UA78636C2 - Method and device of preparing expanded thermoplastic microspheres - Google Patents
Method and device of preparing expanded thermoplastic microspheres Download PDFInfo
- Publication number
- UA78636C2 UA78636C2 UAA200507214A UA2005007214A UA78636C2 UA 78636 C2 UA78636 C2 UA 78636C2 UA A200507214 A UAA200507214 A UA A200507214A UA 2005007214 A UA2005007214 A UA 2005007214A UA 78636 C2 UA78636 C2 UA 78636C2
- Authority
- UA
- Ukraine
- Prior art keywords
- scrapers
- microspheres
- fact
- hollow body
- feeding means
- Prior art date
Links
- 239000004005 microsphere Substances 0.000 title claims abstract description 73
- 238000000034 method Methods 0.000 title claims abstract description 32
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 23
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000000945 filler Substances 0.000 claims description 14
- 238000005054 agglomeration Methods 0.000 claims description 7
- 238000007790 scraping Methods 0.000 claims description 7
- 230000002776 aggregation Effects 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229920002313 fluoropolymer Polymers 0.000 claims description 3
- 239000002344 surface layer Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000010410 layer Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 229920000103 Expandable microsphere Polymers 0.000 abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 21
- -1 for example Substances 0.000 description 8
- 239000000178 monomer Substances 0.000 description 6
- 239000000446 fuel Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000002861 polymer material Substances 0.000 description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 2
- GXDHCNNESPLIKD-UHFFFAOYSA-N 2-methylhexane Natural products CCCCC(C)C GXDHCNNESPLIKD-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- KYPOHTVBFVELTG-OWOJBTEDSA-N (e)-but-2-enedinitrile Chemical compound N#C\C=C\C#N KYPOHTVBFVELTG-OWOJBTEDSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical group ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical class C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- OYKPJMYWPYIXGG-UHFFFAOYSA-N 2,2-dimethylbutane;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(C)(C)C OYKPJMYWPYIXGG-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 235000009051 Ambrosia paniculata var. peruviana Nutrition 0.000 description 1
- 235000003097 Artemisia absinthium Nutrition 0.000 description 1
- 240000001851 Artemisia dracunculus Species 0.000 description 1
- 235000017731 Artemisia dracunculus ssp. dracunculus Nutrition 0.000 description 1
- 235000003261 Artemisia vulgaris Nutrition 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000001138 artemisia absinthium Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- NKKMVIVFRUYPLQ-NSCUHMNNSA-N crotononitrile Chemical compound C\C=C\C#N NKKMVIVFRUYPLQ-NSCUHMNNSA-N 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- WMWXXXSCZVGQAR-UHFFFAOYSA-N dialuminum;oxygen(2-);hydrate Chemical class O.[O-2].[O-2].[O-2].[Al+3].[Al+3] WMWXXXSCZVGQAR-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical class [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- FKLRBKPRLBWRKK-UHFFFAOYSA-N magnesium;oxygen(2-);hydrate Chemical compound O.[O-2].[Mg+2] FKLRBKPRLBWRKK-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 238000004347 surface barrier Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical class [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3461—Making or treating expandable particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3415—Heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3442—Mixing, kneading or conveying the foamable material
- B29C44/3446—Feeding the blowing agent
- B29C44/3449—Feeding the blowing agent through the screw
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/38—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
- B29C44/44—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form
- B29C44/445—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form in the form of expandable granules, particles or beads
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02445192 | 2002-12-20 | ||
