TWM592442U - Alloy structure with surface of low magnesium content - Google Patents

Alloy structure with surface of low magnesium content Download PDF

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TWM592442U
TWM592442U TW108216026U TW108216026U TWM592442U TW M592442 U TWM592442 U TW M592442U TW 108216026 U TW108216026 U TW 108216026U TW 108216026 U TW108216026 U TW 108216026U TW M592442 U TWM592442 U TW M592442U
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magnesium
alloy
layer
magnesium content
content
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TW108216026U
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楊景明
葉子暘
吳俊龍
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艾姆勒車電股份有限公司
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Abstract

本創作公開了一種具有低鎂含量之表面之合金結構,包括一原鎂含量之合金層、以及一形成在所述原鎂含量之合金層外的貧鎂層。其中,所述貧鎂層具有一低鎂含量之表面,能強化合金之焊接性,提升接合的良率。The present invention discloses an alloy structure with a low magnesium content surface, which includes an alloy layer with raw magnesium content and a magnesium-depleted layer formed outside the alloy layer with raw magnesium content. Wherein, the magnesium-depleted layer has a surface with low magnesium content, which can strengthen the weldability of the alloy and improve the yield of the joint.

Description

具有低鎂含量之表面之合金結構Alloy structure with low magnesium content

本創作涉及合金結構,具體來說是涉及具有低鎂含量之表面之合金結構。This creation relates to alloy structures, specifically to alloy structures with surfaces with low magnesium content.

鋁合金是工業中應用最廣泛的金屬材料,鋁合金具有密度低,強度高,熱導率高,以及加工性能好等優點。隨著鋁合金在航太、汽車、機械製造等方面的應用,對鋁合金焊接性能的要求不斷提高,焊接品質的好壞會直接影響到零件的使用。Aluminum alloy is the most widely used metal material in the industry. Aluminum alloy has the advantages of low density, high strength, high thermal conductivity, and good processing performance. With the application of aluminum alloys in aerospace, automotive, machinery manufacturing, etc., the requirements for aluminum alloy welding performance continue to increase, and the quality of the welding will directly affect the use of parts.

在鋁合金中起到強化作用的主要元素為鎂 (Mg),然而,鋁合金中的鎂含量過高,可能是造成焊接不良的原因之一,導致接合的良率難以保證。The main element that strengthens aluminum alloys is magnesium (Mg). However, the excessively high magnesium content in aluminum alloys may be one of the reasons for poor welding, and it is difficult to guarantee the yield of joints.

有鑑於此,本創作發明人本於多年從事相關產品之開發與設計,有感上述缺失之可改善,乃特潛心研究並配合學理之運用,終於提出一種設計合理且有效改善上述缺失之本創作。In view of this, the inventor of this creation has been engaged in the development and design of related products for many years, and feels that the above-mentioned deficiencies can be improved. It is especially dedicated to research and cooperate with the application of academic principles. Finally, he proposes a reasonable design and effectively improves the above-mentioned deficiencies. .

本創作之主要目的在於提供一種具有低鎂含量之表面之合金結構,以解決上述問題。The main purpose of this creation is to provide an alloy structure with a low magnesium content surface to solve the above problems.

為了解決上述的技術問題,本創作所採用的一種技術方案是,提供一種具有低鎂含量之表面之合金結構,包括:一原鎂含量之合金層、以及一形成在所述原鎂含量之合金層外的貧鎂層;其中,所述貧鎂層具有一低鎂含量之表面。In order to solve the above technical problems, a technical solution adopted in this work is to provide an alloy structure with a low magnesium content surface, including: an alloy layer with raw magnesium content and an alloy formed on the magnesium content A magnesium-depleted layer outside the layer; wherein the magnesium-depleted layer has a surface with a low magnesium content.

在一優選實施例中,所述貧鎂層的厚度至少大於10μm。In a preferred embodiment, the thickness of the magnesium-depleted layer is at least greater than 10 μm.

