TWM464821U - Semiconductor device and its terminal area structure - Google Patents

Semiconductor device and its terminal area structure Download PDF

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TWM464821U
TWM464821U TW102207131U TW102207131U TWM464821U TW M464821 U TWM464821 U TW M464821U TW 102207131 U TW102207131 U TW 102207131U TW 102207131 U TW102207131 U TW 102207131U TW M464821 U TWM464821 U TW M464821U
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trench
layer
insulating layer
trenches
conductive material
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TW102207131U
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Wen-Bin Lin
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Economic Semiconductor Corp
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Priority to TW102207131U priority Critical patent/TWM464821U/en
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Priority to CN201420016126.3U priority patent/CN203733800U/en

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Description

半導體裝置及其終端區結構 Semiconductor device and its terminal area structure

本創作係關於半導體裝置及其終端區結構,特別是關於具有溝槽結構之半導體裝置及其終端區結構。 The present invention relates to a semiconductor device and its termination region structure, and more particularly to a semiconductor device having a trench structure and its termination region structure.

肖特基二極體(Schottky diode)是由金屬與半導體接面所構成之半導體裝置,且由於其啟動電壓較低且反應速度較快,目前廣泛地應用在各種電子電路中,例如電源轉換電路。傳統的肖特基二極體結構包含高濃度摻雜的半導體基板,其材料通常為單晶矽;以及作為陰極區之半導體層,係具有與前述基板相同導電性之載子的較低濃度摻雜材料;並具有金屬層或金屬矽化物層形成於輕度摻雜的陰極區上,以形成肖特基能障(Schottky barrier)並構成二極體的陽極。 Schottky diode is a semiconductor device composed of a metal and a semiconductor junction. Due to its low starting voltage and fast response speed, it is widely used in various electronic circuits, such as power conversion circuits. . The conventional Schottky diode structure comprises a high concentration doped semiconductor substrate, the material of which is usually a single crystal germanium; and a semiconductor layer as a cathode region, which has a lower concentration of a carrier having the same conductivity as the substrate described above. a hetero-material; and having a metal layer or a metal telluride layer formed on the lightly doped cathode region to form a Schottky barrier and constituting the anode of the diode.

肖特基二極體的特性為速度快,且僅需較低的正向偏壓,即可有較大的順向電流與較短的反向回復時間。然而,當反向偏壓持續增加時,則會有較大的漏電流(取決於金屬之功函數及半導體之摻雜濃度)。因此,習知技術的溝槽式肖特基能障二極體,便是藉由於溝槽中填入多晶矽或金屬以截止(pinch off)反向漏電流。 Schottky diodes are characterized by high speed and require only a low forward bias to have a large forward current and a short reverse recovery time. However, when the reverse bias voltage continues to increase, there is a large leakage current (depending on the work function of the metal and the doping concentration of the semiconductor). Therefore, the trench type Schottky barrier diode of the prior art is to pinch off the reverse leakage current by filling the trench with polysilicon or metal.

習知的溝槽式肖特基二極體,可參考US 2010/0327288號美國公開專利申請案。圖1(a)為該案所揭示之溝槽式肖特基二極體 裝置,包含:具有一多溝渠結構11之半導體基板12;一第一罩幕層13,形成於該半導體基板12之表面上;一閘極氧化層14,形成於該多溝渠結構11之表面上,該閘極氧化層14並凸出於該半導體基板12之表面;一多晶矽結構15,形成於該閘極氧化層14上,該多晶矽結構15並凸出於該半導體基板12之表面;一第二罩幕層16,形成於該第一罩幕層13上與部份之該多晶矽結構15上;以及一金屬濺鍍層17,形成於該第二罩幕層16、該半導體基板12、該多晶矽結構15和該閘極氧化層14之部份表面上。 A conventional grooved Schottky diode can be found in U.S. Patent Application Serial No. 2010/0327,288. Figure 1 (a) shows the trench Schottky diode disclosed in the case. The device comprises: a semiconductor substrate 12 having a multi-ditch structure 11; a first mask layer 13 formed on a surface of the semiconductor substrate 12; and a gate oxide layer 14 formed on a surface of the multi-ditch structure 11 The gate oxide layer 14 protrudes from the surface of the semiconductor substrate 12; a polysilicon structure 15 is formed on the gate oxide layer 14, and the polysilicon structure 15 protrudes from the surface of the semiconductor substrate 12; a second mask layer 16 formed on the first mask layer 13 and a portion of the polysilicon structure 15; and a metal sputtering layer 17 formed on the second mask layer 16, the semiconductor substrate 12, and the polysilicon layer Structure 15 and a portion of the surface of the gate oxide layer 14.

此外,圖1(a)之溝槽式肖特基二極體,其製作過程包含:提供一半導體基板(12);於該半導體基板(12)上形成一第一罩幕層(13);根據該第一罩幕層(13)對該半導體基板(12)進行蝕刻,以於該半導體基板(12)中形成一多溝渠結構(11);於該多溝渠結構(11)之表面上形成一閘極氧化層(14);於該閘極氧化層(14)上與該第一罩幕層(13)上形成一多晶矽結構(15);對該多晶矽結構(15)進行蝕刻,以將該第一罩幕層(13)之頂面與部份側面加以露出;於部份之該多晶矽結構(15)上與部份之該第一罩幕層(13)上形成一第二罩幕層(16),以將該半導體基板(12)、該多晶矽結構(15)和該閘極氧化層(14)之部份表面加以露出;於該第二罩幕層(16)上與該半導體基板(12)、該多晶矽結構(15)和該閘極氧化層(14)之部份表面上形成一金屬濺鍍層(17);以及對該金屬濺鍍層(17)進行蝕刻,以將該第二罩幕層(16)之部份表面加以露出等步驟。 In addition, the trench Schottky diode of FIG. 1(a) is formed by: providing a semiconductor substrate (12); forming a first mask layer (13) on the semiconductor substrate (12); The semiconductor substrate (12) is etched according to the first mask layer (13) to form a multi-ditch structure (11) in the semiconductor substrate (12); formed on the surface of the multi-ditch structure (11) a gate oxide layer (14); forming a polysilicon structure (15) on the gate oxide layer (14) and the first mask layer (13); etching the polysilicon structure (15) to The top surface and a portion of the first mask layer (13) are exposed; a second mask is formed on a portion of the polysilicon structure (15) and a portion of the first mask layer (13) a layer (16) for exposing a portion of the surface of the semiconductor substrate (12), the polysilicon structure (15) and the gate oxide layer (14); and the semiconductor on the second mask layer (16) Forming a metal sputter layer (17) on a portion of the substrate (12), the polysilicon structure (15), and the gate oxide layer (14); and etching the metal sputter layer (17) to Part of the second cover layer (16) The surface is exposed and the like.

然而,在習知溝槽式肖特基二極體的終端區內,複數溝槽中的多晶矽並未與金屬層電連接,使得元件在反向操作時該複數溝 槽皆為電位浮動狀態,無法延展並分散終端區電場分佈,造成較強電場彎曲現象(electric field crowding),故無法有效地提高崩潰電壓(breakdown voltage),對於較高功率或電壓的半導體裝置而言仍有其應用上的限制。因此,如何設計並製作高崩潰電壓、低反向漏電流的肖特基二極體,遂成為亟待解決的課題。 However, in the termination region of the conventional trench Schottky diode, the polysilicon in the plurality of trenches is not electrically connected to the metal layer, so that the plurality of trenches in the reverse operation of the component The slots are all in a potential floating state, and the electric field distribution in the terminal region cannot be extended and dispersed, resulting in a strong electric field crowding, so that the breakdown voltage cannot be effectively increased for a higher power or voltage semiconductor device. There are still restrictions on its application. Therefore, how to design and fabricate a Schottky diode with high breakdown voltage and low reverse leakage current has become an urgent problem to be solved.

針對前述習知技術的不足,本創作提出一種連結溝槽結構,可廣泛地應用於溝槽式之半導體裝置。藉由將複數溝槽中一部分或數部分之相鄰溝槽導通,半導體裝置中的電場分布即隨之改變,進而可改善其電流-電壓特性。同樣地,亦可進一步藉由改變連結溝槽之配置,來調整半導體裝置的特性,使其適用於不同應用的需求。 In view of the deficiencies of the prior art, the present invention proposes a joint trench structure that can be widely applied to trench type semiconductor devices. By conducting a portion or portions of adjacent trenches in the plurality of trenches, the electric field distribution in the semiconductor device changes, thereby improving current-voltage characteristics. Similarly, the characteristics of the semiconductor device can be further adjusted by changing the configuration of the connection trenches to suit the needs of different applications.

