UA127581C2 - Композитний компонент, що зношується - Google Patents
Композитний компонент, що зношуєтьсяInfo
- Publication number
- UA127581C2 UA127581C2 UAA202105639A UAA202105639A UA127581C2 UA 127581 C2 UA127581 C2 UA 127581C2 UA A202105639 A UAA202105639 A UA A202105639A UA A202105639 A UAA202105639 A UA A202105639A UA 127581 C2 UA127581 C2 UA 127581C2
- Authority
- UA
- Ukraine
- Prior art keywords
- vol
- ceramic
- metal
- metal matrix
- reinforcement
- Prior art date
Links
- 239000002131 composite material Substances 0.000 title abstract 2
- 239000011159 matrix material Substances 0.000 abstract 5
- 229910052751 metal Inorganic materials 0.000 abstract 5
- 239000002184 metal Substances 0.000 abstract 5
- 239000008187 granular material Substances 0.000 abstract 4
- 239000002905 metal composite material Substances 0.000 abstract 4
- 230000002787 reinforcement Effects 0.000 abstract 3
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 abstract 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/02—Casting in, on, or around objects which form part of the product for making reinforced articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/14—Treatment of metallic powder
- B22F1/148—Agglomerating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/14—Casting in, on, or around objects which form part of the product the objects being filamentary or particulate in form
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1017—Multiple heating or additional steps
- B22F3/1021—Removal of binder or filler
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1035—Liquid phase sintering
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/067—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds comprising a particular metallic binder
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/10—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on titanium carbide
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C13/00—Disintegrating by mills having rotary beater elements ; Hammer mills
- B02C13/14—Disintegrating by mills having rotary beater elements ; Hammer mills with vertical rotor shaft, e.g. combined with sifting devices
- B02C13/18—Disintegrating by mills having rotary beater elements ; Hammer mills with vertical rotor shaft, e.g. combined with sifting devices with beaters rigidly connected to the rotor
- B02C13/1807—Disintegrating by mills having rotary beater elements ; Hammer mills with vertical rotor shaft, e.g. combined with sifting devices with beaters rigidly connected to the rotor the material to be crushed being thrown against an anvil or impact plate
- B02C13/185—Construction or shape of anvil or impact plate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C2210/00—Codes relating to different types of disintegrating devices
- B02C2210/02—Features for generally used wear parts on beaters, knives, rollers, anvils, linings and the like
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2201/00—Treatment under specific atmosphere
- B22F2201/20—Use of vacuum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2203/00—Controlling
- B22F2203/11—Controlling temperature, temperature profile
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2301/00—Metallic composition of the powder or its coating
- B22F2301/35—Iron
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2302/00—Metal Compound, non-Metallic compound or non-metal composition of the powder or its coating
- B22F2302/10—Carbide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2304/00—Physical aspects of the powder
- B22F2304/10—Micron size particles, i.e. above 1 micrometer up to 500 micrometer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
- C22C1/051—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
- C22C1/053—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor with in situ formation of hard compounds