在一優選實施例中,所述貧鎂層及所述原鎂含量之合金層是由含鎂的鋁合金所製成,且所述貧鎂層的鎂含量小於所述原鎂含量之合金層的鎂含量。In a preferred embodiment, the magnesium-depleted layer and the alloy layer with raw magnesium content are made of an aluminum alloy containing magnesium, and the magnesium layer with magnesium content less than the alloy layer with raw magnesium content Of magnesium.

在一優選實施例中,所述貧鎂層的低鎂含量之表面是透過削減經處理的鋁合金之表面所形成。In a preferred embodiment, the low magnesium content surface of the magnesium-depleted layer is formed by cutting the surface of the treated aluminum alloy.

是以,本創作提供的具有低鎂含量之表面之合金結構,其具有原鎂含量之合金層、以及形成在所述原鎂含量之合金層外的貧鎂層,且所述貧鎂層具有一低鎂含量之表面,能強化合金之焊接性,提升接合的良率。Therefore, the alloy structure with a low magnesium content surface provided by this work has an alloy layer with original magnesium content and a magnesium-depleted layer formed outside the alloy layer with original magnesium content, and the magnesium-depleted layer has A surface with low magnesium content can strengthen the weldability of the alloy and improve the yield of the joint.

為使能更進一步瞭解本創作的特徵及技術內容,請參閱以下有關本創作的詳細說明與圖式,然而所提供的圖式僅用於提供參考與說明,並非用來對本創作加以限制。In order to further understand the characteristics and technical content of this creation, please refer to the following detailed description and drawings of this creation. However, the drawings provided are for reference and explanation only, and are not intended to limit this creation.

以下是通過特定的具體實施例來說明本創作所公開的實施方式,本領域技術人員可由本說明書所公開的內容瞭解本創作的優點與效果。本創作可通過其他不同的具體實施例加以施行或應用,本說明書中的各項細節也可基於不同觀點與應用,在不悖離本創作的構思下進行各種修改與變更。另外,本創作的附圖僅為簡單示意說明,並非依實際尺寸的描繪,事先聲明。以下的實施方式將進一步詳細說明本創作的相關技術內容,但所公開的內容並非用以限制本創作的保護範圍。The following is a description of the embodiments disclosed in this creation by specific specific examples. Those skilled in the art can understand the advantages and effects of this creation from the content disclosed in this specification. This creation can be implemented or applied through other different specific embodiments. The details in this specification can also be based on different views and applications, and various modifications and changes can be made without departing from the concept of this creation. In addition, the drawings in this creation are only a schematic illustration, not based on actual size, and are declared in advance. The following embodiments will further describe the relevant technical content of the creation, but the disclosed content is not intended to limit the protection scope of the creation.

請參考圖1,為本創作提供的一種具有低鎂含量之表面之合金結構。如圖所示,根據本創作提供的具有低鎂含量之表面之合金結構,其具有一原鎂含量之合金層10、以及一形成在原鎂含量之合金層外的貧鎂層20。其中,所述貧鎂層20具有一低鎂含量之表面201,能強化合金之焊接性,提升接合的良率。Please refer to Figure 1 for an alloy structure with a low magnesium content surface provided for this creation. As shown in the figure, the alloy structure having a surface with low magnesium content according to the present invention has an alloy layer 10 of original magnesium content and a magnesium-depleted layer 20 formed outside the alloy layer of original magnesium content. Wherein, the magnesium-depleted layer 20 has a surface 201 with low magnesium content, which can strengthen the weldability of the alloy and improve the bonding yield.

在本實施例中,原鎂含量之合金層10是含鎂的鋁合金(Aluminum alloy (with Mg)),但也可以是鎂合金 (Magnesium alloy)、或鈦合金 (Titanium alloy),或是其它含鎂的合金,並不加以限制。In this embodiment, the alloy layer 10 with original magnesium content is an aluminum alloy (with Mg) containing magnesium, but it may also be a magnesium alloy (Magnesium alloy), a titanium alloy (Titanium alloy), or other The alloy containing magnesium is not limited.