本創作之一態樣為半導體裝置的終端區結構,其中包含:一半導體層;形成於該半導體層表面之複數溝槽;形成於該半導體層之表面、用於連接該複數溝槽中相鄰之一第一溝槽及一第二溝槽的第一連結溝槽;形成於該複數溝槽之表面、該連結溝槽之表面、及該半導體層未形成該複數溝槽或該連結溝槽之表面的第一絕緣層;形成並填滿於表面具有該第一絕緣層之該複數溝槽及該第一連結溝槽內的導電材料(例如多晶矽或鎢),該第一溝槽及該第二溝槽內所填充之該導電材料會藉由該第一連結溝槽內所填充之該導電材料而導通;至少覆蓋部分該第一絕緣層未接觸該導電材料之表面及該導電材料未接觸該第一絕緣層之表面的第二絕緣層;及至少覆蓋該第二絕緣層之部分表面的金屬層。在該第一溝槽中,可使該第二絕緣層覆蓋部分該導 電材料未與該第一絕緣層接觸之表面,且該金屬層覆蓋其他部分該導電材料未與該第一絕緣層接觸之表面;而該金屬層所覆蓋之該其他部分該導電材料之表面更可形成有一金屬矽化物層或一肖特基金屬層。而該第一連結溝槽可進一步配置為垂直該第一溝槽及該第二溝槽,或垂直於該第一溝槽之切線及該第二溝槽之切線。上述之半導體裝置之終端區結構,可進一步包含用於連接該複數溝槽中之該第二溝槽及一第三溝槽的第二連結溝槽,該第三溝槽鄰次於該第二溝槽;其中該第二連結溝槽與該第一連結溝槽可交錯配置,亦即二者不共線。上述半導體裝置之終端區結構中的該第二連結溝槽,亦可用於連接該複數溝槽中相鄰之一第三溝槽及一第四溝槽,此時該第一連結溝槽與該第二連結溝槽不導通。此半導體裝置之終端區結構可應用於不同型式之半導體裝置,例如肖特基二極體、金屬氧化物半導體場效電晶體、雙極接面電晶體、或絕緣閘雙極電晶體等。 One aspect of the present invention is a termination region structure of a semiconductor device, comprising: a semiconductor layer; a plurality of trenches formed on a surface of the semiconductor layer; formed on a surface of the semiconductor layer for connecting adjacent ones of the plurality of trenches a first trench having a first trench and a second trench; a surface formed on the surface of the plurality of trenches, a surface of the bonding trench, and the semiconductor layer not forming the plurality of trenches or the connecting trench a first insulating layer on the surface; forming and filling the plurality of trenches having the first insulating layer on the surface and a conductive material (such as polysilicon or tungsten) in the first connecting trench, the first trench and the The conductive material filled in the second trench is turned on by the conductive material filled in the first connecting trench; at least a portion of the surface of the first insulating layer not contacting the conductive material and the conductive material are not covered a second insulating layer contacting the surface of the first insulating layer; and a metal layer covering at least a portion of the surface of the second insulating layer. In the first trench, the second insulating layer may be covered by the portion of the guide a surface of the electrically insulating material that is not in contact with the first insulating layer, and the metal layer covers a surface of the other portion of the electrically conductive material that is not in contact with the first insulating layer; and the other portion of the electrically conductive material covered by the metal layer is further A metal telluride layer or a Schottky metal layer may be formed. The first connecting trench can be further configured to be perpendicular to the first trench and the second trench, or perpendicular to a tangent to the first trench and a tangent to the second trench. The terminal region structure of the semiconductor device may further include a second connection trench for connecting the second trench and the third trench in the plurality of trenches, the third trench being adjacent to the second trench a trench; wherein the second connecting trench and the first connecting trench are staggered, that is, the two are not collinear. The second connecting trench in the terminal region structure of the semiconductor device may also be used to connect adjacent one of the third trench and the fourth trench in the plurality of trenches, and the first connecting trench and the The second joint groove is not electrically conductive. The terminal region structure of the semiconductor device can be applied to different types of semiconductor devices, such as Schottky diodes, metal oxide semiconductor field effect transistors, bipolar junction transistors, or insulated gate bipolar transistors.

本創作之另一態樣為一種半導體裝置,具有一主動區及一終端區,包含一半導體層;形成於該半導體層表面之複數溝槽;形成於該半導體層表面且位於該終端區、連接該複數溝槽中相鄰之二溝槽的連結溝槽;一第一絕緣層,形成於主動區中該複數溝槽及該連結溝槽之部分表面,其上緣低於該半導體層未形成溝槽之表面,並形成於該終端區中該複數溝槽之表面、該連結溝槽之表面、及該半導體層未形成該複數溝槽或該連結溝槽之表面;導電材料,形成於該複數溝槽及該連結溝槽內,且完全覆蓋該複數溝槽底部及該連結溝槽底部之第一絕緣層;一第二絕緣層,於終端區中至少覆蓋部分該第一絕緣層 未接觸該導電材料之表面及部分該導電材料未接觸該第一絕緣層之表面;及一金屬層,至少覆蓋該主動區與該第二絕緣層之部分表面。 Another aspect of the present invention is a semiconductor device having an active region and a termination region, including a semiconductor layer; a plurality of trenches formed on a surface of the semiconductor layer; formed on a surface of the semiconductor layer and located in the termination region, connected a connecting trench of two adjacent trenches in the plurality of trenches; a first insulating layer formed on the surface of the plurality of trenches and the connecting trenches in the active region, the upper edge of which is lower than the semiconductor layer is not formed a surface of the trench formed in the termination region, a surface of the plurality of trenches, a surface of the bonding trench, and a surface of the semiconductor layer not forming the plurality of trenches or the bonding trench; a conductive material formed on the surface a plurality of trenches and the first insulating layer in the connecting trench and completely covering the bottom of the plurality of trenches and the bottom of the connecting trench; a second insulating layer covering at least a portion of the first insulating layer in the termination region a surface not contacting the conductive material and a portion of the conductive material not contacting the surface of the first insulating layer; and a metal layer covering at least a portion of the surface of the active region and the second insulating layer.

本創作之另一態樣為肖特基二極體,具有一主動區及一終端區,包含:一半導體層;形成於該半導體層之表面的複數溝槽;形成於該半導體層之表面且位於該終端區的連結溝槽,用於連接該複數溝槽中相鄰之一第一溝槽及一第二溝槽;形成於該複數溝槽之至少部分表面、該連結溝槽之至少部分表面、及該終端區中該半導體層未形成該複數溝槽或該連結溝槽之表面的第一絕緣層;形成於表面具有該第一絕緣層之該複數溝槽及該第一連結溝槽內之導電材料(例如多晶矽或鎢),該第一溝槽及該第二溝槽內所填充之該導電材料藉由該第一連結溝槽內所填充之該導電材料而導通;於該終端區中至少覆蓋部分該第一絕緣層未接觸該導電材料之表面及部分該導電材料未接觸該第一絕緣層之表面的第二絕緣層;及至少覆蓋該主動區及該第二絕緣層之部分表面的金屬層。在上述第一溝槽中,該第二絕緣層可覆蓋部分該導電材料未與該第一絕緣層接觸之表面,且該金屬層覆蓋其他部分該導電材料未與該第一絕緣層接觸之表面。此外,在該主動區中,該半導體層及該導電材料未接觸該第一絕緣層之表面,可進一步形成一金屬矽化物層或一肖特基金屬層。 Another aspect of the present invention is a Schottky diode having an active region and a termination region, comprising: a semiconductor layer; a plurality of trenches formed on a surface of the semiconductor layer; formed on a surface of the semiconductor layer and a connecting trench located in the terminal region for connecting one of the first trench and the second trench in the plurality of trenches; forming at least part of a surface of the plurality of trenches, at least a portion of the connecting trench a first insulating layer on the surface and the semiconductor layer in the terminal region where the plurality of trenches or the surface of the connecting trench is not formed; the plurality of trenches having the first insulating layer formed on the surface and the first connecting trench a conductive material (for example, polysilicon or tungsten), wherein the conductive material filled in the first trench and the second trench is turned on by the conductive material filled in the first connecting trench; At least a portion of the first insulating layer not contacting the surface of the conductive material and a portion of the second insulating layer not contacting the surface of the first insulating layer; and covering at least the active region and the second insulating layer Partial surface metal . In the first trench, the second insulating layer may cover a surface of the conductive material not in contact with the first insulating layer, and the metal layer covers other surfaces of the conductive material not in contact with the first insulating layer . In addition, in the active region, the semiconductor layer and the conductive material are not in contact with the surface of the first insulating layer, and a metal telluride layer or a Schottky metal layer may be further formed.