| PCT/SE2003/002043 WO2004056549A1 (en) | 2002-12-20 | 2003-12-18 | Method and device for pre- expanding thermoplastic microspheres |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA78636C2 true UA78636C2 (en) | 2007-04-10 |
Family
ID=32668935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UAA200507214A UA78636C2 (en) | 2002-12-20 | 2003-12-18 | Method and device of preparing expanded thermoplastic microspheres |
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| JP (1) | JP4474285B2 (pt) |
| KR (1) | KR100764379B1 (pt) |
| CN (1) | CN100429061C (pt) |
| AT (1) | ATE470549T1 (pt) |
| AU (1) | AU2003288874B2 (pt) |
| BR (1) | BRPI0317486B1 (pt) |
| CA (1) | CA2510024C (pt) |
| DE (1) | DE60332955D1 (pt) |
| DK (1) | DK1572432T3 (pt) |
| EC (1) | ECSP055882A (pt) |
| ES (1) | ES2347143T3 (pt) |
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| RU (1) | RU2301739C2 (pt) |
| SI (1) | SI1572432T1 (pt) |
| UA (1) | UA78636C2 (pt) |
| WO (1) | WO2004056549A1 (pt) |
| ZA (1) | ZA200504161B (pt) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US6866906B2 (en) | 2000-01-26 | 2005-03-15 | International Paper Company | Cut resistant paper and paper articles and method for making same |
| US7786181B2 (en) | 2005-12-21 | 2010-08-31 | Akzo Nobel N.V. | Chemical composition and process |
| US8388809B2 (en) | 2006-02-10 | 2013-03-05 | Akzo Nobel N.V. | Microspheres |
| US7956096B2 (en) | 2006-02-10 | 2011-06-07 | Akzo Nobel N.V. | Microspheres |
| WO2010025383A1 (en) | 2008-08-28 | 2010-03-04 | International Paper Company | Expandable microspheres and methods of making and using the same |
| US9365453B2 (en) | 2012-04-19 | 2016-06-14 | Construction Research & Technology Gmbh | Admixture and method for freeze-thaw damage resistance and scaling damage resistance of cementitious compositions |
| US9333685B2 (en) | 2012-04-19 | 2016-05-10 | AkzoNobel Chemicals International B.V. | Apparatus and system for expanding expandable polymeric microspheres |
| WO2013160717A1 (en) | 2012-04-27 | 2013-10-31 | Sa Des Eaux Minerales D'evian Saeme | Article comprising foamed polylactic acid and process of making the same |
| EP2855007A2 (en) | 2012-05-30 | 2015-04-08 | Akzo Nobel Chemicals International B.V. | Microspheres |
| EP2892702B1 (en) * | 2012-09-07 | 2016-08-31 | Akzo Nobel Chemicals International B.V. | A method and a device for preparation of expanded thermoplastic microspheres |
| CN103029257B (zh) * | 2012-12-21 | 2014-11-26 | 杭州富阳东山塑料机械有限公司 | 一种用于发料机的刮刀稳料装置 |
| PL3008029T3 (pl) * | 2013-06-12 | 2017-09-29 | Akzo Nobel Chemicals International B.V. | Sposób i urządzenie do przygotowania ekspandowanych mikrosfer |
| WO2015082579A1 (en) | 2013-12-06 | 2015-06-11 | Construction Research & Technology Gmbh | Method of manufacturing cementitious compositions |
| CA2969302C (en) * | 2014-12-11 | 2023-02-28 | Akzo Nobel Chemicals International B.V. | Apparatus and method for expanding thermally expandable thermoplastic microspheres |
| CN109414672B (zh) | 2016-07-14 | 2021-10-26 | 阿克苏诺贝尔化学品国际有限公司 | 可热膨胀热塑性微球及其制备方法 |
| CN110198821A (zh) * | 2016-11-11 | 2019-09-03 | 生活实验公司 | 使可膨胀性聚合物微球膨胀的方法 |
| EP3678768B1 (en) | 2017-09-04 | 2021-07-14 | Nouryon Chemicals International B.V. | Thermally expandable microspheres prepared from bio-based monomers |
| JP6874223B2 (ja) | 2017-11-21 | 2021-05-19 | ヌーリオン ケミカルズ インターナショナル ベスローテン フェノーツハップＮｏｕｒｙｏｎ Ｃｈｅｍｉｃａｌｓ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｂ．Ｖ． | バイオ系モノマーから調製される熱膨張性ミクロスフェア |
| ES2938007T3 (es) | 2018-11-13 | 2023-04-03 | Nouryon Chemicals Int Bv | Microesferas a base de celulosa térmicamente expandibles |
| KR102659108B1 (ko) | 2019-01-25 | 2024-04-18 | 누리온 케미칼즈 인터내셔널 비.브이. | 디알코올 셀룰로스계 구형 캡슐 |
| CN110715538A (zh) * | 2019-11-15 | 2020-01-21 | 快思瑞科技(上海)有限公司 | 可膨胀微球干燥系统和方法 |
| CN110860260A (zh) * | 2019-12-23 | 2020-03-06 | 快思瑞科技(上海)有限公司 | 超轻质材料连续制备系统和方法 |
| WO2021198487A1 (en) | 2020-04-03 | 2021-10-07 | Nouryon Chemicals International B.V. | Thermally expandable microspheres prepared from bio-based monomers |