在本實施例中,貧鎂層20與原鎂含量之合金層10為一體成形。具體來說,貧鎂層20的低鎂含量之表面201是將經過真空熱處理後的鋁合金削減其表面所形成。並且,貧鎂層20的鎂含量小於原鎂含量之合金層10的鎂含量。In this embodiment, the magnesium-depleted layer 20 and the alloy layer 10 containing the original magnesium are integrally formed. Specifically, the low-magnesium-content surface 201 of the magnesium-depleted layer 20 is formed by cutting the surface of the aluminum alloy after vacuum heat treatment. Also, the magnesium content of the magnesium-depleted layer 20 is less than the magnesium content of the alloy layer 10 of the original magnesium content.

進一步來說,用於製作具有低鎂含量之表面之合金結構的鋁合金可包括有矽、銅、鉛、鋁、錳、鎳、鐵、錫、鎂等元素和不可避免的雜質。所謂不可避免的雜質是指存在於原材料中不可避免的混入的物質,但不會對鋁合金的特性造成影響,因此為容許的雜質。其中,矽元素可用於增加鋁合金的強度,銅元素可用於增強鋁合金的硬度,鉛元素可用於增強鋁合金的加工性。Further, the aluminum alloy used to make the alloy structure with a low magnesium content surface may include silicon, copper, lead, aluminum, manganese, nickel, iron, tin, magnesium and other elements and inevitable impurities. The unavoidable impurities are substances that are unavoidably mixed in the raw materials, but do not affect the characteristics of the aluminum alloy, so they are allowed impurities. Among them, silicon element can be used to increase the strength of aluminum alloy, copper element can be used to enhance the hardness of aluminum alloy, lead element can be used to enhance the workability of aluminum alloy.

請再配合圖2,本創作提供的具有低鎂含量之表面之合金結構可透過一種合金表面處理方法來獲得,主要包括以下步驟:Please refer to Figure 2 again. The alloy structure with low magnesium content provided by this creation can be obtained by an alloy surface treatment method, which mainly includes the following steps:

(1) 真空熱處理:將鋁合金M放在治具P上且放在真空爐(圖略)內,以>15℃/min的升溫速度進行升溫,優選升温至500℃~600℃ (如是其它合金,則需依據會跑到合金表面的元素會從幾度開始跑),持溫時間>30min,冷却時間>120min。所述真空熱處理的真空度優選為>10 -4torr。另外,也可將鋁合金M放在治具P上且放在保護氣氛爐(圖略),在保護氣氛(如N2,Ar)中加熱,優選氧含量>50ppm。 (1) Vacuum heat treatment: put the aluminum alloy M on the jig P and put it in a vacuum furnace (figure omitted), and increase the temperature at a temperature increase rate of >15℃/min, preferably to 500℃~600℃ (if other For alloys, it is necessary to run from a few degrees according to the elements that will run to the surface of the alloy), temperature holding time> 30min, cooling time> 120min. The vacuum degree of the vacuum heat treatment is preferably >10 -4 torr. In addition, the aluminum alloy M can also be placed on the jig P and placed in a protective atmosphere furnace (not shown) and heated in a protective atmosphere (such as N2, Ar), preferably with an oxygen content >50 ppm.

(2) 獲得表層具有高鎂含量的富鎂層30a (Mg-rich layer)、厚度>10μm之貧鎂層20a (Mg-poor layer)、以及原鎂含量之合金層10a (Original Mg-content layer)的一合金結構。所述富鎂層30a的鎂含量為0.1~100%。另外,貧鎂層20a的厚度視真空度與真空熱處理的持溫時間及持溫溫度而不同,真空度越高,持溫時間越久、持溫溫度越高,則貧鎂層20a的厚度越厚。並且,合金結構中的貧鎂層20a下緣到與治具P接觸的地方即為原鎂含量的鋁合金,也就是說,鋁合金沒有露出表面與真空接觸的地方,不會產生富鎂層30a及貧鎂層20a。(2) Obtain a magnesium-rich layer 30a (Mg-rich layer) with a high magnesium content in the surface layer, a magnesium-poor layer 20a (Mg-poor layer) with a thickness of >10 μm, and an alloy layer 10a (Original Mg-content layer) with original magnesium content ) Of an alloy structure. The magnesium content of the magnesium-rich layer 30a is 0.1-100%. In addition, the thickness of the magnesium-depleted layer 20a differs depending on the degree of vacuum and the holding time and temperature of the vacuum heat treatment. The higher the degree of vacuum, the longer the holding time and the higher the holding temperature, the thicker the thickness of the magnesium-depleted layer 20a . Moreover, the lower edge of the magnesium-depleted layer 20a in the alloy structure to the place in contact with the fixture P is the aluminum alloy with the original magnesium content, that is, the aluminum alloy does not expose the surface to the vacuum contact, and the magnesium-rich layer will not be generated 30a and magnesium-depleted layer 20a.