本創作之另一態樣為肖特基二極體之製造方法,包含下列步驟:(1)於半導體層上形成溝槽結構,該溝槽結構包含複數溝槽及連結該複數溝槽中相鄰二溝槽之複數連結溝槽;(2)形成第一絕緣層,該第一絕緣層覆蓋該溝槽結構之表面及該半導體層未形成該溝槽結構 之表面;(3)於覆蓋該第一絕緣層之該溝槽結構中形成導電材料以填滿該溝槽結構;(4)形成第二絕緣層,用於覆蓋該第一絕緣層未接觸該導電材料之表面及該導電材料未接觸該第一絕緣層之表面;(5)移除部分之該第二及第一絕緣層,使其中之該導電材料上緣及該半導體層未形成溝槽區域之表面露出;(6)至少於露出之該導電材料上緣及該半導體層未形成溝槽區域之表面形成一金屬矽化物層或肖特基金屬層;(7)形成一第一金屬層,以覆蓋移除部分之該第二及第一絕緣層之區域以及部分之該第二絕緣層;及(8)形成一保護層,以覆蓋部分該第一金屬層及部分該第二絕緣層。上述的形成溝槽結構步驟,更可包含:(1A)於該半導體層上形成一硬罩層;(1B)圖案化該硬罩層,使該半導體層欲形成該溝槽結構之部分露出;(1C)以乾式蝕刻方式使未受該硬罩層覆蓋之區域形成該溝槽結構;及(1D)移除圖案化後之該硬罩層。上述的圖案化該硬罩層之步驟,更可包含使用光微影及乾式蝕刻等方式。上述形成該第一絕緣層之步驟,可使用熱氧化或化學氣相沉積方式形成一二氧化矽層。上述形成該導電材料之步驟可進一步包含:(3A)以化學氣相沉積方式沉積該多晶矽,使該多晶矽覆蓋該第一絕緣層並填滿表面具有該第一絕緣層之該溝槽結構;及(3B)以乾式蝕刻去除部分之該多晶矽,使該第一絕緣層之上緣及填滿該溝槽結構之該多晶矽上緣露出;其中移除部分之該第二及第一絕緣層後,該主動區中之溝槽內的該第一絕緣層上緣會低於該半導體層未形成溝槽之表面。上述於露出之該導電材料上緣及該半導體層未形成溝槽區域之表面形成金屬矽化物層之步驟則可包含:(6A)於移除部分之該第二及第一絕緣層的區 域內形成一第二金屬層;(6B)以熱退火(thermal annealing)方式使該導電材料上緣及該半導體層未形成溝槽區域之表面與該第二金屬層反應,形成該金屬矽化物層;及(6C)移除該第二金屬層。在上述的肖特基二極體之製造方法中,移除部分之該第二絕緣層及該第一絕緣層的區域內之溝槽中的該第一絕緣層上緣,可低於該半導體層未形成溝槽部分之表面;此外,步驟(5)移除部分之該第一絕緣層及該第二絕緣層後,未移除之該第一絕緣層及該第二絕緣層的邊界可位於該複數溝槽中之一溝槽內之導電材料上緣。 Another aspect of the present invention is a method for fabricating a Schottky diode, comprising the steps of: (1) forming a trench structure on a semiconductor layer, the trench structure comprising a plurality of trenches and connecting the phase of the plurality of trenches a plurality of adjacent trenches connecting the trenches; (2) forming a first insulating layer, the first insulating layer covering a surface of the trench structure and the semiconductor layer not forming the trench structure a surface; (3) forming a conductive material in the trench structure covering the first insulating layer to fill the trench structure; (4) forming a second insulating layer for covering the first insulating layer not contacting the The surface of the conductive material and the conductive material are not in contact with the surface of the first insulating layer; (5) removing portions of the second and first insulating layers such that the upper edge of the conductive material and the semiconductor layer are not grooved (6) forming a metal telluride layer or a Schottky metal layer at least on the exposed upper surface of the conductive material and the surface of the semiconductor layer where the trench region is not formed; (7) forming a first metal layer And covering the region of the second and first insulating layers and a portion of the second insulating layer; and (8) forming a protective layer to cover a portion of the first metal layer and a portion of the second insulating layer . The step of forming the trench structure may further include: (1A) forming a hard mask layer on the semiconductor layer; (1B) patterning the hard mask layer to expose a portion of the semiconductor layer to form the trench structure; (1C) forming a trench structure by a region that is not covered by the hard mask layer by dry etching; and (1D) removing the patterned hard mask layer. The step of patterning the hard mask layer may further include using light lithography and dry etching. In the above step of forming the first insulating layer, a cerium oxide layer may be formed by thermal oxidation or chemical vapor deposition. The step of forming the conductive material may further include: (3A) depositing the polysilicon by chemical vapor deposition, covering the first insulating layer and filling the trench structure having the first insulating layer on a surface; and (3B) removing a portion of the polysilicon by dry etching, exposing an upper edge of the first insulating layer and an upper edge of the polysilicon filling the trench structure; wherein after removing the second and first insulating layers, The upper edge of the first insulating layer in the trench in the active region may be lower than the surface of the semiconductor layer where the trench is not formed. The step of forming a metal telluride layer on the exposed upper surface of the conductive material and the surface of the semiconductor layer not forming the trench region may include: (6A) removing the portion of the second and first insulating layers Forming a second metal layer in the domain; (6B) reacting the upper edge of the conductive material and the surface of the semiconductor layer not forming the trench region with the second metal layer by thermal annealing to form the metal telluride And removing (6C) the second metal layer. In the above method for manufacturing a Schottky diode, the upper edge of the first insulating layer in the trench in the region of the second insulating layer and the region of the first insulating layer is removed, which may be lower than the semiconductor The layer does not form a surface of the trench portion; further, after the step (5) removes the portion of the first insulating layer and the second insulating layer, the boundary of the first insulating layer and the second insulating layer that are not removed may be An upper edge of the conductive material located in one of the plurality of trenches.

基於上述本創作之意旨,透過加入連結溝槽之終端區結構,可使半導體裝置具有比習知技術更高的崩潰電壓。本創作之具體實施方式說明於後。 Based on the above intention of the present invention, the semiconductor device can be made to have a higher breakdown voltage than the prior art by adding the termination region structure of the connection trench. The specific implementation of this creation is described later.

11‧‧‧多溝渠結構 11‧‧‧Multi-ditch structure

12‧‧‧半導體基板 12‧‧‧Semiconductor substrate

13‧‧‧第一罩幕層 13‧‧‧First mask layer

14‧‧‧閘極氧化層 14‧‧‧ gate oxide layer

15‧‧‧多晶矽結構 15‧‧‧ Polycrystalline structure

16‧‧‧第二罩幕層 16‧‧‧Second mask

17‧‧‧金屬濺鍍層 17‧‧‧Metal Sputter

34,34a,34b,34c,221~223‧‧‧溝槽 34, 34a, 34b, 34c, 221~223‧‧‧ trench

31‧‧‧主動區 31‧‧‧Active Area

32‧‧‧終端區 32‧‧‧ Terminal Area

33‧‧‧半導體層 33‧‧‧Semiconductor layer

37‧‧‧導電材料 37‧‧‧Electrical materials

38,67‧‧‧金屬層 38,67‧‧‧metal layer

39,68‧‧‧保護層 39,68‧‧‧Protective layer

61‧‧‧磊晶層 61‧‧‧ epitaxial layer

62‧‧‧硬罩層 62‧‧‧ hard cover

65‧‧‧多晶矽 65‧‧‧Polysilicon

66‧‧‧金屬矽化物層(肖特基金屬層) 66‧‧‧metal telluride layer (Schottky metal layer)

211~216,351,352‧‧‧連結溝槽 211~216,351,352‧‧‧Link groove

361,641‧‧‧第一絕緣層 361,641‧‧‧first insulation

362,642‧‧‧第二絕緣層 362,642‧‧‧Second insulation

631,632,633,634‧‧‧光阻層 631, 632, 633, 634 ‧ ‧ photoresist layer

圖1(a)為習知溝槽式肖特基二極體之橫截面示意圖,圖1(b)為其部分溝槽結構之俯視示意圖。 1(a) is a schematic cross-sectional view of a conventional trench Schottky diode, and FIG. 1(b) is a top plan view of a portion of the trench structure.

圖2(a)為本創作提出之一肖特基二極體的部分溝槽與連結溝槽俯視示意圖;圖2(b)為本創作提出之另一肖特基二極體的部分溝槽與連結溝槽俯視示意圖;圖2(c)為本創作提出之另一肖特基二極體的部分溝槽與連結溝槽俯視示意圖;圖2(d)為本創作提出之另一肖特基二極體的部分溝槽與連結溝槽 俯視示意圖。 2(a) is a schematic top view of a portion of a trench and a connecting trench of a Schottky diode according to the present invention; FIG. 2(b) is a partial trench of another Schottky diode of the present invention. FIG. 2(c) is a top view of a portion of the trench and the connecting trench of another Schottky diode proposed by the present invention; FIG. 2(d) is another schematic of the present invention. Partial trench and joint trench of base diode A bird's eye view.

圖3(a)~(c)為本創作提出之肖特基二極體的不同位置橫截面示意圖。 3(a) to (c) are schematic cross-sectional views of different positions of the Schottky diode proposed in the present application.

圖4(a)為習知肖特基二極體之電場分布示意圖,圖4(b)為本創作提出之肖特基二極體的電場分布示意圖。 4(a) is a schematic diagram showing the electric field distribution of a conventional Schottky diode, and FIG. 4(b) is a schematic diagram showing the electric field distribution of the Schottky diode proposed in the present invention.

圖5為本創作提出之肖特基二極體與習知肖特基二極體的電流-電壓曲線比較示意圖。 FIG. 5 is a schematic diagram showing current-voltage curves of a Schottky diode and a conventional Schottky diode according to the present invention.

圖6(a)~(z)為本創作提出之肖特基二極體的製造流程示意圖。 Fig. 6(a)~(z) are schematic diagrams showing the manufacturing process of the Schottky diode proposed in the creation.

