inst Francais Du Petrole | Procédé et dispositif de décokage. |
| US5645711A (en) * | 1996-01-05 | 1997-07-08 | Conoco Inc. | Process for upgrading the flash zone gas oil stream from a delayed coker |
| US5645712A (en) | 1996-03-20 | 1997-07-08 | Conoco Inc. | Method for increasing yield of liquid products in a delayed coking process |
| US6129217A (en) | 1996-03-29 | 2000-10-10 | Corn Products International, Inc. | Hydrocyclone and separator assemblies utilizing hydrocyclones |
| US5824194A (en) | 1997-01-07 | 1998-10-20 | Bechtel Corporation | Fractionator system for delayed coking process |
| US5954949A (en) * | 1998-03-25 | 1999-09-21 | Unipure Corporation | Conversion of heavy petroleum oils to coke with a molten alkali metal hydroxide |
-
2002
- 2002-04-11 US US10/121,897 patent/US6919017B2/en not_active Expired - Lifetime
-
2003
- 2003-04-09 EG EG2003040333A patent/EG23435A/xx active
- 2003-04-10 KR KR1020047015063A patent/KR100964418B1/ko active IP Right Grant
- 2003-04-10 CN CNB038079895A patent/CN1266253C/zh not_active Expired - Fee Related
- 2003-04-10 BR BRBR122012025977-2A patent/BR122012025977B1/pt not_active IP Right Cessation
- 2003-04-10 BR BRPI0308822A patent/BRPI0308822C8/pt unknown
- 2003-04-10 CA CA2479092A patent/CA2479092C/en not_active Expired - Fee Related
- 2003-04-10 MX MXPA04009812A patent/MXPA04009812A/es active IP Right Grant
- 2003-04-10 MY MYPI20031334A patent/MY132765A/en unknown
- 2003-04-10 EP EP03728375A patent/EP1495089A1/en not_active Withdrawn
- 2003-04-10 JP JP2003584211A patent/JP4417726B2/ja not_active Expired - Fee Related
- 2003-04-10 WO PCT/US2003/011245 patent/WO2003087267A1/en active Application Filing
- 2003-04-10 EA EA200401351A patent/EA006143B1/ru not_active IP Right Cessation
- 2003-04-10 BR BR0308822-7A patent/BR0308822A/pt not_active IP Right Cessation
- 2003-04-10 AU AU2003234719A patent/AU2003234719B2/en not_active Ceased
- 2003-04-10 EP EP08006501A patent/EP1970426A1/en not_active Withdrawn
- 2003-04-11 AR ARP030101278A patent/AR039407A1/es active IP Right Grant
- 2003-04-11 TW TW092108393A patent/TWI256972B/zh not_active IP Right Cessation
- 2003-10-04 UA UA20041109197A patent/UA78778C2/uk unknown
-
2004
- 2004-09-17 ZA ZA2004/07504A patent/ZA200407504B/en unknown
- 2004-10-19 NO NO20044443A patent/NO342768B1/no not_active IP Right Cessation
-
2005
- 2005-03-21 US US11/086,950 patent/US7476295B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US6919017B2 (en) | 2005-07-19 |
| EP1495089A1 (en) | 2005-01-12 |
| CN1646663A (zh) | 2005-07-27 |
| AU2003234719B2 (en) | 2008-10-23 |
| TW200307035A (en) | 2003-12-01 |
| EA006143B1 (ru) | 2005-10-27 |
| EA200401351A1 (ru) | 2005-04-28 |
| US7476295B2 (en) | 2009-01-13 |
| WO2003087267A1 (en) | 2003-10-23 |
| NO20044443L (no) | 2004-10-19 |
| MXPA04009812A (es) | 2004-12-13 |
| AU2003234719A1 (en) | 2003-10-27 |
| BRPI0308822B1 (pt) | 2019-05-07 |
| MY132765A (en) | 2007-10-31 |
| BR122012025977B1 (pt) | 2015-08-04 |
| NO342768B1 (no) | 2018-08-06 |
| AR039407A1 (es) | 2005-02-16 |
| ZA200407504B (en) | 2005-12-28 |
| CA2479092C (en) | 2010-04-20 |
| CA2479092A1 (en) | 2003-10-23 |
| CN1266253C (zh) | 2006-07-26 |
| US20050194290A1 (en) | 2005-09-08 |
| BR0308822A (pt) | 2005-01-04 |
| KR100964418B1 (ko) | 2010-06-16 |
| EP1970426A1 (en) | 2008-09-17 |
| KR20040106304A (ko) | 2004-12-17 |
| JP2005532420A (ja) | 2005-10-27 |
| EG23435A (en) | 2005-08-22 |
| BRPI0308822B8 (pt) | 2019-05-28 |
| US20030192810A1 (en) | 2003-10-16 |
| BRPI0308822C8 (pt) | 2019-06-25 |
| JP4417726B2 (ja) | 2010-02-17 |
| TWI256972B (en) | 2006-06-21 |
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