(3) 進行表面削減處理:將獲得的合金結構進行表面削減處理來削減富鎂層30a,削減掉富鎂層30a之後可得到低鎂含量的一焊接表面。所述焊接表面即為貧鎂層20a的一低鎂含量之表面201a,並且貧鎂層20a會因為50℃以上的非真空下烘烤消失,越高溫度消失速度越快。因此,貧鎂層20a要適合焊接,厚度至少要>10μm。另外,表面削減之方式可為酸洗/鹼洗/研磨/拋光/蝕刻等非加熱式減薄方法,或其它加熱式減薄方法,或其它在真空或保護氣氛或惰性氣氛下之減薄方法,如電漿清潔等。(3) Surface reduction treatment: The obtained alloy structure is subjected to surface reduction treatment to reduce the magnesium-rich layer 30a. After the magnesium-rich layer 30a is reduced, a welded surface with low magnesium content can be obtained. The welding surface is a low magnesium content surface 201a of the magnesium-depleted layer 20a, and the magnesium-depleted layer 20a will disappear due to non-vacuum baking above 50°C, and the higher the temperature, the faster the rate of disappearance. Therefore, the magnesium-depleted layer 20a should be suitable for welding, and the thickness should be at least >10 μm. In addition, the surface reduction method may be non-heating thinning methods such as pickling/alkali cleaning/grinding/polishing/etching, or other heating thinning methods, or other thinning methods under vacuum or protective atmosphere or inert atmosphere , Such as plasma cleaning.

進一步來說,本實施例的鋁合金M為具有鎂(Mg)元素的6系鋁合金,因為有Mg元素強化的6系鋁合金,具有較沒有Mg元素強化的3系、1系鋁合金(純鋁)還要強的強度,且經過高溫軟化後,尚能使用後續的熱處理製程,回復其強度硬度,本結構只會少量改變表面元素濃度,不會大量影響整體的元素含量,可以有效維持6系鋁合金原本的特性,例如可熱處理、強度強等。但是,本結構可以使6系的鋁合金形成類比於易於焊接的3系及1系鋁合金的低鎂表面之狀況。Furthermore, the aluminum alloy M of the present embodiment is a 6-series aluminum alloy with magnesium (Mg) element. Since the 6-series aluminum alloy strengthened with Mg element has 3-series and 1-series aluminum alloys less strengthened with Mg element ( (Pure aluminum) has stronger strength, and after softening at high temperature, it can still use the subsequent heat treatment process to restore its strength and hardness. This structure will only change the surface element concentration by a small amount, will not greatly affect the overall element content, and can be effectively maintained. The original characteristics of 6-series aluminum alloy, such as heat treatment and strong strength. However, this structure can make the 6-series aluminum alloy form an analogous state to the low-magnesium surface of the 3-series and 1-series aluminum alloys that are easy to weld.

需說明的是,本創作提供的方法及結構除了應用在鋁合金,也可以應用在其它含鎂的合金上。此外,此方法及結構不限於去除鎂含量,其它容易在真空中揮發或是聚集到合金表面之元素也可適用,如鋅等。也就是說,本創作除了能應用在強化鋁合金之焊接性外,也可以應用在其它合金需要減少表面存在易氧化固溶元素,如鎂、鋅等。It should be noted that the method and structure provided in this creation can be applied to other magnesium-containing alloys in addition to aluminum alloys. In addition, this method and structure are not limited to the removal of magnesium content, and other elements that are easy to volatilize in vacuum or accumulate on the alloy surface, such as zinc, are also applicable. In other words, in addition to strengthening the weldability of aluminum alloys, this creation can also be applied to other alloys that need to reduce the presence of easily oxidized solid solution elements, such as magnesium and zinc.