依據前述之發明意旨,以下配合圖式說明本創作具體實施方式之例示。其中各圖式所揭示之元件結構僅為輔助說明之用,並不代表實際結構之尺寸或比例,亦非限定實際元件全部之組成。 Illustrative of the specific embodiments of the present invention will be described below in conjunction with the drawings. The structure of the components disclosed in the drawings is for illustrative purposes only, and does not represent the size or proportion of the actual structure, nor does it limit the overall composition of the actual components.

對應於圖1(a)之習知肖特基二極體結構,圖1(b)相當於其終端區之溝槽部分的俯視圖,亦可將之理解為半導體裝置製造過程中使用的部分光罩圖案。本創作之一具體例為具有連結溝槽的半導體裝置之終端區,利用連結溝槽將習知溝槽式半導體裝置中之某些溝槽加以導通,其終端區部分的俯視圖可如圖2(a)~(d)所示。同樣地,圖2(a)~(d)亦可理解為溝槽部分之光罩圖案。圖2(a)~(d)與圖1(b)之差異在於增加不同配置之連結溝槽,其個別對應之元件,亦將隨該等連結溝槽配置之差異而有不同的電壓-電流特性。圖2(a)所對應的元件,其複數連結溝槽211用於導通終端區最內側之溝槽221與溝槽222;當各個溝槽與連結溝槽內填入導電材料之後,溝槽221、222與連結溝槽211 內的導電材料電位將會相同。然而,連結溝槽亦可繼續向外延伸配置。如圖2(b)之圖案所示,進一步包含複數連結溝槽212,用以連結溝槽222與溝槽223;其中,連結溝槽211與連結溝槽212可對應設置於一直線上,亦可如圖2(b)所示不共線地交錯配置,二者相對位置的不同將對應產生半導體裝置內的不同電場分布,亦即不同的電流-電壓曲線。此外,連結溝槽亦可如圖2(c)所示採取分區配置。圖2(c)除了有相當於圖2(a)的複數連結溝槽211,用以連結最內側的兩個溝槽,更包含複數連結溝槽213、214、215、及216,使最外側的五個溝槽得以導通。圖2(d)則是以圖2(b)為基礎,進一步設置複數連結溝槽214、215、及216,以連結最外側的四個溝槽。換言之,圖2(c)、(d)所揭示之結構具有兩組溝槽,同組之溝槽相互導通,而不同組的溝槽並不會導通。換言之,填入導電材料之後,同組之溝槽將為等電位。基於相同的概念,亦可延伸出更多組溝槽的設計。 Corresponding to the conventional Schottky diode structure of FIG. 1(a), FIG. 1(b) corresponds to a top view of the trench portion of the termination region, and can also be understood as a part of the light used in the manufacturing process of the semiconductor device. Cover pattern. One specific example of the present invention is a terminal region of a semiconductor device having a connection trench, and some trenches in a conventional trench semiconductor device are turned on by using a connection trench, and a top view of a terminal region portion thereof can be as shown in FIG. 2 ( a)~(d). Similarly, Figures 2(a)-(d) can also be understood as the reticle pattern of the groove portion. The difference between Fig. 2(a) and (d) and Fig. 1(b) is that the connection trenches with different configurations are added, and the corresponding components will also have different voltage-currents depending on the difference of the configuration of the connection trenches. characteristic. 2(a), the plurality of connection trenches 211 are used to turn on the innermost trenches 221 and trenches 222 of the termination region; after the trenches and the trenches are filled with conductive material, the trenches 221 , 222 and the joint groove 211 The potential of the conductive material inside will be the same. However, the joining grooves can also continue to extend outwardly. As shown in the pattern of FIG. 2( b ), a plurality of connecting trenches 212 are further included for connecting the trenches 222 and the trenches 223 . The connecting trenches 211 and the connecting trenches 212 can be correspondingly disposed on a straight line. As shown in Fig. 2(b), they are not collinearly staggered, and the relative positions of the two will correspond to different electric field distributions in the semiconductor device, that is, different current-voltage curves. In addition, the connection trench can also be configured in a partition as shown in FIG. 2(c). 2(c), in addition to the plurality of connecting grooves 211 corresponding to FIG. 2(a), for connecting the innermost two grooves, further comprising a plurality of connecting grooves 213, 214, 215, and 216 for the outermost side The five grooves are turned on. 2(d) is based on FIG. 2(b), and further, a plurality of connecting grooves 214, 215, and 216 are provided to connect the four outermost grooves. In other words, the structure disclosed in Figures 2(c) and (d) has two sets of trenches, and the same set of trenches are electrically connected to each other, and different sets of trenches are not turned on. In other words, after filling the conductive material, the trenches of the same group will be equipotential. Based on the same concept, more sets of trench designs can be extended.

此處所謂「導通」,在溝槽結構製作上的意義,係使二個或二個以上的溝槽連接並相通;當溝槽中填入導電材料之後,其效果則是電性上的導通。然而,連結溝槽211~216之型式或尺寸並不以圖2(a)~(d)所示者為限,本領域具有通常知識者當可依元件效能之需求或製程條件限制,選擇合適的型式與尺寸。例如,圖2(a)~(d)中揭示之連結溝槽均與各複數溝槽垂直,或是與各複數溝槽彎曲處的切線垂直,然而這僅是本創作之例示,並非連結溝槽之結構特徵的限制。另一方面,使溝槽之間導通亦不限於使用連結溝槽,例如在圖1(a)的習知結構中,可將其第二罩幕層16開孔,並使金屬濺鍍層17亦填滿該 等開孔,則部分溝槽中之多晶矽結構15也會藉由金屬濺鍍層17而導通。對半導體裝置領域具有通常知識者而言,本創作提出之連結溝槽可適用於各種具有溝槽之終端區的半導體裝置,例如肖特基二極體、金屬氧化物半導體場效電晶體(MOSFET)、雙極接面電晶體(BJT)、或絕緣閘雙極電晶體(IGBT)等。 The term "conduction" as used herein refers to the fabrication of a trench structure in which two or more trenches are connected and connected; when the trench is filled with a conductive material, the effect is electrically conductive. . However, the type or size of the connection grooves 211 to 216 is not limited to those shown in FIGS. 2(a) to (d), and those skilled in the art may select the appropriate ones depending on the requirements of the component performance or the process conditions. Type and size. For example, the connecting grooves disclosed in FIGS. 2(a) to (d) are perpendicular to the respective plural grooves or perpendicular to the tangent of the bending of each of the plurality of grooves, but this is merely an illustration of the present creation, and is not a connecting groove. The limitations of the structural features of the trough. On the other hand, the conduction between the trenches is not limited to the use of the connection trenches. For example, in the conventional structure of FIG. 1(a), the second mask layer 16 can be opened and the metal sputter layer 17 can be Fill it up When the holes are opened, the polysilicon structure 15 in the partial trenches is also turned on by the metal sputtering layer 17. For those of ordinary skill in the field of semiconductor devices, the proposed connection trenches can be applied to various semiconductor devices having trench terminal regions, such as Schottky diodes, metal oxide semiconductor field effect transistors (MOSFETs). ), bipolar junction transistor (BJT), or insulated gate bipolar transistor (IGBT).

以圖2(b)所示之溝槽結構為例,圖3揭示其所對應之肖特基二極體的橫截面結構。首先,圖3(a)相當於是圖2(b)沿線段A-A’之橫截面結構,由於線段A-A’位置所致,圖3(a)所顯示之溝槽部分與習知結構近似〔參見圖1(a)〕。然而,圖3(b)、圖3(c)則分別相當於是圖2(b)中沿線段B-B’、線段C-C’之橫截面結構。由圖3(b)可明顯看出連結溝槽沿線段B-B’導通溝槽221與222,而圖3(b)則可明顯看出連結溝槽沿線段B-B’導通222與223。 Taking the trench structure shown in FIG. 2(b) as an example, FIG. 3 discloses the cross-sectional structure of the corresponding Schottky diode. First, Fig. 3(a) is equivalent to the cross-sectional structure along line A-A' of Fig. 2(b). The groove portion shown in Fig. 3(a) and the conventional structure are due to the position of the line segment A-A'. Approximate [see Figure 1 (a)]. However, Fig. 3(b) and Fig. 3(c) correspond to the cross-sectional structure of the line segment B-B' and the line segment C-C' in Fig. 2(b), respectively. It can be clearly seen from Fig. 3(b) that the bonding trenches are electrically connected to the trenches 221 and 222 along the line segment B-B', and in Fig. 3(b), it is apparent that the bonding trenches are turned on 222 and 223 along the line segment B-B'. .