| EP4126334A1 (en) | 2020-04-03 | 2023-02-08 | Nouryon Chemicals International B.V. | Thermally expandable microspheres prepared from bio-based monomers |
| CN115666775A (zh) | 2020-05-20 | 2023-01-31 | 诺力昂化学品国际有限公司 | 具有低膨胀温度的可热膨胀纤维素基微球 |
| CN111688097B (zh) * | 2020-06-29 | 2021-09-10 | 鹤山市盛世光华隔热材料有限公司 | 一种提高发泡塑料材料质量的方法 |
| CN116867566A (zh) | 2021-02-22 | 2023-10-10 | 诺力昂化学品国际有限公司 | 基于纤维素的可热膨胀微球 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH535413A (de) * | 1971-07-01 | 1973-03-31 | Luwa Ag | Vorrichtung zum Trocknen eines fliessfähigen Stoffes |
| US3804378A (en) * | 1971-12-16 | 1974-04-16 | Mac Millan Bloedel Containers | Method and apparatus for producing an expanded polymer material |
| JPS55137928A (en) * | 1979-04-16 | 1980-10-28 | Kanegafuchi Chem Ind Co Ltd | Method and apparatus for preliminarily foaming particle of foamable thermoplastic resin |
| US4379106A (en) * | 1981-01-09 | 1983-04-05 | Bussey Harry Jun | Method of expanding heat expandable thermoplastic elements with steam and a horizontal expander with a feed near the bottom for expanding the heat expandable element |
| US5228775A (en) * | 1989-05-04 | 1993-07-20 | Blentech Corporation | Reversing blender agitators |
| AU658430B2 (en) * | 1991-05-24 | 1995-04-13 | Pierce & Stevens Corporation | Process for drying microspheres |
| FR2699089B1 (fr) * | 1992-12-14 | 1995-06-16 | Flurial Sa | Dispositif de filtrage auto-nettoyant pour fluides renfermant des particules solides. |
| CN1505557A (zh) * | 2001-03-29 | 2004-06-16 | 金东熙 | 制造发泡的热塑树脂小球的设备和方法 |
-
2003
- 2003-12-18 RU RU2005122926/12A patent/RU2301739C2/ru active
- 2003-12-18 CA CA002510024A patent/CA2510024C/en not_active Expired - Fee Related
- 2003-12-18 ES ES03781256T patent/ES2347143T3/es not_active Expired - Lifetime
- 2003-12-18 MX MXPA05005875A patent/MXPA05005875A/es active IP Right Grant
- 2003-12-18 AT AT03781256T patent/ATE470549T1/de active
- 2003-12-18 AU AU2003288874A patent/AU2003288874B2/en not_active Ceased
- 2003-12-18 BR BRPI0317486A patent/BRPI0317486B1/pt not_active IP Right Cessation
- 2003-12-18 CN CNB2003801068745A patent/CN100429061C/zh not_active Expired - Lifetime
- 2003-12-18 KR KR1020057010399A patent/KR100764379B1/ko active IP Right Grant
- 2003-12-18 DE DE60332955T patent/DE60332955D1/de not_active Expired - Lifetime
- 2003-12-18 PT PT03781256T patent/PT1572432E/pt unknown
- 2003-12-18 JP JP2004562225A patent/JP4474285B2/ja not_active Expired - Lifetime
- 2003-12-18 DK DK03781256.7T patent/DK1572432T3/da active
- 2003-12-18 WO PCT/SE2003/002043 patent/WO2004056549A1/en active Application Filing
- 2003-12-18 SI SI200331865T patent/SI1572432T1/sl unknown
- 2003-12-18 EP EP03781256A patent/EP1572432B1/en not_active Expired - Lifetime
- 2003-12-18 PL PL375898A patent/PL207926B1/pl unknown
- 2003-12-18 UA UAA200507214A patent/UA78636C2/uk unknown
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2005
- 2005-05-23 ZA ZA200504161A patent/ZA200504161B/en unknown
- 2005-06-21 EC EC2005005882A patent/ECSP055882A/es unknown
- 2005-07-18 NO NO20053527A patent/NO20053527L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003288874A1 (en) | 2004-07-14 |
| BR0317486A (pt) | 2005-11-16 |
| DE60332955D1 (de) | 2010-07-22 |
| DK1572432T3 (da) | 2010-10-11 |
| NO20053527D0 (no) | 2005-07-18 |
| JP4474285B2 (ja) | 2010-06-02 |
| JP2006511360A (ja) | 2006-04-06 |
| BRPI0317486B1 (pt) | 2016-08-23 |
| RU2301739C2 (ru) | 2007-06-27 |
| MXPA05005875A (es) | 2005-08-29 |
| CA2510024A1 (en) | 2004-07-08 |
| ES2347143T3 (es) | 2010-10-26 |
| AU2003288874B2 (en) | 2006-09-14 |
| ECSP055882A (es) | 2005-09-20 |
| CN100429061C (zh) | 2008-10-29 |
| EP1572432A1 (en) | 2005-09-14 |
| EP1572432B1 (en) | 2010-06-09 |
| ZA200504161B (en) | 2006-08-30 |
| WO2004056549A1 (en) | 2004-07-08 |
| KR20050086905A (ko) | 2005-08-30 |
| ATE470549T1 (de) | 2010-06-15 |
| PL375898A1 (en) | 2005-12-12 |
| PT1572432E (pt) | 2010-09-03 |
| CN1729087A (zh) | 2006-02-01 |
| RU2005122926A (ru) | 2006-02-27 |
| KR100764379B1 (ko) | 2007-10-08 |
| CA2510024C (en) | 2008-12-02 |
| SI1572432T1 (sl) | 2010-10-29 |
| PL207926B1 (pl) | 2011-02-28 |
| NO20053527L (no) | 2005-09-20 |
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