綜合以上所述,本創作所提供的一種具有低鎂含量之表面之合金結構,其具有原鎂含量之合金層、以及形成在所述原鎂含量之合金層外的貧鎂層,且所述貧鎂層具有一低鎂含量之表面,能強化合金之焊接性,提升銲錫接合的良率。In summary, the alloy structure with low magnesium content surface provided by this work has an alloy layer with original magnesium content and a magnesium-depleted layer formed outside the alloy layer with original magnesium content, and the The magnesium-depleted layer has a surface with low magnesium content, which can enhance the weldability of the alloy and improve the yield of solder joints.

以上所述僅為本創作之較佳可行實施例,其並非用以侷限本創作之專利範圍,凡依本創作申請專利範圍所做之均等變化與修飾,皆應屬本創作之涵蓋範圍。The above is only a preferred and feasible embodiment of this creation, and it is not intended to limit the scope of the patent of this creation. Any changes and modifications made in accordance with the patent scope of this creation shall fall within the scope of this creation.

10,10a:原鎂含量之合金層 20,20a:貧鎂層 30a:富鎂層 201,201a:低鎂含量之表面 M:鋁合金 P:治具10,10a: alloy layer with original magnesium content 20, 20a: magnesium poor layer 30a: Magnesium-rich layer 201,201a: Low magnesium content surface M: aluminum alloy P: Fixture

圖1示意性地示出了本創作具有低鎂含量之表面之合金結構。FIG. 1 schematically shows the alloy structure of the surface with low magnesium content in this creation.

圖2示意性地示出了本創作的合金表面處理方法。FIG. 2 schematically shows the alloy surface treatment method of the present creation.

10:原鎂含量之合金層 10: Alloy layer with original magnesium content

20:貧鎂層 20: magnesium-depleted layer

201:低鎂含量之表面 201: Low magnesium content surface

Claims (4)

一種具有低鎂含量之表面之合金結構,包括:一原鎂含量之合金層、以及一形成在所述原鎂含量之合金層外的貧鎂層;其中,所述貧鎂層具有一低鎂含量之表面。An alloy structure with a low magnesium content surface includes: an alloy layer of raw magnesium content and a magnesium-depleted layer formed outside the alloy layer of raw magnesium content; wherein the magnesium-depleted layer has a low magnesium content Content of the surface. 如申請專利範圍第1項所述的具有低鎂含量之表面之合金結構,其中,所述貧鎂層的厚度至少大於10μm。The alloy structure having a surface with low magnesium content as described in item 1 of the patent application range, wherein the thickness of the magnesium-depleted layer is at least greater than 10 μm. 如申請專利範圍第1項所述的具有低鎂含量之表面之合金結構,其中,所述貧鎂層及所述原鎂含量之合金層是由含鎂的鋁合金所製成,且所述貧鎂層的鎂含量小於所述原鎂含量之合金層的鎂含量。The alloy structure with a low magnesium content surface as described in item 1 of the patent application scope, wherein the magnesium-depleted layer and the original magnesium content alloy layer are made of an aluminum alloy containing magnesium, and the The magnesium content of the magnesium-depleted layer is less than the magnesium content of the alloy layer with the original magnesium content. 如申請專利範圍第1項所述的具有低鎂含量之表面之合金結構,其中,所述貧鎂層的低鎂含量之表面是透過削減經熱處理的鋁合金之表面所形成。The alloy structure with a low magnesium content surface as described in item 1 of the patent application range, wherein the low magnesium content surface of the magnesium-depleted layer is formed by reducing the surface of the heat-treated aluminum alloy.
TW108216026U 2019-12-02 2019-12-02 Alloy structure with surface of low magnesium content TWM592442U (en)

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