本創作之另一具體例為一肖特基二極體結構,如圖3(a)所示,其結構可區分為主動區31及終端區32,並包含半導體層33(可例如是較低摻雜濃度之磊晶層)及複數溝槽34,且主動區31及終端區32之交界位於其中一溝槽之側壁。參照圖3(b)及(c),本創作此具體例中包含複數連結溝槽351及352,形成於半導體層33之表面且位於終端區32內,用於連接複數溝槽34之中的相鄰二溝槽。其中,圖3(b)之連結溝槽351對應於圖2(b)之連結溝槽211,圖3(c)之連結溝槽352對應於圖2(b)之連結溝槽212。第一絕緣層361係形成於複數溝槽34、複數連結溝槽351、352之至少部分表面、及終端區32中半導體層33未形成溝槽之表面。關於此處「部分表面」之描述請參考圖6(p),係 指在主動區的溝槽內,第一絕緣層641的最上緣低於磊晶層61未形成溝槽之原始表面;換言之,第一絕緣層641並未完全覆蓋每個溝槽的所有表面。然而,此特徵僅為本創作之例示,可能依元件結構與製程特性而有變化,亦有可能第一絕緣層641完全覆蓋每個溝槽的所有表面。導電材料37則形成於複數溝槽34及複數連結溝槽351、352內,藉由複數連結溝槽351、352內所填充之導電材料37可使相鄰之二溝槽內的導電材料導通。請再參考圖6(p),其中多晶矽65係填滿溝槽中第一絕緣層641內部之空間。在習知技術中,導電材料是否填滿溝槽可能依元件結構與製程特性而有變化;例如當溝槽寬度(相對於深度)較大時,導電材料可能並未填滿第一絕緣層內部之空間,亦即導電材料中央凹陷程度太大,導致並未完全覆蓋溝槽底部之第一絕緣層。然而基於本創作之主旨,若導電材料未完全覆蓋溝槽底部之第一絕緣層,可能導致同一溝槽內的導電材料不導通,而連結溝槽也無法使相鄰之二溝槽導通。另外,在終端區32中,第二絕緣層362覆蓋第一絕緣層361上緣表面及導電材料37上緣之表面。在主動區31中,金屬矽化物層形成於半導體層33上緣之表面及導電材料37上緣之表面,亦可能形成於第一絕緣層361未接觸半導體層33及導電材料37而露出之表面(因比例較小,圖3(a)~(c)中均未繪示,請參考圖6(q)元件編號65)。金屬層38則覆蓋該金屬矽化物層表面及第二絕緣層362之部分表面,最外層並可覆蓋保護層39。 Another specific example of the present invention is a Schottky diode structure, as shown in FIG. 3(a), the structure of which can be divided into an active region 31 and a termination region 32, and includes a semiconductor layer 33 (which can be, for example, lower) A doped concentration epitaxial layer) and a plurality of trenches 34, and the boundary between the active region 31 and the termination region 32 is located on a sidewall of one of the trenches. Referring to FIGS. 3(b) and 3(c), the present embodiment includes a plurality of connection trenches 351 and 352 formed on the surface of the semiconductor layer 33 and located in the termination region 32 for connecting the plurality of trenches 34. Adjacent to the two grooves. The connection groove 351 of FIG. 3(b) corresponds to the connection groove 211 of FIG. 2(b), and the connection groove 352 of FIG. 3(c) corresponds to the connection groove 212 of FIG. 2(b). The first insulating layer 361 is formed on at least a part of the surface of the plurality of trenches 34, the plurality of connection trenches 351, 352, and the surface of the termination region 32 where the semiconductor layer 33 is not formed with a trench. Please refer to Figure 6(p) for a description of the "partial surface" here. It is meant that in the trench of the active region, the uppermost edge of the first insulating layer 641 is lower than the original surface of the epitaxial layer 61 where the trench is not formed; in other words, the first insulating layer 641 does not completely cover all surfaces of each trench. However, this feature is merely an illustration of the present invention, and may vary depending on the component structure and process characteristics, and it is also possible that the first insulating layer 641 completely covers all surfaces of each trench. The conductive material 37 is formed in the plurality of trenches 34 and the plurality of connection trenches 351 and 352. The conductive material 37 filled in the plurality of trenches 351 and 352 can electrically conduct the conductive material in the adjacent trenches. Referring again to FIG. 6(p), the polysilicon 65 fills the space inside the first insulating layer 641 in the trench. In the prior art, whether the conductive material fills the trench may vary depending on the component structure and the process characteristics; for example, when the trench width (relative to the depth) is large, the conductive material may not fill the inside of the first insulating layer. The space, that is, the central depression of the conductive material is too large, resulting in the first insulating layer not completely covering the bottom of the trench. However, based on the main idea of the present invention, if the conductive material does not completely cover the first insulating layer at the bottom of the trench, the conductive material in the same trench may not be turned on, and the connecting trench may not turn on the adjacent trench. In addition, in the termination region 32, the second insulating layer 362 covers the upper edge surface of the first insulating layer 361 and the surface of the upper edge of the conductive material 37. In the active region 31, a metal telluride layer is formed on the surface of the upper edge of the semiconductor layer 33 and the upper surface of the conductive material 37, and may also be formed on the surface of the first insulating layer 361 which is not exposed to the semiconductor layer 33 and the conductive material 37. (Because of the small proportion, not shown in Figure 3 (a) ~ (c), please refer to Figure 6 (q) component number 65). The metal layer 38 covers the surface of the metal telluride layer and a portion of the surface of the second insulating layer 362, and the outermost layer may cover the protective layer 39.

在圖3(a)~(c)、圖6(q)及前段說明揭示的結構中,金屬矽化物層係用於形成肖特基能障,亦可使用一肖特基金屬層替代之, 其材料可例如為鋁或鉬;而金屬層38的功能則是作為接觸電極。然而,此僅為本創作關於肖特基能障之例示,若使用適當之材料(例如鋁),金屬層38可同時作為電極並形成肖特基能障。此時在主動區中不須金屬矽化物層或肖特基金屬層,金屬層38可直接形成於導電材料未接觸第一絕緣層之表面、第一絕緣層未接觸導電材料之表面、及半導體層未形成溝槽或連結溝槽之表面。 In the structures disclosed in FIGS. 3(a) to (c), FIG. 6(q) and the preceding paragraph, the metal telluride layer is used to form a Schottky barrier, and a Schottky metal layer may be used instead. The material may be, for example, aluminum or molybdenum; and the metal layer 38 functions as a contact electrode. However, this is merely an illustration of the Schottky barrier of this creation. If a suitable material, such as aluminum, is used, the metal layer 38 can serve as both an electrode and a Schottky barrier. At this time, the metal germanide layer or the Schottky metal layer is not required in the active region, and the metal layer 38 can be directly formed on the surface of the conductive material not contacting the first insulating layer, the surface of the first insulating layer not contacting the conductive material, and the semiconductor The layer does not form a trench or a surface that joins the trench.

此外,在圖3(a)~(c)所示之本創作的具體例中,主動區中鄰接終端區之最內側溝槽為溝槽34a,亦即主動區內各溝槽之導電材料37藉由金屬層38與終端區之溝槽34a內的導電材料37電連接,又溝槽34a藉由連結溝槽351、352與溝槽34b、34c電連接,使得溝槽34a內導電材料之電位連帶溝槽34b、34c內導電材料之電位均相同。相對地,在圖3(a)~(c)所示的終端區結構中,溝槽34a、34b、34c以外的溝槽互不導通,其內之導電材料37則仍具有浮動之電位。 In addition, in the specific example of the present invention shown in FIGS. 3(a) to (c), the innermost trench adjacent to the termination region in the active region is the trench 34a, that is, the conductive material 37 of each trench in the active region. The metal layer 38 is electrically connected to the conductive material 37 in the trench 34a of the termination region, and the trench 34a is electrically connected to the trenches 34b, 34c by the connection trenches 351, 352, so that the potential of the conductive material in the trench 34a The potentials of the conductive materials in the associated trenches 34b, 34c are the same. In contrast, in the terminal region structure shown in FIGS. 3(a) to (c), the trenches other than the trenches 34a, 34b, and 34c are not electrically connected to each other, and the conductive material 37 therein still has a floating potential.

本創作提出之肖特基二極體結構,可藉由連結溝槽的設置而改變元件中之電場分布,具有改善電性之效果。圖4(a)、(b)揭示習知肖特基二極體與本創作之肖特基二極體的電場分布,可看出二者之差異。圖4(a)對應於習知之肖特基二極體結構,圖4(b)則是基於本創作主旨將終端區鄰近主動區的三個溝槽導通之結構。由圖4(a)與圖4(b)的對照可看出,習知結構的電場分布較為集中,而採用本創作提出之結構則可將電場分布向外延伸,使電場不至於過度集中於主動區。由於電場強度越集中,越容易產生電壓崩潰或擊穿之結果,因此本創作提出之結構可具有較高的耐壓性,亦即反向偏壓時具有較高的崩潰 電壓。根據上述說明,圖5是本創作提出之肖特基二極體與習知肖特基二極體的電壓-電流曲線模擬比較。其中可看出,本創作之肖特基二極體確實具有顯著提高的崩潰電壓。本創作之主旨在於使傳統溝槽式半導體裝置中一部分或數部分的溝槽導通,藉此分散主動區的電場強度;而此特徵並不限於上述之溝槽式肖特基二極體,亦可適用於其他具有類似原理與結構之半導體裝置,例如二極體或電晶體等。 The Schottky diode structure proposed in the present invention can change the electric field distribution in the element by the arrangement of the connection grooves, and has the effect of improving electrical properties. 4(a) and 4(b) show the electric field distribution of the conventional Schottky diode and the Schottky diode of the present invention, and the difference between the two can be seen. 4(a) corresponds to the conventional Schottky diode structure, and FIG. 4(b) is a structure in which the three trenches of the terminal region adjacent to the active region are turned on based on the main purpose of the present invention. It can be seen from the comparison between Fig. 4(a) and Fig. 4(b) that the electric field distribution of the conventional structure is concentrated, and the structure proposed by the present invention can extend the electric field distribution so that the electric field is not excessively concentrated. Active area. Since the electric field intensity is more concentrated, the voltage breakdown or breakdown is more likely to occur, so the structure proposed by the present invention can have higher withstand voltage, that is, a high breakdown when reverse bias is applied. Voltage. Based on the above description, FIG. 5 is a voltage-current curve simulation comparison between the Schottky diode of the present invention and the conventional Schottky diode. It can be seen that the Schottky diode of this creation does have a significantly increased breakdown voltage. The main purpose of the present invention is to turn on a part or a plurality of trenches in a conventional trench type semiconductor device, thereby dispersing the electric field intensity of the active region; and the feature is not limited to the above-described trench Schottky diode. It can be applied to other semiconductor devices having similar principles and structures, such as diodes or transistors.