- C22C1/055—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor with in situ formation of hard compounds using carbon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0047—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
- C22C32/0052—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
- C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
- C22C33/0278—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
- C22C33/0285—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Powder Metallurgy (AREA)
- Crushing And Grinding (AREA)
Abstract
Даний винахід належить до композитного компонента, що зношується з ієрархічною структурою, що містить армування в найбільш схильній до зносу частині, де армування містить тривимірно зв'язану мережу міліметрових металокерамічних композитних гранул, які періодично чергуються з міліметровими проміжками, де зазначені металокерамічні композитні гранули містять щонайменше 52 об. %, переважно щонайменше 61 об. %, більш переважно щонайменше 70 об. % мікрометрових частинок карбіду титану, втілених у першу металеву матрицю, де металокерамічні композитні гранули мають щільність щонайменше 4,8 г/см3, де тривимірно пов'язана мережа металокерамічних композитних гранул з її міліметровими проміжками втілена в другу металеву матрицю, де зазначене армування містить у середньому щонайменше 23 об. %, більш переважно щонайменше 28 об. %, найбільш переважно щонайменше 30 об. % карбіду титану, причому перша металева матриця відрізняється від другої металевої матриці, де друга металева матриця містить литий залізний сплав.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP20166110.5A EP3885061A1 (en) | 2020-03-27 | 2020-03-27 | Composite wear component |
PCT/EP2021/057409 WO2021191199A1 (en) | 2020-03-27 | 2021-03-23 | Composite wear component |
Publications (1)
Publication Number | Publication Date |
---|---|
UA127581C2 true UA127581C2 (uk) | 2023-10-18 |
Family
ID=70050005
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
UAA202105639A UA127581C2 (uk) | 2020-03-27 | 2021-03-23 | Композитний компонент, що зношується |
Country Status (22)
Country | Link |
---|---|
US (1) | US20220023944A1 (uk) |
EP (4) | EP3885061A1 (uk) |
JP (2) | JP7177290B2 (uk) |
KR (1) | KR20210145251A (uk) |
CN (3) | CN116638064A (uk) |
AU (1) | AU2021243493B2 (uk) |
BR (1) | BR112021023975A2 (uk) |
CA (1) | CA3136701C (uk) |
CL (1) | CL2021002688A1 (uk) |
CO (1) | CO2021013840A2 (uk) |
DK (1) | DK3938127T3 (uk) |
ES (1) | ES2944723T3 (uk) |
FI (1) | FI3938127T3 (uk) |
MA (1) | MA55329B1 (uk) |
MX (1) | MX2021012526A (uk) |
MY (1) | MY195381A (uk) |
PE (1) | PE20220120A1 (uk) |
PL (1) | PL3938127T3 (uk) |
PT (1) | PT3938127T (uk) |
UA (1) | UA127581C2 (uk) |
WO (1) | WO2021191199A1 (uk) |
ZA (1) | ZA202107498B (uk) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4155008A1 (en) * | 2021-09-23 | 2023-03-29 | Magotteaux International S.A. | Composite wear component |
CN114559039A (zh) * | 2022-02-08 | 2022-05-31 | 徐州徐工矿业机械有限公司 | 一种耐磨陶瓷颗粒弥散分布的铁基陶瓷预制体及其制造方法 |
EP4299209A1 (en) | 2022-07-01 | 2024-01-03 | Magotteaux International S.A. | Metal matrix composite grinding ball |
EP4368312A1 (en) * | 2022-11-10 | 2024-05-15 | Sandvik SRP AB | A cemented carbide based composite article |
CN115612909B (zh) * | 2022-12-19 | 2023-08-04 | 西安稀有金属材料研究院有限公司 | 网状分布陶瓷颗粒增强增韧的铁基复合材料及其制备方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
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US3785801A (en) * | 1968-03-01 | 1974-01-15 | Int Nickel Co | Consolidated composite materials by powder metallurgy |
US3623849A (en) * | 1969-08-25 | 1971-11-30 | Int Nickel Co | Sintered refractory articles of manufacture |
SE399911C (sv) | 1976-02-05 | 1980-02-18 | Sandvik Ab | Slitdetalj med hog slitstyrka och god hallfasthet, sammansatt av hardmetall och gjutjern |
DE3315125C1 (de) | 1983-04-27 | 1984-11-22 | Fried. Krupp Gmbh, 4300 Essen | Verschleissbestaendiger Verbundkoerper und Verfahren zu seiner Herstellung |