本創作之另一具體例為肖特基二極體的製造方法,其中各步驟形成之結構如圖6(a)~(z)所示,以下依序加以說明。其中,圖6(a)~(z)均為橫截面圖,該橫截面與圖3(a)(圖2(b)沿線段A-A’)之位置相同,故並未如圖3(b)或(c)可呈現出連結溝槽351、352之橫截面結構。然而,本領域具有通常知識者當可藉由對照圖2(a)~(d)揭示之溝槽結構俯視圖,充分瞭解並實施以下所述之內容。 Another specific example of the present invention is a method for producing a Schottky diode. The structure formed in each step is as shown in Figs. 6(a) to (z), and will be described below in order. 6(a) to (z) are cross-sectional views, which are the same as those of FIG. 3(a) (Fig. 2(b) along line A-A'), so it is not as shown in Fig. 3 ( b) or (c) may exhibit a cross-sectional structure of the joint grooves 351, 352. However, those skilled in the art will fully understand and implement the following description by referring to the top view of the trench structure disclosed in FIGS. 2(a) to (d).

如圖6(a)所示,首先在較高摻雜之矽基板(圖中未繪出)上形成較低摻雜濃度之磊晶層61,其材質可例如為N型之單晶矽,且其厚度需可供後續步驟形成溝槽結構,例如約為1~60微米(μm)。 As shown in FIG. 6(a), a lower doping concentration epitaxial layer 61 is first formed on a highly doped germanium substrate (not shown), and the material thereof may be, for example, an N-type single crystal germanium. And the thickness needs to be able to form a trench structure in a subsequent step, for example, about 1 to 60 micrometers (μm).

如圖6(b)所示,於磊晶層61之上形成硬罩(hard mask)層62,硬罩層62之材料可例如是二氧化矽(SiO2),其製作方式可採用例如熱氧化(thermal oxidation)或化學氣相沉積(Chemical vapor deposition)。硬罩層62之主要功能是在後續蝕刻溝槽時遮蔽非溝槽之區域,故其厚度取決於溝槽所需蝕刻深度,以及蝕刻過程中對磊晶層61與硬罩層62二種不同材料之蝕刻速率比。 As shown in FIG. 6(b), a hard mask layer 62 is formed on the epitaxial layer 61. The material of the hard mask layer 62 may be, for example, hafnium oxide (SiO 2 ). Thermal oxidation or chemical vapor deposition. The main function of the hard mask layer 62 is to shield the non-trench regions when subsequently etching the trenches, so the thickness depends on the etching depth required for the trenches, and the epitaxial layer 61 and the hard mask layer 62 are different in the etching process. The etch rate ratio of the material.

為使硬罩層62形成所需之圖案,圖6(c)~(f)為使用光微 影(photo lithography)及乾式蝕刻(dry etch)之流程,惟可採用之製程並不以此為限。首先在硬罩層62上塗布光阻(photo resist)層631〔圖6(c)〕;其次藉由曝光、顯影等步驟移除部分之光阻層631而形成所需之圖案〔圖6(d)〕;接著進行蝕刻,例如可採用乾式蝕刻,依據光阻層631之圖案在硬罩層62上形成實質相同之圖案〔圖6(e)〕;移除剩餘之光阻層631之後,即可得到圖6(f)所示圖案化之後的硬罩層62。參照前述之說明,本創作提出之肖特基二極體結構具有複數連結溝槽,故在形成圖6(d)結構的曝光步驟中,所使用之光罩圖案在終端區溝槽部分可如圖2(a)~(d)所示。以使用正光阻為例,圖2(a)~(d)中的溝槽結構即為光罩中的透光部分。 In order to form the hard mask layer 62 into a desired pattern, Figures 6(c) to (f) are used to light micro- The process of photo lithography and dry etch is not limited to the process. First, a photo resist layer 631 is applied on the hard mask layer 62 (FIG. 6(c)); secondly, a portion of the photoresist layer 631 is removed by exposure, development, etc. to form a desired pattern (FIG. 6 (FIG. 6) d)]; then etching is performed, for example, dry etching may be employed, and substantially the same pattern is formed on the hard mask layer 62 according to the pattern of the photoresist layer 631 [FIG. 6(e)]; after the remaining photoresist layer 631 is removed, The hard mask layer 62 after patterning as shown in Fig. 6(f) can be obtained. Referring to the foregoing description, the Schottky diode structure proposed in the present invention has a plurality of joint trenches, so that in the exposure step of forming the structure of FIG. 6(d), the mask pattern used in the trench portion of the termination region can be as Figure 2 (a) ~ (d). Taking the positive photoresist as an example, the groove structure in FIGS. 2(a) to (d) is the light transmitting portion in the reticle.

硬罩層62之圖案係用於在磊晶層61形成溝槽結構,如圖6(g)所示。此處使用之蝕刻製程可使用例如非等向性較佳的乾式蝕刻,在未受硬罩層62覆蓋之磊晶層61表面上形成溝槽後,再將剩餘之硬罩層62移除,即可得到如圖6(h)所示之具有溝槽結構的磊晶層61。溝槽結構的深度一般可例如約0.5~30微米。 The pattern of the hard mask layer 62 is used to form a trench structure in the epitaxial layer 61 as shown in FIG. 6(g). The etching process used herein may use, for example, a dry etching which is preferably anisotropic, and after forming a trench on the surface of the epitaxial layer 61 not covered by the hard mask layer 62, the remaining hard mask layer 62 is removed. An epitaxial layer 61 having a trench structure as shown in Fig. 6(h) is obtained. The depth of the trench structure can generally be, for example, about 0.5 to 30 microns.

磊晶層61在形成溝槽後,可藉由例如但不限於熱氧化或化學氣相沉積等方式,於其上形成第一絕緣層641。如圖6(i)所示,第一絕緣層641完整地覆蓋磊晶層61各溝槽的表面以及未形成溝槽之原始表面,其厚度可例如約0.08~1微米,通常溝槽深度越深則第一絕緣層641的厚度越大。與先前技術不同的是,此步驟形成之第一絕緣層641相當於同時形成圖1(a)中的閘極氧化層43及第一罩幕層A1。 After the epitaxial layer 61 is formed, the first insulating layer 641 can be formed thereon by, for example, but not limited to, thermal oxidation or chemical vapor deposition. As shown in FIG. 6(i), the first insulating layer 641 completely covers the surface of each trench of the epitaxial layer 61 and the original surface where the trench is not formed, and the thickness thereof may be, for example, about 0.08 to 1 micrometer, and generally the trench depth is The thickness of the first insulating layer 641 is deeper. Different from the prior art, the first insulating layer 641 formed in this step is equivalent to simultaneously forming the gate oxide layer 43 and the first mask layer A1 in FIG. 1(a).

形成第一絕緣層641後,接著在上述溝槽中形成多晶 矽;此處可使用之材料並不以多晶矽為限,亦可使用鎢或其他導電材料。圖6(j)為使用化學氣相沉積方式在第一絕緣層641上形成多晶矽65,藉由化學氣相沉積的特性,多晶矽65可填滿溝槽並在基板整體上方形成一定厚度之膜層,此上方膜層之厚度通常取決於溝槽之寬度,溝槽越寬時需要的多晶矽65之上方膜層越厚。其次,利用乾式蝕刻對基板上方之多晶矽65進行反蝕刻(etch back),除去上方之多晶矽膜層而使第一絕緣層641之上緣表面(亦即不在溝槽內表面之部分)露出,如圖6(k)所示。多晶矽65在溝槽中的填充程度取決於不同之製程與結構設計,圖6(k)中相當於多晶矽填滿第一絕緣層所包圍之空間。如前所述,由於本創作係以連結溝槽使終端區內的相鄰二溝槽導通。若溝槽較寬或較淺時,反蝕刻步驟可能將中央部分的多晶矽完全移除,而導致溝槽底部之第一絕緣層露出;此時,同一溝槽內的多晶矽本身即已非完全導通,形成連結溝槽亦無法使相鄰之二溝槽完全導通。因此,依據本創作之主旨,此處的反蝕刻步驟須保留多晶矽至少填滿溝槽底部,亦即完全覆蓋溝槽底部之第一絕緣層。 After the first insulating layer 641 is formed, then polycrystalline is formed in the trench 矽; The materials that can be used here are not limited to polysilicon, and tungsten or other conductive materials can also be used. 6(j) is a polycrystalline germanium 65 formed on the first insulating layer 641 by chemical vapor deposition. By virtue of the characteristics of chemical vapor deposition, the polysilicon 65 can fill the trench and form a film of a certain thickness over the entire substrate. The thickness of the upper film layer generally depends on the width of the trench, and the wider the trench, the thicker the film layer above the desired polysilicon 65. Next, the polysilicon 65 over the substrate is etched back by dry etching, and the upper polysilicon film layer is removed to expose the upper edge surface of the first insulating layer 641 (ie, not part of the inner surface of the trench), such as Figure 6 (k). The degree of filling of the polysilicon 65 in the trench depends on the different process and structure design. In Fig. 6(k), the polycrystalline germanium fills the space surrounded by the first insulating layer. As described above, since the present invention connects the adjacent trenches in the termination region by the connection trenches. If the trench is wider or shallower, the reverse etching step may completely remove the polysilicon in the central portion, and the first insulating layer at the bottom of the trench is exposed; at this time, the polysilicon in the same trench itself is not fully turned on. The formation of the joint groove also prevents the adjacent two grooves from being completely turned on. Therefore, in accordance with the teachings of the present invention, the reverse etching step herein must retain the polysilicon at least filling the bottom of the trench, that is, completely covering the first insulating layer at the bottom of the trench.

經過前述步驟處理後,繼續在基板上形成一第二絕緣層642,例如可使用化學氣相沉積方式形成二氧化矽層,如圖6(1)所示。 After the foregoing steps, a second insulating layer 642 is formed on the substrate. For example, a ceria layer can be formed by chemical vapor deposition, as shown in FIG. 6(1).

圖6(m)~(p)為移除部分第一絕緣層641及第二絕緣層之642步驟,用於形成主動區之開口。首先在第二絕緣層642上塗佈光阻層632〔圖6(m)〕,並經曝光及顯影等步驟後移除開口區域之光阻層632〔圖6(n)〕;其次藉由未移除之光阻層632作為遮罩,以蝕刻方式移除開口部分之第一絕緣層641與第二絕緣層642〔圖6(o)〕。其中,可採 用例如乾式蝕刻或其他蝕刻方式。此外,圖6(o)亦揭示第一絕緣層641於溝槽內之部分並未被移除,故在主動區之溝槽內的第一絕緣層641即具有閘極氧化層之功能。移除剩餘之光阻層632後,截面之結構如圖6(p)所示。 6(m) to (p) are steps of removing a portion of the first insulating layer 641 and the second insulating layer 642 for forming an opening of the active region. First, a photoresist layer 632 is applied on the second insulating layer 642 (Fig. 6(m)), and the photoresist layer 632 in the open region is removed after exposure and development, etc. (Fig. 6(n)); secondly by The photoresist layer 632 which is not removed serves as a mask, and the first insulating layer 641 and the second insulating layer 642 of the opening portion are removed by etching (FIG. 6(o)). Among them, For example, dry etching or other etching methods are used. In addition, FIG. 6(o) also discloses that the portion of the first insulating layer 641 in the trench is not removed, so that the first insulating layer 641 in the trench of the active region has the function of a gate oxide layer. After removing the remaining photoresist layer 632, the structure of the cross section is as shown in Fig. 6(p).

完成圖6(p)之結構後,下一步是在元件主動區中形成一金屬矽化物(silicide)層66,如圖6(q)所示。首先在主動區形成一金屬層,例如可使用蒸鍍(evaporation)或濺鍍(sputtering)方式形成鎳或鈦膜,再經由熱退火(thermal annealing)過程使金屬與磊晶層61表面(未形成溝槽部分)及溝槽中的多晶矽65上緣表面反應,而在接面處形成金屬矽化物層66,金屬矽化物層66與磊晶層61之接面即形成肖特基能障(Schottky barrier)。然而在實際製程中,金屬矽化物層亦可能形成於第一絕緣層641未與多晶矽65或磊晶層61接觸之表面上。如前所述,金屬矽化物層66亦可使用一肖特基金屬層取代之,例如可形成一鋁膜或鉬膜使其至少覆蓋主動區。此外,也有可能省略此步驟,直接以後續步驟中金屬層67與磊晶層61之接面形成肖特基能障。 After completing the structure of Fig. 6(p), the next step is to form a metal silicide layer 66 in the active region of the element, as shown in Fig. 6(q). First, a metal layer is formed in the active region. For example, a nickel or titanium film can be formed by evaporation or sputtering, and the metal and the surface of the epitaxial layer 61 are formed through a thermal annealing process. The trench portion) reacts with the upper surface of the polysilicon 65 in the trench, and a metal telluride layer 66 is formed at the junction, and the junction of the metal telluride layer 66 and the epitaxial layer 61 forms a Schottky barrier (Schottky Barrier). However, in an actual process, a metal telluride layer may also be formed on the surface of the first insulating layer 641 not in contact with the polysilicon 65 or the epitaxial layer 61. As previously mentioned, the metal telluride layer 66 can also be replaced with a Schottky metal layer, for example, an aluminum film or a molybdenum film can be formed to cover at least the active region. In addition, it is also possible to omit this step and directly form a Schottky barrier in the subsequent step in the junction of the metal layer 67 and the epitaxial layer 61.

圖6(r)~(v)為形成金屬電極結構之步驟。首先在整個元件表面沉積一金屬層67〔圖6(r)〕,接著塗佈光阻層633〔圖6(s)〕,其次以曝光及顯影等方式移除光阻層633之外圍部分,使未移除之光阻層633覆蓋主動區及終端區〔圖6(t)〕,接著在光阻的遮蔽下對金屬層67進行蝕刻,亦即移除元件區域以外之金屬層67〔圖6(u)〕,最後移除剩餘之光阻層633〔圖6(v)〕。金屬層67如使用適當材料製作(例如鋁),可同時作為電極並形成肖特基能障,故可省略前述之金屬矽化層 或肖特基金屬層。 6(r) to (v) are steps of forming a metal electrode structure. First, a metal layer 67 is deposited on the surface of the entire device (Fig. 6(r)), followed by coating the photoresist layer 633 (Fig. 6(s)), and then removing the peripheral portion of the photoresist layer 633 by exposure and development, etc. The unremoved photoresist layer 633 covers the active region and the termination region (Fig. 6(t)), and then the metal layer 67 is etched under the shielding of the photoresist, that is, the metal layer 67 outside the component region is removed. 6(u)], finally removing the remaining photoresist layer 633 [Fig. 6(v)]. The metal layer 67 can be formed as an electrode and a Schottky barrier can be formed by using a suitable material (for example, aluminum), so that the aforementioned metal germanide layer can be omitted. Or Schottky metal layer.

最後,圖6(w)~(z)所示為形成保護層結構之步驟。首先在整個元件表面沉積一保護層68〔圖6(w)〕,可使用例如二氧化矽或氮化矽作為材料;接著塗佈光阻層634,並以曝光及顯影等方式在主動區上方形成開口〔圖6(x)〕;然後對保護層68進行蝕刻,移除主動區上方未被光阻覆蓋之保護層68使電極露出作為歐姆接觸之用〔圖6(y)〕;最後移除剩餘之光阻層634〔圖6(z)〕。至此,即完成本創作之一具體例的半導體裝置之基本結構。 Finally, Figures 6(w)~(z) show the steps of forming a protective layer structure. First, a protective layer 68 (Fig. 6(w)) is deposited on the surface of the entire device, and for example, ceria or tantalum nitride can be used as a material; then the photoresist layer 634 is coated and exposed to the active region by exposure and development, etc. An opening is formed (Fig. 6(x)); then the protective layer 68 is etched to remove the protective layer 68 over the active region that is not covered by the photoresist to expose the electrode as an ohmic contact (Fig. 6(y)); Except for the remaining photoresist layer 634 (Fig. 6(z)). Thus far, the basic structure of the semiconductor device of one specific example of the present creation is completed.

以上所述之各具體例,僅為本創作實施方式之例示,並非窮盡列舉所有可能之變化。申請人主張之權利範圍如後述申請專利範圍所載,其中各請求項之文義及均等範圍均為本專利之權利範圍所涵蓋,前述發明說明或圖式之內容自不得作為解釋申請專利範圍之限制。 The specific examples described above are merely illustrative of the embodiments of the present invention and are not exhaustive of all possible variations. The scope of the claims of the applicant is set forth in the scope of the patent application, and the scope of the claims and the scope of the claims are covered by the scope of the patent, and the contents of the foregoing inventions or drawings are not to be construed as limiting the scope of the patent application. .