US5066546A (en) | 1989-03-23 | 1991-11-19 | Kennametal Inc. | Wear-resistant steel castings |
BE1018130A3 (fr) * | 2008-09-19 | 2010-05-04 | Magotteaux Int | Materiau composite hierarchique. |
BE1018129A3 (fr) * | 2008-09-19 | 2010-05-04 | Magotteaux Int | Impacteur composite pour concasseurs a percussion. |
BE1018127A3 (fr) * | 2008-09-19 | 2010-05-04 | Magotteaux Int | Dent composite pour le travail du sol ou des roches. |
WO2010105151A2 (en) * | 2009-03-13 | 2010-09-16 | Smith International, Inc. | Carbide composites |
US8834786B2 (en) * | 2010-06-30 | 2014-09-16 | Kennametal Inc. | Carbide pellets for wear resistant applications |
CN101899585B (zh) * | 2010-07-23 | 2012-11-28 | 西安交通大学 | 复合耐磨件的预制体及用该预制体制造耐磨件的方法 |
EP2606996A1 (en) * | 2011-12-23 | 2013-06-26 | EPoS S.r.L. | A method for sintering metal matrix composite materials |
CN103878346B (zh) * | 2014-03-12 | 2016-01-13 | 昆明理工大学 | 一种陶瓷颗粒多尺度增强金属基体复合材料的制备方法 |
CN104209498B (zh) * | 2014-07-24 | 2017-02-15 | 昆明理工大学 | 一种陶瓷颗粒增强金属基复合材料界面改性层的制备方法 |
CN104148651B (zh) * | 2014-08-25 | 2016-04-13 | 南通高欣耐磨科技股份有限公司 | 一种TiC硬质合金复合磨辊的制备方法 |
CN104148618B (zh) * | 2014-08-25 | 2016-06-08 | 南通高欣耐磨科技股份有限公司 | 一种TiC基硬质合金网格复合增强磨辊 |
MX2018005895A (es) | 2015-11-12 | 2018-08-28 | Innerco Sp Z O O | Composicion de polvos para la fabricacion de insertos de fundicion, los insertos de fundicion y el metodo de obtencion de zonas locales compuestas en piezas de fundicion. |
CN106001561B (zh) * | 2016-06-03 | 2018-10-23 | 广东工业大学 | 一种多级复合金属陶瓷、其制备方法及盾构刀具 |
CN106925761B (zh) * | 2017-05-10 | 2019-03-26 | 重庆罗曼新材料科技有限公司 | 陶瓷颗粒金属复合材料预制体及陶瓷金属复合耐磨件的制备方法 |
CN108380850B (zh) * | 2018-03-28 | 2020-03-17 | 昆明理工大学 | 一种陶瓷颗粒多尺度增强金属基复合耐磨耙齿齿头及其制备方法 |
US20200384580A1 (en) * | 2019-06-04 | 2020-12-10 | Kennametal Inc. | Composite claddings and applications thereof |
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2020
- 2020-03-27 EP EP20166110.5A patent/EP3885061A1/en not_active Withdrawn
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2021
- 2021-03-23 UA UAA202105639A patent/UA127581C2/uk unknown
- 2021-03-23 PT PT217128701T patent/PT3938127T/pt unknown
- 2021-03-23 DK DK21712870.1T patent/DK3938127T3/da active
- 2021-03-23 PE PE2021001729A patent/PE20220120A1/es unknown
- 2021-03-23 WO PCT/EP2021/057409 patent/WO2021191199A1/en unknown
- 2021-03-23 FI FIEP21712870.1T patent/FI3938127T3/fi active
- 2021-03-23 BR BR112021023975A patent/BR112021023975A2/pt unknown
- 2021-03-23 MA MA55329A patent/MA55329B1/fr unknown
- 2021-03-23 MX MX2021012526A patent/MX2021012526A/es unknown
- 2021-03-23 EP EP23159758.4A patent/EP4219044A1/en active Pending
- 2021-03-23 JP JP2021564218A patent/JP7177290B2/ja active Active
- 2021-03-23 CN CN202310632434.2A patent/CN116638064A/zh active Pending
- 2021-03-23 KR KR1020217035493A patent/KR20210145251A/ko not_active Application Discontinuation
- 2021-03-23 EP EP21712870.1A patent/EP3938127B1/en active Active
- 2021-03-23 PL PL21712870.1T patent/PL3938127T3/pl unknown
- 2021-03-23 CA CA3136701A patent/CA3136701C/en active Active
- 2021-03-23 ES ES21712870T patent/ES2944723T3/es active Active
- 2021-03-23 MY MYPI2021005975A patent/MY195381A/en unknown
- 2021-03-23 CN CN202310632463.9A patent/CN116638065A/zh active Pending
- 2021-03-23 CN CN202180002908.4A patent/CN113784810B/zh active Active
- 2021-03-23 EP EP23159760.0A patent/EP4215297A1/en active Pending
- 2021-03-23 AU AU2021243493A patent/AU2021243493B2/en active Active
- 2021-09-30 US US17/491,345 patent/US20220023944A1/en active Pending
- 2021-10-05 ZA ZA2021/07498A patent/ZA202107498B/en unknown
- 2021-10-14 CL CL2021002688A patent/CL2021002688A1/es unknown
- 2021-10-15 CO CONC2021/0013840A patent/CO2021013840A2/es unknown
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2022
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