211,213,214,215,216‧‧‧連結溝槽 211,213,214,215,216‧‧‧Link trench

Claims (13)

一種半導體裝置之終端區結構,包含:一半導體層;複數溝槽,形成於該半導體層之表面;一第一連結溝槽,形成於該半導體層之表面,用於連接該複數溝槽中相鄰之一第一溝槽及一第二溝槽;一第一絕緣層,形成於該複數溝槽之表面、該連結溝槽之表面、及該半導體層未形成該複數溝槽或該連結溝槽之表面;導電材料,形成於表面具有該第一絕緣層之該複數溝槽及該第一連結溝槽內,且該第一溝槽及該第二溝槽內之該導電材料藉由該第一連結溝槽內之該導電材料而導通;一第二絕緣層,至少覆蓋部分該第一絕緣層未接觸該導電材料之表面及部分該導電材料未接觸該第一絕緣層之表面;及一金屬層,至少覆蓋該第二絕緣層之部分表面。 A termination region structure of a semiconductor device, comprising: a semiconductor layer; a plurality of trenches formed on a surface of the semiconductor layer; a first connection trench formed on a surface of the semiconductor layer for connecting the phase of the plurality of trenches a first trench and a second trench; a first insulating layer formed on a surface of the plurality of trenches, a surface of the bonding trench, and the semiconductor layer not forming the plurality of trenches or the connecting trench a surface of the trench; the conductive material is formed on the surface of the plurality of trenches having the first insulating layer and the first interconnecting trench, and the conductive material in the first trench and the second trench is formed by the conductive material The conductive material in the first connection trench is turned on; a second insulating layer covers at least a portion of the surface of the first insulating layer not contacting the conductive material and a portion of the conductive material not contacting the surface of the first insulating layer; A metal layer covering at least a portion of the surface of the second insulating layer. 如申請專利範圍第1項所述之半導體裝置之終端區結構,於該第一溝槽中,該第二絕緣層覆蓋部分該導電材料未與該第一絕緣層接觸之表面,且該金屬層覆蓋其他部分該導電材料未與該第一絕緣層接觸之表面。 The terminal region structure of the semiconductor device according to claim 1, wherein the second insulating layer covers a surface of the first insulating layer that is not in contact with the first insulating layer, and the metal layer Covering other portions of the surface of the conductive material that are not in contact with the first insulating layer. 如申請專利範圍第2項所述之半導體裝置之終端區結構,其中該金屬層所覆蓋之該其他部分該導電材料之表面更形成有一金屬矽化物層或一肖特基金屬層。 The terminal region structure of the semiconductor device according to claim 2, wherein the other portion of the conductive material covered by the metal layer is further formed with a metal telluride layer or a Schottky metal layer. 如申請專利範圍第1項所述之半導體裝置之終端區結構,其中該第一連結溝槽與該第一溝槽及該第二溝槽垂直,或與該第一溝槽之切線及該第二 溝槽之切線垂直。 The termination structure of the semiconductor device of claim 1, wherein the first connection trench is perpendicular to the first trench and the second trench, or a tangent to the first trench and the first two The tangent of the groove is vertical. 如申請專利範圍第1項所述之半導體裝置之終端區結構,更包含一第二連結溝槽,用於連接該複數溝槽中之該第二溝槽及一第三溝槽,該第三溝槽鄰次於該第二溝槽。 The termination structure of the semiconductor device of claim 1, further comprising a second connection trench for connecting the second trench and the third trench in the plurality of trenches, the third The trench is adjacent to the second trench. 如申請專利範圍第5項所述之半導體裝置之終端區結構,其中該第二連結溝槽與該第一連結溝槽不共線。 The termination structure of the semiconductor device of claim 5, wherein the second connection trench is not collinear with the first connection trench. 如申請專利範圍第1項所述之半導體裝置之終端區結構,更包含一第二連結溝槽,用於連接該複數溝槽中相鄰之一第三溝槽及一第四溝槽。 The termination structure of the semiconductor device of claim 1, further comprising a second connection trench for connecting adjacent one of the third trench and the fourth trench. 如申請專利範圍第1項所述之半導體裝置之終端區結構,其中該半導體裝置為一肖特基二極體、一金屬氧化物半導體場效電晶體、一雙極接面電晶體、或一絕緣閘雙極電晶體。 The terminal region structure of the semiconductor device according to claim 1, wherein the semiconductor device is a Schottky diode, a metal oxide semiconductor field effect transistor, a bipolar junction transistor, or a Insulated gate bipolar transistor. 一種半導體裝置,具有一主動區及一終端區,包含:一半導體層;複數溝槽,形成於該半導體層之表面;一連結溝槽,形成於該半導體層之表面且位於該終端區,用於連接該複數溝槽中相鄰之一第一溝槽及一第二溝槽;一第一絕緣層,形成於該主動區中該複數溝槽及該連結溝槽之部分表面,且其上緣低於該半導體層未形成該複數溝槽或該連結溝槽之表面,該第一絕緣層並形成於該終端區中該複數溝槽之表面、該連結溝槽之表面、及該半導體層未形成該複數溝槽或該連結溝槽之表面;導電材料,形成於表面具有該第一絕緣層之該複數溝槽及該連結溝槽內,且完全覆蓋該複數溝槽底部及該連結溝槽底部之第一絕緣層; 一第二絕緣層,於該終端區中至少覆蓋部分該第一絕緣層未接觸該導電材料之表面及部分該導電材料未接觸該第一絕緣層之表面;及一金屬層,至少覆蓋該主動區與該第二絕緣層之部分表面。 A semiconductor device having an active region and a termination region, comprising: a semiconductor layer; a plurality of trenches formed on a surface of the semiconductor layer; a bonding trench formed on a surface of the semiconductor layer and located in the termination region, And connecting a first trench and a second trench adjacent to the plurality of trenches; a first insulating layer is formed on the surface of the plurality of trenches and the connecting trench in the active region, and The surface of the plurality of trenches or the connecting trench is not formed on the semiconductor layer, and the first insulating layer is formed on the surface of the plurality of trenches, the surface of the connecting trench, and the semiconductor layer in the termination region The surface of the plurality of trenches or the connecting trench is not formed; a conductive material is formed on the surface of the plurality of trenches having the first insulating layer and the connecting trench, and completely covers the bottom of the plurality of trenches and the connecting trench a first insulating layer at the bottom of the groove; a second insulating layer covering at least a portion of the surface of the first insulating layer not contacting the conductive material and a portion of the conductive material not contacting the surface of the first insulating layer; and a metal layer covering at least the active a portion of the surface of the second insulating layer. 一種肖特基二極體,具有一主動區及一終端區,包含:一半導體層;複數溝槽,形成於該半導體層之表面;一連結溝槽,形成於該半導體層之表面且位於該終端區,用於連接該複數溝槽中相鄰之一第一溝槽及一第二溝槽;一第一絕緣層,形成於該複數溝槽之至少部分表面、該連結溝槽之至少部分表面、及該終端區中該半導體層未形成該複數溝槽或該連結溝槽之表面;導電材料,形成於表面具有該第一絕緣層之該複數溝槽及該連結溝槽內,且該第一溝槽及該第二溝槽內之該導電材料藉由該連結溝槽內之該導電材料而導通;一第二絕緣層,於該終端區中至少覆蓋部分該第一絕緣層未接觸該導電材料之表面及部分該導電材料未接觸該第一絕緣層之表面;及一金屬層,至少覆蓋該主動區與該第二絕緣層之部分表面。 A Schottky diode having an active region and a termination region, comprising: a semiconductor layer; a plurality of trenches formed on a surface of the semiconductor layer; a bonding trench formed on a surface of the semiconductor layer and located at the surface a terminal region for connecting one of the first trenches and a second trench adjacent to the plurality of trenches; a first insulating layer formed on at least a portion of the surface of the plurality of trenches, at least a portion of the bonding trenches The surface of the semiconductor layer does not form the surface of the plurality of trenches or the connecting trench; the conductive material is formed on the surface of the plurality of trenches having the first insulating layer and the connecting trench, and the The conductive material in the first trench and the second trench is electrically connected by the conductive material in the connecting trench; a second insulating layer covering at least a portion of the first insulating layer in the termination region is not in contact The surface of the conductive material and a portion of the conductive material are not in contact with the surface of the first insulating layer; and a metal layer covering at least a portion of the surface of the active region and the second insulating layer. 如申請專利範圍第10項所述之肖特基二極體,於該第一溝槽中,該第二絕緣層覆蓋部分該導電材料未與該第一絕緣層接觸之表面,且該金屬層覆蓋其他部分該導電材料未與該第一絕緣層接觸之表面。 The Schottky diode according to claim 10, wherein in the first trench, the second insulating layer covers a surface of the conductive material not in contact with the first insulating layer, and the metal layer Covering other portions of the surface of the conductive material that are not in contact with the first insulating layer. 如申請專利範圍第10項所述之肖特基二極體,其中該導電材料為多晶矽或鎢。 The Schottky diode according to claim 10, wherein the conductive material is polycrystalline germanium or tungsten. 如申請專利範圍第10項所述之肖特基二極體,更包含一金屬矽化物層或一肖特基金屬層,至少形成於該主動區中該半導體層及該導電材料未接觸該第一絕緣層之表面。 The Schottky diode according to claim 10, further comprising a metal telluride layer or a Schottky metal layer, at least formed in the active region, the semiconductor layer and the conductive material not contacting the first The surface of an insulating layer.
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